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By T. Miura, Y. Mori, H. Aoki

In a flash smelting furnace, easily combustible concentrate particles excessively oxidized and melt. The excessively oxidized molten particles then collide with less oxidized solid ones to create uniform oxidized molten particles. This collision phenomenon plays a very important role in achieving high smelting performance. The authors developed a mathematical model describing above combustion phenomena. This model incorporated fluid flow, heat and mass transfer, chemical reactions and collisions of concentrate particles. Both gas flow and particle motion were calculated using the Eulerian method. Copper concentrate was assumed to consist of chalcopyrite(CuFeS2). Considered in the concentrate reactions were the decomposition of CuFeS2, and the oxidation of the resulting sulfur(S) and pyrrhotite(FeS) to produce magnetite(Fe30 4) and sulfur dioxide(S02). Moreover a reaction due to concentrate particle collisions, in which Fe304 in the excessively oxidized molten particle reacts with FeS in the less oxidized particle, was also considered. The particle collisions were assumed to occur according to a collision probability rule obtained by computational experiments. Particle growth in diameter was described as a change in the volume fractions of particle phases. When applied to a commercial flash smelting furnace, this model reproduced the particle growth and component transfer as observed in the actual furnace.

Jan 1, 2007

By S. W. Marcuson, P. J. Mackey

The 1973 Oil Embargo and succeeding disruptions in supply had a profound effect on energy costs and consumption patterns in the developed world. This was especially true in the USA where post World War II growth, fueled by low-cost imported oil, left the country dependent on uninterrupted oil shipments from the volatile Middle East. In this atmosphere, Professor H.H. Kellogg of Columbia University, convinced of the necessity of good environmental stewardship by the writings of the era’s leading environmentalists, developed a methodology for evaluating energy and process efficiency of metallurgical processes and wrote a series of papers describing and applying the techniques. One of these, "Energy Use in Sulfide Smelting of Copper" is recognized as a seminal work which both described the state of energy usage in copper smelting in the mid-1970’s and portended future developments. The background to these papers is examined and the current and past Cu-Ni matte smelting practices in Canada are examined in the context of the results. Data from early 20th century publications describing reverberatory and blast furnace operation is employed to show that energy consumption for much of the century was several multiples higher than that calculated for best reverberatory operation in the 1970’s.

Jan 1, 2015

By The Staff

"A general description of the equipment, personnel and work sequence •being used in the sinking of a circular, concrete lined, 14 foot diameter shaft which at present is at a depth of 2,484 feet. Equipping, lining and sinking of the shaft is being carried out concurrently and waste is re-moved using a mechanical mucker.INTRODUCTIONTHE BUCHANS UNIT of the American Smelting and Refining Company operates a group of mines at Buchans, Newfoundland. Buchans is in the centre of the Province (Lat. 48°47'N.; Long. 56°50'W.), five miles north of Red Indian lake at an elevation of 900 feet and is accessible by 37 miles <Jf private railway which connects with the Canadian National railway at Millertown Junction, and by 47 miles of gravel highway, which connects with the Trans-'Canada Highway at Badger."

Jan 1, 1959

By Erik Spiller

"Water and cyanide are highly contentious and conflict issues that many gold mining companies encounter worldwide when dealing with local farming communities, industries and cities competing for water as well as non-government and government organizations. Historically, the gold industry has used processes that required minimum amounts of water to treat and recover gold at locations around the world. Examples are dry grinding for refractory gold treatment in the late 1800s and early 1900s and dry blowing in arid/desert regions to recover alluvial gold. In recent times, new dry processing equipment has been developed and include equipment such as air tables and jigs. Researchers have also modified a Knelson concentrator to concentrate gold from dry solids. High pressure grinding rolls (HPGR) with air classifiers are used to treat industrial minerals and pilot trials have shown that the technology can be applied to comminute refractory gold ores ahead of roasting. Dry stacked tailings is being applied on gold mines to reduce overall water consumption This paper will review the available technologies that in combination may be able to substantially reduce the quantity of water used in the processing of gold ores.INTRODUCTION Water makes up most of the world: the planet is 75% water. Some 97.5% is saline water largely in the oceans, so that only 2.5% is fresh water and useful for human needs. The demand for water is driven primarily by population and concomitant economic growth. Overall, some 70% of the water withdrawn from the environment is used in agriculture, 20% by industry, 7% by households and 3% for mining (Brown, 2003: Maupin et al., 2010). Whilst the water needs of the mining industry are minor compared to those of agriculture, an operating mine requires a relatively large quantity of water on a daily basis to carry out operations. Mining activities are often located in remote, arid environments, with limited access to water. There are a multitude of water resources available to the mining industry for its needs. However, much of this water is saline and over the last two decades there has been a continual decline in water quality (i.e. salinity has increased). In today‘s world, there are enormous internal and external pressures to reduce water consumption at a mine, and/or alternatively use water not considered a resource by the local community. Strategies to meet these objectives can be achieved by implementing good water management practices, by recycling process water, reducing water losses by evaporation and seepage (i.e. by increasing and improving dewatering practices) and employing new technologies such as dry stacking and dry processing (Dunne, 2010)."

