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By Chamberlain A. C, Fisher N, Avraamides J

The thermal decomposition of sodium ethyl xanthate (SEX) adsorbed onto activated carbon was studied by coupled thermogravimetric analysis-Fourier transform infrared spectroscopy (TG-FTIR). Two discrete mass losses were observed, in the temperature ranges 100 - 230¦C and 200 - 340¦C. The same two gases, carbonyl sulphide (COS) and carbon disulphide (CS2), were the main gases evolved in each of the mass losses. Samples of activated carbon from two industrial plants were obtained and analysed by TG-FTIR. COS and CS2 were not detected in one of the samples. The other sample did show evidence of COS and CS2, which indicated that fouling of the carbon by SEX was still present. Other organic compounds were detected in the evolved gas stream of both samples, indicating the presence of organic reagents other than SEX.

Jan 1, 1996

By Sorokin M. L, Komkov A. A

Flash smelting of nickel sulphide concentrate has been practiced at WMC's Kalgoorlie Nickel Smelter for 20 years. The mineralogy of the concentrate from the original mines was particularly suited to this process. However, taking a strategic view, potential new processing routes should be fully evaluated as possible replacements for the current technology. The Vanyukov process has been under development in Russia for the past 40 years and has been successfully applied on a large scale to the smelting of copper concentrates, at two locations - Norilsk and Balkhash. The potential for the application of the Vanyukov process to the smelting of nickel concentrates offers a number of processing advantages, including smaller reactor and decreased dependence on fuel oil. This paper reports on preliminary investigations into the application of the Vanyukov process to the smelting of nickel concentrates. At this stage the investigations are limited to semi-quantitative comparisons and modelling studies.

Jan 1, 1992

By Gao K, Wu C, Langley J. M, Waugh B, Farrell K

The dissolution of carbon from carbonaceous materials into molten iron is a key step in various ironmaking operations. For example, in new direct smelting processes, carbon in the form of coal is injected into the molten iron bath, which leads to the dissolution of carbon. In foundry operations, typical recarburizer materials can range from high purity graphite to chars. The dissolution performance of these" materials is critical to the operation and could dictate the efficiency and economics of the process.Dissolution kinetics has been studied by various investigators to explain the influence of melt conditions and carbon type (Sahajwalla et al, 1994; Shigeno, Tokuda, and Ohtani, 1985; Orsten and Oeters; 1988; Ganguly and Reid, 1992; Wright and Taylor, 1993). The influence of melt sulphur content on the dissolution kinetics has been characterised (Sahajwalla et al, 1994), with sulphur retarding the rate of carbon dissolution. The carbon dissolution from different sources is seen to vary significantly even under similar melt conditions. This observation has been explained by investigators on the basis of the varying ash content present in the carbonaceous materials. However, ash content alone cannot account for the variability in dissolution kinetics reported in other studies. One such study is presented below.In a recent study (Sahajwalla et al, 1994), pulverised carbonaceous materials were injected into the molten iron bath and the" dissolution kinetics was established. The dissolution of graphite and glassy carbon, which contain almost 100 per cent carbon, was seen to be significantly different when the molten iron contained sulphur. The influence of melt sulphur content was explained on the basis of different wetting behaviour observed.Importantly, the study showed that even pure carbon sources dissolved at significantly different rates. Hence, their performance could not be explained on the basis of ash content.The key difference between graphite and glassy carbon is in their atomic structure. Graphite is highly ordered whereas glassy carbon has relatively poor ordering in its atomic structure. This study showed that the atomic structure in carbonaceous materials can have a significant effect on their dissolution performance.The focus of the present investigation which stems from the past study described above (Sahajwalla et al, 1994), is to investigate the influence of atomic structure of carbonaceous materials on their dissolution into Fe-C-S melts.The specific objective of this study is to determine the relationship between dissolution kinetics and crystallographic character of carbon sources. In order to accomplish this goal, a range of different materials representing a spectrum of carbon sources have been chosen for the investigation. These materials include brown coal char, two types of Auscarb (A and B), and commercial graphite. Auscarb is prepared by calcining Auscoal at 1000°C. Auscoal is made from chemically cleaned Australian coals (Bowling, Chandler and Waugh, 1990). Part 1 of this paper details the dissolution performance of the materials studied, while Part 11 describes the X-ray diffraction study. The relationship between the atomic structural dimension and dissolution rate constant is discussed in light of the results obtained.

