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By J. Leja, J. H. Schulman

FROTH flotation is usually effected by the addition of a collector agent and a frothing agent to an aqueous suspension of suitably comminuted mineral ores. The action of collectors is to adsorb onto the surfaces of minerals to be separated, sensitizing them to bubble adherence. The action of frothers has, in the past, been accepted as that of froth formation only, brought about by a lowering of the air/water interfacial tension. Substances capable of producing froth are classed1a,b according to their relative capacities for production of froth-volume and froth stability in the simple frother-water system. The purpose of this paper is to show that the surface active agents acting as frothers become effective only when there is a suitable degree of molecular interaction taking place between collector molecules and frother molecules at the air/water and solid/ water interfaces. Further, the discussion will demonstrate that the actual mechanism of adherence of an air bubble to a suitably collector-coated particle is due to the molecular interaction collector-frother. This leads to the formation of a continuous interfacial film of associated molecules, anchored to the mineral by polar groups of the collector, and enveloping the whole bubble. The tenacity of adhesion mineral-to-bubble results from the strength and the visco-elasticity of this mixed film.

Jan 2, 1954

By M. J. Fairweather

"The development of means to maximize the selectivity between galena and sphalerite in lead zinc ores is extremely important to the lead-zinc industry. Two challenging studies recently undertaken by Cominco will be reviewed. The first required an unusually fine grind to achieve liberation between galena and sphalerite. The second contained partially altered galena which resulted in unusual early activation of sphalerite under normal flotation conditions. Means by which lead and zinc separation were optimized in these two ores will be discussed.There are two important factors in the separation of minerals by froth flotation: particle size distribution (grind) and pulp chemistry. Pulp chemistry includes a number of factors including pH, Eh, collector type and concentration, inorganic depressants, organic depressants and activators.Grind is important for two reasons. A sufficiently fine grind is required to optimize liberation. However, if the mineral dissemination is too fine, mineral selectivity in the flotation process is impaired. Due to the hydrodynamic constraints of conventional mechanical flotation cells, flotation works best over the single decade size range between 10 and 100 microns. The majority of new ores treated by Cominco until relatively recently were comparatively simple. The major factor in their treatment was defining optimum grind size. Accordingly, the focus within mineral processing at Cominco was on grind and supporting liberation studies. The relationships between grind, liberation and flotation response are intuitively easy to understand. An idealized relationship is shown in the first figure."

Jan 1, 1991

By T. W. West

INTRODUCTION This paper presents an assessment of conventional flotation technology. In addition it presents some ideas which can be used to change the perception of what may be done with conventional flotation equipment to maximize its efficiency. Perspective of Conventional Flotation Technology 1. Flotation in many coal preparation plants is defined as something between a necessary evil and a non-viable concept because: -Too much art is required on a continuous basis to achieve uniformly acceptable results. -It is expensive, the capital cost in dollars per ton of circuit feed for flotation and dewatering is high. -It is a difficult process to use when SO2 reduction governs system design and equipment selection. -It creates a product (fine coal froth) that is difficult to dewater in the presence of BTU/lb as-received pressures. -It is a difficult process to control from a management standpoint, there are no dependable set points to rely on. 2. Many froth cell circuits are 0.5m x 0 (nominal 28 M x 0) feed which is sourced from screen/cyclone underflows. The original intent was to obtain maximum yield at acceptable product quality and moisture using disc filters. (See Figure #1) 3. An alternate to conventional flotation and its perceived to be limits of efficiency, capital costs, etc. is to move towards such developing flotation technologies as column flotation, reverse flotation, and microbubbles. A lot of work is being done to move these concepts thru pilot stages into full scale, commercial plant operation. The majority of the coal producers and coal preparation plant designers view these concepts as being in the development/pilot plant stages. OBJECTIVES Based on the preceeding comments of the perspectives of the coal producers and plant designers, the options are limited. They can make do with what they have available to them in the way of industry standard equipment and practices or they can move forward with developing technology. I feel there is a third option: what can we really do today with what is available to us, without reinventing the wheel? APPROACH 1. When processing coal against ash and SO2 restrictions, the fine clean coal stream can be the best stream on the clean coal conveyor due to the release by size and the ability to create a high BTU/low sulfur (dry basis) product. 2. Targets: -Consistent raw coal size consist in the plant feed . -Do not put pyrites in the froth cells. -Adjust criteria defining good flotation away from yield towards maximum BTU recovery at minimum ash. -Limit the froth cell feed size consist to 0.15 mm x 0 (nominal 100M x 0). -Establish and maintain a correct, consistent percent solids in the froth cell feed. -Select flotation reagents with care. -Introduce reagents in the proper sequence.

