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By K Hines

Anglo Platinum is the worldÆs largest producer of platinum group metals, and also produces large quantities of nickel, copper and cobalt at its Refining complex in Rustenburg, South Africa. In 1995 Anglo Platinum embarked on a smelter modernisation project, primarily to reduce site emissions to below the guideline limit of 20 tonnes per day SO2, but also to increase the converting capacity in line with future projected production profiles. To achieve these requirements the existing Pierce Smith converters were replaced with a single large Ausmelt converter and a new acid plant. This was the first time that an Ausmelt furnace had been used for converting, but it had the advantages of being a very robust furnace and was fully enclosed, giving good gas capture. It was thus considered the most appropriate technology from both a process and an environmental perspective. It also enabled the smelting and converting furnaces to be decoupled. The plant was commissioned from late 2001 and the first tap was in June 2002. Despite being a new technology, ramp-up has been similar to other large scale pyrometallurgical operations. Numerous process improvements have been made since start-up, most notably a change from two-stage batch to fully continuous, resulting in the plant now operating above design in terms of throughput. Optimisation of freeboard accretion control was also a major component of the ramp-up activity. This paper discusses the commissioning and ramp-up issues of the new Ausmelt converting furnace, concentrating on the design and process changes, and summarises current operating performance against the original design objectives.

Jan 1, 2005

By M Fimeri, R Williamson

Sample sizing in the iron ore industry requires significant manual effort to collect, transport, and sieve the samples as well as record, process and report the data. Efforts have been made to automate this process, which essentially emulate the manual process, except that a person is replaced by a robot. Even in these cells, the sieving and sizing operation consumes a significant proportion of robot time. The proposed doubling of production from AustraliaÆs iron ore mines over the next five years will place increasing pressure on sample sizing and interest is increasing in alternative automated methods. One such method is the adaptation of computer vision technology which has been successfully introduced into the mining industry in a range of applications including feed size distribution to SAG mills and oversize detection from screening stations. The limitation of this technology is that only the top surface is visible and this is used as an indicator of total size distribution. Obviously in a sample plant, where 100 per cent of the sample must be measured for acceptable quality assurance, this approach is unacceptable. In order to capture 100 per cent of the sample using computer vision technology a monolayer must be formed either by spreading the sample across a moving surface, such as a conveyor or vibrating platform, and passing this under a camera. This will become a æsurgingÆ load which presents specific problems for some types of computer vision systems, namely those relying on a 2D approach. In this paper a 3D computer vision technology will be described which overcomes the problems associated with measuring particle size in a monolayer and experimental results will be presented which demonstrate its effectiveness for lump and fine iron ore sample size measurement.

Jan 1, 2008

By J Mauk, R Ruddock

The Taharoa ironsand deposit is 1600 hectares in size and is located 144 km south of Auckland on the west coast of the North Island, New Zealand. The sand predominantly contains heavy mineral-rich sediments, quartz, and feldspars. One hundred and two samples were collected from all areas of the mine, from the stockpile, black sand areas, tailings and Te Akeake Sands. Samples were collected with the primary focus on the next predicted mining path and secondly on gaining a good geographic spread throughout the mine. All samples were analysed for the dry, wet and particle density, the porosity and the magnetic, non-magnetic and clay minerals content.Stockpile samples had an average magnetic mineral content of 92 percent. Dry, wet and particle density values for stockpile material exceed all values from untreated ironsand samples with average values of 2.8g/cm3, 2.9g/cm3 and 4.4g/cm3 respectively. Black sand samples from the mine came from various areas such as the central area, the forest, the southern area and the benches. All black sand samples are remarkably consistent, with dry and wet density values between 2.3 û 2.5g/cm3 and particle densities that range from 3.7 to 3.9g/cm3. The porosity values are comparable to all other areas of the mine (average 37 per cent). The tailings and Te Akeake Sands have different physical properties due to their different mineral contents. The dry, wet and particle densities are all lower than that of all other areas with averages of 2.1g/cm3, 2.2g/cm3 and 3.3g/cm3 respectively. These lower values reflect the lower magnetic mineral content (average 18 per cent) and the associated increase in non-magnetic mineral content (average 78 per cent).