Jan 1, 2017

By S. C. Ells

Within the Dominion of Canada occurrences of petro-liferous shales have been known for many years. Nevertheless, with the exception of a comparatively brief period, Canada has had to depend largely on foreign sources for its supplies of crude petroleum and petroleum products. Attempts were made to retort local shales in 1859, near Collingwood, Ontario, and again in 1862, near Baltimore, New Brunswick. In each instance these attempts were abandoned owing to the rapidly increasing production of well petroleum from the newly discovered pools of western Ontario and Pennsylvania. Now, after a lapse of nearly sixty years, attention is again directed to the commercial value of Canadian shales as a possible source of crude petroleum. Province of Nova Scotia: The principal deposits of oil-shales occur in Pictou and Antigonish counties and have been known for more than 60 years. During the three years following its discovery, several thousand tons of a particularly rich sub-variety, known as stellarite (stellar coal or oil coal) was mined near Stellarton in Pictou county. It is stated that stellarite yielded upwards of 10,000 cubic feet of 36 candle gas, and that selected samples gave a yield equivalent to 170 Imperial gallons (204 U.S. gallons) of crude petroleum per ton. The average petroleum content of a cargo shipped to Boston was 48 Imperial gallons (57.6 U. S. gallons) and the associated shale or &apos;bat&apos;, gave a yield of 39 Imperial gallons (46.8 U.S. gallons). Part of the above output was shipped to retorting works in Boston and in Portland, and part was mixed with bituminous coals for the enrichment of illuminating gas. Following the discovery of well petroleum in Ontario and in the United States, the mining of stellarite ceased.

Jan 1, 1925

By Gareth Barnes

Traditional approach to improvement is driven by good ideas from good people, but whilst the business case may sound good, when the project is complete, we often have not delivered on expectations.  Why not? The best way to successfully predict the outcomes of an improvement effort in a complex process is through using statistical modelling, which considers the impact of uncertainty within interacting processes.  Applying Theory of Constraints in a model helps leaders to quickly determine: Where the constraining process(es) is/are Where improvements will add the most value How much improvement should be targeted - before the next constraint takes over The confidence level of achieving a given target, which gives us a clear pathway to improvement. This paper presents an analysis of statistical modelling applications at Vale’s Manitoba Operations to achieve the 2025 targets. Using statistical modelling of the Business Structure, the team identified a series of process improvements through a Theory of Constraints Analysis. Value Stream Maps (VSMs) were used to define the required data, apply statistical modelling, and conduct training sessions enabling the Manitoba team to identify the constraining influences. Scenario testing in the Statistical models helped identify the Hierarchy of Constraints and specify the pathway to improvement. How to Improve a Business Video link https://vimeo.com/344418155

May 4, 2025

By M. V. Rowley, D. D. Warkentin

With high commodity prices, tightening operating budgets and increasing disposal costs, there is an increasing interest in processing municipal waste streams, such as the ash derived from combustion processes. This paper describes laboratory development work for a process to recover metal values from the finer fractions of these wastes. The work was initially aimed at recovery of copper and the removal of lead and other heavy metals from the ash residue, but results showed gold and silver recovery to be an important objective as well. The process uses gravity and flotation as the principal separation steps, with gold recovery occurring mainly in the flotation stage. The particle size range and chemistry of the ash presented numerous challenges to developing a suitable flotation method, but an effective flowsheet was developed by separating the ash into a fine fraction and a separate slime fraction, each with a unique flotation strategy. Specialized conditioning stages and careful reagent selection have resulted in effective gold and silver recovery from a range of ash types and sources. The work has resulted in a patent being issued for a process based on this novel approach to the treatment of combustion wastes.

