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By C. M. Flynn

The Bureau of Mines prepared and investigated xanthated sawdust adsorbents to determine their effectiveness in removing heavy metal ions from dilute aqueous solutions, mine-drainage waters, and brines. Stripping of the metal values from the metal-laden adsorbent was also investigated. The treated sawdusts had an adsorption capacity of 0.3 to 0.4 meg/g dry adsorbent for Mn, Co, Ni, Cu, Ag, Zn, Cd, Hg, or Pb from feed solutions with pH 5 to 6. The feed solutions tested included mine-drainage waters and geothermal brine. Effluent metal concentrations as low as 0.05 to 0.1 mg/l were obtained at effluent pH values of 6 to 9. The order of affinity of metals for the sawdust adsorbent is Na«Ca~Mg~Mn<Zn<Ni<Cd<Pb~Cu. The presence of Ca, Mg, or Na in concentrations as high as 2 g/l does not seriously impair the heavy-metal adsorption. Metals were desorbed from the metal-laden adsorbent by elution with dilute mineral acids, sodium cyanide, or salts of ethylenediaminetetra-acetic acid.

Jan 1, 1979

By Jeffrey Johnson, Thomas Brady, Radford Langston, Mary MacLaughlin, Hendrik Kirsten

The magnitudes and directions of in situ stresses affect the stability of mine openings, as well as the type and amount of ground support needed to maintain a safe working environment for miners. Using hollow inclusion stress cells, researchers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health obtained two in situ stress measurements from the face of two footwall lateral drifts at the Stillwater Mine near Nye, MT. The first measurement, obtained in 1997, was collected under the valley beneath the Stillwater River. The second measurement was obtained in 2002 under the main frontal massif of the Bear tooth Mountains in the western sector of the mine. Although few data are available, the major principal stress under the valley has been recorded as nearly horizontal in a north-south direction perpendicular to the ore body, while beneath the mountains, stress runs east-west parallel to the ore body. This paper documents the measurements, describes the in situ stress state, and discusses a finite-difference analysis of the biaxial test.

Compare the fire endurance of paneled steel stoppings with that of traditional concrete block Stoppings. Background Permanent stoppings or partitions arc used in mines to separate ventilation airways. The ability of stoppings to retain their structural integrity for a minimum length of time under lire conditions and prevent the spread of flame and toxic combustion products to an adjacent airway is critical. The success of miners in reaching safety during a fire depends largely on the presence of uncontaminated airways. Traditionally, permanent stoppings for coal mines are constructed of concrete blocks. Recently, paneled steel stoppings that satisfy many of the requirements demanded of permanent stoppings, such as incombustibility and strength, have been introduced. Their use also introduced concerns such as the ability of a steel stopping to maintain its ventilation control function when exposed to a fire and the potential that the fire could transmit enough heat through the stopping to ignite combustible materials on the unexposed side. To address these concerns, the Bureau of Mines investigated the fire endurance of galvanized steel and concrete block stoppings.

Jan 1, 1989

Improve transmission of data from an underground mine monitoring system to a remote, mass-data storage system. Background Instrumentation systems in underground mines must operate under environmental extremes of dust and humidity, local electromagnetic/radio frequency (EM/RF) interference fields, and potentially explosive atmospheres. During a recent roof-bolt study performed by the Bureau of Mines, it was necessary to transmit a large quantity of data to a data storage system. Conventional wire cable transmission presented several limitations which often required special electrical isolation or physical protection. Because conventional wire cable presented certain problems, the Bureau of Mines investigated alternative means of data transmission. The research investigation led to the selection of fiber optic cable for data transmission applications. The fiber optic method of data transmission offers several advantages: ? Since the transmission medium consists of light waves, it is safe to use in gassy mines. Where applicable, MSHA permissibility standards for peripheral devices must be met. ? It is lightweight and rugged. ? It can operate up to 131000 feet (4km) without repeaters and without EM/RF field interference.

Jan 1, 1986

Provide low-cost fire protection for big bulldozers. Approach A fire protection system, previously used on mobile logging equipment and adapted to surface coal augers, has now been adapted for use on large mining bulldozers. How It Works Heat sensors mounted in the engine compartment and hydraulic hose areas detect the fire, usually before the operator does. This causes the system to automatically discharge A-B-C class dry chemical extinguisher through a fixed piping system. The system can also be manually activated from either the opera-tor&apos;s cab or ground level. Location of the principal components of the system are shown in the drawing The heat sensors of the sys-tem consist of bimetallic strip switches which operate at about 10000F temperature. Switch operation results in release of compressed gas from a small storage cylinder. The gas expands to blow the dry chemicals out of the nozzles, in a spray that lasts about 15 seconds. The compressed gas used is usually nitrogen, although carbon dioxide is also used.