Jan 1, 1996

Evidence abounds for sea-level change having occurred throughout geological and recent time. Driven by climatic changes, by cycles of glaciation and deglaciations, and by tectonics the position of sea-level relative to the crust has been going up and down since oceans first formed. Rates of these differential movements have been as high as 10 mm/year during the last major deglaciation as sea-level rose by about 150 m in about 15000 years. Tectonic processes can also produce change in sea-level relative to the crust of several mm/year as in, for example, the uplift of the Huon Peninsula in Papua New Guinea. To understand what is happening to sea-level today and what may be happening in the future it is necessary to understand the geological and climatic processes that have caused sea-level to change in the past and the best laboratory for the study of these processes is the geological and geomorphological record. Evidence for observations of sea-level change throughout Late Pleistocene and Holocene time is plentiful in the Australian region. Temporal variability is characterized by a low-stand, at more than 100 m below the present level, at about 20 000-18 000 years ago followed by a rapid rise and transgression of the continental margin up to about 6000 years ago. After this time sea-levels remained within a few metres of their present value but the patterns of change are not everywhere the same. The depth of the low stand at about 18 000 years ago does not appear to have been the same everywhere. Nor does the time at which sea-level first reached its present value appear to have been everywhere the same. The fluctuations about present sea-level during the past 6000 years appear to have been different in different localities. As yet there has not been a wholly satisfactory quantitative explanation for this spatial variability. How much, if any, is indicative of vertical tectonics? How much is the result of the Earth's response to the changing surface loads as mass is exchanged between ice sheets and the oceans? Can any of it be attributed to past changes in global climate? Or are the observations just wrong?

Jan 1, 1990

By S Raval

The estimation of greenhouse gas emissions from coalmines is increasingly becoming a priority for both operators and regulators. At the same time, involved scientific challenges in the methane measurements is generating significant interest from global research community. Various technology providers are also actively engaged in improving their sensors and platforms to address the measurement challenges and capitalise the market opportunities. This presentation highlights rapidly evolving multifaceted landscape of coalmine greenhouse gas emissions. It covers the advances in sensors for the detections, including ground-based, airborne, and satellite-based systems as well as models for the emission estimations, including attempts to reduce the involved uncertainties.

Sep 1, 2024

The common notion that the Box Hole Bore mineralization represents a variant of the Mississippi Valley type, has not been supported by the present investigation. Most of the common characteristics of Mississippi Valley type, namely 1. saturated saline brines; 2. low temperature domain; 3. mineralization in intraformational breccias and collapsed anticlinal structures; 4. hydrocarbon-rich or foetid carbonates, and 5. very simple geochemistry seem not to be applicable. The Box Hole Bore mineralization features: 1. moderately saline brines (18% NaCl); 2. very high temperature (495¦-520¦C) and low density brines, of critical vapour:water ratio and low pressure of formation (700 bars); 3. mineralization confined by faults and ex- tending laterally into carbonates of high pore volume such as stromatolitic dolo- mites; 4. ore environment characterized by oxidizing conditions, such as ferruginous carbonate and silica sands of high energy environment (heavy mineral banding) and 5. more complex geochemistry than is normal for Mississippi Valley type deposits (copper sulphosalts, and appreciable silver content). Additionally, the ore has un- usual textures formed by the replacement of carbonates and barite by large idiomorphic galena crystals. The pressure and temperature domains of the Box Hole Bore mineralization indicate post- Devonian emplacement and local high heat flow, possibly related to the Alice Springs Orogeny. Because of high lead and zinc trace element con- tents (100-600 ppm) of the carbonates, even out- side mineralized areas, it is possible that the mineralizing fluids have derived their metal con- tent from a local source, possibly aided by evap- oritic concentrations of the tidal to supratidal sequences. The new model for Box Hole Bore gives treater importance to the confining faults.

