Search Documents

By G. Morin, F. Chiesa, B. Duchesne

The Quality index is a useful tool allowing to assess the metallurgical quality of aluminium AlSiMg foundry alloys (A356/357). Its value is calculated from the ultimate tensile strength and elongation; it increases with the metallurgical quality of the casting, i.e. with finer dendrites, lower microporosity and inclusion count and lower iron content. This Quality index does not depend on the degree of temper applied during the heat treatment (aging time and temperature). After defining the Quality index, it will be explained how it can be predicted from the knowledge of the local solidification conditions obtained from modelling. The paper will then present four case studies of castings for which the prediction of the Quality index by modelling was made. These case studies from different authors will involve the three most common casting processes used for producing high integrity aluminium castings, namely: sand casting, permanent mould casting and investment casting (lost wax). In all cases, the accuracy of the prediction will be assessed by comparing the predicted Quality index distributions to the experimental values based on the published measured values of the local tensile properties.

Jan 1, 2006

By J. A. Abols, P. M. Grady

Recovery via gravity is one of the oldest mineral processing methods available. Unfortunately, the use of gravity techniques for gold recovery has been in decline for the past century as more effective chemical processes such as flotation and leach/CIP have been developed. Recently, with the push towards more sustainable environmental outcomes, the benefits of gravity separation have become more apparent. While gravity as a unit process is not usually capable of achieving as high a recovery as flotation or whole ore cyanidation, a combination of gravity devices alone or in conjunction with these processes can offer significant advantages to the operator. This paper reviews the range of gravity devices available, their application and the results that can be achieved by maximizing gravity through the use of a combination of gravity recovery devices. Three case studies are provided.

Jan 1, 2005

By John S. Stevenson

THE Twin "J" Mine, operated by Twin "J" Mines, Limited, represents an amalgamation of the old Lenora, Tyee, and Richard III mines (see Figure 1) on mount Sicker, eight miles by road, northwesterly, from the city of Duncan, on Vancouver island. These mines produced 253,000 tons of copper-gold ore between 1898 and 1909 (see Table I). During the more recent period of production from these properties, July, 1943, to May, 1944, Twin ?J? Mines, Limited, mined and milled ore with values mainly in copper and zinc, and minor values in gold, silver, and lead. Figures are not available for this later production. Field work at the property was started by the writer in 1941 and continued in 1943 and 1944.

Jan 1, 1945

By Tadeusz W. Wlodek

THE known phenomenon that a test-piece of ferro-magnetic steel is magnetic after it has been broken in tension indicates that, while it is being loaded, the steel acquires magnetic properties. In the present investigation of the influence of the stress on the magnetic flux, repeated pulsating stresses of increasing amplitude, varying from zero to the maximum tensile value, i.e., pull-pull loading, were employed. The specimens were prepared from two types of carbon steel and two of alloy steel. The magnitude of the magnetic flux was determined indirectly. The voltage and mode of variation of the electromotive force induced in a coil surrounding the stressed steel specimen were measured as an indication of the varying magnetic flux within the specimen. Curves representing the electromotive force induced by the varying magnetic flux show that as the tensile load increased so also the magnetic flux increased, with a corresponding increase in measured e.m.f. At a certain stress there is a sharp bend in the voltage curve (point Win the diagram, Figure 5); this critical stress corresponds very closely with the yield stress (0.2 per cent permanent strain). Beyond this point, slight increases in the stress produce large increases in the voltage. The wave form of the e.m.f. was registered on an oscillograph. Analysis of the curves so obtained demonstrated the necessity of continuing these experiments, in order to determine the type of induced wave form associated with various types and amplitudes of stresses. In these experiments, the shape of the stress wave was sinusoidal, although the shape of the induced e.m.f. was sinusoidal only up to a certain load and became more and more complex above this load.

