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By R. Abela

In over ninety per cent of mineral sand plants, the most commonly used equipment is the spiral concentrator. The tonnage treated over typical spiral plants can range from as low as 200 ton per hour up to 6 000 tons per hour. Due to the limited capacity of each spiral, plants consist of multiple spirals assembled into banks. The mixture of minerals present in the sand feed requires several spiral stages to achieve the desired mineral recovery. Due to the complexity of the spiral circuits, there are always some design and operating problems that present themselves in plants. These range from slurry distribution, spirals operating at incorrect design parameters and feed variations. The material being treated is difficult to maintain in suspension due to its high density, resulting in segregation and preferential flow in pipelines, distributors and sumps. The objective of this paper is to highlight common problems associated with spiral installations to designers and operators of plants. Practical solutions are recommended in order to prevent and minimize these mistakes in the design. These solutions may be used to improve performance on operating plants.

Jan 1, 2003

By Dale Preece, Stephen Chung, Qian Liu

Stoping is one of the widely adapted methods in underground mining. In this method, fanned or parallel holes are often drilled from a top sill down to a sub- level in the ore zone and blasted ring by ring into a stope for excavation. At Brunswick Mine of Canada, this technique has been used daily in conducting production blasts. However, when mining into the West Ore Zone, it has been identified strategically that a mass stope blast, involving the blasting of rock from the 3-sub level down to the 1-sub level, should be considered to ensure the safe operation and regaining of access to the trapped main ore zone. The challenge of this mass blast lies in the control of ground vibration and precise timing for blasting 800 holes drilled in six blocks from three different levels within 6.5 seconds, to allow sufficient void to be created in each level for the muck moving in order from the upper to the lower levels without bridging. This paper describes stope blast simulations using a discrete element computer code for modeling blast-induced rock displacement in conjunction with a precision electronic programmable delay timing system for various stope geometries including a drop raise blast at the start of the mass blast. The modeling concept is also described in the paper.

Jan 1, 2003

The area around Big Bell was actively explored and sporadically mined for gold from 1904 onwards. The lease was named Big Bell in 1913. The property became established as a major mining centre with the development of the Big Bell underground mine in 1936. Mining operations commenced in late 1937 and ceased in January 1955, after milling 5.56 million tonnes of ore and producing nearly 21 tonnes of gold. In 1969 Australian Consolidated Minerals Ltd (A.C.M.) acquired the deposit then explored it alone and in joint venture until the current joint venture agreement with a subsidiary of Placer Pacific Limited (PPL) was negotiated in 1984. Following exploration and evaluation of near surface mineralisation, and a reassessment of the remnant pillars underground, the concept of a large open pit in conjunction with an underground mine evolved. The feasibility study was completed in October 1987, and the decision to go ahead was formally announced on 2nd December 1987. Placer Dome Technical Services Ltd were contracted to be the Project Managers, commencing construction on site early in January 1988 and handing the plant over to the operators 13 months later. The capital cost of the project at handover was estimated to be $133 million. The operating team commenced pre-production stripping of the open pit on 1st May 1988. By 31st January 1989 almost 16.0 million tonnes had been stripped and 350,000 tonnes of ore stockpiled.

Jan 1, 1989

By D. R. Wilburn

This summary of international mineral exploration activities for 2008 draws upon available information from industry sources, published literature and U.S. Geological Survey (USGS) specialists. The summary provides data on exploration budgets by region and mineral commodity, identifies significant mineral discoveries and areas of mineral exploration, discusses government programs affecting the mineral exploration industry, and presents analyses of exploration activities by the mineral industry based upon these data. Two types of information are reported and analyzed in this annual review of international exploration for 2008: 1) budgetary statistics expressed in U.S. nominal dollars provided by Metals Economics Group (MEG) of Halifax, Nova Scotia (Metals Economics Group, 2008a, b), and 2) information on regional and site-specific exploration activities that took place in 2008 and compiled by the USGS. The MEG information summarizes planned company budgets for worldwide exploration activities in 2008, primarily for precious metals (gold, platinum-group metals and silver) and base metals (copper, lead, nickel and zinc). MEG includes information on additional mineral commodities only where it is available. Information on uranium exploration was included in the MEG overview for the first time in 2007, although this information was not included in the USGS analysis. The MEG survey methodology was changed in 1999 to include companies with exploration budgets between $100,000 and $2.9 million, as well as those companies included in prior studies whose anticipated budgets were above $2.9 million. MEG estimates that its post-1999 surveys cover at least 90 percent of world nonferrous nonfuel mineral exploration budgets. The 2008 survey is reported by MEG to cover an estimated 95 percent. Companies that chose not to participate in the MEG study, private companies that do not publish data, and government-funded exploration activities make up the majority of the remaining 5 percent. MEG included 91 more companies in its 2008 survey than it did in 2007 USGS compilations of site data described here primarily include nonfuel minerals, with an emphasis on base metals, diamond and precious metals. Analyses are based on information provided by USGS mineral commodity and country specialists and by other USGS scientists, as well as industry contacts and trade journals.