Jan 1, 1978

Provide reasonably priced, reliable fire protection for loading shovels. Approach An automatic fire, sensing and suppression system using both dry chemical and Halon 1301 was developed. It is more rugged than similar industrial-type fire protection systems. How It Works Temperature sensors detect heat from a fire, and trigger the system. These sensors are located inside the machinery house and under the house and shovel frame where it rotates around the crawler chassis ring gear. An alarm is sounded, and extinguishing agents are released either in the machinery house or in the ring gear area. The system can also be triggered by a manual control. If the fire Is detected in the machinery house, all power is shut down to the motor-generator sets, ventilation fan, and all electrical controls. Doors are automatically closed. After a delay to allow time for the ventilation fan to stop, Halon 1301, a gaseous fire extinguishing agent, is released inside the machinery house until it reaches a concentration of about 7 percent. This concentration is sufficient to extinguish a fire, but isn&apos;t toxic to personnel

Jan 1, 1980

By David M. Hyman

Outbursts are sudden and violent releases of gas and coal that result from a complex function of geology, stress regime, and gas pressure and content. The Bureau of Mines has reviewed methods for prediction and mitigation of such outbursts in use worldwide, as an aid in selecting the proper techniques for use in specific mine environments. Outburst-prone coal may be distinguished from normal coal by its sorption-desorption velocity. Three types of methods used to characterize the kinetics of sorption-desorption are described; all are based on the ability of outburst-prone coal to release, through desorption, methane or carbon dioxide much more rapidly than normal coals. Other prediction methods, based on borehole samples, are also described. Various mitigation methods described and evaluated include (1) working the least stressed, less disturbed, lowest gas content seam in multiple-seam areas; (2) mine opening geometry; (3) inducer shot firing; (4) water infusion; (5) localized stress relief, using boreholes or by cutting a reliever slot in the longwall face; and (6) other gas drainage methods.

Jan 1, 1987

By A. F. Colombo

Infrared spectroscopy employing attenuated total reflectance (ATR) techniques on thin films of dried gelatinized starch solution was used during Bureau of Mines research to determine the structural and impurity differences in starch products and to correlate these characteristics with the flotation response of a nonmagnetic taconite. All of the starch products evaluated gave spectrograms which were characteristic of the anhydroglucose monomer and its polymerization product. Distinct infrared absorption peaks caused by the protein molecule were observed and were used to classify the starches. Correlation of laboratory flotation of calcium-activated gangue from a Mesabi Range nonmagnetic taconite and infrared spectra produced from gelatinized starches showed that protein impurities and linear chain structure limited the effectiveness of starches as iron mineral depressants. Starch products having spectrograms similar to pure amylopectin were generally good depressants for iron oxides, were effective at about one-half the addition that was required for starches that gave infrared responses similar to pure amylose, and yielded acceptable iron concentrates containing 61.5 percent iron and 6.5 percent silica.

Jan 1, 1969

By W. M. Dressel

Over 2 million tons of steel furnace dust containing approximately 100,000 tons of zinc and 10,000 tons of lead are produced each year. Recycling of the dusts would conserve mineral resources, lessen land area requirements for disposal, decrease pollution problems, and aid in solving our balance of payment problem. Steelmaking dusts can be pelletized and thermally treated to remove lead and zinc and to reduce the iron oxide to form metallized pellets. In laboratory tests more than 99 pct of the zinc and 85 pct of the lead was volatilized from the dust by roasting at 1,000° C in carbon monoxide. The volatilized material can be collected and treated further for lead and zinc recovery. Reduction and volatilization of over 95 pct of the zinc and most of the lead was achieved by roasting self-reducing mixtures of steel furnace dusts and high carbon steelmaking wastes in an inert atmosphere at 1,100° C. Over 80 pct of the iron in the resulting pellets was metallized.

