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By S. Fawell, H. R. Manouchehri

The main electrophysical properties, i.e., dielectric constant and electrical conductivity, of pure calcite, quartz and wollastonite mineral samples were measured and their triboelectric charge attributes were investigated by contacting minerals particles with different tribochargers made from different materials. In addition the energetic work function values for mineral samples were estimated due to their acquisition charge. Besides, the behaviour of triboelectrically charged of different particle size fractions of mineral samples were inferred. Finally an attempt were made to translate the findings from single mineral systems to a real carbonate ore. The results exposed good prospects to beneficate the examined minerals by triboelectric separation.

Jan 1, 2002

By S. Goto, S. Yamashita, K. Hata

"The average consumption of zinc dust for purification of zinc leaching solution is more than 25 kg per tonne of electrolytic zinc. Authors proposed to remove impurities in zinc leaching solution by electrolysis instead of cementation by zinc dust. The effects of copper and arsenic on electrodeposition of cobalt in zinc sulfate solution were examined fundamentally using a potentiostat. It is observed that cobalt is easily deposited on a cathode at potentials under -480mV with arsenic. Mesh cathodes of stainless steel and lead anodes were used in a small electrolytic cell and the electrolyte was circulated through 'the electrodes during the electrolysis. The effect of electrolyte circulating rate , pH, cell temperature, current density, and concentration of copper and arsenious ions on removal of cobalt were studied. Removal of Cd and Ni are also examined.IntroductionCobalt is difficult to remove from a zinc leaching solution by a simple cementation reaction using zinc dust. However, it is easily precipitated by zinc dust with co-addition of arsenious or stibinous oxide and copper ion in practical operations(I), (2), (3). The consumption of zinc dust for purification is 16-152 kg per tonne of electrolytic zinc and 65% of this zinc dust consumption is used for cobalt purification. The average retention time for purification of cobalt is 4.5 hours (1). A more economical process for purification is desired instead of zinc dust. The mechanism of this acceleration effect of copper and arsenious oxide on removal of cobalt are explained by the authorsas follows; a galvanic cell is formed between zinc dust and copper which is precipitated firstly, and cobalt is reduced on copper as Co-As alloy by this galvanic current(2). This assumption was confirmed in experiments using a galvanic cell with a membrane( 4). The following galvanic reactions occur between zinc dust and copper precipitate; on copper cathode,2H+ + 2e -= Hz(g)2Coz+ + 2HAs02 + 6H ++ 10e -= 2CoAs + 4HzOand on zinc anode,Zn = Zn = 2+ 2e –This galvanic current becomes almost zero in a zinc sulfate solution which includes only cobalt and no arsenious oxide, and cobalt is weakly deposited on a copper cathode. Cobalt deposition requiers a high degree of cathodic polarization. However, the galvanic current flows almost constantly in an electrolyte, which includes arsenious oxide, and the cathode potential is kept at about -500mV. Cobalt is precipitated as Co-As on the cathode.The authors assumed that cobalt may be removed by electrolysis at a very low current density instead of zinc dust and the following experiments were carried out. In the first part of this paper, the fundamental experiments using a potentiostat on the behaviour of cobalt in zinc sulfate solution are described. In the second part, the results of the electrolysis are reported. Cobalt is removed by a new type of an electrolytic cell, which was desigoed to <Iccelerate the rate of deposition of cobalt. The removal of cadmium and nickel in a solution which includes cobalt and arsenic are also examined."

Jan 1, 1997

By Roland Kammel

In combination with various physical and chemical methods also electrochemical techniques are most frequently used to improve the recovery of metals from aqueous dilute process streams or effluents e.g. in electroplating, metal finishing, mining and metallurgical plants. To insure cathodic metal recoveries with favorable current efficiency and high throughputs per unit of cell volume seve¬ral types of electrolysis cells have been developed comprising extended electrode surface areas and/or intensive electrolyte. agitation. The practical experiences with these units indicate especially for the electrolytic recovery of metals whose values are high, that the treatment cost permits profitable operations with relativly short payback periods for the units. Anodic reactions can be utilized for the removal of undesired anion contents or buildups of impurities. Appropriate combinations of these recovery methods are used to improve the versatility and the overall economy. Industrial applications reveal their potentional as addidtive techniques for existing processes to reduce the metal content of effluents to values that meet the guide lines of environmental legislation whereas integrated in-operation recovery methods are nowadays increasingly introduced to approach nearly close-loop operations.