Jan 1, 2009

By Hargraves A. J

The paper outlines events at the Collinsville State Coal Mine, Queensland, leading to the practice of full face multiple shotfiring in bord and pillar development places. The 1954 disaster is referred to, and factors involved in simultaneous shotfiring in coal are discussed. Promising preliminary multiple shotfiring tests at the Colliery are described, as well as the resulting routine measures adopted, and the changes involved. The subsequent inducing of two outbursts under safe conditions by remote multiple shotfiring is given as justification for the changes made.INTRODUCTIONFollowing a disastrous instantaneous outburst (1.0.) of coal and gas at the Collinsville State Coal Mine in 1954, the necessity for inducer shotfiring for the control of possible further outbursts was established. However this mine, immediately classified as gassy after the 1954 outburst, is subject to the general restrictions pertaining to gassy mines which at present preclude the use of inducer shotfiring due particularly to the non-existence of a permitted exploder for more than six shots, and further, because permitted multipleexploders are not designed for remote firing through long lengths of cable. This situation was met by arresting or reducing progress in the production places, thereby reducing the danger of outbursts while means were being considered to achieve overall maximum safety.In August 1957 two full faces were successfully blasted in experimental simultaneous rounds. In June 1958 four full faces were blasted, and in October 1958 full face grunching without prior cutting, Le. inducer shotfiring, was introduced in No. 1 Tunnel as a production feature. In March 1960 it...

Jan 1, 1960

By Walter Fuchs

IT is now generally conceded that coal is the product of deposition and transformation of debris of forests and swamps.29 Ample data are available to illustrate the metamorphosis of biochemical substances through biological action; other data show the progressive regional metamorphism existing in coal beds ;25 and numerous examples of change effected by intrusion of igneous dikes into coal deposits have been established.23 However, often the relative importance of the biological and the geological factor in determining the character of the various natural coals is a debatable question. Since both biological and geological factors are ever present in nature, the problem, at first glance, would appear to resemble certain probability problems: specifically the simultaneous toss of two coins, with the biological factor as heads and the geological as tails. The probability is 2 : I for the combined effect of both factors, as compared to the exclusive effect of either one, if the a priori probability is the same for each factor. This condition can be analyzed by a thermodynamic treatment of data, which may be obtained from a consideration of pertinent biological, chemical, geophysical and geological facts. SYNOPSIS OF BIOLOGICAL AND CHEMICAL FACTS The biosphere is not sterile; i.e., microorganisms are always present. Microorganisms have been established in the ocean deep, under the ice of the polar regions, in the sand of the deserts, and in swamps far below the surface. The various biological media may be acid, neutral, or alkaline, and they may or may not be readily accessible to air. Microorganisms are encountered almost everywhere, except where the temperature is not within the range tolerable by microbial life. Of course, with changing conditions, the type of microorganisms will change. All chemical products of life-proteins, fats, carbohydrates, lignins, waxes, resins may serve as a habitat of microorganisms. In the decomposition of a medium. some microorganisms macerate organic matter mechanically and remove certain constituents for their own nutrition; others decompose a large part of the organic matter but may leave certain constituents undecomposed. Some attack only certain specific ingredients of the organic matter. All of them build up cell substance. The nitrogen content of the medium largely determines the degree of decomposition. Below 1.7 per cent nitrogen, growth of microorganisms and hence decomposition of organic material is retarded; consequently organic material will accumulate.17, 32 Such accumulations of organic material may give coal eventually. Coals differ in type and rank. The nature of the original vegetation and the conditions attending the transformation of the accumulated debris determine the type of coal such as bright, splint, cannel, and algal or boghead coals. Chemical analysis of representative samples of a given type of