Jan 1, 1984

A study of the bacterial oxidation of naturally occurring high-purity sulphide minerals (FeS2, Fel_xS, CuFeS2, Cu2S) has been conducted using a mesophilic strain of T. 6ejtAooLcdcth4. As well as metal analyses and solution pH, partitioning of sulphide sulphur into elemental sulphur and sulphate ion has been monitored. Partially oxidised sulphide substrates have been characterised at regular time intervals by X-ray diffraction methods and extra-cellular organic compounds reporting into leach solution have been identified by'thin layer chromatography. The results indicate that the S¦/SO4 2 partitioning of the sulphide substrates is independent of cell inoculum size and initial pulp density and varies with solution pH, Eh, leaching time and mineralogical properties of the individual sulphide minerals. The signifi- cance of results for applications in selective flotation, coal desulphurisation and agglomera- tion has been outlined.

Jan 1, 1984

By R Lau

In recently completed road tunnel projects in Queensland, such as the Airport Link and the Clem7 tunnels, there is a smoke duct running along the roof of the carriageways to extract smoke in case of fire. In New South Wales, no road tunnels have a smoke duct. In the Melbourne City Link tunnels, there is a small smoke duct running along the roof. All of the tunnels are safe as claimed by the designers and authorities. However, there is significant cost associated with providing a full size smoke duct compared with no smoke duct. This paper is going to present a comparison of the road tunnel safety with a smoke duct and those without one from a risk perspective. It further discusses the cost-effectiveness of such provisions and whether similar levels of safety could be achieved without a smoke duct.CITATION:Lau, R, 2014. Smoke duct or no smoke duct for road tunnels, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 83–86 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By A J. Moore

To control the airblast from blasting to regulatory limits at environmentally sensitive sites near the Collinsville Coal Mining Operations, it has been necessary for Thiess Mining to incorporate a wavefront reinforcement analysis model in the predictive environmental airblast design. Controlling airblast from cast blasting 70 m high faces with 2000-3000 kg of explosives per hole within 700 m of houses presents a considerable challenge to the blasting personnel. This paper describes the model used and summarises the results of an investigation designed to quantify the increase in airblast indicated by wavefront reinforcement diagrams to further calibrate the model for future prediction.

Jan 1, 2004

By Tumilty JA, Douglas WD

With a view to characterising activated carbons with respect to their ability to adsorb gold from cyanide solutions, an attempt was made to establish correlations between the equilibrium capacity constant of the activated carbon for gold (k value) and five other parameters. These parameters were percentage ash content, iodine number, methylene blue value, surface area, and pH respectively. Twenty four different proprietary brand activated carbon products were examined, the correlations being established by means of linear regression analysis. It was shown that a significant correlation only existed between k and pH value. This was interpreted in terms of the presence of oxide complexes on the activated carbon surface. Further test specifications as developed at the Anglo American Research Laboratories are also outlined with a view to the selection of activated carbons suitable for use in' a carbon-in-pulp operation. Methods for assessing both the capacity and the kinetic response of carbons for gold adsorption are presented, while the measurement of attrition resistance, particle size distribution and moisture and solubles content is also outlined. The measurement of the capacity constant for gold adsorption together with attrition resistance are considered to be necessary in the initial selection of a suitable carbon.

Jan 1, 1982

By Wilson PH

A research programme sponsored through the Australian Mineral Industries Research Association investigated two aspects of mine aerodynamics on model scale. These were aero- dynamic losses in (a) shaft/airway intersections and (b) losses created by mine cages moving in a combined haulage/ventilation shaft. The shaft/airway intersections studied included base and intermediate levels for both upcast and downcast. shafts, with one to four rectangular airways intersecting a circular shaft. Changes in intersection geometry were limited to the installation of 45¦ conical brow cutoffs of varying size and the addition of simple flow control devices. The relative air- flows between the airways and the downstream shaft were varied over a range employed in Australian mining practice. In general, experiments revealed that a small brow cutoff was significantly better than none at all, and a simple device such as a cone can reduce losses and improve flow stability at an intersection. The mine cage studies determined the effect on aerodynamic loss of cage area blockage, height/length ratio, openings in cage walls and surface roughness due to external structural members. The results show that in a combined haul- age/ventilation shaft, when the relative air