Jan 1, 1988

By Michael Drozd

Introduction Flotation is a recovery process that utilizes natural or chemically-introduced hydrophobicity of minerals to separate ore from gangue by attaching the ore particles to bubbles. Flotation has been known since 1906, when it was patented by E. L. Sulman, H. G. K. Pickard and John Ballot. Flotation's first documented plant use was in 1911, when it was used on gravity tailings from a zinc plant. Cyanide leaching was first patented in 1887. Most early precious metals flotation was linked to lead or copper concentrates. Most precious metal flotation is linked to sulfide recovery and utilizes such reagents as xanthates, dithiophosphates and thiocarbanilides. But the involvement of flotation in precious metals recovery does not have to be limited to active flotation of the gold and silver bearing minerals. Flotation can be used to remove interfering minerals, such as carbon, or cyanicides, such as copper, arsenic bearing minerals or other cyanide complexing minerals. Cyanide Leaching The use of cyanide to recover precious metals is the backbone of the industry. The various recovery processes that use cyanide are: 1. Leaching-Counter Current Decantation(CCD) Merrill-Crowe 2. Carbon-in-pulp (CIP) 3. Carbon-in-leach (CIL) 4. Vat leaching 5. Heap leaching These processes are selected depending on ore grade, ore leaching characteristics, reserve size and capital limitations. Ore grade is used as the first criteria to determine the type of cyanide plant required. However, the reserve size can determine whether a ground ore alternative is used. The ore leaching characteristics may indicate that the higher recovery, associated with a process that employs grinding, is the only economic recovery alternative. There are some extremely large leaching plants with grades that would be non-economic for some existing heap leach plants. Many factors, such as strip ratios, metal recovery and reserve size, determine what the ultimate plant design will be. The exact processing scheme that is used, is a multifaceted decision matrix, which gives the process metallurgist some job security. Precious Metal Recovery Using Flotation Flotation recovery can conceivably be used on any ore that has been ground. Many operations utilize gravity separation on the ore to remove native gold from the ore prior to sending it to cyanide leaching. On certain ores, where the gold is in visible nuggets or particles, this processing alternative is advantageous because the native gold cyanide recovery is