Jan 1, 1941

By D. K. Denton, J. M. Girard, D. F. Scott, T. J. Williams

Personnel from the Spokane Research Laboratory, National Institute for Occupational Safety and Health, examined an underground pillar at the Homestake Mine, Lead, SD. Investigations involved strain relief and seismic tomography studies in the mine, and ultrasonic velocity measurements on pillar core in the laboratory. Measured octahedral normal stress was 37 MPa (5,366 psi); seismic P-wave velocities averaged 5.2 km/s (17,060 ft/s); and ultrasonic velocities at a pressure of 39.6 MPa (5,750 psi) averaged 6.3 km/s (20,669 ft/s). The difference between in-mine and laboratory velocities is attributed to the attenuation of seismic energy by mine fractures larger and more numerous than those in the samples of core measured in the laboratory. Using these results, researchers hypothesize that pillar rocks have the ability to withstand stress an order of magnitude greater than they currently sustain.

By Choon Kooi Quan

Water availability is essential for mining and minerals processing. To provide government and industry with recent data for water use planning and management, the Bureau of Mines canvassed a number of U.S. producers of nonfuel minerals to determine their water use in 1984. Data were analyzed and compared with previously published data in order to examine historical trends in water utilization in the nonfuel minerals industry and to estimate water requirements in the year 2000. Total water use in the domestic nonfuel minerals industry during 1984 was estimated at 2,267 billion gal, of which 571 billion gal was new water and 1,696 billion gal recirculated water. The largest users of water were the phosphate rock, iron ore, copper, sand and gravel, and crushed stone industries, together accounting for almost 90% of total used. More than one-half of all water was used in Florida, Michigan, and Minnesota. In the year 2000, total water use will amount to an estimated 2,679 billion gal, of which 810 billion gal will be new water and 1,869 billion gal recirculated water. Most of this water would be used in producing the foregoing suite of minerals,

Jan 1, 1988

The compilation of the sampling nomogram is an essential tool in the optimization of a sampling protocol and allows the operator to track the change in relative variance of the sampling error (the Fundamental sampling error) during steps of comminution and mass reduction in the process of recovery of the aliquot for analysis. The data required for the compilation of the nomogram are centred on the sampling constant K and the exponent, alpha (a) of the nominal fragment size. Five methods for establishing K have been identified, but two of them, the duplicate sampling analysis method and the heterogeneity test method purport to provide such constant. The step by step procedure for each of these two methods was examined using broken ores from three mines, Mponeng mine, Kloof mine, and Lily mine. Two of these mines (Mponeng and Kloof) are typical Witwatersrand-type gold mines, and the third is an Archaean-type shear related gold deposit situated in the Barberton Greenstone belt. The results suggest that the factor K derived using the heterogeneity test is very accurate, but applies only to a single size fraction in the spectrum of comminuted materials. The calculation of gold grain sizes using this method appear to be too small and do not conform with the results from detailed mineralogical studies. The factors K and alpha derived using the duplicate series analysis are appropriate for use across a wide spectrum of comminution sizes and also provide realistic gold grain sizes, comparable with the equivalent circular diameter of gold grains identified in mineralogical studies of the ores.