Jan 1, 1992

By Tedd E. Lister, Andre Anderko, Peiming Wang

Mobile electronic devices such as smart phones and tablets are a significant source of valuable metals that should be recycled. Value metals in phones are gold, palladium, silver, copper, cobalt and nickel. Devices now contain increasing amounts of rare earth elements (REE). Effective recycling schemes should include the recovery of these critical materials. Targeted recycling of items containing more of the less available critical materials could address their future criticality. This presentation will describe an electro-hydrometallurgy approach to efficient recycling of metals from scrap mobile electronics. The electrorecycling (ER) process generates oxidizing agents at an anode while reducing dissolved metals at the cathode. Development of the process involved generation of E vs pH diagrams, complemented with metals dissolution experiments used to assess the effectiveness of various solution chemistries. Although several schemes were envisioned, a two stage process has been the focus of work: 1) initial dissolution of Cu, Sn, Ag and magnet materials using Fe+3 generated in acidic sulfate and 2) final dissolution of Pd and Au using Cl2 generated in an HCl solution. Results from laboratory work will be discussed.

Jan 1, 2014

ELECTROREFINING Canadian 1,023,691 -Removal of bismuth from slime filtrate in the Betts process refining of lead. The filtrate is subjected to electrolysis in a cell having an anode of crude lead and a cathode of refined lead under operating conditions to preferentially deposit bismuth on the cathode. The substantially bismuth-free filtrate is recycled for use in the process as the electrolyte for producing high-purity lead. S. Hirakawa and R. Oniwa, assigned to Mitsui Mining & Smelting Co., Ltd. Jan. 3, 1978. 8 pp. (204-73). Filed: 2-18-74 (192,810). Same: U.S. 4,026,776, dated May 31, 1977.

Jan 1, 1979

By . A. C. Atenas

Control of arsenic in the Potrerillos&apos; Refinery electrolyte has been obtained by withdrawing a bleed stream of circulating electrolyte and ensuring the ratio of [O]/[As] in the cast anodes is maintained between 0.9 and 1.0. In order to achieve this control the anode oxygen must be adjusted, depending on the arsenic level in the cast anodes. It has been necessary to modify the time of the reduction step in the anode furnace refining process. Control of this ratio has permitted electro refining of anodes with high levels of arsenic, up to 3000 ppm, while minimizing the volume of electrolyte that must be removed for impurity control so as not to affect the copper concentration in the electrolyte. However this control strategy is not useful when the arsenic concentration in the cast anode is too high, because it is limited by the maximum oxygen concentration allowable for a good quality anodic. Costs have been reduced in anode furnace refining because it is no longer necessary to use alkaline flux injection to remove the arsenic in cast anodes.