Jan 1, 1944

By R. C. Rowe

THIS paper is an endeavour to analyse the ideal and practical functions of government technical mining services, and their relationship to the National Domain, as well as to one another. its spirit is not critical, even though at times it may appear to besoin fact. It is a serious effort to divert a trend in public thought which delights in calling itself practical whereas it is really merely short-sighted. The author refers particularly to the idea that governmental research is a luxury which should be curtailed in the interests of economy, and turned over to private enterprise or the provinces. In order that we obtain the proper perspective of the question, it is advisable to indulge in a little history. In the year 1842, the Geological Survey of Canada was formed under the guidance of William (later Sir William) Edmund Logan. The literature on the founding and history of the Geological Survey of Canada is extensive, and therefore it is unnecessary to go into detail here regarding it. It might be mentioned, however, that the Geological Survey of Canada is only seven years younger than the Geological Survey of Great Britain (founded in 1835), and is only exceeded in age on the American continent by the State Geological Surveys of New York, Pennsylvania, Massachusetts, and Michigan, which were founded between 1833 and 1836. In 1877, the Geological Survey became a permanent government institution as a branch of the Department of the Interior. It should be noted, however, that the Director of the Survey ranked as a Deputy Minister and reported direct to the Minister. This continued until 1907. In 1886, the Mineral Resources and Statistics Division of the Geological Survey was formed. Some years later, the Canadian Institute of Mining and Metallurgy (then the Canadian Mining Institute), backed by the mining press, began to agitate for the establishment of a Dominion Department of Mines, and in 1907 such a department was founded by the Geology and Mines Act of that year, with a separate Cabinet portfolio for the position of Minister of Mines.

Jan 1, 1939

By József L. Margitfalvi

Different Au/MgO catalysts modified with Mn, and Fe were prepared by precipitation-deposition. The catalysts were characterized by XRD, FTIR, Temperature Programmed Reduction (TPR) and CO chemisorption and were tested in CO oxidation in the temperature range of 243-523 K. The catalytic tests using both Temperature Programmed Oxidation (TPO) technique and time on stream (TOS) experiments revealed the high activity of catalysts prepared. In TPO experiments the modification by Mn significantly increased the activity above 300 K, however in the subambient temperature range the activity decreased considerably. Catalysts modified by iron did not show any decrease in the activity below 300 K, while the activity at high temperature increased significantly. Catalysts modified by Mn, Fe showed higher activity, selectivity and stability in preferential CO oxidation, carried out in the presence of hydrogen than the unmodified Au/MgO catalysts. Results of in situ FTIR spectroscopy on both the base Au/MgO and the iron modified catalyst unambiguously revealed the formation of ionic gold in the presence of CO/O2 mixture. The formation of this species was strongly hindered in catalyst modified by manganese. Results obtained strongly support the need for the formation of "metal ion - metal nanocluster" ensemble sites. These sites are involved in the activation of the CO molecule prior to its reaction with atomic oxygen. It is suggested that at subambient temperature these ensemble sites contain mainly ionic forms of gold, while at higher temperature iron or manganese ions are involved in CO activation.

Oct 1, 2003

By L. Bichler, C. J. Verdon

In this work, the effect of doping yttria stabilized zirconia (YSZ) with 5, 10 and 15 mol% erbium oxide (Er2O3, erbia) was investigated using spark plasma sintering (SPS) technique. Sintering was carried out at 1300°C with 30 and 60MPa uniaxial pressures and a 5min hold time. Densification kinetics were studied using displacement response from the SPS machine. As-sintered microstructure characterization was carried out via scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques, while chemical composition was characterized by energy dispersive X-ray spectroscopy (EDS). The results suggest that sintering carried out at 60MPa produced high density composites even though erbia dopants were found to inhibit material densification and grain growth during sintering. 5, 10 and 15mol% erbia- YSZ had cubic crystal structures, as verified by XRD analysis.