Jan 1, 2002

By K C. Corin, C T. O’Connor

In recent years it has been shown that the concept of using partial molar excess Gibbs energy (G̅ex) to explain the behaviour of collectors in the recovery of minerals can be usefully applied to explain flotation performance. Fundamentally this is because hydrophobicity of a mineral particle on which a collector is adsorbed may be strongly related to the fact that the alkyl chain associated with the collector behaves in the same way as any hydrocarbon would in an aqueous medium. This hydrocarbon-water system represents a classical non-ideal mixture, and such mixtures are quantified thermodynamically by determining the activity coefficient of the hydrocarbon moiety of the collector and hence its G̅ex in the mixture. It has been shown that G̅ex is a more rigorous indicator of the contributions of various alkyl groups of a collector than HLB (Corin and O’Connor, 2014) and was also able to explain aspects of froth behaviour (Harris and O’Connor, 2017) and hydrophobicity (O’Connor, 2021). The present paper is aimed at extending the above concepts in two different ways. Firstly, a study is undertaken of a range of results previously reported in which various reagents containing different alkyl groups were analysed in terms of their effect on contact angle and their performance as flotation reagents in terms of recovery. These results sustain the previous observations that there is a robust positive relationship between hydrophobicity as indicated by flotation recovery and contact angle and G̅ex of the alkyl group associated with the collector. Secondly, on the basis of the observation that increases in G̅ex are indicative of increases in the hydrophobicity of the mineral particle-collector aggregate, a study was undertaken to examine the effect of ions typical of electrolytes in water as well as the effect of the presence of alcohols and of pH on G̅ex of the collector alkyl group. In the former two instances the absence of any correlation between G̅ex and recoveries supported the proposition of the respective authors of these studies that the major effect of these electrolytes and added alcohols may be on particle–bubble attachment rather than on the hydrophobicity of the mineral/collector in the aqueous system. On the other hand, the effect of pH on G̅ex correlated reasonably well with changes reported in the literature on the effect of pH on recovery and contact angle.

Aug 24, 2022

By T C. Souza Pinto, M Safari, F S. Hoseinian, D Deglon, L Leal Filhoc

In this study, the effect of hydrodynamic parameters on the iron ore reverse was investigated in a mechanical flotation cell. The work carries out using the case study of Iron ore from Vale in Brazil. The influence of hydrodynamic factors such as froth height, impeller speed, superficial gas velocity and solids percentage were evaluated on the quartz flotation. The results showed that the hydrodynamic conditions have a great effect on the flotation performance, especially on the fine and coarse quartz. The size-by-size analysis of the froth products showed that froth height, impeller speed, superficial gas velocity and solids percentage have a significant effect on true flotation quartz particles. The increase in the froth height decreased the recovery of quartz particles. The increase in the impeller speed increases the recovery of quartz particles to an optimum. The increase in the superficial gas velocity improved the flotation of coarse quartz particles. The increase in the solids percentage increases the recovery of quartz particles.

Sep 18, 2023

A major new mine to be developed at Pike River during 2005 has been designed to have a minimal impact upon the environment, and an overall net conservation gain. The Pike River Coalfield is located on the West Coast of the South Island of New Zealand on the top of the Paparoa Range approximately 46 km north east of the coastal town of Greymouth. Pike River Coal Company Ltd (PRCC) holds a 40 year mining permit over the coalfield.   In October 2004, the Minister of Conservation granted PRCC access through 1.25 km of Department of Conservation land via an access agreement, and the Environment Court issued a number of consents for the development and operation of the mine, in addition to some existing consents.   The underground mine at Pike River is located under land administered by Department of Conservation, and has been designed to avoid or mitigate adverse environmental effects and integrate into the natural bush surroundings. The mine process has been designed to operate within an environmentally sensitive area and will incorporate technologically advanced methods of mining and processing. The mine process involves hydro mining of the coal, and transportation via a 12 km coal water slurry pipeline, to a dewatering complex located on PRCC land. This will ensure that traffic in the Pike River Catchment up to the mine is minimised.   An extensive series of management plans and monitoring programmes will be used to ensure that the environmental effects of the mine activities are minimised, by evaluating the performance of managerial procedures, and physical mechanisms in place to avoid or mitigate the effects. Trial mining and substance management plans in conjunction with an orthophoto and surface monitoring protocol will ensure that surface features, and water ways are protected from any adverse effects. The Blue Duck enhancement, and pest and predator control programme will help ensure that an overall net conservation gain is achieved.   Developing transparent working relationships and good communication with Department of Conservation, Iwi (Ngati Waewae and Ngai Tahu), and local environment groups has been and remains very important in the development of this project.