Jan 1, 2007

By T. Sugawara, H. Sekimoto

Electrorefining of low-grade copper alloys containing various amounts of nickel, lead, antimony, bismuth, arsenic, selenium, silver, and gold in sulfamic acid media was demonstrated. The copper concentration of the alloys used as an anode was 70–90 wt%. The electrolyte contained 100 g L-1 of free sulfamic acid and 40 g L-1 of cupric ion. Galvanostatic electrolysis was conducted at 200–300 A m-2 in the electrolyte using a low-grade copper alloy anode and a stainless steel cathode at 25C. The terminal voltage was approximately 0.8 V at the start of the electrolysis, although it increased periodically to approximately 2.0 V and then shortly returned to its initial value. Nickel, lead, and arsenic from the anode dissolved in the electrolyte and were removed. Antimony, bismuth, selenium, and silver were removed as solids. Consequently, a dense copper cathode was obtained, and the concentration of copper was evaluated by inductively coupled plasma – optical emission spectrometry to be 99.82–99.99 wt%. INTRODUCTION Electrorefining of copper is conventionally carried out in a sulfuric acid electrolyte using crude copper assaying at 99.5 wt% Cu as the anode (Biswas & Davenport, 1994). Elements more noble than copper do not react anodically, and consequently, they are distributed in anode slimes. Elements less noble than copper dissolve from the anode. Nickel and arsenic are stabilized as aqueous species. Lead, antimony, and bismuth react with water, sulfuric acid, or arsenic acid to form barely soluble compounds; thus, they are distributed in anode slimes. An emerging issue in the electrolytic refining of copper is an increase of impurities in crude copper used as the anode (Moats et al., 2013). This is due to an increase in the content of impurities in copper concentrates as well as an increase in the types of secondary copper feedstocks (e.g., E-Scraps, automotive shredder residues, and smelting residues) treated in the copper pyrometallurgical process. An extreme case is a copper smelter that does not use copper concentrates as feedstocks. In such a process, copper-bearing feedstocks are smelted in a top submerged lance furnace to prepare low-grade copper alloys assaying at 80– 90 wt% Cu (Sekimoto et al., 2013). Such low-grade copper is not acceptable as an anode in the conventional copper electrolytic refining process because it is easily passivated during electrolysis. Consequently, electrolytic copper is produced by leaching the atomized low-grade copper in a sulfuric acid solution with oxygen, followed by electrowinning. However, electrowinning should be avoided whenever possible because the electrical energy consumed in electrowinning is 5–10 times higher than that consumed in electrorefining. Therefore, the development of technologies for electrorefining of low-grade copper alloys is desirabl.

Jan 1, 2019

Zinc produced by pyrometallurgical processing techniques suffers the disadvantage of restricted market potential because of its impurity contents, typically lead and cadmium. Market zinc to the Special High Grade (SHG) standard can only be produced by reflux distillation refining, which is costly in terms of energy and equipment, and potentially capacity limiting. Recent published laboratory work suggested that molten salt electrorefining of zinc metal is a potentially much cheaper alternative to the reflux distillation refining. The extrapolation of the laboratory results to an industrial configuration, however, resulted in an estimated power consumption for electrorefining and associated costs offering no advantage over current reflux distillation practice. A review of this estimate now shows that a serious error in calculation was made, and that the energy consumption for the electrorefining of molten zinc would be an order of magnitude lower than that for reflux distillation refining. While this is a promising indication, further research is required before development towards an industrial scale operation is warranted. This would particularly relate to the extent to which adverse electrolyte deterioration may take place and its potential effect on the anode and cathode efficiencies of the process. This paper considers the laboratory investigations required to explore the industrial potential of the molten salt electrorefining of zinc and foreshadows some of the practical problems to be solved in further development.

Jan 1, 2000

By Olli Hyvärinen

The capacity of Outokumpu Pori Copper Refinery has been increased by 50 % to 70 000 t/a in the last five years by adopting periodic current reversal, reducing spacing and installing some new cells in the old tank house building. Five years operation of PCR has proved that it is possible to achieve additional capacity with PCR and yet produce high quality cathodes. The impurity level in anodes has considerably increased, and recently, arsenic, antimony and sometimes bismuth have displaced nickel as the most critical impurity.

Jan 1, 1987

By V. V. Satya Prasad, A. Sambasiva Rao

Electroslag melting technologies have recently been developed for recycling light scrap of valuable metals and alloys such as superalloys and oxygen free high conductivity (OFHC) copper at Defence Metallurgical Research Laboratory (DMRL), Hyderabad. Conventionally, electroslag melting processes use consumable electrodes. Because of the difficulty in compaction of scrap into a consumable electrode of satisfactory quality, non-consumable electrodes such as graphite and water-cooled copper have been designed. Electroslag remelting using a water-cooled non-consumable electrode was developed to melt scrap of a nickel base superalloy. Sound ingots with smooth surface finish and properties comparable to vacuum melted superalloys could. be obtained from scrap using this process. A modified electroslag crucible melting process using graphite crucible and graphite electrode was developed for recycling OFHC copper scrap. Copper ingots with less than 10 ppm oxygen and electrical conductivity"" 100% IACS could be produced. The same process was also utilized to produce copper-based alloys such as copper-chromium and copper-titanium starting from copper scrap.