Jan 1, 2017

By W. Hawker, A. M. Ivana

"Pressure oxidation is used to liberate gold from refractory sulphide ore and concentrates with over fifteen autoclaves in operation. Despite the importance of pressure oxidation, the autoclave chemistry and chemical thermodynamics are not well established. For example, there is no consensus on aqueous iron speciation or stability of jarosite phases. Additionally, there remains questions about basic ferric sulphate formation and stability. In addition to a review of the current state of knowledge, a methodology to study the ferric precipitation reaction and relate the results to chemical thermodynamic predictions is presented which will be used to accurately define the phase boundaries of the iron precipitates in the future (hematite, jarosite and basic ferric sulphate).INTRODUCTION With declining availability of orebodies that respond to simple leaching conditions, pressure oxidation has become a prevalent technology to liberate gold locked in sulphide mineral matrices. Gold pressure oxidation was established 32 years ago, with McLaughlin being the first facility in 1985 (Thomas & Pearson, 2016). Pressure oxidation is carried out at elevated temperatures ranging from 180 to 240°C as shown in the summary of operations in Table 1 (Ruonala et al., 2016; Fleming, 2010).A considerable amount of research has been done to study iron solubility and precipitation under autoclave conditions (Tozawa & Sasaki, 1986; Umetsu et al., 1977; Sasaki et al., 1993; Fleuriault, 2016; Cheng & Demopoulos, 2004; Papangelakis et al., 1994; Yue et al., 2003). These reports provide a description of the process chemistry and iron behaviour in the autoclave. However, there remain questions about the type and stability of aqueous species and solid phases. This detailed information is required to build a robust chemical thermodynamic model of the system, allowing for equilibrium and kinetic reaction limitations to be discerned."

Jan 1, 2017

By Rob Boom, Yasuyuki Tozaki, Frank M. Wheeler

Selection of a suitable site for a metallurgical plant is crucial for the success of the business case. For a brownfield project, with the decision to locate the project on a site with existing production facilities and activities, the selection of the site has been made. For a greenfield project, important economic and logistical considerations include proximity to primary and secondary resources and/or to the market, infrastructure, and access to energy and water. National and regional aspects, including the social license to operate, can be decisive in final site selection. Key to recruiting and retaining a labour force are proximity to urban areas, along with weather and health conditions at the site. Risk factors include site geotechnical parameters and topography, contamination, as well as probability and types of potential natural disasters.

Jan 1, 2015

By Joo Hyun Park, Hyun-Sik Park

"Gold is one of the most valuable and precious metals. But, the extraction efficiency of gold from natural resources is very low and labor-intensive due to very low concentration of gold, i.e.,1–5 ppm, which means that gold extraction processes produce extensive amounts of tailings. The gold content in printed circuit boards (PCB) from waste mobile phones is about 100 to 400 ppm, which is enormously greater than the concentration found in natural ores. Consequently, processes for recycling waste PCB and gold mine tailings become of increasing importance to maintain a sustainable society. As processing these waste materials by pyrometallurgical methods has become more economically attractive, understanding the thermodynamic behavior of gold in smelting slags under oxidizing and reducing conditions has become increasingly important. Therefore, in this study, the effects of slag chemistry, oxygen potential and temperature on gold solubility in smelting slags are discussed. From the results presented, the predominant species of gold is strongly dependent on the basicity of slag. Furthermore, more basic slags showed higher solubility of gold at a given oxygen partial pressure, and more oxidizing atmospheres enhanced the dissolution of gold to the molten slag phase. As a consequence, careful control of the slag composition during pyro-processing of gold-containing waste materials is required to maximize gold recovery. INTRODUCTIONGold has good physicochemical properties. Thus, it plays an increasingly important role in industrial applications. For example, over 300 tons of gold are used annually in electronic components (Hageluken &Corti, 2010).However, 75% of all gold ever produced has been extracted since 1910 and gold reserves in the world are becoming rapidly depleted (Louis & Pluchery, 2012).The cost of gold production and its price in the market have increased rapidly during last 20 years as shown in Figure 1, and interest in the recycling of gold-containing materials has naturally increased.The wastes from electronic equipment (e-wastes) contain large amounts of precious metals compared to their own respective ores, and therefore such wastes may be considered as a secondary source of valuable metals. For instance, the concentration of gold in natural ore is commonly 0.5–15 g/ton-ore (0.5–15 ppm), while its concentration in electronic circuit boards is over 10 times higher, typically being about 150 ppm in expansion cards and over 10,000 ppm in central processing units(Barbieri et al., 2010).Also, gold mine tailings are discharged after the flotation process as slurry form then stored near the operating plants (approx. 100 ton per day in one Korean gold mine). Gold mine tailings contain gold at about 1–2 g/ton. This is the reason why Au-containing materials such as e-wastes and mining wastes are highly important sources of gold (Yamasue et al., 2009)."

