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By A. K. Debnath

The water resource is key to survival of the mankind and this resource is now becoming critical in many parts of globe including India. As per an assessment of Central Ground Water Board (CGWB) of India, a huge shortfall of about 58 billion m3 of water is anticipated by the year 2050. In order to counter this shortfall, there is thrust from Government of India to adopt water conservation measures. National Environment Policy, 2006 of Government of India also stresses upon the need to take up water conservation measures for water security of the country. The coal mines in India provide an excellent opportunity to take up water conservations measures therein. The mine water is not acidic unlike western countries and it conforms to the prescribed regulatory standards. This nature?s gift is utilized in Coal India Limited by allowing mine voids to get filled with mine water. The net recharge potential of the opencast mining area is found to be about 5% in comparison to 2% in non-mining area offering good prospects for ground water recharge. The seasonal rainwater is also diverted into mine voids left at the end of mining operations which act as huge reservoirs/ pit lakes for storage of the water. They also serve as surface water bodies for recharging of water table in the surrounding areas. The area and space left from where coal has been extracted completely in underground mines and will not be entered by any man or machinery after the extraction, called goaf, are also potential source of water conservation. These additional water resources created are being utilized for meeting the industrial, domestic, irrigation and other requirements of the projects and local communities eliminating the need to tap other fresh water resources including ground water. Presently, 75% of the water demand of the coal mining project is being met from the water stored in the mine pits. In future, CIL is likely to create about 3.3 billion m3 of water resource, on an average, in its opencast mines alone. In the mine closure plan of opencast mines, the last cut is proposed to be developed into water body for recharge of ground water and creating additional water resources. A clean potential source of potable water is thus developed after mine closure. This will ensure water security of the country.

Aug 1, 2013

By N. Melnyk

"FOREWORDThis paper provides a unique description of a method devised for mining a very thick steeply dipping seam of soft gassy coal which was prone to spontaneous combustion. The editors con¬sider that the information in this paper should be important to those who may have to consider mining such seams again at some time in the future and therefore believe that the paper warrants reprinting in the present volume. The author was ask¬ed to review the paper and to add any additional relevant in¬formation. He provided the accompanying footnote, only a month before his death on April 22, 1982.IntroductionIn the past, the Cadomin Coal Company has opened four mines, all in the same coal seam or its folds. Three of these were opened from river level by horizontal entries or rock tunnels. and the fourth, the present working mine, by vertical shafts. This paper deals largely with some operating phases of this fourth mine, with which the writer has been associated.The seam worked here is a thick, steep, bituminous seam, and the writer feels there is a paucity of published data on the mining of such seams. Possible reasons for this are that such seams do not lend themselves to intensive development or mining, there is little chance to mechanize because of the extreme pitch, and operations are fraught with many problems. In addition the present operations in this particular' seam are being carried on at a level below the former workings, introducing new problems, not encountered on the upper level.Coal will, without question, long continue to be an impor¬tant factor in the national economy, and some of the best coal is to be found in thick, steep seams. But with the exhaustion of the easily-mined coal near the outcrops, future coal will have to come more and more from lower levels. At Cadomin there is still considerable coal on the second level, below the old river-workings, and there is a possibility that, in the future, still lower levels will be worked. It is the purpose of this paper to indicate some phases of such lower-level operations and to invite discussion."

Jan 1, 1985

By M. Bigdeli Karimi

In this study, the effect of strain level and holding time in semisolid temperature range via SIMA process on AS21 Mg alloy was investigated. Some cylindrical samples of this alloy with 1cm in height and 2.5cm in diameter (H/D=0.4) were compressed to 10%, 20%, 30% and 40% at 300-C. Then, the samples were reheated in semisolid temperature range at 614°C for various times. The results of optical microscopy and image analysis showed that with increasing of strain and holding time, dendritic structure changed to equi-axed structure, gradually. Also, the best conditions to obtain good globular structure were achieved. Furthermore, it was seen that after compression and reheating, Mg2Si intermetallics with Chinese script morphology converted to dispersed-fine particles which were distributed into the ci-Mg grains.