Jan 1, 2014

By Jerry C. Tien, Yingjiazi Cao

"Coal spontaneous combustion (SponCom) is a natural phenomenon in underground operations, which can either happen naturally or be triggered by human activities. For underground operations, espe-cially in coal, SponCom can happen frequently as a result of air leakage, although its incubation period may vary depends on types of coal and surrounding environment, resulting in uncertainty in control. In China, most of the underground coal operations now use longwall mining method because of its superior safety, high productivity and efficiency. With an increased popularity, there is also an increasing necessity to study spontaneous combustion, its occurrence and management. There have been many theoretical analysis and experimental studies over the past half century hoping to understand the occurrence of coal combustion and its control measures to better understand the occurrence and to design controlling measures to limit the dam-age it causes. In this paper, research on coal spontaneous combustion fundamentals from these three aspects will be reviewed, gaps highlighted and possible directions for future studies. INTRODUCTION The history of anthropic development is the history of human's energy utilization progress. From the first usage of fire, people have been continuingly seeking energy resources on earth. Coal, as an abundant, economic and convenient source of fuel quickly became indispensable and made significant contribution to economic growth worldwide. With technology and societal development, people are becoming more and more coal-dependent, but at the same time, problems of fossil fuel combustion came into sight. In global coal mining industry, spontaneous combustion has now presented one of the most challenging safety issues, it is also believed that it has contributed significantly toward the climate change. It is essential that more effort be invested to examine the cause of SponCom and its control measures. Coal SponCom is a complex process, with both physical and chemical inter-actions among various interrelated factors such as local airflow distribution, ventilation pressure, methane emissions (if any), and physical surroundings underground. With the advent of powerful computers, simulation techniques and af-fordable modelling packages in recent years, significant advances have been made in understanding sponta-neous combustion. But because of the complex nature of combustion and varying underground conditions, there are still areas that need further examining. This paper will focus on illustrating the current research of coal spontaneous combustion and addressing research gaps and future study areas."

Jan 1, 2019

By R. Elliott, C. A. Pickles, J. Peacey

As the nickel sulfide ore deposits become decreasingly viable as a source of nickel metal, increasing attention is being paid to the exploitation of the nickeliferous laterite ores. Attempts to produce a high grade ferronickel concentrate from these ores by pyrometallurgical methods face several challenges, in particular the selective recovery of the highly disseminated nickel from the reduced ore. The current work explores strategies for maximizing the size of ferronickel particles formed in order to improve the selective recovery of the ferronickel by magnetic separation. The effect of various coal, elemental sulphur, pyrite and sodium sulphate additions on ferronickel particle formation and size at 1000°C have been investigated. It has been observed that increased coal additions leads to a moderate improvement in the size of the ferronickel particles, while the presence of any sulphur bearing reagent leads to a significant increase in particle size. The retention of sulphur in the reduced material has also been studied, showing sodium sulphate has the highest retention, followed by pyrite and then elemental sulphur. An inverse trend was observed in the efficiency of sulphur retention on the basis of residual mass of sulphur per unit mass of reagent added.

Jan 1, 2015

By J. E. Nesset, F. Rosenblum, J. A. Finch, R. Payant

ABSTRACT Under certain conditions of moisture and oxygen, sulphides can spontaneously self-heat. We tested a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by the rest potential difference between sulphides and particle size. A series of binary sulphide mixtures was tested. Individual sulphides and mixtures with low rest potential difference did not self-heat, but mixtures of high rest potential difference did. When testing pyrite-sphalerite mixtures, self-heating increased inversely with particle size, with the fineness of the pyrite governing self-heating, indicating the rate-limiting step is the reduction reaction. The results support the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on hydrogen sulphide as an intermediate product is proposed. The understanding gained will be of interest to those involved in storage, shipping, and disposal of sulphides.