Jan 1, 1993

By T. Negeri, M. Boisclair

"A hybrid process consisting of flotation and magnetic separation has been developed to concentrate multi-phase rare earth minerals associated with a carbonatite ore that contains a significant amount of niobium. Fine grinding to a d80 of <65 microns was required to obtain acceptable separation of 92% of the contained total rare earth oxide (TREO) and niobium in half the feed mass. Whereas it was possible to obtain 85% of TREO in 28% of the feed mass through staged cleaning, it was demonstrated that at least 87% and 85% recoveries of TREO and Nb respectively could be achieved in 16% of the feed if the rougher-scavenger concentrates were calcined, quenched, reground to <25 µm and then magnetically upgraded. The paper discusses the overall concept of the flowsheet and the experimental strategies that led to this progress. INTRODUCTIONOut of the approximately 250 minerals known to contain rare earth elements (REEs), only about 60 of them contain REEs in significant amounts. Over 95% of the world’s rare earth oxides (REOs) are believed to occur in the form of three minerals (Pradip & Fuerstenau, 1991) namely bastnaesite (Ce,La,Y)CO3F, monazite (Ce,La,Nd,Th)PO4 and xenotime Y(PO)4. An estimated 51.4% of global REO resources are hosted by carbonatite deposits with the same three minerals as major constituents (Weng et. al., 2015). Any one of the REEs or commonly all of them can be found in these minerals (Ravnaas, 2010). As the demand for critical REEs increases due to the ever increasing applications in advanced technologies, many deposits containing other forms of REE minerals will have to be developed. REE minerals are extensively dispersed and intergrown with several oxides, silicates, carbonates, and phosphate minerals. Consequently it is possible to liberate them only at fine grinding and is thus difficult to separate and produce high grade rare earth mineral concentrates. Most of these minerals contain other important elements such as tantalum (Ta), niobium (Nb), uranium (U), and thorium (Th) in varied quantities. REE minerals in the same ore may exist as carbonates, fluorocarbonates, niobates, silicates, phosphates etc. in association with gangue minerals belonging to different mineralogical groups."

Jan 1, 2016

By Marisa Martins

Este trabalho aborda o processamento de rejeito proveniente do circuito de flotação de minério de ferro da mina de Cauê. A amostra utilizada no presente estudo apresentou teores médios de 27% de Fe, 59% de SiO2 e 1,4% de Al2O3. A concentração de hematita contida neste rejeito foi avaliada, utilizando-se flotação aniônica em meio ácido e na presença do ânion SiF6 2-, como depressor da ganga silicatada. De posse da caracterização granulométrica, química e mineralógica do rejeito, ensaios tecnológicos de flotação foram executados, objetivando a avaliação dos variados sistemas de reagentes. Diferentes dosagens dos depressores H2SiF6 e Na2SiF6 e ainda de três diferentes tipos de coletores aniônicos foram avaliados. Os melhores resultados foram alcançados pelos coletores do tipo ácido graxo e sulfonato de petróleo, os quais geraram concentrados contendo 66% de Fe e 4% de SiO2, e recuperações metalúrgicas de Fe de 59% e 71%, respectivamente.

Aug 16, 2017

By Ana Carolina Fernandes Reis

O objetivo do trabalho foi investigar a recuperação metalúrgica da flotação de sulfeto de ouro utilizando diferentes tamanhos de partículas, a partir de ensaios de moagem e flotação em bancada, visando analisar o melhor desempenho e seletividade do processo. O minério em estudo apresenta um teor médio de ouro de 5,28 ppm e 0,59% de S. Nos testes verificou-se uma correlação diretamente proporcional entre a recuperação mássica e metalúrgica, ambas mostraram-se inversamente proporcional a seletividade no concentrado. A granulometria com 90% passante na malha de 0,053mm obteve o melhor resultado de recuperação tanto do ouro como de sulfetos, em contra partida, apresentou o menor grau de seletividade.

Aug 16, 2017

By Marcello Rodrigues Cruz

O presente estudo objetivou avaliar as diferenças no processo de flotação entre as frações -0,150 +0,038 mm e -0,038 mm, bem como a redução de custo no processo de flotação. Verificou-se que as frações apresentam resultados bem distintos em recuperação mássica, recuperação metalúrgica, seletividade, razão de enriquecimento e teor de sílica no concentrado, condições ideais de adição de reagentes e qualidade final de concentrado e rejeito entre as frações e também se comparada a ao experimento controle, composto com a mesma amostra sem ser fracionada. Através dos testes executados segundo o planejamento fatorial, foram estabelecidos os pares de variáveis ótimas para a flotação para cada fração distinta e as possíveis otimizações utilizando-se a ferramenta estatística. Os resultados obtidos dos testes de bancada apontaram que a amostra composta e as frações separadas apresentam comportamentos distintos quanto às variações dos fatores dosagem de amina, dosagem de amido e pH de flotação e que os resultados do processo melhoram significativamente em relação ao processo sem o tratamento fracionado.