Jan 1, 2000

By Ralph H. Nafziger

The Bureau of Mines, in cooperation with the Idaho National Engineering Laboratory, has electroslag melted a V-5Ti-5Cr alloy using a fused CaF2, flux. The alloy is a candidate for use in future fusion reactors. One objective of this research was to evaluate the feasibility of the electroslag melting process in separating simulated radioactive isotopes from the V alloy to demonstrate recyclability. Small amounts of Ca, Y, and Mn were added as surrogates for radioactive isotopes. Results showed that this vanadium alloy can be electroslag melted satisfactorily. The impurities added intentionally were removed or decreased successfully. Among the major alloying constituents, Cr was retained but there were some Ti losses. The latter may be controlled with process refinements. This research suggests that the electroslag melting process could be a suitable method for recycling V alloys after use in future fusion reactors, or for processing other reactive metal alloys with more immediate applications.

Jan 1, 1996

By D. W. Heard

Electrospark Deposition (ESD) is a low heat-input, high energy density, micro-welding process. The short pulse duration and high-pulse frequency, in combination with the small amount of material transferred during each pulse, results in the evolution of extremely rapid cooling rates, believed to approach 105-106 °C/s [1]. This rapid solidification event results in the refinement of the microstructure to the nanostructured or amorphous level [2, 3]. Figure 1 displays the resultant microstructure of an Al-17%Si alloy deposited by the ESD process. Furthermore, it was determined that the microstructure of the deposit remained unchanged after subsequent layers were welded onto the presented layer. Freeforming of materials is a rapid prototyping process in which the deposited feedstock is built-up to the desired geometry in a near-net shape manner. Figure 2 displays the automated set-up employed produce three dimensional freeformed objects via multiple deposition trials of the ESD process. The automated XYZ table is equipped with CNC software to transform CAD renderings into three dimensional tool paths. Figure 3 displays an Al-12Si freeformed gear (2" diameter, 12 teeth) produced by the ESD process, prior to removal from the substrate. An SEM analysis of the freeformed component showed that the microstructure did not coarsen during the deposition of subsequent layers during the freeforming process, as depicted in Figure 4, resulting in the production of a bulk nanostructured component. This paper represents a summary of the capabilities of ESD to fabricate advanced materials possessing refined microstructure. In particular, results on the microstructural evolution obtainable for various wear-related systems will be presented. In addition, the feasibility of using the ESD process to freeform three-dimensional objects via multiple deposition passes will be presented and accompanied by a characterization of the properties of the freeformed component. [1] R. N. Johnson, "ElectroSpark Deposition: Principles and Applications," in Society of Vacuum Coaters, 2002, pp. 87-92. [2] J. Milligan, D. W. Heard, and M. Brochu, "Formation of nanostructured weldments in the Al-Si system using electrospark welding," Applied Surface Science, vol. 256, pp. 4009-4016. [3] S. Cadney and M. Brochu, "Formation of amorphous Zr41.2Ti13.8NilOCul2.5Be22.5 coatings via the ElectroSpark Deposition process," Intermetallics, vol. 16, pp. 518-523, 2008.

Jan 1, 2010

By R. Farhat

Coating systems that yield a thermally grown oxide (TGO) protective layer have been proposed as a potential method for extending the lifecycle of components exposed to high temperature corrosion. This is particularly relevant to the petrochemical industry, where any reduction in corrosion rates can yield substantial cost reductions. The primary goal of this project is to develop a coating repair procedure and to investigate the oxidation performance of the repaired location. Electrospark deposition (ESD) was used to repair spalled segments of TGO grown on MCrA1Y substrates using various electrodes possessing mixed crystal structures. Specifically, electrodes of NiCoCrA1Y (BCC-FCC mixtures) and CoNiCrA1Y (FCCBCC mixtures), were deposited and oxidized to develop the TGO using a heat treatment of 24 hours at 1000°C in air. This presentation will focus on the microstructural evolution of the base metal and ESD repair on damaged area, in both as- deposited and oxidized forms. Results of SEM and XRD analysis will be presented.