Jan 1, 2017

By L. Drisdelle, S. Gendron

"Survival in today&apos;s business climate requires participation of all employees in a Total Quality Management Program encompassing everything - ""safety, quality of products, quality ofet1ch and every job done, and of course production "". We all know what needs to be accomplished, but struggle with how to do it, especially in an industry which has not always experienced management/union cooperation, and mistrust is still present.This paper describes a process to improve team work and employee involvement in Inco&apos;s nickel carbonyl refinery at Copper Cliff The process involves facilitatorship training for all employees, and a system for reinforcing and accomplishing the required behavioural change. The system is described in detail and a number of examples are presented. At the refinery, the staff is starting to understand as Max DePree recently wrote ""Without Quality Behaviour, you cannot have Quality Product"". IntroductionThe Copper Cliff Nickel Refinery (CCNR) is Inco&apos;s largest and most modern nickel refinery, which celebrated its twentieth year of successful operation in April 1993.The heart of the refinery is the Inco pressure carbonyl (IPq plant which produces high purity nickel pellets and specialty powders by refining an approximate 80% nickel granule feed. The carbonyl plant is a modem chemical plant with very special and demanding requirements for safety and environmental protection due to the toxic nature of the refining gas.Since 1987, there has been an emphasis at CCNR on a comprehensive Total Quality Improvement (TQI) Program which was designed based on recognizing customers&apos; needs for improved systems for quality management. This program is customer oriented and comprises such elements as team organizational concepts, customer audits, process assessment and internal quality auditing.A detailed review of progress was made in early 1991 and it became apparent that the ""ownership"" of the TQI program was not broad based. In fact, the program was very much a staff driven effort and fell far short of total employee involvement and relentless continuous improvement that are now considered essential to remain competitive and stay in business.Inco staff has now come to regard that early phase of our TQI program as ""the technical aspects of total quality improvement"".The safety experience was also puzzling. Even though the safety statistics were good with an average lost time frequency of 1.6 for the last five years, the perfonnance improvement had plateaued and remained pretty much the same. Clearly a new approach was required if significant progress and continuous improvement was to be made."

Jan 1, 1994

By I. Thobadi, C. Pawlik, K. Bisaka, S. Mokoena, M. Erwee

The PyEarth™ process developed at Mintek has been demonstrated successfully at pilot scale. Nine tons of ore containing 2.3 mass % of total rare earth oxides (TREO) from a dormant mineralogically complex iron-rich ore deposit, was subjected to a concentrating smelting step in a 200 kW DC open-arc pilot furnace and the rare earths from the resulting slag were extracted via a hydrometallurgical route. This ore deposit is practically not amenable to extraction by conventional methods. The testwork results proved that the PyEarth™ process was able to optimize the extraction of rare earths while minimizing waste through the removal of iron as a saleable iron alloy. Reduction of iron to the alloy in the smelting step was found flexible, efficient, and controllable, while rare earths were left virtually unreduced in the slag phase. The slag chemistry is selected to optimize both the smelting and leaching performances as well as the alloy composition. Leaching of the resulting slag was found possible and most efficient in hydrochloric acid amongst other lixiviants tested.