Jan 1, 2007

By W. B. Xie

The hardening behaviour and microstructure evolution of Cu-30Ni-30Mn alloys aged at 350 °C has been investigated utilizing optical microscope, scanning electron microscope, transmission electron microscopy and Vickers hardness tester. The results show that the discontinuous precipitation of NiMn phase results in a remarkably hardening effect in Cu-30Ni-30Mn alloy during aging at 350 °C. The maximum hardness (~494HV) is attained in the sample after aged for 48 h. The NiMn precipitates are ordered and have a face-centered tetragonal structure. The coherent orientation relationship between the NiMn precipitates and Cu matrix is (220)Matrix // (220)P, [1-1-2]Matrix // [1-1-2]P. In addition, there is a linear relationship between hardness and volume fraction of the discontinuous precipitation, which indicates that the hardness increment of Cu-Ni-Mn alloys aged at 350 °C is attributed to the microstructure characteristics of discontinuous precipitation. The high strength of discontinuous precipitation colony is caused by the formation of nanoscale NiMn precipitates with a lamellar structure in discontinuous precipitation. INTRODUCTION Cu-Ni-Mn alloys are attractive candidates for oil drilling, aerospace and energy applications due to their high elasticity, high strength and excellent corrosion resistance (Sun et al., 2009; Liu, Yang, Xia, Jiang, & Gui, 2016). The high strength of the Cu-Ni-Mn alloys is mainly attributed to the precipitation of NiMn phase (Shapiro, Tyler, & Lanam, 1974; Xie et al., 2015). The uniformly dispersed nanoprecipitates formed by continuous precipitation can impede dislocation movement, and thereby lead to a significant improvement in strength of traditional precipitation-strengthened alloys. However, it is reported that there are two precipitation types observed in Cu-Ni-Mn alloys, namely, continuous precipitation and discontinuous precipitation (Shapiro et al., 1974). The discontinuous cellular colony with a lamellar structure nucleates at grain boundaries, and progressively grows inward the grain on the process of discontinuous precipitation (Ng, Bettles, & Muddle, 2011). It is found that the discontinuous precipitation can occur in many Cu-based alloys, such as Cu-Ni- Mn alloy (Shapiro et al., 1974), Cu-Be alloy (Monzen, Hasegawa, & Watanabe, 2010) and Cu-Ni-Sn alloy (Zhao, & Notis, 1998). Many studies consider that the discontinuous precipitation results in a detrimental effect on hardness and strength, and the discontinuous precipitation occurring during aging treatment should be suppressed (Markandeya, Nagarjuna, & Sarma, 2004; Semboshi, Sato, Iwase, & Takasugi, 2016). The mechanical properties can also be improved by discontinuous precipitation in AZ91 magnesium alloy (Tamura, Kida, Suzuki, & Soda, 2009) and AM30 magnesium alloy (Saikawa et al., 2012). Jun (2017) found that the reduced interlamellar spacing of precipitate fibers in discontinuous cellular colony leads to a significant increase in hardness. Indeed, the strengthening contribution of discontinuous precipitation is similar to that of continuous precipitation in Cu-20Ni-20Mn alloy. Discontinuous precipitation of NiMn phase can provide a significant strengthening effect in Cu-Ni-Mn alloys.

Jan 1, 2019

By W. Zieman

"The low consumption of reagents can probably be attributed to a good clean type of ore. The cyanide level is kept at 0. 8 lb/ ton of solution and the lime at 1. 8 to 1.9 lb per ton of solution (pH 12. 2 to 12 .3). Experience in cutting down the lime level in half produced troubles in the presses, in the refinery and resulted in higher cyanide consumption. Finally the residue increased under these conditions, High lime always seems to prevent the trouble from occurring.A survey at one mine of the taxable work, performed in the mine shops for use in the mine, showed that under the new regulations, this had increased some 30 times what it was before the new rules came into effect on June 14, 1963.A water softener idea is incorporated at Lamaque with the crude addition of 100 lb of lime per shift to a spare agitator to precipitate the bicarbonates as carbonates from the water before it enters the mill. The lime titration of the softened water is about 0,2 to 0.3 lb per ton of solution (pH 11). This water is used mainly on the filters as washes."