Jan 1, 2011

By J. J. Cilliers, J-A. Lamamy, J. N. Rasera, K. Hadler

Production of oxygen on the moon can be achieved by reduction of lunar soil. One such reduction technology, hydrogen reduction, favours a high proportion of ilmenite in the feedstock. Ilmenite is present in lunar soil as a minor mineral phase, but it can be upgraded using electrostatic separation. This study presents the results of a preliminary investigation into the operating parameters and sensitivities of a free-fall electrostatic mineral separator for lunar applications. Samples of ballotini and ilmenite as well as simple binary mixtures of the two were tribocharged on copper and passed through a uniform electrostatic field. The field is varied to change the electrostatic force acting on the particles. The proportion of material reporting to the positive electrode collectors, negative electrode collectors or the central collector was measured to determine the separation performance. The data confirmed that the charge transferred from the tribocharger to each species is in agreement with the triboelectric series; ballotini was found to charge positively on copper and ilmenite negatively. Particle-particle contacts were dominant, however, resulting in a somewhat symmetrical particle distribution in the collectors. These findings indicate that the copper tribocharger design requires optimisation in order to substantially increase particle-wall contacts. Four binary mixtures with feed grades of ilmenite ranging from 5% to 20% were prepared and tested. This study found that a higher ilmenite head grade resulted in a higher concentrate grade (26.3% from a head grade of 20%) with low recovery (3.4%). In contrast, the lower feed grade resulted in a low concentrate grade but higher recovery. The mass yield of ilmenite was 1.4 times greater for the highest-grade feed than for the lowest. A subsequent study into the reprocessing of middling fraction found a nearly constant relationship between cumulative grade and recovery. This is the first investigation into the effect of feed grade on the concentrate grade and recovery for lunar mineral processing. Keywords: Lunar resources, beneficiation, electrostatic, SRU, ISRU

Jan 1, 2020

By M. A. Bergougnou, I. Inculet, K. I. Burgess

This paper describes the electrostatic methods of separating various minerals, reviews the principles of fluidization and outlines the technique of electrostatic sorting in fluidized beds. The application of the method to the benefication of coal is emphasized.

Jan 1, 1970

By I. I. Inculet, M. A. Bergougnou, J. D. Brown, R. M. Quigley, D. K. Faurschou

"Coal from Hat Creek, B. C., has been successfully beneficiated to remove ash while retaining calorific value by a dry electrostatic separation process using a fluidized bed for triboelectrification. Two samples of Hat Creek coal used in the beneficiation experiments have been characterized particularly with respect to their mineral and clay content. The calorific value recovery exceeds the simple dry coal recovery because of the heat lost in altering the clay minerals of the ash fraction during burning. Recoveries and ash contents of the beneficiated coal are comparable to recoveries by water washing, but the dry process avoids the potential water pollution problems.IntroductionProposals have been made which suggest an interim Canadian coal production target for the end of the century which will require a four- to fivefold increase over the 1977 production. This implies a nominal annual growth rate of about 6070 to achieve a production rate of 115 to 140 million tonnes/year. Whether or not this target is realistic, it is becoming increasingly evident that coal must be utilized more fully on a world-wide basis. The crisis in Iran has provided the latest stimulus to renewed interest in Canadian coals for domestic use and export.The emerging new era of coal utilization for fuel and chemical feedstock will not, however, generally tolerate the level of coal technology which prevailed prior to the availability of abundant cheap oil and natural gas. Economic, environmental and resource management considerations will necessitate, for example, the use of improved methods of beneficiating coal. Continued development and application of conventional processes, principally aqueous, involving heavy media and cyclones will solve many of the problems. However, less conventional processes may be preferable or necessary in certain applications."

Jan 1, 1980

By Floyd L. Prestridge

A test of a solvent extraction (SX) pilot plant featuring electrostatic coalescence has been performed by C-E Natco at the United Nuclear uranium mill in Church Rock, New Mexico. Operating in parallel with the United Nuclear SX system, the C-E Natco electrostatic SX pilot plant exhibited comparable extraction efficiency to the United Nuclear system which utilizes conventional mixer-settlers. The C-E Natco pilot, however, operated at much higher liquid loading rates and exhibited less communication between the aqueous phases of the extraction and stripping circuits.