Jan 1, 2005

This is the time of year tor the presidential address, and with the present incumbent engaged in the coal mining industry, it will therefore come as no surprise to you that the theme of my address this evening is concerned with coal.There are other reasons for this apart from my contact with the coal industry. At present, coal is supplying considerable overseas revenue at a time when the remainder of the mining market is in a somewhat depressed state. That times will change goes without saying, if history is to be believed.However, so far so good for coal. My first reaction when The Institute indicated its wish that I be president for 1976 was to become deeply conscious of the honour bestowed on me.On consideration, I realized that very few past presidents have been intimately connected with the coal mining industry to the extent of indulging in it for lengthy periods as a full time occupation or, conversely, a part time interest for a long time. It also appears that not one had started their career in the industry. In my case, 'also, there were 8 very interesting years ,as a gold miner and metallurgist before commencing in coal.It therefore seemed appropriate to endeavour to discover ,why this should be so, as coal mining is now a very important part of a very important industry. What were the reasons why the industry took so long to emerge when there were ample reserves of easily accessible coal?Frankie and Johnnie in their bar room epic of the depression years concluded, and I paraphrase, that "their story held no moral, their story told no tale". If my story has such a message, it could perhapsbe construed as reinforcing the oft-repeated dictums, true or false, that "history repeats itself" or "man never learns".Coal mining is by far our oldest major Australian industry except for agriculture. Its history is almost as old as that of settlement:For various reasons, there has been a glamour associated with metal mining ventures which prob...

Jan 1, 1976

By J Vann, S Jackson, O Bertoli

Ordinary kriging and non-linear geostatistical estimators are now well accepted methods in mining grade control and mine resource estimation. Kriging is also a necessary step in the most commonly used methods of conditional simulation used in the mining industry. In both kriging and conditional simulation, the search volume or ækriging neighbourhoodÆ is defined by the user. The definition of this search can have a very significant impact on the outcome of the kriging estimate or the quality of the conditioning of a simulation. In particular, a neighbourhood that is too restrictive can result in serious conditional biases. The methodology for quantitatively assessing the suitability of a kriging neighbourhood involves some simple tests (which we call æQuantified Kriging Neighbourhood AnalysisÆ or QKNA) that are well established in the geostatistical literature. The authors argue that QKNA is a mandatory step in setting up any kriging estimate, including one used for conditioning a simulation. Kriging is commonly described as a æminimum variance estimatorÆ but this is only true when the neighbourhood is properly defined. Arbitrary decisions about searches are highly risky, because the kriging weights are directly related to the variogram model, data geometry and block/sample support involved in the kriging. The criteria to look at when evaluating a particular kriging neighbourhood are the following: the slope of the regression of the ætrueÆ block grade on the æestimatedÆ block grade; the weight of the mean for a simple kriging; the distribution of kriging weights themselves (including the proportion of negative weights); and the kriging variance. Outside of the technical geostatistical literature, there is little in the published domain to describe the nature of QKNA and no practical presentation of case examples. In this paper we attempt to redress this by setting out the calculations required for QKNA and defining some approaches to interpreting the results. Several practical worked mining case examples are also given. Finally some comments are made on using the results of QKNA to assist with block size selection, choice of discretisation and mineral resource classification decisions.