Jan 1, 2010

By D. H. Gurinsky, D. G. Schweitzer

The empirical equilibrium constantsd the heat of reaction for the reduction have been determined from 300° to 500°C. The mechanisms of the oxidation of uranium and magnesium from dilute bismuth solutions have been investigated. The kinetics of some of the reactions were affected by air adsorbed on the uranium oxides. THE Liquid Metal Fuel Reactor studied at Brook-haven National Laboratory uses a solution of uranium in bismuth as the fuel. Corrosion and stability problems require that the fuel solution contain corrosion inhibitors and deoxidants. Of the additives tested, magnesium has been found to be the best deoxidant and zirconium the best corrosion inhibitor in bismuth. Some experiments1 indicate that magnesium may play a secondary role in increasing the effectiveness of zirconium in inhibiting corrosion. The work reported here was intended to determine the relative concentrations of Mg and U required to prevent oxidation of the uranium fuel in the event of an air leak. In addition, an attempt was made to identify some of the mechanisms of the oxidation and reduction reactions occurring in the liquid bismuth solutions. EXPERIMENTAL Apparatus and Procedure—The equipment shown in Fig. 1 was designed so that the reaction kinetics could be studied as functions of temperature, melt composition, pressure, and flow rate. At the start of a run, the 10-liter bell jar (F) is removed by opening the bottom Dresser fitting (L), and the bismuth and additives are placed in a pyrex crystallizing dish (I). The bell jar is replaced, the system is evacuated to 10-5 to 10-6 mm Hg and then the heater (J) is turned on. When the selected temperature is reached, the oxidizing gas is admitted to the system to the desired pressure as read on the manometer (D). Gas is introduced through the slide tube (Q) which has a pyrex frit (R) sealed to its bottom. Stirring is accomplished by immersing the end of the tube in the melt. To maintain a constant pressure under flow the input and evacuation rates must be equalized. To obtain this condition stopcock (C) is closed and flowmeters (B) are matched. The reaction is "stopped" by closing the inlet flowmeter and quickly evacuating the system. To obtain a liquid metal sample, the system is evacuated with the sampler positioned near the surface of the liquid. The sampler, Fig. 2, is then immersed until its thermocouple reading matches thermocouple (G) Fig. 1. The system is then pressurized with helium which forces the solution through the frit. Twenty to 30 min elapsed between the time the system was evacuated and sampled. During evacuation and pressurization of the system, the temperature variations did not exceed ± 5°C. While bubbling occurred the temperature remained constant to within 1/2 oC. The volume of the equipment was determined by adding a known volume of air at atmospheric pressure to the evacuated system and noting the resulting pressure.

Jan 1, 1962

By D. S. Choi

This paper describes an improved source location technique for microseismic events related to coal mining. A system of non- linear distance equations is solved with the use of the Newton-Raphson method. This computational method is- advantageous when the number of geophones is limited. In addition, this paper includes the results of the analysis of data from several instruments which characterize both mine seismicity and environmental noise such as vehicle traffic. Analysis of the mine seismicity has contributed to a better understanding of caving above a longwall gob and of what constitutes stable ground conditions.

Jan 1, 1990

The great problem at Port Pirie and many other lead smelters has always been to keep the lead content of the slags down to a low level. This has been done in the past largely by empirical methods, the lead content varying from less than 1 per cent to over 4 per cent, the more usual figure being something under 2 per cent. Subsidiary to this, but of major importance in the future, was the extraction of the considerable quantities of zinc in the slag. At this stage little was known about the constitution of the slags apartfrom their chemical composition. Some early work on slag constitution was carried out in the B.H.A.S. Research Laboratories between 1919 and 1921, but except for a microscopic examination of a few thin sections the greater part of this investigation wasdevoted to the recovery of the zinc content of the slag by leaching methods.In 1949, therefore, it was decided to initiate a programme of fundamental research into the constitution and properties of the lead blast furnace slags. The information thus gained would give a clearer picture of reactions taking place in the slag, both in the blast furnace and during dezincing.There was also the hope that these results would lead to improved industrial techniques resulting in smaller lead losses, and, taking the long-term view, to efficient methods of producing zinc from the slags.A series of investigations was therefore begun at various centres over a period of time. These were:1. A mineralogical examination of the slags by Dr. A. B. Edwards of the Mineragraphic Section, C.S.I.R.O.2. A study of the thermodynamics of various slag com...

Jan 1, 1956

By J. O. Marsden

Over the past eight years, Phelps Dodge (a subsidiary of Freeport-McMoRan Copper & Gold, Inc.) devoted a significant amount of effort to the development of a suite of processes for the effective hydrometallurgical treatment of copper sulfide concentrates. This effort resulted in the development of high-temperature (>200ºC) and medium-temperature (150° to 165ºC) pressure leaching processes. Specific configurations of both processes have been commercially demonstrated at Phelps Dodge?s facility in Bagdad, Arizona. This paper reviews in detail the chemistry of medium-temperature pressure leaching of copper concentrates and reports on the process development work conducted by Phelps Dodge and others for this technology. This paper is Part I of a four-part series on this technology. Part II covers the development of medium-temperature pressure leaching and direct electrowinning technology; Part III considers the large-scale demonstration of the MT-DEW-SX process at Bagdad, Arizona; and Part IV addresses the development and design of a full-scale commercial application at Morenci, Arizona.