Jan 1, 2012

By Oyku Selimoglu

The key to successful mine production plan and subsequent operation is efficient mine layout design and optimization. Pit layout design and optimization allow the delineation and extraction of mineable reserves and the minimum waste subject to slope stability, economic, quality and quantity constraints. Many design and optimization software packages have been developed to aid this intensive and challenging process. These packages include VULCAN, SURPAC, DATAMINE, GEMCOM, MICROLYNX, MEDSYSTEM and MINESIGHT. These software packages are developed as integrated computer-aided systems used for database creation, survey, geological and geostatistical modeling, mine planning and production optimization and environmental modeling. In Turkey, many mining companies still plan and design mine layouts with traditional hand methods. In this study, VULCAN has been used to design and optimize the Eti-Bor A.S. Kestelek Boran Open Pit Mine in Western Turkey. The main objective is to show the company the superior advantages of mine planning software for designing and optimizing mine layouts over the traditional hand methods. Drill hole data used by the company to estimate the reserves for planning are used in this study. The ore grade varies between %1,04 B2O3 to %47,33 B2O3. The pit toe and crest strings are projected using variable batter angles and berm distances. On the north side, batter angle is 180 and berm distance is 25 meters, on the south side, batter angle is 320 and berm distance is 15 meters. In addition to that open pit bench height is 10 meter. The concepts of block modeling are applied to the Kestelek open pit mine with detailed ore grade modeling for each block. The Lerchs-Grossmann?s algorithm is used to optimize this mine based on the block model, the economic block values for each block and the underlying field constraints. The results from VULCAN were similar to the estimates by hand. The reserve estimates from VULCAN is 13,192,870 tons compared with the hand estimate of 13,200,000 tons, overburden estimates of 15,622,889 m3 compared with 15,000,000m3 obtained by hand with a stripping ratio 1.18:1 (m3:ton) from VULCAN versus 1.14:1 (m3:ton) from hand estimate. Vulcan improves the efficiency, speed and reproducibility of the planning results. It provides mining engineers, geologists and surveyors with a cost-effective modular system for assessing and planning the mine layouts. Furthermore, Vulcan?s specific modules allow efficient access and manipulation of databases, open pit mine design, block models, optimized 3D mine layouts, and more. However, for competitive business in Eastern Europe, VULCAN should improve its software support. Effective training, help desk support systems and nearby distributors with just-in-time solutions to company problems will generate competitive business for VULCAN.

May 1, 2007

By J. Shanks

A S far back as 1925, Brazeau Collieries, Limited, became interested in .briquetting. This was brought about by complaints from their principal customer that stack losses, due to a high percentage of fine coal in their mine run, were excessive. The Company considered oil spraying of the fines. This, after some experiments and tests had been made, was ruled out as uneconomical and impracticable. When sufficient oil to be effective was put into the fines, it caused the coal in the tender of stoker-fired engines t0 arch over the screw feeder. The Company ultimately placed their problem in the hands of the Re-search Department of the University of Alberta. Experimental work was carried on by this department over a period of more than a year. The results obtained and the experience gained in this research work were conveyed to Brazeau Collieries in a report dated October 31st, 1929, and in a supplementary report dated February 2nd, 1935. Most of the results obtained in experimenting with Brazeau coal are embodied in a brochure, reprinted from the proceedings of the Second International Conference on Bituminous Coal, Vol. 19-24-28, entitled Principles in the Briquetting of Coking and Non-Coking Bituminous Coals, by E. Stansfield and W. A. Lang. All who are interested in briquetting should read this brochure. In the writer's opinion, iris the most important treatise on the subject printed in recent years. The results given in the paper are, of course, those obtained in laboratory investigation. It was pointed out to the writer that it would be most interesting to have such results correlated with those obtained in commercial practice. In this short paper, an attempt is made to do so.

Jan 1, 1942

By M. Cossette, P. C. A?tcin

At present there is considerable confusion in the asbestos industry with regard to density and porosity measurements of asbestos. In order to clarify the situation, various notions of porosity and density are defined by means of simple schemes and clear symbols are proposed to denote them. An experimental procedure is then preposed and outlined, which is based upon Archimedes' principle. Experimental conditions at each stage of the method are explained clearly in order to minimize the opportunity for errors. Finally, the results of a study on the porosity and density of asbestos minerals having various characteristics are presented.