Jan 1, 2003

By D B. Donato

Gold mining cyanide-bearing solutions can pose a risk, cause significant wildlife deaths and adverse public relations and result in non-compliance with regulatory conditions. The International Cyanide Management Code for the Manufacture, Transport and Use of Cyanide in the Production of Gold (the Code) was developed as a voluntary code to encourage industry-wide improvements in managing cyanide responsibly. The Code requires design and implementation of robust monitoring programs for compliance under the following standards of practice: 4.1, 4.4 and 4.9. A robust monitoring regime can be complicated as each processing and tailing system is different. The following systems are commonly used in Australia: carbon-in-leach (CIL); carbon-in-pulp (CIP); heap leach process ponds; tailing waste disposal systems; peripheral discharge, central discharge and in-pit disposal. Some terrestrial wildlife can be denied access by fencing tailing storage facilities (TSFs) or other physical barriers, therefore limiting wildlife interaction with cyanide-bearing tailing and solutions to mainly birds and bats. While wildlife monitoring programs for processing and TSFs contain similar core attributes, it is necessary to adapt monitoring to take into account the site-specific features of each system. These core attributes are discussed in this paper, with reference made to cyanide concentration and associated methodologies. The issue is considerably complicated if tailing solutions are deemed or discovered to be toxic to wildlife. Essentially cyanides are required to be measured to gain an understanding of the concentrations to which wildlife may be exposed. This usually equates to measuring the cyanide concentration of solutions entering and leaving a tailing system. To assess the risk to wildlife presented by tailing and heap leach systems it is necessary to monitor both the hazard (cyanide concentrations) and the exposure (live wildlife species, presence and interaction). These tasks need not be arduous and a system of simple frequent monitoring has been developed and implemented for Code compliance. The wildlife monitoring developed by Donato Environmental Services (DES) and used at mining operations departs from the industry norm. It documents observer effort, live wildlife presence, habitat and behaviour in a tailing system, as well as deaths and carcasses. A greater understanding of wildlife cyanide toxicosis associated with this monitoring approach will enable mining companies to adopt a proactive approach to significantly reduce, or preferably eliminate, the impact on wildlife and assist in gaining Code compliance.

Jan 1, 2007

By B Cope, N Hastings, D Webb

A Feasibility Study was completed in late 2002 to ascertain the risk and reward profile from the proposed deepening of operations at Perseverance Nickel Mine in Western Australia. The system and approach adopted to this brownfields extension work is outlined and the main components of the study are overviewed. In particular, emphasis is given to the integration of mine design and scheduling tools through to financial evaluation. Detailed comment is given on the ability of the system used to provide a robust project schedule complete with 3D animation. The level of importance in eliminating scheduling errors is demonstrated in relation to the reported bottom line viability of the project. It is suggested that this is an area where brownfields Feasibility Studies have lacked clarity and authenticity, leading to the creation of an unrealistic benchmark for project implementation.

Jan 1, 2003

Now that Japan has achieved a remarkable high growth and joined the ranks of economic powers, she is required to take a stance proper to her new position toward international co- operation among Western advanced countries, economic/technical aids to Southeast Asian and Pacific LDCs, and others. As a field subject to such international cooperation programs, the development/use of coal resources has been winning increasing attention in recent years. Coal is positioned as one of promising alternative energies. With Southeast Asia plus Japan and the EEC serving as the two nucleus polar regions, total coal demand in the free world is projected to jump 37% in the year 2000 from the present level and steaming coal imports in the world, primarily destined for power generation, almost double the 1983 level. Such being the situations, Japan's tech- nologies related to coal resource development, if successfully introduced into coal-producing countries to help them boost their production, can directly lead to international cooperation that Japan is now required to fulfill. At home, however, the Japanese coal industry has been just on the wane due to various press- ing problems, such as wider differentials between overseas and domestic coal and deeper/ remorter mining. The industry was named atop in a list of the industries requiring restruct- uring at a meeting of the Economic Structure Study Committee held prior to the decision- making of the 8th coal policy, which slashed coal production planned for the last fiscal year of its life to some 10 million tons, a drop of as much as 50% from nominal output planned in the 7th policy. Under such circumstances at home and abroad, a pioneer study has been under way since fiscal 1984 as part of Japan's energy cooperation in the Pacific. The study is based on the Pacific coal flow concept hammered out by the Agency of Natural Resources and Energy of the MITI.