Jan 1, 1983

By Henry A. Wentworth

(New York Meeting, February, 1912.) ELECTROSTATIC separation of ores in its present form is generally known as the Huff&apos; process from the name of Charley H. Huff, of Boston, Mass., through whose constant and persistent labors (with the invention of Clinton E. Dolbear as a basis) the successful commercial process embracing separative machinery and the various electrifying devices has been developed step by step, and the finances for the long period of development provided, and the method finally established and recognized throughout the world as an important and successful addition to the ore-dressing department of metallurgy. The permanent field-success of electrostatic separation began in 1908 with a 20-ton Huff experimental mill built specially for the purpose by the American Zinc, Lead.& Smelting Co., in Platteville, Wis., a plant which was a success from the start and was gradually increased in capacity as the market-conditions warranted to 100 tons of concentrates per day. Much credit is due to the above-mentioned company for its initial venture, and for its assistance in applying the process to field use. Prior to 1908 electrostatic separators had been installed and operated (but for a comparatively short time, however) in a number of places; some under the patents of Mr. Dolbear by himself and associates, and some under the patents of Lucien I. Blake and Lawrence N. Morscher, by W. G. Swart, mining engineer, of Denver, who has always been a courageous advocate of electrostatic separation. Due to the difficulties experienced in the generation of the electrical charges, the primitiveness of the separators, the wooden construction instead of iron as at present, the lack of control of the electrical fields and other difficulties overcome by the later inventions of the Huff Electrostatic Separator Co.,

Jun 1, 1912

Electrostatically charged water droplets efficiently suppress breathable dust produced during open air rock crushing operations, according to recently completed independent tests conducted for the Environmental Protection Agency. Since a primary rock crusher produces very heavy clouds of dust, this application was selected as an appropriate test site to measure the efficiencies of new "charged fogging" equipment in mining and mineral processing operations. EPA&apos;s Industrial Environmental Research Laboratory, Research Triangle Park, NC, contracted TRC-Environmental Consultants Inc. of Wethersfield, CT, to conduct a full-scale demonstration of a recently developed electrostatic fogger, designed to project a charged fog spray at distances up to 15.2 m. Test results indicated overall fogger efficiencies of approximately 70%. The Fogger IV* employed in these tests is reportedly the largest charged logger ever made, with an extremely long operating range. The original fogger was designed for indoor dust control; this fourth generation version is designed for fugitive dusts, indoor and outdoor, and has an operating range up to 15.2 in.

Jan 6, 1981

By O. H. Eschholz

THE electrostatic process of fume precipitation is an excellent example of the successful application of scientific knowledge to an industrial operation. Originally proposed for the precipitation of sulphuric acid mists, it has been extended until at present there is practically no fume carrying gas to which the method cannot be applied. Among the more common applications are: the recovery of non-ferrous smelter flue-dust, iron blast-furnace dust, cement dust, and potash fume. It should be borne in mind that the process is restricted to the precipitation of suspended particles, either liquid or solid, and does not separate gaseous constituents. However, -by proper temperature control, mixtures of vapors having different temperatures of condensation to either solids or liquids may he selectively precipitated. The process consists essentially of subjecting suspended particles, including those too minute to be effectively acted upon by centrifugal or gravitational forces, to such an electrical force that they are driven from the gas stream, acting as a conveyer, and deposited upon a suitable receiving surface. This directional impulse is obtained front the interaction of charged particles and an electrostatic field of definite intensity gradient existing between two dissimilar electrodes, known as discharge and receiving electrodes. In principle, the equipment is equally simple. As shown diagrammatically in Fig. 1, it consists of: (1) A source of high-potential direct current, requiring: (a.) Source of alternating-current energy. (b) Means of transforming from tow voltage to high voltage. (c) Means of converting alternating to direct current. (2) Precipitation chamber having: (a) Transmission tubes for fume-laden gases. (b) Suitably designed and disposed electrodes. (c) Means for affecting removal of deposited solids.

Jan 8, 1918