Jan 1, 2007

During the past Two years in reef gold mining, "indicators" have received great attention at the hands at the Victorian gold seekers. Many years ago, what was caned the" indicator lode," was struck in Ballarat East, on the course of which extremely rich deposits of gold were discovered but as to its being a .qeneral experience in reefs or leaders no one ever dreamed. Now, however, we find that these "indicators" are frequently to be met with, though they differ very much in different localities, making it, therefore, a difficult matter for other than a careful minel' to follow them. The necessity of following "indicators" for the purpose of developing gold is now recognized, and the policy of following them up has been attended with much success in this field. In the case of Messrs Shaw and Sons, at Wedderburn, those gentlemen began to work on an "indicator" here five years ago, and immediately thereafter more by accident than anything else they being at that time inexperienced as regards "indicators " came upon gold bearing quartz, which continued payable so long as the" indicator" aud the stone were in conjunction with each other, but as soon as they parted company the stone ceasedto be of any value then, by following the" indicator," as the latter intersected fresh bodies of stone they proved again more or less payable, until a fortnight or so ago the Messrs. Shaw turned out 4 tons of stone, which yielded £1,825, with also profitable workingup to the present moment. Where they are now working is a mile north of their original find thus proving that "indicators" travel considerable distances and have something to do with the gold deposits found in reefs. On the direct course of Shaw's "indicator," as high as hundreds of ozs to the ton was obtained from the stone but, just a few inches from either side in the same" leader," not a colour could be got. Whatever the cause-whether by electricity or some unknown force in nature-the gold is found on the course of these" indicators" and nowhere else, and-as each of the Victorian Government Geologists admit-their value to the gold-seeker as a means of leading to' gold cannot be over-estimated.

By A. Koski

A pond rehabilitation and environmental education project were proposed by Cleveland-Cliffs Michigan Operations (CCMO) and approved by the Michigan Department of Environmental Quality (MDEQ) and the United States Environmental Protection Agency (USEPA) as partial fulfillment of conditions for a stream mitigation permit. The goals of the project were the rehabilitation of a pond on a tributary of a local trout stream, enhancement of public access and appreciation, and the initiation of a site-based environmental educational curriculum. Cleveland-Cliffs undertook a suite of actions to rehabilitate a pond created by a previous mining operation in 1912 and make accessible to local schools the aquatic and riparian ecosystems. Cleveland-Cliffs partnered with the local governmental unit and two local school districts. The rehabilitated pond and riparian zone provide an accessible natural area that local residents can use for such activities as hiking, biking, walking, fishing and nature study. Vegetative enhancement includes the planting of native shrubs, wildflowers and showy herbaceous plants in the pond, on the riparian fringe and the surrounding area. An interpretive trail was developed around the pond with signs created by a local master watercolor artist. Local schools built and installed picnic tables, benches and a kiosk. Cleveland-Cliffs created pond lesson plans tied to the Michigan Curriculum Framework, developed inexpensive teaching kits and hosted a workshop for teachers from nine local schools. Classes regularly utilize the pond during the school year conducting environmental studies. Nesting boxes, wildflower gardens, bat houses, frog deformity surveys and water quality studies are a few of the activities that classes have conducted at the pond.

Jan 1, 2007

By M. W. Franklin, D. W. Hendriks

"Changing ore types, feed grades and c1rculat1ng loads are some of the many factors that can make flotation feed-back control difficult. To control a flotation circuit using conventional fixed-parameter control algorithms, one must either tune the controllers very often or tune the controllers to the middle of the normal operating range. The former approach is very time consuming, while the latter approach can lead to long periods of either very sluggish responses or highly reactive responses which can lead to instability. The problem becomes compounded if feed-forward variables are introduced, creating even more variables to tune. An alternative to a fixed-parameter control algorithm is an adaptive control algorithm. An adaptive control algorithm continuously retunes itself based on previous reactions to its changes. Feed-forward control also becomes much more viable because the algorithm will tune the feed-forward parameters and the feed-back parameters simultaneously. Using the combination of feed-forward and feed-back tuning is an effective way to decouple the loops needed in flotation circuits where one circuit feeds into another. The advantages of adaptive controllers over conventional controllers will be introduced through the use of a simulator. Also discussed will the be the implementation of adaptive controllers at Brunswick Mining and some of the modifications that are available to help solve more difficult control problems.Brunswick Mining is located just outside of Bathurst, New Brunswick. The concentrator processes approximately 10250 tonnes per day of ore that assays at approximately 8.9 %zn, 3.6 %Pb, 0.3 r.cu and I 00 gram/tonne of Ag. The four products produced are zinc concentrate assaying 51 %Zn, lead concentrate assaying 34 %Pb, copper concentrate assaying 21 %Cu, and a bulk concentrate assaying 32 %Zn and 18 %Pb."