Aug 1, 2018

By Kavetsky A

A new model of flotation is presented which allows predictive calculations of total solids flows and metal grades and recoveries to be made for industrial flowsheets. A method of making these calculations is presented and illustrated with examples. The problem of determining sufficient flotability characteristics from a sample of circuit feed to predict the behaviour of that specific ground ore in the flotation circuit (ie performing flotometric analysis) is addressed, and some suggestions are made for its solution. A feature of the flotation model is its practical technological orientation, allowing determination of a small number of ore flotability parameters by fitting observed batch kinetic flotation data. The unit model explicitly includes the cell aeration as total bubble area per unit pulp volume, and pulp residence time. Although more complex unit models are feasible, it is thought that this model is sufficiently realistic to illustrate the points made. The modelling approach is illustrated by application to flotation data from a Kambalda ickel circuit. The model is parameterised and ore flotability parameters are back-calculated from batch kinetic data. These parameters are then used to fit the observed behaviour of the industrial circuit by numerically adjusting the unit aerations. Finally, it is shown how the model may be used to predict the effect of circuit and ore changes on the circuit&apos;s technological indices.

Jan 1, 1992

By P. W. Bridgman

FLOW and fracture are admittedly complicated phenomena of which we are yet only partially masters. There is not even universal agreement as to the details of the language best adapted merely to describe the phenomena, to say nothing of any theory. Certain points of view, however, are widely held, and there are certain general expectations as to what sort of procedures will prove permissible. A complete description of any situation involving fracture would demand a complete history of all the variables in the control of the experimenter. The experimenter endeavors so to choose his independent variables that they are adequate to determine completely the situation in the sense that when an experiment is repeated on the same initial material and with the independent variables running through the same sequence, all the other measurable properties of the system will also run through the same course. It is, I think, the universal conviction that when we are dealing with phenomena of flow and fracture, the most important of the necessary variables are the external forces acting on the various parts of the body; when the force history repeats, with certain obvious restrictions such as that temperature must be constant and non- mechanical forces, such as magnetic field, must be small enough to be ineffective, then the history of all measurable properties will repeat; in particular the alteration of geometrical shape due to flow will run through the same course, and when fracture comes, the character of the fracture will be reproduced. Complete mastery of merely the descriptive aspects of flow and fracture would demand the ability to predict the entire course of flow and complete characterization of the final fracture for every possible combination of forces, varying in time in all possible ways, when applied to bodies of all possible shapes. This full situation is obviously of prohibitive complexity. The first stage in reduction to manage- able simplicity is to resolve the total situation into the sum of contributions made by small elements. Our thesis is that if each of the elements is adequately characterized, the behavior of the whole system is fixed. The element is usually taken of a simple geometrical shape, suggested by the mathematics best adapted to the particular situation. The forces acting across the faces of the elements are ultimately determined by the forces acting across the free faces of the whole system. The detailed process of finding the precise forces on the faces of all the elements in terms of the external forces involves the use of a special mathematical invention, the stress, a constructional quantity consisting of six components. The stress at any point in the body is determined by both the external force system and by the physical properties of the body at all points; quite different stresses prevail at the interior of bodies of the same shape under the same external forces in the elastic and plastic ranges. The forces on the faces of any element are, however, uniquely determined by the stress system at the element. Our fundamental thesis

Jan 1, 1944

By X. Xe, B. Myhre, N. Zhou, B. Sandberg, Z. Chen

Effects of microsilica and reactive alumina type on flowability, flow decay and working time of Al2O3-SiC-C castables for blast furnace trough were investigated. The results show that at a targeted self flow values of (80 ± 10)%, water demand markedly decreases with increased microsilica addition. The nature of reactive alumina has a strong influence on flowability of the castables. Higher microsilica content contributes to a longer working time. The flow decays gradually until the working time and then drops abruptly. In addition, microsilica have positive effect on both cold strength and hot strength.