Jan 1, 1964

By A. McLean, Q. R. Yang, Y. D. Yang, G. F. Zhang, P. Wu

A considerable amount of waste slag from the pyrite roasting process is discharged every year. Recovery of iron from the waste slag is of great interest for comprehensive use of mineral resource, reduction of environment impact and improvement of economical benefit to related companies. The objectives of the present work are focused on: (1) Compare various procedures for recovery of iron from the waste slag and select a best procedure for industrial trial which is roasting of the waste slag under reducing condition followed by magnetic separation; (2) Investigate the optimum conditions for maximum recovery of iron from the waste slag. The experimental result shows that under the treatment condition found in this work about 36 to 40% of the iron oxide was recovered from the waste slag, where the iron content in the concentrate is 57%. The total recovery ratio of iron, up to 70%, from the waste slag was achieved. After the treatment, sulphur content in the waste slag was reduced significantly and gangue materials, such as SiO2, Al2O3 and TiO2, were reduced effectively.

Jan 1, 2011

By L. Gutierrez, M. Pawlik

The rheology artificial mixtures of bitumen with fine quartz of varying bitumen content, as well as actual oil sand ores, was investigated under different physicochemical conditions (pH, temperature). All rheological measurements were conducted using a Haake Rotovisco VT550 rotational viscometer, connected to a fixture specifically designed to measure properties of settling suspensions. It was found that at low bitumen contents (1 %, wt.) the pH of the slurries was the most important parameter that controlled the rheology of quartz-bitumen slurries. At higher bitumen contents (10%, wt.), it was a combination of high temperature and high pH that gave the lowest apparent viscosities and yield stresses of the model mixtures. These model observations correlated well with the rheology data obtained for slurries of actual oil sand ores. The overall results were discussed in terms of aggregation-dispersion phenomena between bitumen and mineral particles.

Jan 1, 2009

By P. S. Arthur

The copper I SAS MELT? process is a submerged lance bath smelting technology. In the 20 years since the process was first demonstrated on a semicommercial scale at Mount Isa in north-west Queensland, Australia, copper ISASMELT? plants have been constructed to treat concentrates or secondary raw materials around the world. The process is operating in smelters in Australia, the USA, Belgium, India, Germany, China and Zambia. ISASMELT? plants have been installed to improve the environmental performance of operating smelters and reduce costs for smelting companies. A new copper furnace is being commissioned at Southern Peru Copper Corporation in early 2007, while more furnaces are under design for installation in Kazakhstan and Peru. Copper ISASMEL T? plants are supplied as complete technology packages including engineering design services for the furnace and key ancillaries, supply of core equipment, provision of intensive training programs in operating plant environments and commissioning assistance services. The proven technology transfer process ensures successful implementation of submerged lance bath smelting into large scale plants. This paper summarises developments at recently constructed copper ISASMELT? plants.

Jan 1, 2007

By R. J. Young, S. J. Tennant, A. D. Drummond

"Gibraltar Mines is located on the western slope of Granite Mountain, 230 air miles north of Vancouver, B.C. and 38 miles north of Williams Lake, B.C. There are four mineable zones within the copper-molybdenite deposit: Gibraltar East, Gibraltar West, Pollyanna and Granite Lake. Open-pit reserves are 358 million tons which average 0.37% Cu and 0.016% MoS2 at a 0.25% Cu cut-off. The Granite Mountain pluton is one of the several Jurassic-Cretaceous intrusions which outcrop along the east side of the Fraser River fault system between Williams Lake and Prince George, B.C. The original Granite Mountain quartz diorite has been metamorphosed by a cataclastic deformation which foliated the rock on a regional scale. Attendant to the development of the foliation, the rock was saussuritized such that the present mineralogy is compatible with that of the greenschist facies. The presence of garnet-bearing assemblages is explained by a restricted increase in water pressure. Pre-mineral intrusive phases within the saussuritized quartz diorite are: (1) leucocratic quartz diorite, (2) aplite and (3) quartz-feldspar porphyry. A late chloritized hornblende dacite dyke is post-mineral. Quartz-feldspar porphyry and leucocratic quartz diorite are locally present on the inner sides of the Gibraltar East, Pollyanna and Granite Lake pits. Their presence suggests a core around which occurs an elliptically shaped sulphide-bearing stockwork. The stockwork, which comprises four ages of vein development, is imposed on and partly controlled by the regional foliation of the samssuritized quartz diorite."