Jan 1, 1987

By D J. Williams, M S. Zbik, A Shokouhi

There is a considerable difference in the particle size distribution (PSD) of clay mineral-rich coarse coal reject with variations in the test moisture state and the chemistry of the water used for testing. The coarse coal reject tested were collected from Jeebropilly Mine, located in the Ipswich Coalfields of south-eastern Queensland. Differences between the results of dry and wet sieving analysis indicate a significant breakdown of the clay mineral-rich coarse coal reject on wetting-up. Wet sieving caused a breakdown of the gravel-sized fraction to silt and clay size without significant breakdown to sand size. There is also a considerable variation in the results of hydrometer analyses of the clay mineral-rich coarse coal reject with variations in the chemistry of the water used, particularly at the fine end of the particle size range. The waters used included tap water, coal processing water and deionised water. In addition, the method of dispersion applied prior to hydrometer analysis can have a significant effect on the PSD of clay mineral-rich coarse coal reject, with boiling and sonic vibration causing the most breakdown of the clay particles. This paper describes the testing methodology used and the test results obtained, and attempts to explain the results in terms of clay mineralogy and water chemistry.CITATION:Shokouhi, A, Williams, D J and Zbik, M S, 2015. Influence of water on particle size distribution of clay mineral-rich coarse coal reject, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 239–246 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By Moxon NT, Torrace AC

The detonation pressure of an explosive is a function of its density and its velocity of detonation (VOD) and relates directly to the degree and manner in which the explosive loads the surrounding rock. The suitabil- ity of an explosive to any particular situation is determined not so much by the total energy released but more by the rate at which it is released. As the science of rock blasting advances it is becoming economically more important to quantify explosive performance, particularly with respect to quality control and fragmentation. As part of a major explosive user, BHP Central Research Laboratories have developed a number of tech- niques to determine the detonation characteristics of explosives. These include a method of continuous velocity of detonation measurement based on the SLIFER principle. This not only enables the VOD of the explo- sive to be determined, but also has the versatility to allow factors such as under priming, slow run up, the effect of water, variable energy load- ing and the velocity of the shock wave in the stemming to be assessed. Multi point VOD systems have also been developed for more routine appli- cations. With a minor modification they can be used to determine the absolute delay of detonators accurately and economically. Direct deto- nation pressure measurement methods have also been developed based on piezoresistive techniques. Future developments include the incorpo- ration of all the above techniques into a single, portable package, allow- ing easy use on the mine site.

Jan 1, 1988

By R Dunne, S Hart, G Levay

While water represents a major proportion of the mineral pulp processed in flotation circuits, relatively little research effort has been committed to understanding and controlling the influence of water quality on this process. Historically, this probably stems from the perception of water as an inert transport medium. However, the changing attitude towards water as a valuable resource, has given impetus to increasing requirements to use relatively impure make-up water supplies such as treated effluents and a high proportion of internally recycled water. In turn, this has resulted in the need for a more detailed focus on process water quality and its control to minimise adverse effects on sulfide flotation. Along these lines, prior to commissioning of a new concentrator at their Cadia Hill Gold Mine, Newcrest Mining was proactive in examining potential water sources and the influence of water quality on flotation of their copper/gold bearing ore. An extensive water quality survey of all major potential water supplies to the concentrator was undertaken. The flotation performance of the Cadia ore in each of these waters was investigated on a laboratory scale. The results of these studies identified that water quality could indeed have a significant influence on the flotation process. Since operations at the Cadia Hill concentrator began, water quality surveys of both make-up water sources and recycled flotation circuit waters have been carried out on a regular basis. By doing this, a database of water quality has been established which can be compared with plant performance. In parallel with the water quality surveys, a series of laboratory flotation tests have been conducted using a standard ore and waters from various streams to monitor changes in flotation performance as a function of water quality. These tests have indicated that certain water types may have a significant influence on plant performance. More research is required to better understand the impact of water quality on sulfide flotation. This understanding will help operators to minimise adverse effects, while maintaining the best utilisation of available water resources.