Jan 1, 2004

By A. Andreas Hejja

Flow of slag and settling of matte in slag resistance electric furnaces are discussed in conjunction with furnace geometries, stirring action of the electrodes, buoyancy and electromagnetic effects. The rectangular electric furnace was regarded as a channel reactor and the mode of slag flow as a channel flow. The flow is affected both by buoyancy and electromagnetic forces, however the effect of electromagnetic forces is minimal. The flow velocity is made up of two components; (i) that developed by the action of the electrodes, and (ii) the bulk flow velocity determined by the smelting rate and the volume of the reactor. Slag samples were taken from various depths of the molten bath and were analyzed microscopically to determine the size and distribution of matte particles, The action of the electrodes was described by a simple mathematical formula indicating a balanced settling rate in the area of electrode action.

Jan 1, 1996

By Donald J. Hallbom

Limonitic nickel laterites slurries exhibit complex rheological properties including time dependency that varies from thixotropy to rheopexy. Chronic problems may occur if plant designers and operators fail to take time dependency into account. Stress decay tests indicate that laterite slurry takes roughly two minutes to approach steady state after a step change in the shear rate. As a result, most rheometer measurements are taken at a non-equilibrium state, making evaluation difficult. Two minutes is also long relative to the time that a unit of slurry in a processing plant is at any given shear state, so the slurry may never reach equilibrium. This paper presents a method to describe the rheology of laterite slurry using a Flow Array, which describes the rheology using an array of instantaneous flow curves crossed by an equilibrium flow curve. A rate equation for structural change in non-equilibrium conditions allows time dependence to be efficiently modeled. This flow array allows the flow behavior of time- dependent slurry to be predicted in non-equilibrium conditions using a simple time-step methodology. Keywords: Rheology. nickel laterite, hydraulic transport, pressure acid leach, flow array

Jan 1, 2004

By F. Hosseini

Shaping of metals by thixoforming relies on the unusual flow behavior of semisolid slurries containing nondendritic solid phase. The Flow behavior of metallic alloys containing both solid and liquid phases is investigated in the low solid fraction range (, 55%). This behavior depends on both the solid fraction and the shear rate. Four different shear rates is applied using back extrusion technique and flow stress versus true strain in different solid fraction is compared. It is well accepted that the flow stress s of alloys in their semi-solid state obeys to a thixotropic behavior, due to agglomeration and dissagglomeration phenomena during forming. The load-displacement curves produced from the tests may show an initial peak, believed to originate from a skeletal structure which rapidly breaks down under shear. Apparent viscosity obtained from this method is compared with other works and the proper power law of pseudo plastic state is introduced.

Oct 1, 2011

By P. Vlasak, Z. Chara

Since the flow behaviour of slurry containing both coarse and very fine particles has not been sufficiently clarified, the paper focuses on the experimental study of the particle size distribution, time and intensity of shearing and the effect of chemical agents on the hydraulic gradient versus the average velocity relationship of fluidic ash slurries in the laminar and turbulent regimes. The recirculation pipe loop with smooth stainless steel pipes of inner diameters 26.8 and 36 mm was used for measuring the ash-water mixtures flow parameters. The dense fluidic ash-water mixtures behave as time dependent non-Newtonian slurries. Shearing, the addition of bottom ash or chemical agents, favourably affects the flow behaviour of dense fluidic ash-water slurries. The hydraulic gradient in the laminar region significantly decreases; also the laminar/turbulent transition region is reached for lower flow velocity.

Jan 1, 2007

By Christie GB, Mainwaring DE, Leong YK

High solids brown coal slurries have been prepared with concentrations approaching those achieved with bituminous black coals. The high inherent water content and macroporosity of Victorian brown coals have been reduced in a controlled manner by chemical and mechanical means. The hydrophobicity of the coal surface has been increased sufficiently to reduce the tendency for swelling and water uptake. This together with densification has allowed the solids content to be progressively improved from 25% solids with raw coal to 65% solids with modified coals. Both raw brown coal and modified brown coal suspensions show shear thinning behaviour resulting in lower viscosities at higher flow rates. All coal suspensions displayed a yield stress once sufficient solids concentration was achieved. This yield stress can be used in the prevention of solids settling. Under simple shear mixing the network structure that provides the yield stress quickly breaks down to a low viscosity fluid with reduced yield stress and a pumpable consistency. The time necessary for structural recovery is in the order of days permitting shut-down and start-up of fuel delivery systems.