Jan 1, 1973

By D. A. Le, T. S. Nguyen

"In Canada and other countries, several types of rock formations are being considered for the geological disposal of radioactive wastes. In order to better understand the ability of these rocks to contain and isolate the wastes, the Canadian Nuclear Safety Commission collaborates with different international research organizations and has access to experimental data from Underground Research Laboratories (URLs) in the world. Such an URL is situated in Opalinus Clay, at Mont Terri, Switzerland. An experiment, consisting of the excavation of a tunnel followed by water and gas injections in a test section of the tunnel, was performed at the URL. The authors have developed a mathematical model, based on the poromechanics theoretical framework, to simulate those phases of the experiment. The constitutive relationship for the stress-strain behaviour of Opalinus Clay takes into account its inherent anisotropy due to bedding. The model was able to capture the main features of the experiment such as the prediction of the shape and extent of the excavation damage zone and its influence on water and gas migration.INTRODUCTIONIn Canada and many other countries, several types of rock formations such as crystalline rocks and sedimentary argillaceous rocks, are being studied for the disposal of used nuclear fuel from nuclear power plants. Geological disposal relies on multiple natural and engineered barriers for the long-term containment and isolation of the wastes. The host rock is a major natural barrier and is the subject of extensive research. The Canadian Nuclear Safety Commission (CNSC), Canada’s nuclear regulator, will be responsible for the licensing of future deep geological repositories. In order to evaluate the safety of deep geological repositories, CNSC staff keep abreast of scientific developments by collaborating with national and international partners on experimental and theoretical research on the long term performance of those engineered and natural barriers. Through that collaboration, the CNSC has access to data resulting from experiments performed at different Underground Research Laboratories (URLs)."

Jan 1, 2015

By Troy Boisjoli, Sean Hillacre, Matt Batty

Discovered in 2014, the Arrow Uranium Deposit has undergone rapid development through successive drilling programs informed by geostatistical drill hole spacing studies. An independent third-party geostatistical drill hole spacing study was completed by Clayton V. Deutsch Consultants Inc. in 2017, evaluating the uncertainty of thickness, grade, density, and areal limit of the Arrow Deposit to determine a drill hole spacing suitable for Indicated Mineral Resources. Indicated spacing was defined to be 24 to 32 metres (“m”) to be within 15% of predicted for a nominal quarterly production volume with a probabilistic tolerance between 75 and 90%. The study not only defined the Indicated Mineral Resource resultant from the 2016 drill program, but also provided drill hole targeting criteria for subsequent drill programs aiming to convert Inferred to Indicated Mineral Resources. A subsequent geostatistical drill hole spacing study on the Arrow Deposit was completed by Clayton V. Deutsch with Resource Modeling Solutions in December 2018 to define Measured Mineral Resource spacing in support of the 2019 drill campaign. The study resulted in a drill hole spacing of 9 to 17 m to be within 15% of predicted for monthly and quarterly production volumes using an accepted industry probabilistic tolerance of 90%.