Jan 1, 2017

By Nathan Deisman

Coupled reservoir geomechanical simulations have become a key component of caprock integrity assessments for SAGD operations. This work demonstrates the differences of stress evolution when considering coupled versus uncoupled reservoir simulation. Coupled simulation involves the use of a reservoir and a geomechanical simulator with feedback to each simulator to update reservoir or geomechanical variable (permeability, porosity, relative permeability, pressure, temperature, saturations). Uncoupled simulation only passes the pressure and temperature to the geomechanical simulation with no reservoir simulator updating. Therefore, it is possible to complete uncoupled simulations exclusively with no knowledge of geomechanical flow property evolution. However, it is important to understand the differences between the stress evolution in each model for caprock integrity analysis. A single geological model was selected and parametric analysis was completed while varying the geomechanical the production injection pressures (1600 kPa, 1900 kPa, 2200 kPa) for a reservoir with an initial pressure at the injector of 1300 kPa. The results of the six uncoupled and coupled models are compared through the changes in mean stress, shear stress, and strength with focus on geomechanical assessment of caprock integrity.

Jun 1, 2012

By Helmut Ehnes

Over 330 million accidents at work happen world wide every year, only counting those leading to more than four days absence. More than 350,000 end fatal. Two million people more die every year due to work-related diseases. To sum this up: around 2.4 million people die every year because of work conditions. Among many risky industries, mining stands out. While mining represents just 1% of employees globally, it unfortunately represents 8% of all occupational fatalities. Mining operations go along with a variety of hazards. Not only in large operations, as they first come to mind, but also in the manifold small scale mines, with an estimated 13 million labourers worldwide exposed to substances such as dust, mercury and other chemicals, while also dealing with poor ventilation, inadequate space and overexertion. But is the number of severe accidents and diseases inevitable or can we change this situation? We can make mining sustainably safer, but we need a successful strategy to do so. A high potential lies in Vision Zero. Vision Zero is a prevention strategy for a safe future without fatal or serious occupational diseases, work accidents and traffic accidents. First defined as early as in the 19th century by Eleuthère Irénée du Pont, its very successful elements were adopted by many European countries first aiming at road safety, then extended to safety and health at work. Vision Zero?s holistic elements cover technology, workplaces, rules, and people as fields of action. By focussing on severe and fatal accidents, its application increases the level of safety and health overall.

Aug 1, 2013

By Ellis Thomson

The microscope is now used extensively not only in the examination of solid ore but also in the determination of fragmental mill products. It has therefore become a matter of paramount importance to be able to mount and polish fragmental as well as solid specimens in the easiest and most efficient way, so that the minerals present may be readily determined. In the case of the solid ore the ordinary mount of plasticine set on a glass or metal slide serves for most practical purposes. An improvement on this is furnished by the small brass container inside of which the specimen is mounted in a cementing medium of sealing wax. The latter is the method in use at Harvard University. It has the advantage of uniform height, thus obviating the necessity of a slide of any sort. It is also easily catalogued as the brass holder may be stamped with a convenient series of letters and numbers that will serve as a label. Other advantages of this type are the ease with which any particular part of the section may be re-located, the excellent storing facilities afforded by mounts of uniform size, and the possibility of polishing ten or a dozen sections at the same time by means of a holder which is placed over the polishing wheel, is geared with it, but revolves the opposite way.

Jan 1, 1926

By André Piché

"Over the last ten years, several developments have been undertaken to conceive a machine capable of carrying out simultaneously all the mining tasks in hard rock deposits: cutting, mucking, hauling, ground support and dust control.The main advantages of continuous mining over conventional drill and blast is the elimination of the cyclical nature of the actual methods. Other advantages sought are improved stability of mine openings, higher productivity, lower costs, and a cleaner and safer mining environment. Noranda has con-tributed to these developments in a major way. As a member of HDRK, Noranda participated in the development of two mechanical continuous mining machines; the TM60 and the Wirth. Noranda also undertook a development of its own based on the utilization of electricity to break rock. This technology is called plasma blasting (PBT). The concept of plasma blasting is illustrated in Figure 1.When the operating voltage is reached (18kV), the energy is released through a high current switch (500k A) into a coaxial powercable. It is then delivered to the tip of an electrode inserted into a drill hole which is filled with an electrolyte (water). When the energy reaches the electrolyte, it is instantaneously transformed into a high temperature, high pres-sure plasma that produces a shock wave capable of breaking rock(1).After initial testing of the plasma blasting technology in the lab and in the feld, two experimental platforms were constructed. The first one, a test bench, was erected at the Noranda Technology Centre in Pointe Claire, Quebec.(2)The second one is a rock breaker prototype based on a standard diesel-powered carrier (Fig. 2). Each platform was equipped with a 300 kJ pulsed-power module.In 1993, the rock breaker prototype was used for an extensive series of tests in the field. During that campaign, over 700 oversized boulders were blasted. The results of the tests demonstrated that more durable components for PBT were needed. The test bench was then used to successfully develop and test long-lasting components (probe, switch, cable, connector) that can be adapted to industrial platforms leading to the commercialization of the technology."