Jan 1, 1972

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By Songgen He, Jianchun Guo

With the development of complex, unconventional and deep reservoirs, it shows that many rocks behave plastically with the influence of clay and confining pressure. Traditional linear elastic hydraulic fracturing initiation models are not good predictors for elastic-plastic reservoirs. With the deformation theory of plasticity, a power hardening constitutive equation was developed in piecewise approximation method. Based on the nonlinear constitutive equation, a model of the stress field around the wellbore was developed considering fracturing fluid penetrating effect and in-situ stress anisotropy. At last, coupled with the maximum tensile strength criterion and Mohr-Coulomb criterion, a new elastic-plastic hydraulic fracturing initiation model was built. The following conclusions were summarized in the paper: (1)The piecewise power hardening constitutive equation based on the deformation theory of plasticity can accurately describe the nonlinearity of elastic-plastic deformation. (2)Whether the rock is yielded or not is determined by in-situ stress, yield stress, Biot coefficient and pore pressure. (3)Plastic yield has little influence on radial stress but significant impact on circumferential stress. The radius of the plastic zone is positively correlated with in-situ stress but negatively correlated with yield stress, power hardening index, pore pressure and Biot coefficient. (4)Initiation modes include tensile failure and shear failure when rock is yielded. (5) For elastic-plastic reservoir, the initiation pressure predicted by linear elastic model is much lower if the rock is yielded.

Jan 1, 2015

By Robert B. Parsons

"Starting January 1, 1987 employers, employees, and other taxpayers are confronted with a new set of rules dealing with the taxation of travel and housing benefits relating to isolated posts in Canada, and tax deductions relating thereto. The new rules may not be the simplest in the world, but they are reasonably fair and at least offer a hitherto unknown degree of certainty as to how such allowances are to be treated. IntroductionThe first shoe fell on February 26, 1986 when Finance Minister Michael Wilson' s first budget presented the framework for the future tax treatment of travel and housing benefits (so-called ""northern allowances"") provided to residents in remote regions of Canada. The second shoe fell some ten months later on December 22, 1986 when the Minister of Finance filled in the earlier announced framework with detailed rules. We now have a complete picture of the tax treatment of northern allowances. Here is what the picture looks like with effect from January 1, 1987.According to Revenue Canada, the net housing benefit to employees will be equal to the value of the accommodation provided, less any rent they have paid. In major centres such as Yellowknife and Whitehorse, having a developed rental housing market, the benefit amount will be based on the fair market value of the rental accommodation in that location. In other areas, employers will be required to value the housing benefits and, to assist employers, Revenue Canada has provided the following guidelines: Common shelter- $100 per month including the value of subsidized utilities Apartment! duplex-$270 per month excluding the value of subsidized utilities, or $400 per month including the value of subsidized utilities House-$450 per month excluding the value of subsidized utilities, or $650 per month in- c1uding the value of subsidized utilities.The amounts established as the values of accommodation will be adjusted annually after 1987 based on the housing component of the Consumer Price Index."

Jan 1, 1987

By K. Chattopadhyay

Fluid flows in metallurgical reactors play a vital role on liquid metal cleanliness for both ferrous and non-ferrous metallurgy. Thus, it is absolutely critical to understand different fluid flow mechanisms, and the use of computational methods to model the complex non-isothermal, turbulent, single- and multiphase-flows, has to be appreciated. The present case study emphasizes on controlling the flow of liquid steel in a tundish and enhancing liquid metal cleanliness. CFD modeling was used to build a robust mathematical model, and effects of flow control furniture and non-isothermal conditions were analyzed. The mathematical model was validated against water model experiments. Parameters that were conducive for inclusion removal were identified and implemented in the plant. Some flow control devices could increase inclusion removal to a great extent compared to the existing configurations. In cases, where a hot ladle was poured into a relatively cooler tundish, inclusion removal was better, whereas results were catastrophic in cases where colder liquid was poured from ladle to the tundish. Similar techniques can be applied for other liquid metals including light metals and non-ferrous metals.