Jan 1, 2020

By Derek Apela, Coralee Heske, Bunyamin Kahraman, Muhammad Adi

Effective blast fragmentation is essential in underground mining, as it directly influences downstream processing efficiency and operational expenses. This study investigates the application of Non-Newtonian Fluids (NNF) as stemming materials, presenting a novel method to enhance energy confinement, minimize environmental impact, and optimize blast performance. NNFs exhibit shear-thickening behaviour, enabling them to transition between fluid-like and solid-like states under stress, which renders them suitable for regulating explosive gas ejection during blasting. Field trials were performed by Vale Base Metals in Thompson, Manitoba, in their underground nickel mine to evaluate conventional slag stemming against NNF-based stemming in production-scale blasts. Emulsion explosives were employed, and blast performance was assessed through velocity of detonation (VOD) measurements, vibration monitoring, and AI-assisted fragmentation analysis using WipFrag. Preliminary results indicate that NNF stemming improves fragmentation, resulting in a reduction of D50 by as much as 38%, enhances energy confinement, and may decrease the incidence of hole plugging and re-drilling in subsequent blasts. This study presents an alternative to conventional stemming methods, highlighting potential advantages for enhanced safety, efficiency, and sustainability in blasting operations. Additional research and field trials are necessary to improve implementation protocols and facilitate the widespread adoption of this unique method in the mining sector.

May 4, 2025

By F. E. Goodwin

Since the last CIM Zinc and Lead Conference ten years ago, significant technical and market forces have influenced how these metals are used, and the geographic distribution of their uses. Unprecedented price fluctuations have opened competitiveness issues, while the rapid growth of the Chinese market has created challenges both inside and outside China. Recent technical developments in battery energy storage, coatings, castings and chemical applications of lead and zinc will be reviewed together with the influence of these trends on end use markets.

Jan 1, 2008

By Rodgers Peale

The Waite mine, as it is locally termed, is situated in the Rouyn district, in the townships of Duprat and Dufresnoy, Quebec, and lies about 340 miles north of Toronto. Due to the impetus given prospecting in the Rouyn district by the discovery, some years ago, of copper-gold ore on the Horne claims, many exploration parties were put into the field. Early in 1925, J. H. C. Waite, C. H. Ackerman, and T. Montgomery staked the claims which now comprise the mine beating their names. Trenching and diamond drilling soon disclosed an ore-body of commercial size and grade, and by the end of 1928 a shaft had been sunk 300 feet and the mine was producing 150 tons of direct-smelting copper ore a day. In the summer of 1925, Dr. H. C. Cooke, of the Geological Survey, made a reconnaissance survey of the property (1), and since that time work of the same nature has been done by several others. MacGregor has published some interesting data on the Amulet mine (2). Using as a background a summer's work on the Horne claims at Noranda, the writer spent the summer of 1929 at the Waite.

Jan 1, 1931

By D. W. Boydell

The response of reclaimed gold tailings to acid leaching was investigated in the laboratory, followed by a pilot-plant program in which the operations of CCD, CIX and SX were tested with plant feed material. These results formed the basis for the design of the extension to the existing uranium plant at Blyvooruitzicht Gold Mine, commissioned in July 1977. This circuit consists of slimes-dam reclamation by bucket-wheel excavator at a rate of 100,000 t solids per month, acid leaching in pachucas, a five-stage CCD washing section, two parallel C1X absorption columns and two elution columns, SX and an ADU precipitation section. Barren solution is recycled to the CCD section as wash and to the repulper at the slimes dam. The performance of the plant during the first year of operation is compared with the predictions on which the plant design was based. Rated capacity was achieved within three weeks of start-up at a nominal dissolved uranium recovery in the ion-exchange section of around 98%. Owing to recycle, the over-all recovery in the ion-exchange and solvent extraction sections is somewhat higher than this figure.