Jan 1, 1987

By Wenjun Duan, Zhimei Wang, Tianwei Wu, Qingbo Yu

In order to recover the waste heat of molten blast furnace slag, a reactor with top-submerged lance was established. The numerical simulation and experiment study of the flow characteristic in the reactor were conducted. The mathematical model of reactor was established and the Euler-Euler model was employed to simulate the gas-liquid flow in molten slag bath. Meanwhile, the experiment results were obtained and compared with the simulation to testify the accuracy of the established model. According to the bubble behavior in bath, there were four stages: initial expansion stage, bubble detachment stage, freedom lift up stage and bubble broken stage. When the flow field in bath fully developed, the gas fraction decreased with the increasing of bath depth. During injection process, the area near the nozzle and lower the bath would first generate two symmetric heliciform flow regime, and then the flow regime in whole bath would become irregular because of bubble lifting up and rupturing. The gas fraction in bath, the average velocity and turbulence energy of slag would decrease before it increased to maximum and then it would keep fluctuate in a range.

Mar 1, 2018

By Partridge A. C

Pinched Sluices, in a variety of guises, are used extensively for the separation of minerals according to density. In the authors&apos; work a pilot-scale sluice has been constructed with provision for splitting the discharge stream into a number of layers. The composition and flowrate of the stream can thus be analysed as a function of depth and the results presented graphically. The effects of such parameters as total flowrate, pulp composition and particle size on overall performance can be clearly seen from such data.

Jan 1, 1979

By L Barro

There is currently a worldwide interest in coal-oil technology as the search continues for alternative energy sources to reduce the consumption of petroleum crude. An important aspect of this coal-oil technology study is to obtain information on the flow properties of coal-oil slurries. While some work has been reported on the flow behaviour of black coal-oil suspensions, very little work on brown coal-oil suspensions has been reported. In this paper flow characteristics of brown coal-oil suspensions for various coal concentration and temperatures have been presented. A capillary rheometer, designed to handle settling suspension, has been used for determining rheological properties. Brown coal of 0.0725 mm average particle diameter has been used in this work. The oil was a coal derived product having a boiling point range of 234¦C - 319¦C. Apparent viscosity of all suspensions was found to increase on storage due to ageing. Ageing might have occurred due to physicochemical interactions between coal and oil. Flow behaviour of some suspensions changed from Newtonian to non-Newtonian on storage. Apparent viscosity increased sharply with increase in solids concentration and suspensions at higher concentration behaved as non Newtonian liquids. Viscosity decreased with increase in temperature; rate of decrease slowed down with increase in temperature.

Jan 1, 1980

By Barro L

There is currently a world wide interest in coal-oil technology as the search continues for alternative energy sources to reduce the consumption of petroleum crude. An important aspect of this coal-oil technology study is to obtain information on the flow properties of coal-oil slurries. While some work has been reported on the flow behaviour of black coal-oil suspensions, very little work on brown coal-oil suspensions has been reported. In this paper flow charac- teristics of brown coal-oil suspensions for various coal concentration and temperatures have been presented. A Capillary rheometer, designed to handle settling suspension, has been used for deter- mining rheological properties. Brown coal of 0 0725 mm average particle diameter has been used in this work. The oil was a coal derived product having a boiling point range of 234¦- 319¦C, Apparent viscosity of all suspensions was found to increase on storage due to ageing. Ageing might have occurred due to physico- chemical interactions between coal and oil. Flow behaviour of some suspensions changed from Newtonian to non-Newtonian on storage.

Jan 1, 1980