Jan 1, 1978

This paper records the observations of faulting in the Black Star mine workings. By classifying the faults into two groups, i.e., strike faults and transverse faults, and by pointing out the differences between the groups and their effects on the silver-lead-zinc orebodies, a time relationship between the two groups of faults and the sulphide mineralisation is suggested.GENERAL GEOLOGY AND MINERALISATIONFolding and faulting are closely related to the mineralisation in the shales by silver-lead-zinc and iron sulphides.Commonly the various sulphides are fine-grained and closely associated with one another. However, exceptions do occur locally, where massive coarse galena, sphalerite, pyrite, and to a lesser extent chalcopyrite, have been observed singly or closely associated one with the other.In the main, the sulphide mineralisation forming the orebodies occurs as replacement of, and infilling along, the sheared bedding planes of the finely bedded shale host rock.The shales in general strike north-south with an average dip to 60° to the west; strong shearing along the bedding planes is evidenced by much slickensiding and slaty cleavage.Sequences of finely bedded shales of varying stratigraphic thicknesses alternate with very. massive beds, and it is in the more highly sheared thinner beds that the greatest concentration of sulphides occurs. The unmineraIised massive beds of shale, 11 in. up to 12 in. in thickness, occur singly or in groups between, and to a lesser extent. within, the orebodies. The massive beds resisted sulphide replacement and impart to the orebodies a most prominent banded structure.

Jan 1, 1953

There was a time, in the memory of some here tonight, when the annual meeting of The Institute was a nostalgic occasion. Often, in the 1920s, there was comment on the decline of Australian mining and on the lack of new mineral discoveries. When some of our Presidents prayed then for a new Bendigo, and instead were given a Mount Isa, they were justifiably disappointed because of the vastly different capital requirements.In 1967 the mining picture is very different. The recent mining developments in Australia are certainly as important as several Bendigos and several Kalgoorlies. The mining industry in Australia has never been more dynamic than today (Table 1). And if we ask why it is so dynamic, the answer lies in the role which overseas capital is playing in the industry. The contribution of overseas capital should concern us not only because we are members of the mining and metallurgical profession, but also because we have a duty to make our profession contribute as much as possible to the well-being of Australians. It is not sufficient to argue that overseas capital is good for the mining industry; we must also examine whether it is good for the economy and the nation. In this context the current criticism of the inflow of overseas capital into Australian mining is useful, for it gives us an opportunity to see what has resulted from the inflow.In discussing this question I do not suggest that we emulate Captain Hancock, that legendary Moonta mine manager who, according to Oswald Pryor's cartoon, used to say to his miners: "When I say a thing is, it is, even if it isn't". The question can only be discussed on a factual basis; and I would submit that many of the important facts relating to overseas capital in our mining industry are often overlooked or ignored. I would further submit, on the basis of these facts, that Australia's present day mining industry has been largely built on overseas capital and that the overall benefits of that capital to Australia have been enormous.

Jan 1, 1967

By Bronson B

The geotechnical and environmental aspects of heap leaching are very closely tied during design, operations and closure. Potential environmental impacts from heap leaching are mostly due to land disturbance and water quality issues, including both groundwater and surface water. Water quality issues are mostly related to containment design, which is primarily a function of proper sizing of the facilities and site specific liner design. Geotechnical analyses is the dominant discipline in providing cost efficient, operationally effective and environmentally sound heap leach facility designs. Much has been published on geotechnical aspects of heap leach design, for example Van Zyl, Hutchison and Kiel (1988) and Van Zyl (1987). This paper will emphasize a few specific aspects related to the geotechnical and environmental consideration for heap leach projects. These aspects are: ò site investigation; ò containment design; ò slope stability; ò heap flow dynamics; and ò closure design. Design of a heap leach project must consider not only the operating life but also closure and post-closure considerations. As a matter of standard practice, designing for closure is an extremely important concept. Not only is it important for environmental aspects, but experience also shows that projects designed for closure will be overall more economical for the total life cycle of the project. Closure considerations are also important during project feasibility evaluations to ensure that total life cycle costs are evaluated.