Jan 1, 1979

By M. Lahtinen

Traditionally, there have been three main methods for iron removal in the hydrometallurgical production of zinc. These methods are atmospheric precipitation of jarosite or goethite and pressurised precipitation of hematite. Jarosite precipitation is without doubt the leading and the most commonly used technology for iron removal. However, jarosite precipitation has some drawbacks, such as a low iron content (and, thus, high residue volume), high moisture content after filtration and often a high zinc content. These features make any environmentally acceptable way of using or disposing of jarosite more expensive, as compared to hematite and goethite. The importance of environmental regulations has grown in the zinc industry during the last decade, which will have an increasing effect on new investments. Hematite has several advantages over jarosite, such as a high iron content, low moisture and low zinc content. An important advantage of hematite is that it is suited for further use in the cement industry. However, until now the need for autoclave equipment has limited the spread and implementation of hematite precipitation in the zinc industry. Outokumpu Technology Oy has recently developed an alternative method for iron removal, which is the atmospheric precipitation of hematite. A patented method for precipitating hematite at atmospheric pressure is presented and compared with conventional methods for iron removal. The process conditions, the quality of the hematite precipitate and the environmental aspects are also discussed.

Jan 1, 2006

By C. H. Lee, T. T. Wang

"Exampling of the tunneling task in the Tsengwen Reservoir Transbasin Diversion (TRTD) in southern Taiwan, this study investigates the application of the Drilling Survey System (DRISS) in both Drilling and Blasting (D&B)- and Tunnel Boring Machine (TBM)-excavated sections. In the D&B section, a nonlinear relationship exists between drilling energy and uniaxial compressive strength of rock mass, in which a reasonable coefficient of determination can be analyzed statistically. Additionally, the DRISS accurately predicted an unfavorable section with a valuable position. The magnitude of uniaxial compressive strength back calculated using DRISS data also matches those acquired from geological investigations with different approaches. Study results indicate that the DRISS is an effective tool for fore-probing of both D&B- and TBM-excavated tunnels. INTRODUCTIONModern advancements in geological and geophysical investigations, and drilling techniques, have provided valuable information for detecting and interpreting geological conditions of rock tunnels with a resolution of several to ten of meters (Brückl et al., 2001, 2008, Lorang et al., 2005). Nevertheless, construction risks remain considerable during tunnel excavation, especially when a tunnel was excavated by a Tunnel Boring Machine (TBM). Predictions of the local fault, shear zone, and other minor geological features, which may cause moderate collapse or excessive deformation of rocks surrounding the tunnel, before tunnel excavation is highly desirable for high-quality tunnel construction and economically efficient project management.Rather than conventional geophysical prospection methodologies, which always favor large-scale investigation with moderate precision, this study focuses on the drilling method probing ahead of a tunnel. The goal of such an investigation is not only to prevent catastrophic collapse, but also to provide quantitative or semi-quantitative information for estimation of the mechanical parameters of rock mass.For the tunneling task in the Tsengwen Reservoir Transbasin Diversion (TRTD) in southern Taiwan, a drilling survey system is adopted for fore probing. Data collected from both drilling and blasting (D&B) and TBM-excavated sections are analyzed statistically and discussed. The applications of the Drilling Survey System (DRISS) are addressed accordingly."

Jan 1, 2015

By Russell McIntosh

"The Madsen mine is in the southeastern part of Baird township, in Red Lake area, Ontario. It lies about 6 miles southwest of the town of Red Lake, with which it is connected by an all-weather road.The Madsen Red Lake Gold Mines Company was formed in March, 1935, to take over the holdings of the Falcon Gold and Jomac Gold syndicates. During 1935 an4 the early part of 1936 No. 1 shaft was sunk and drifts driven on four levels, all on a narrow quartz vein in a granite dyke.In July, 1936, the Austin zone was discovered about half a mile north of No. 1 shaft by Austin McVeigh, a prospector employed by the Company. Diamond drilling showed that the zone included an orebody worth development, and in 1937 No. 2 shaft was sunk, three levels opened up and sufficient ore outlined to justify the installation of a mill. Milling commenced in August, 1938, at the rate of 300 tons a day, which was later increased to 400 tons a day.The total production from 1938 to 1946 was 1,116,307 tons from which gold and silver having a value of $9,949,010 were recovered. The gold produced ranged from a minimum of 0.1910 oz. a ton in 1939 to a maximum of 0.2827 oz. in 1944. The average grade in 1946 was 0.2345 oz. to the ton."