Jan 1, 1996

By P. Klossek

It is estimated that China accounts for 94% of the world supply of rare earths (Roskill, 2011). This fact, together with the impact of China?s export policy, poses a substantial risk to the security of the rare earth supply as well as a rare earth price risk. This situation has motivated an increase in the number of rare earth projects under development, i.e., there are currently more than 440 worldwide (Technology Metals Research, 2012). However, economically and environmentally acceptable processing technology to produce tradable products from rare earths (e.g., separated rare earth oxides) is not freely available on the market at the moment. In this respect, a lot of research and development has been initiated on this topic, in academia as well as in industry. Using a proprietary model and scenario-based analysis, we studied the impact that the development of rare earth processing technologies would have on the rare earth market and the economic feasibility of rare earth projects mentioned before. The analysis showed that this impact varies depending on the technology type (e.g., technology can affect project production volume, cost structure or both) and the legal context of the invention (e.g., free or limited by patenting availability of a new technology). The effect of a technology which influences project production volume is not the same as of a technology which changes project cost structure. The impact of a patented processing technology differs from the impact of a processing technology which is freely available on the market. In the case of a new technology which is limited by patenting, its impact depends on the market position (?producing?, ?next-coming?, or ?not producing? project) of the patent holder. The paper contributes to existing research by studying the dependence of the expected micro- and macroeconomic impact of rare earth processing technology developments on the properties of a new technology (e.g., costs, legal framework etc.). By this means, the paper adds to existing knowledge and attempts to make the rare earths market more transparent and predictable from a perspective outside China.

Aug 1, 2013

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012

By Stephen Mullowney

Outline ? Setting the stage ? Deal activity ? Q1 2013 update ? Key deal sectors ? Deals by geography ? Outlook for 2013 Key Observations 2012 ? Major retreat in M&A activity ? Glencore-Xstrata deal dwarfs all other deals ? Gold & copper dominate deal activity

May 1, 2013

By O. A. Ojo, N. Esmaeili

"The effects of brazing and use of composite powder mixture as interlayer material on hot corrosion resistance of brazed IN738 superalloy were studied. Brazing was observed to result in significant reduction in the hot corrosion resistance of the superalloy. However, application of composite powder mixture, which consists of additive superalloy powder, enhanced the hot corrosion resistance of brazed samples. It is also found that although the use of composite powder mixture increased hot corrosion resistance of brazed alloy, if the additive powder completely melts, which is possible during brazing, it can significantly reduce the hot corrosion resistance of the brazed joint. Elemental micro-segregation during solidification of the joint with completely melted powder mixture produces chromium depleted zones and consequently reduces hot corrosion resistance, since a uniform distribution and adequate chromium concentration is necessary to combat hot corrosion. This has not been previously reported in the literature and it is crucial to the use of composite powder mixture for enhancing the properties of brazed superalloys.INTRODUCTION Superalloys have been developed in response to the increasing demand for materials with higher resistance to corrosion and creep and also with higher mechanical strength at higher temperatures (Smith, 1981). Ni-base superalloys are predominantly used in manufacturing hot sections of gas turbine engine components. This is due to their high strength and corrosion resistance in extremely high temperature service environments which is typical for hot sections of gas turbine engines (Miglietti, 2009). The continuous demand for higher efficiency and output has resulted in the use of higher operating temperatures and gas pressure in modern gas turbine engines (Jahnke & Demny, 1983). Consequently, this has caused thermal and mechanical stresses which result in severe degradation and damage of gas turbine engine components due to creep, fatigue and hot corrosion (Zhang, Feng, & He, 2006). The decision to replace or repair damaged parts depends on the overall repair cost and expected life of the repaired components (Jahnke & Demny, 1983). However, in most cases, it is more cost effective to repair damaged parts rather than use a full replacement."

Jan 1, 2017