Jan 1, 1986

By Moinpour M

The kinetics of reduction of copper (cuprous) sulphide with CO-CO2-He gas mixtures, using an excess of CaO(s) as a sulphur-scavenging substance were investigated in the temperature range 855° - 950°C by a thermogravimetric method. Several gas compositions were employed at each temperature. Potential carbon deposition was overcome by preheating the reducing gas mixture. The phase-composition and the morphology of partially reactedsamples were analysed by a SEMlEDAX unit. The reduction rates showed strong dependence on the bulk gas compositions (CO, CO2) and, in most cases, the rate declined with rising temperature. The rate-controlling step appears to be the diffusion of CO2 gaseous species through the micropores of the CaS(s) - product layer which builds up around the CaOcore.

Jan 1, 1989

By J. -P. Saindon, L. D. Nel, A. E. Hall, S. G. Hardcastle

"This paper reports on an investigation into gas and dust concentrations in Ruttan Mine's exhaust air. The values obtained indicate that there is excellent potential to recirculate approximately 25% of the hot exhaust air into the intake air to reduce winter heating costs. Contaminant concentrations vary significantly during the course of the working shift and decrease in the mine exhaust system as the air returns to surface. A proposed on-line control system is outlined which would permit recirculation to be implemented with a pay-back period of less than two years. IntroductionIncreased energy costs and depressed mineral prices have resulted in mines, which use winter ventilation air heating, reviewing their systems to try to reduce costs. Heating costs can be significant, for example, Potash Corporation of Saskatchewan spends an average of $580,000 per mine per year and Ruttan mine spends approximately $IM per year on propane for its direct-fired heating system.Several method s of reducing heating costs have been considered and the following have potential application.Heat Exchange Between Exhaust andIntakeThis is usually accomplished by run-round glycol systems. The system is limited by ice formation on the coils in wet exhaust air and by the low exhaust air temperature, usually l0ºC. It also requires close proximity of the intake and exhaust airways to ma~e the cost of the connecting pipeline and pump systems economic . A feasibility study by Inco's Thompson operation reported that a proposed system of this type had a 19-year payback period and was, therefore, uneconomic. Potash Corporation of Saskatchewan is currently investigating plastic heat exchangers for a trial system because of corrosion on metal exchangers. It has the advantage of a 17°C exhaust temperature and relatively dry exhaust air.Waste Heat ReclamationThe waste heat from compressors and hoists can be used for heating in some mines. The feasibility of such a system depends on the individual layout and the proximity of the heat source to the inlet airway. Other mines have considered using the exhaust air in greenhouses to provide a cash crop."

Jan 1, 1988

By P O. Koons, R J. Norris, S C. Cox

 The Southern Alps is an active oblique collisional zone which has a characteristic wedge-shaped geometry above a low-angle ductile shear zone. The Main Divide region is a relatively low strain zone above this ductile shear zone, and is _deforming principally along steeply dipping strike-slip faults. Extensional fractures are common at a high angle to the regional structural trend. These steeply dipping structures act as conduits for gold-bearing fluids from depth, and small mesothermal gold deposits have formed at several structural levels including the near-surface region. Gold has also been deposited in a meteoricmetamorphic fluid mixing zone near a conductive thermal anomaly on the western slopes of the mountains. These various gold deposits and their well-constrained structural and tectonic settings can be used as analogues for larger, deeper-eroded mesothermal gold deposits in the Mesozoic Otago Schist belt. High level Miocene veins in NW Otago have formed beneath the main divide of the initiating Southern Alps. Late metamorphic gold-bearing veins formed as fluid escaped from the ductile-deforming crustal root beneath Mesozoic mountains.  

Jan 1, 1997

The copper-clay deposits consist largely of goethite and clayey mudstones carrying native copper, cuprite, and chalcocite. The mudstones are of Ordovician age, are interbedded with Fe-Mn carbonates, and probably contained syngenetic iron and copper sulphides. The secondary copper minerals have been derived from post-Devonian weathering in situ and also by deposition from surfaee and underground waters draining the adjacent mineralized volcanic rocks.

Jan 1, 1969