Jan 1, 1974

By C. J. Chindgren

The Bureau of Mines investigated the technical problems involved in recovering commercial-grade vanadium products from alkaline solutions of low vanadium content. Conditions were defined for precipitating calcium vanadates from sodium vanadate solutions with calcium chloride and calcium hydroxide and for dissolving the precipitates with acid, sodium carbonate, and sodium bicarbonate to obtain vanadium-enriched solutions from which either red cake or ammonium metavanadate was recovered. Calcium vanadates with CaO:V205 mole ratios of 2, 3, and 4 were produced with recoveries of 93 to 100 percent. Optimum recovery of the low-lime variety of calcium vanadate was obtained by employing excess calcium chloride and adjusting the pH to a range of 8.0 to 8.5. High vanadium extractions were obtained in concentrated solutions by dissolving the calcium vanadate precipitates with any of the reagents tested. The resulting extracts contained 25 to 125 grams V205 per liter. Conventional procedures used to precipitate either red cake or ammonium metavanadate from the enriched solutions gave excellent vanadium recoveries.

Jan 1, 1967

By J. D. Marchant

As part of its mission to assure the maximum recovery and use of the Nation&apos;s mineral resources, the Bureau of Mines, investigated an improved procedure for producing rare earth-silicon alloys. For example, a charge consisting of 681 grams of mixed rare-earth oxides, 309 grams of ferrosilicon (75 wt-pct Si), and 182 grams of aluminum metal along with a flux consisting of 681 grams of CaO and 45 grams of MgO was reacted at 1,500° C in an induction furnace. Good slag-metal separation was achieved. The alloy product contained, in weight-percent, 53 RE, 28 Si, 11 Fe, and 4 Al with a rare earch recovery of 80 pct. In current industrial practice rare earth recoveries are usually about 60 pct in alloy products that contain approximately 30 wt-pct each of rare earths and silicon. Metallurgical evaluations showed the alloys prepared in this investigation to be as effective in controlling the detrimental effect of sulfur in steel and cast iron as the commercial rare earth-silicon-iron alloys presently used in the steel industry.

Jan 1, 1980

By Thomas A. Gray, Lynn M. Crayne, Michael A. Trevits, Phil Glogowski

Mine seals can be remotely constructed in underground coal mines, through vertical boreholes, when direct access to a fire is impossible or considered to be too dangerous. This method has great merit because boreholes can be drilled to specific mine areas and seals can be positioned close to a fire zone. The technology however, can be largely ineffective if the constructed seals do not provide effective barriers to airflow or cannot be used to impound water and other inert materials. Unfortunately, no viable alternatives exist to sealing the entire mine at the ground surface. Full-scale remote mine seal construction research is being conducted at the National Institute for Occupational Safety and Health’s (NIOSH) Lake Lynn Laboratory (LLL). Under this effort, Howard Concrete Pumping Company and GAI Consultants, Inc. have joined forces to evaluate a potentially significant improvement to the current state-of-the-art. This paper will cover development of novel technology for remote mine seal construction, evaluation of the materials used, construction practice, and follow-up testing.

By Benjamin W. Haynes

Materials from phosphate rock mining and processing were analyzed for fluorine and uranium content as part of the Bureau of Mines program to more effectively recover resources from mining and mineral processing reject materials. The analysis of both feed and waste materials generated in the beneficiation and acidulation of phosphate rock was performed to obtain information on the disposition and concentration of these elements in phosphate rock processing streams. Fluorine was determined by a distillation-titration method and by ion chromatography. Uranium was determined by the dibenzoylmethane (DBM) method, the reliability being confirmed by roundrobin analysis of samples within Bureau of Mines research centers. National Bureau of Standards (NBS) Standard Reference Material (SRM) 120b-Phosphate Rock was also analyzed for fluorine and uranium to verify procedures and results. Fluorine values ranged from 0.3 wt-pct in gypsum filter cake to 3.7 wt-pct in phosphate rock concentrate. Uranium ranged from less than 5 µg/g in gypsum filter cake to 200 µg/g in a dried clay slime.

Jan 1, 1981

By E. A. Johnson

As part of its effort to reduce the environmental impact associated with mining and metallurgical operations, the Bureau of Mines used a modified form of the Environmental Protection Agency&apos;s Extraction Procedure toxicity test on copper reverberatory slags that contained low, medium, and high levels of the impurity elements As, Pb, Sb, Bi, and Zn. All tests resulted in extracts that did not exceed those limits published in the May 19, 1980, Federal Register; there-fore, these solid wastes were designated as nonhazardous for most landfill disposal situations. However, arsenic and lead levels disturbingly close to the allowable limits--and even higher levels of copper and zinc, for which there are no established limits--leached from the high-impurity-element granulated slags. These slags should be handled in such a way so as to minimize the possibility of water contamination. One baghouse dust was tested according to the EPA procedure and found to exceed the extract limits by a factor of 10. This solid waste may be considered hazardous.