Jan 1, 1994

By D Mukendi-Ngalula, G Hearn

Beach sand minerals from the volcanic rock structures of the Drakensberg, Kwazulu-Natal, (South Africa) have been processed. Screening, flotation, spiral concentration and magnetic separation methods were used either separately or successively in an attempt to concentrate monazite minerals. Products thereof and those from a long time (up to 72 hours) microwaves treatment of the finally produced ilmenite-bearing minerals have been studied using the M÷ssbauer effect spectroscopy. The 57Fe M÷ssbauer effect spectroscopy has demonstrated its versatility and power in monitoring the ilmenite internal reduction mechanism and products and, in characterising the iron-bearing phases contained in different products from the beach sand minerals processing. Microwaves heating of ilmenite for up to 38 hours reduced internally the Fe3+ from the ilmeniteÆs structure. A more prolonged microwaves heating (up to 72 hours) re-oxidised the mineral. 61 per cent natural ilmenite recovery was obtained in the floating products of a spiral concentrated -212+106 ¦m screened and beach sand minerals fraction. A preferential concentration of hematite with a 62 per cent recovery was found in the sinking products while the combination of screening-spiral separation-magnetic separation and flotation yielded a floating product with the highest ilmenite and the highest hematite abundanceÆs (71 per cent, 19 per cent respectively). A natural ilmenite containing 87 per cent ilmenite and 13 per cent hematite could be produced and extracted from the sinking products of the flotation process collected subsequently to the spiral concentration and the initial screening.

Jan 1, 2000

The Banda arc, a U-shaped orogenic belt which separates oceanic crust of the Banda Sea from continental crust underlying the Australian- New Guinea shelf, has been interpreted to mark the convergent boundary between the northward-moving Indian Ocean- Australian plate and the Southeast Asian plate (Hamilton, 1979; von der Borch, 1979; Bowin et al., 1980). East of the island of Sumba (Fig. 1), the oceanic crust of the Indian Ocean has been completely subducted and Australian crust is now thrust under the Banda arc. Controversy has centered over the interpretation of the Timor trough as the surface location of subduction and the significance of the Savu Sea between Timor and Flores as either a forearc basin or the continuation of the Java trench (Karig et al., 1987). Two concentric island ridges, called the inner and outer Banda arcs (Hamilton, 1979), separate Australian continental crust from the oceanic crust of the Banda Sea (von der Borch, 1979) (Fig. 1). The inner arc is a typical volcanic island arc composed of calc-alkalic volcanic rocks of Neogene age, while older (Permian and younger) complexly deformed sedimentary and metamorphic rocks make up the outer arc. Timor is the largest and most extensively studied island of the outer arc and is separated from the inner arc by the Savu Sea. The triangular-shaped Savu Sea appears to be a complex forearc basin divided by a series of buried basement ridges (Karig et al., 1987). The outer, convex side of the Banda arc is followed by a major negative bathymetric feature known ne rho Timor trnnnh

Jan 1, 1987

This paper summarises the results of a study carried out for the Sustainable Minerals Institute, University of Queensland, aimed at identifying the major water-related issues facing the minerals industry internationally and the research required to support the development of practicable solutions. An overview is given of the sources and uses of the worldÆs water resources and of the regional and global sustainability of water supply and management. Agriculture is the worldÆs major user of water; it wastes more water than the minerals industry uses. Water reform and its potential impact on the minerals industry are discussed with particular reference to Australia and South Africa. The sources, uses and management of water on mine and processing sites are outlined. Particular attention is paid to the importance of groundwater as a source of often saline water that can be used in mineral processing and for other purposes. Aquifer storage and recovery has the potential to help conserve water resources. Generally, the major uses of water on mining and processing sites are for mineral processing and refining and for the associated tailings disposal. Water consumption for these purposes may be reduced by recycling process water, using saline water, paying close attention to water management, thickening tailings and using techniques such as dry stacking and paste. A change in the minerals processing paradigm in respect of water use could come through research into new, improved and less costly dry processing techniques. The treatment of mine and processing water will be required increasingly before water is reused, stored, discharged or sold, and before sites are decommissioned. Research and development are required to reduce costs and develop new treatment methods. Mine closure and decommissioning raise a number of long-term water issues requiring continuing generic and site-specific research and development.