Jan 1, 2003

By G Chitombo, G Lewis

The knowledge of the expected run of mine (ROM) fragmentation during the feasibility study of a green field site is essential for the design of downstream crushing and milling processes. However,the prediction of blast fragmentation can be a challenging process due to the uncertainty related to the blast design and rock mass parameters. In general,a number of possible blast designs are considered in a feasibility study,with factors such as bench height and blasthole diameter influencing the design. Rock mass parameters are normally derived from a limited number of geotechnical diamond drill cores. Although diamond drill core can provide detailed information concerning intact rock strength (unconfined compressive strength and point load),it provides limited structural information to predict the in situ block size distribution of the rock mass. The in situ block size is an essential input to the prediction of the fragmentation distribution, in particular the coarse end. This paper outlines the methodology of blast fragmentation modeling undertaken for a green field feasibility study at the Riska gold deposit in Indonesia. The favoured milling process for the feasibility study was dump leaching,with no crushing of the ore material extracted from the pit. For this reason,blast fragmentation was a critical issue to be addressed by the study. A range of blast designs were considered with bench heights and blasthole diameters ranging from 4 m to 7 m and 76 mm to 102 mm respectively. Rock mass data was obtained from 19 diamond drill cores across the deposit (total drill length approximately 2200 m). Intact rock strength was estimated from qualitative strength descriptors,while the in situ block size distribution of the rock mass was estimated from the Rock Quality Designation (RQD) of the core. The methodology of fragmentation prediction involved a number of steps including the estimation of rock mass parameters from diamond drillhole data including the estimation of the in situ block size, delineation of blast domains within the deposit,and the assessment of the impact of various blast design parameters and rock mass variation on the predicted fragmentation distribution. The modelling process for the Riska green field site highlighted the need for additional rock mass data to be collected post feasibility stage and once the development of the mine commenced.

Jan 1, 2004

By Saghafi A, Kelly M, Williams R. J

A two year program of research into the feasibility of long-hole drilling for improved gas emission control has been undertaken at Appin Colliery. State of the art equipment was employed involving cableless electronic surveying and down-hole motor drilling. The project involved the drilling of 1000 m long, in-seam boreholes in the Bulli seam and boreholes of similar length drilled cross measure and then in-seam along the underlying Balgownie seam. A new concept for gas drainage was defined, employing long-holes for both predrainage and post drainage.

Jan 1, 1988

By D Ray, D Brett

A clay-capping trial was established in 1996 on Magazine Dump at the Mt Lyell Copper Mine. The trial was initially constructed under the Mount Lyell Remediation Research and Demonstration Program, a co-operative venture between the State and Federal governments. The detailed engineering design for the clay cover included the following features; reshaping and compaction of dump batters, 5 m vertical bench interval, overall side-slopes of 2.5:1, emplacement of clay in four 150 mm lifts, compaction by a 10 t vibrating roller or ætrack rollingÆ on batters with density testing for quality control. A small section at the base of the dump ( The trial also generated certain unexpected findings. Field permeability tests on the cover yielded uncertain results and oxygen remains available throughout the dump. The flow data indicate that, while total outflow has decreased as a result of storm shedding, inputs from groundwater and batter infiltration are still significant. Outflow during the driest weeks of the year may have risen following capping. Detailed assessment of the data is hampered by insufficient pre-capping information; however, there is a possibility that conductivity flux emitted when flows in the receiving environment are at their annual minimum is unchanged or worse post-capping.

Jan 1, 2003

By Jiaxin Zhou

Acid mine drainage is a serious and chronic environmental problem of mining. This paper discusses the factors affecting the rate of acid generation by mine rocks and illustrates the relevance of these factors to the mines of the Northern Territory, Australia. The factors may be divided into two groups: internal factors and external factors. The first group covers characteristics of ores, mine waste rocks, tailings, etc and the second group covers surrounding conditions. The latter is further divided into four sub-groups, viz surrounding temperature and pressure, chemical conditions (ferrous/ferric adsorption ratio, total iron concentration, oxygen concentration and pH), surrounding biological conditions and mechanical conditions. Special attention is given to the surrounding P-T conditions, especially water partial pressure, and its relevance to the Northern Territory mines.