Jan 1, 2015

By K. Yamaguchi

"This Precious metals content copper scrap is treated with a copper smelting process, and copper and precious metals are recovered. The precious metal lost in the slag is increasing with increasing of treated scrap amount. To determine the portion of the precious metals chemically dissolved and that associated with the mechanically trapped matte in the slag will be a key factor to improve the recovery of those metals. The distribution of precious metals between copper matte and FeOx-SiO2 slag phases is determined at 1300 oC and a fixed partial pressure of SO2 of 0.1 atm for the matte grades from 40 to 70 mass% of copper. The distribution ratios show a tendency to increase when the grade of matte is increased. In addition, the solubility of platinum and rhodium in the FeOx-SiO2-CaO slag under the air and the solubility of platinum in the FeOx-SiO2 slag equilibrated with a pure platinum or the Pt-Cu alloy were determined at 1300oC in the range of oxygen partial pressure from 10-9 to 10-7. The solubility of platinum and rhodium in the slag tends to increase with increasing content of copper in the slag and oxygen partial pressure. INTRODUCTIONThe stringency of the supply and demand of platinum group metal (PGM) intensifies by localization for resources and increase of the demand for PGM, furthermore, smelting and the recycling of PGM in the nonferrous smelting process take an important role. Scrap containing a precious metal for the purpose of collection of PGM is treated by copper smelting recently. With increase of the treatment amounts, loss of PGM in slags is the serious problem.In considering of PGM loss in slags, knowledge of the distribution behavior for PGM between slag and matte phases or slag and copper phases and the PGM solubility in slags is important. The distribution ratios of silver and gold between the FeOx-SiO2 slag and the Fe-Cu matte were reported by Roghani (Roghani et al., 2000), Shinha (Shinha et al., 1985) and Takeda (Takeda et al., 1993) However, there is no data for the PGM distribution ratio. On the other hand, the PGM solubility in slags was reported by Sano (Sano et al., 1997) However, there is very few report for the solubility of PGM in the nonferrous smelting slags."

Jan 1, 2012

By G. A. Vissac

In this paper we intend to deal particularly with the economic side of coal washing as it applies to our mines. We will then discuss why the dry-cleaning process has been selected, and give a brief description of our plant, dwelling only on its specific features and referring the reader to the numerous papers published on the subject for any details on the principles and machinery used in dry cleaning. ECONOMIC DISCUSSION The washery introduces an extra cost for depreciation, operation, and loss in treatment. A certain proportion of the coal, now being sold, and which the miners have been paid for. will have to be wasted. As a whole, the total increase in cost would be approximately 60 cents per ton. On the possibility of recovering this amount depends the success of the washery. There are two advantages to be expected from the washery, the first, which occurs at the mine and which will be certain; the second, more difficult to estimate, because it depends upon convincing our customers that they should pay more for a better product.

Jan 1, 1924

By Jochen Petersen, Jean-Paul Franzidis, Allan Nesbitt

This study presents a method for the determination of intra-particle diffusivities in ion-exchange resins for the purposes of evaluating the state of resin degradation during service. The method uses a zero length column (ZLC) in a closed circuit with variable speed pump and reservoir. The intra-particle diffusion is determined from absorption data by using the Nernst-Plank approximation along with the ‘mass transfer factor’ - which is a product of the mass transfer coefficient (kf )and the concentration of the adsorbing ion in the liquid at the surface of the resin - in a computer algorithm fitting simulated curves to experimental data.. Through this approach the changed intra-particle diffusivity, of a gel-type acid resin, over a 1000 loading and elution cycles, is shown.

Jan 1, 2014