Jan 1, 1982

By Lisa Steiner, Robin Burgess-Limerick

In 2004, there were 646 underground coal mines in the USA employing 37,445 miners. These mines reported 3556 injuries to MSHA that year - 17% were associated with bolting machines (593 injuries), 8% with continuous miners (283 injuries), and 4% each with Scoop/LHD (1 51 injuries), shuttle cars (134 injuries), and personnel transport (145 injuries). The use of the frequency of reported injuries for the prioritization of risk control strategies has limitations because of the tendency to underestimate the importance of relatively rare but high-consequence events. Injury reports also underestimate the contribution of risk factors such as whole body vibration, which have a long-term cumulative contribution to an elevated risk of injury. However, taking these limitations into consideration, the results of the injury narrative analysis suggest the following hazards as the highest priority for elimination or control: • rock falling from supported roof • inadvertent or incorrect operation of bolting controls • handling continuous miner cable • collisions while driving LHD/Scoop, shuttle cars and personnel transport • rough road while driving or traveling in LHD/Scoop, SC & PT

By Norwood B. Melcher

This report describes preliminary experiments by the Federal Bureau of Mines on the practicability of adding raw pellets of taconite concentrate to blast furnace feeds. The usual industrial practice is to harden the pellets by heating before they are charged to the furnace. The Bureau research demonstrated that raw pellets could be successfully smelted in an experimental furnace with no significant change in coke consumption and only a moderate increase in dust losses. The dust loss was 43 pounds per ton of metal for an all-pellet charge, compared with 7 pounds per ton for an all-sinter charge. Raw taconite pellets undergo only slight degradation during charging to the furnace if 1 percent bentonite is used as a binder. INTRODUCTION Fines and concentrates must be consolidated or agglomerated into larger masses before they can be smelted in a commercial blast furnace. Such agglomeration is usually done by sintering, pelletizing, nodulizing, or briquetting. Sintering has been the more common practice, but with the advent of taconite concentrates pelletizing is increasing in importance.

Jan 1, 1960

By A. C. Fieldner

The Bureau of Mines has recently conducted a study of results obtained in analyzing similar samples of coal and coke by 25 laboratories throughout then country, in comparison with results obtained in the Bureau&apos;s coal laboratory at Pittsburgh. The purpose of this work was primarily to obtain a comparison of the methods of coal analysis used by the laboratories of the American Gas Association. Therefore, four standard samples of coal end one of coke ware prepared in the Bureau of Mines coal laboratory at Pittsburgh, and portions sent to each laboratory. At the same time, a like number of standard samples were submitted to 12 commercial laboratories rot affiliated with the Association, for the purpose of comparing their analyses with the results is obtained by the U. S. Bureau of Mines and the American Gas Association. Tire comparison is based on the average of 24 analyses by the Bureau of Mines on each kind of coal, and the accompanying curves show the deviation from this average analysis, together with deviations from the check limits of the American Society for Testing Materials.

Jan 1, 1923

By Martin H. Stanczyk

Freezing to dewater typical Florida phosphate rock slime as demonstrated in laboratory tests appeared to have potential commercial use because of indicated moderate energy requirements, good compaction of dewatered solids, and effective recovery of usable water. After freezing, thawing, decanting, and filtering, batch freezing of gallon-size 13.7 percent solids slime samples yielded 42 percent solids products. Cationic amine, used as a process additive, yielded 46.8 percent solids product with significant filter area reduction. Semicontinuous 8 stage freezing tests also produced thickened slimes. Cooling and freezing 13.7 percent solids slime from 30° to minus 10° C required removal of 183 Btu per pound of slime; Carnot cycle calculation indicated that the theoretical minimum energy to transfer this heat was 27.8 Btu per pound. To produce 1 ton of 44 percent solids slime from 13.7 percent sol-ids slime, the calculated theoretical energy required for cooling and freezing was 52.3 kilowatt-hours. During the research heat capacity and heat of fusion data were determined for the slime at various percent solids.