Jan 1, 1994

By B, G Strobos, J P. Maree, N Smit

In mining and processing operations where minerals, high in pyrite and low in calcite/dolomite are processed, acid is generated, which needs to be neutralised. Ticor at Empangeni in South Africa (SA) produces rutile (TiO2), leucoxene (TiO2 plus iron compounds), titanium (Ti), zircon (Zi) and ilmenite (TiO2 plus iron compounds). Neutralisation is required in the processing plant where acid is leached into the wash water. This water needs to be treated to a quality suitable for re-use in the metallurgical process or to a higher quality to make it suitable for discharge into the Empangeni sewage system (SA). For re-use the water needs to be neutral and under-saturated with respect to gypsum while for discharge into the sewage system the sulfate concentration needs to be reduced to less than 500 mg/L (as SO4). Acid mine water is generally neutralised with lime. Disadvantages associated with lime are the costs and maintenance of the slaking equipment as well as hazards, associated with handling of the alkali. The cost of powdered limestone (CaCO3) in South Africa, a by-product, is 50 - 60 per cent cheaper than lime. A technology has been developed where limestone is used for neutralisation of acid mine water instead of lime. This development includes: Limestone handling and dosing system. A novel, robust system has been developed where waste CaCO3 from the paper industry is slurried to a constant density. A full-scale plant was constructed to evaluate its performance (Figure 4). The dosing system consists of an inclined slab onto which the limestone is stored and from where it is slurried into a make-up tank. The density of the slurry in the make-up tank is controlled via a loadcell that measures the weight of the tank (operated at constant volume) and activates/deactivates the spray of the recycle slurry onto the slab. Integrated limestone neutralisation/lime treatment process. In this process powdered CaCO3 is used for neutralisation and partial sulfate removal of acid leached from the coal washing plant. The sulfate concentration can be further reduced to below the saturation level of gypsum (ie 1200 mg/L) through gypsum crystallisation by means of lime treatment, resulting in metal precipitation (eg Fe3+ and Al3+). CO2- treatment for CaCO3 precipitation. The pH of the lime treated water can be adjusted to pH levels of 8.5 and lower using CO2. The CO2, generated during limestone neutralisation (Equation 2), can be captured and used in this stage of the process. The first two stages (limestone- and lime neutralisation) of this technology have been implemented on full-scale at Ticor to treat the effluent of the process. The constructed plant is 80 m3/hr and differs from coal processing plants by way of not containing Fe(II) and Fe(III) in the water. The CO2-treatment stage (Stage 3) will soon be implemented at IHM as part of a program to optimise the technology for maximum benefits.

Jan 1, 2003

By N TassT, J Cyr

At the East Sullivan site, wood wastes covering the abandoned mine tailings impoundment prevent sulfide oxidation by creating an anoxic environment. The addition of coarse ligneous wastes and their high permeability favour infiltration, resulting in a water table rise that maintains most tailings under water saturation and thus provides an additional protection against sulfide oxidation. Moreover, high infiltration allows a more rapid flushing of acid prone groundwater generated prior to the cover placement, which could cause acid mine drainage over a long period of time. Finally, the pore-waters under the cover are characterised by a strong reducing potential, high alkalinity, and near neutral pHs. These conditions favour sulfate reduction and base metal precipitation as sulfides and as carbonates. Pore-water composition monitored from 1992 to 1998 showed a significant Fe2+ decrease, following cover placement. Thereafter, the restoration strategy capitalised on the alkaline and reductive properties of the waters underlying the wood-waste cover. An original treatment of acid effluents, based on the recirculation of water discharging around the impoundment through the organic cover, was implemented. In 2002, the recirculated water from May to October had a mean pumping rate of 240 m3/h, for a total volume of 800 000 m3. Data gathered near the dispersal zone from 2000 to 2002 show that despite the recirculation of acid water (pH ÿ3), the pH decreases by only one unit from 7 to 6, during the recirculation period, ie from May to November. However, alkalinity decreases from 800 to 100 mg/L-CaCO3. Despite this decrease, the alkalinity is back up to 800 mg/L-CaCO3 the following May, thanks to sulfate reduction. From 2000 to 2002, Fe2+ concentration in the pore waters near the dispersal zone is maintained below 2 mg/L. Evolution of surface water quality suggests that the contaminated groundwater flush is completed in the north and north-west area of the impoundment; the east sector is under recovery, while the south sector remains the most problematic. A wood-waste cover, besides limiting sulfide oxidation, can fill the role of alkaline reducing barrier for the treatment of these acidogenic waters, until a balance between acidity and alkalinity in the effluent is reached.

Jan 1, 2003