Jan 1, 1954

By H. Ishimoto

It always has been a serious issue to improve safety in mine sites, demolition work sites, and civil engineering work sites. Especially, collision accidents caused by construction equipment damage not only the productivity of operations but also the health and life of workers in those work sites. To solve this problem, a variety of worker auto-detection means are developed so far, but they have not still become widely used in actual worksites. There have been two controversial points in the prior methods. One is that they were not enough in respect of the detection accuracy and certainty, and the other one is that the information of the detection results was not comprehensible to the operator of equipment. In this paper, the functional requirements of the obstacle detection system in earth moving work site is redefined at first, and then, it is proposed to apply a stereo vision to the obstacle detection system for an excavator. The system consists of horizontally arrayed two digital cameras with low distortion lens, an image processing controller, and a monitor for an operator in the cab. Stereo vision calculates the depth image from images of two cameras and detects the presence of obstacles, its distance, direction, and dimensions. Sensed obstacles are informed to the operator in the monitor image. Preliminary experiments are conducted with a stereo vision system mounted on a real equipment in a demonstration site. The result shows that two controversial points of the conventional technologies are improved, and that the applicability of this system is validated.

Aug 1, 2013

By S. Steinlechner, S. Wegscheider

"In the past, the metallurgical industry was most of the time dedicated on their main commodity, recovering base metals like zinc, copper or lead but leaving other valuable side elements in the generated residues. As a result, these accompanying minor elements, like gold, silver, indium or also PGMs can be found in the dumps of the corresponding industry. Because of political unrest, strikes, economic reasons or decreasing primary resources leading to a high supply risk, also those mentioned minor elements moved into the focus of the recycling industry. Therefore, beside the base metals, first of all the recovery of those minor metals would be of high interest contributing to the economic viability of recycling processes, although they occur in much smaller quantities in materials. In this context, residues from zinc industry, like leaching residues or precipitation residues show high potential to carry silver as well as indium next to lead and zinc. Therefore, the paper summarizes carried out thermochemical calculations investigating a possible recovery of silver as well as indium by volatilization and the influence of zinc and lead on this process. Based on these theoretical investigations with HSC, trials in lab scale were done verifying the obtained results.INTRODUCTIONHuge amounts of iron precipitate, mainly jarosite get landfilled every year although there is a high content of valuable metals in this residue beside iron. Nevertheless, jarosite has to be dumped due to the presence of contaminating heavy metals. The accumulation of these residues takes up massive land on the one hand but also causes a series of environmental problems in ecosystems on the other. Moreover, some toxic ingredients such as arsenic and cadmium can be dissolved in rain water and are therefore harmful to the health of the aquatic systems. (Erdem & Özverdi, 2011; ÖzverdI & Erdem, 2010) Approximately 0.5 t of dry jarosite accumulate in the production of 1 t of zinc by the hydrometallurgical zinc-winning route (Svens, 2010). Jarosite is a precipitation residue formed during the iron removal. In general, the iron already exists in the zinc ore which is why zinc ferrite builds up during the roasting step of the zinc ore. Zinc ferrite is only soluble in strongly acidic solutions and during the hot acid leaching step it gets dissolved while zinc and iron enter the solution. It is necessary to get rid of the iron because otherwise it would deposit on the cathode first due to its precious character which would be harmful in the zinc-winning electrolysis. Nevertheless successful investigations were done by adding chlorine to the jarosite to recover silver. These findings leads to another residue which occurs in huge amounts – electric arc furnace dust (abbreviated with EAFD) from the iron and steel industry. In 2013 the annual electric steel production reached about 451 million tons. Around 15-20 kg of EAFD is produced per ton of steel in an electric arc furnace (EAF), creating approximately up to 9 million tons of dust per year. (Grabda, Oleszek, Shibata, & Nakamura, 2014; World Steel Association) Next to elements like zinc, lead and iron, chlorine and fluorine are present in this dust. While galvanized steel plates in the scrap act as a source for zinc, casting powders, flame retardants and synthetic coatings are responsible for the chlorine and fluorine contents in the dust."

Jan 1, 2016