Jan 1, 1971

By James J. Olson

The Bureau of Mines used micro fracture density analysis of quartz grains in thin sections and diametric pulse velocity measurements along preblast and postblast cores to determine the nature and extent of rock damage produced by small (0.25-,0.50-,1.0-, and 2.0-kg) charges of high intensity explosive (C-4) in granite. Pulse velocities from the postblast cores were significantly lower than velocities from the preblast cores and, with the core logs, provided clear identification of the upper and sometimes the lower limits of most severe damage. These zones ranged from about 1.68 ft for the 0.25-kg blast to 4.16 ft for the 2.0-kg blast. Microfracture densities from postblast cores were significantly higher and more variable than densities measured from preblast cores. The microfracture density measurements showed that microscopic damage was present far past the zones of most severe damage as delineated by the pulse velocity logs and core logs. An exponential relation-ship was observed between the micro fracture density levels and the charge weight.

Jan 1, 1973

By VAN. H. MANNING

During the nine years that have elapsed since the Bureau of Mines was established in 1910, the work of the bureau has included many investigations that have proved of high value to the Nation. Eleven mining experiment stations established by act of Congress have greatly increased the bureau's usefulness; being situated in the mining fields, these stations are closely in touch with industrial needs, and the results of their research and educational work are more directly available to those engaged in the mining, metallurgical, and mineral industries. In the United States mining is second in importance to agriculture only. The Federal Government annually appropriates large sums in the interest of agriculture, whereas the appropriations for mining are relatively small. But the nation-wide popularity of Government assistance to agriculture should not overshadow the need of Federal assistance to the mineral industry. With scientific management farms can be made to produce indefinitely without any depletion of the potential resources of the soil, but the mineral wealth of a country is a fixed quantity, and every year's production brings nearer its ulti- mate exhaustion. As the deposits of the richer or more readily available ores, espe- cially those in the West, have been depleted, development of methods for mining and treating the leaner or more inaccessible ores has lagged, so that meeting the increasing demands for certain metals is becoming more and more difficult. In some branches of mining the small inde- pendent operator is greatly handicapped. He has to rely on custom mills and smelters for the profit or loss of his product, and because of relatively inefficient methods of milling or smelting he may receive no return for much of the ore he mines. Even though the small operator thinks he knows of improved methods of obtaining the metals from the ores, he can not afford to install the necessary machinery or to carry on experiments that may or may not prove successful. In view of the increasing need of metals and the impossibility of renewing the ore supplies, efforts should be directed toward developing the most economical and efficient methods in mining and metal- lurgy. The great mining companies carry on independent research work, some of them on a large scale; but as such work is usually undertaken for gainful purposes, these companies do not feel under any obligation to give the results of their investigations to the world. Clearly the solution of the difficulty is to place in the mining districts trained mining and metallurgical engineers who will investigate and solve the problems for the benefit of the whole industry. It is with this purpose in view that experiment stations of the Bureau of Mines have been established to investigate economy, efficiency, and safety in mining, and to make public the results of the investigations. The Federal Government can be of most help in developing the mineral resources of the country when its forces are brought in direct contact with these resources. Mining is as old as civilization, but only within a generation has this country busied itself with any other problem of mining than the amount of mineral products that could be put upon the market. Little concern was felt if much of the metal in an ore was wasted, if the miner lived in unsanitary surround- ings and died of preventable disease, or if accidents occurred fre- quently and from causes that could easily be controlled. Now we realize that the waste of any resource is inexcusable. The mineral wealth of the country can be mined but once. The task before the Nation is to recover as much metal as possible from the ore in the ground, and to do this in the most economical way without waste of human life. This task is of such magnitude as to warrant aid from the Government through experiment stations. In its efforts to make the work of these stations of most benefit to the mineral industry the Bureau of Mines seeks the cooperation of State authorities, of mine operators, of miners' organizations, and of every person interested. These experiment stations also serve an educational purpose. Gen- erally speaking, mining is not a preferred occupation. The miner should have reason to take greater interest in his work; he should feel that the experiments the Government is making affect him vitally by enabling him to increase his production and by making his work safer. The mine operator should realize that the Government stands ready to aid him, and he should know that he can bring his own problems to a Government organization that is trained and equipped to solve them. The surest method of accomplishing these results is to carry the work of the Bureau of Mines into the mining regions through the establishment of experiment stations easily accessible both to the mine operator and to the miner. Many miners in this country do not read English, but they can understand motion pictures of mining methods; they can learn how lives can be saved in case of accident; and they can appreciate the larger results gained by modern methods and equipment. In every

Jan 1, 1919