Jan 1, 2003

By Parfitt RL

A quarter of the North Island, New Zealand is covered by weathered volcanic tephras of mainly andesitic and rhyolitic compositions. Rapid weathering of basic volcanic glass and slower weathering of acidic glass have produced short-range order alumino-silicate clays such as allophane. Although amorphous to x-rays they have a high degree of local structure. Allophane comprises hollo spheres of approximately 40 diameter and 7 X wall thickness. This small particle size and morphology gives a very high surface area (up to 800 m2/g). Ferrihydrite is another short-range order clay of similar small size and high surface area; it has ò formed from the rapid oxidation of water containing ferrous iron derived from volcanic rocks. The quantity of allophane present in tephra depends upon the climate, the nature of the volcanic glass and the time it has weathered. In New Zealand highest amounts (-50%) occur in beds of andesitic ash deposited on old ignimbrite surfaces with mean annual rainfalls >1600 mm. Both allophane and ferrihydrite will react with oxyanions, such as phosphate, arsenate or borate, and remove them from solution. Other anions such as fluoride also react with aluminium sites on the mineral surface. At NZ Soil Bureau, Department of Scientific and Industrial Research (DSIR), New Zealand, techniques have been developed for granulating allophane to enable it to be used to remove pollutants from solution without dispersion into the liquid phase. This granulated allophane can be used to remove phosphate from sewage effluent or fluoride from tap water without having a sedimentation stage to remove the clay.

Jan 1, 1987

In the future to excavate sufficient coal for power generation, two dredgers would be required to dig overburden or interseam 70010 of the time and three dredgers 40010 of the time. One overburden system was not adequate for this requirement, making coal production reliability vulnerable. TS5 spreader is the new machine element of this system. The selection of the best type of machine configuration to suit the application was then subject to an internal SECV VE Study, a registration of interest and a tender for two machine alternatives. This paper outlines the reasons why SECV planned the Secondary Overburden System and how the Krupp machine met these requirements. It also identifies the main design features of the machine and its constructability which will allow the machine to be operational by the end of May, 1990.

Jan 1, 1989

By G R. Ballantyne, M S. Powell, M Tiang

This paper reviews the proportion of energy attributable to comminution within the Australian gold and copper mining sector. The need for this is motivated by inconsistencies in the quoted energy usage data and the lack of a common basis for reporting the fraction of energy in mining that is attributable to comminution. This study should form a reliable basis from which to assess both demand and opportunities to reduce energy consumption.The proportion of milling energy was calculated for the major producers in the Australian gold and copper sector. A sampling methodology created by Powell et al (2003 - 2010) was initially used to provide an accurate and meaningful measure of the energy used in the comminution process. However, no useful method for grouping similar mines was found. Fortunately, a surprisingly large amount of high quality data was found from a number of different sources, allowing the development of robust relationships to be used to estimate a high proportion of the unknown values. The fraction of energy attributable to comminution was found to be dependent on how the total energy consumption was defined. For instance, comminution accounted for 52 per cent of the electrical energy, but only 21 per cent of the total energy publicly reported by the mines because a substantial proportion of energy used on a mine is in the form of transportation fuel (mostly diesel). Critically, the measured electrical energy consumption does not account for transmission and generation losses, while diesel energy usage is typically quoted according to its calorific value. This review proposes that diesel should instead be converted via the mechanical efficiency factor for diesel engines. Using this conversion, comminution was found to account for 36 per cent of the available energy on average. This approach allows a useful basis of comparison for mines regardless of whether milling energy is obtained from electrical or diesel generation. A summary of the results are shown in Figure 7 with other values obtained from literature. The total comminution energy assessed in this study accounts for 1.3 per cent of AustraliaÆs electricity consumption, this figure will increase as the other mineral commodities are added to the study.CITATION:Ballantyne, G R, Powell, M S and Tiang, M, 2012. Proportion of energy attributable to comminution, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 25-30 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012