Search Documents

By W. C. Phalen

"Tho the term “magnesite” is generally applied to the iron-bearing carbonate of magnesium, such as is found in Austria and Hungary, by some Austrian magnesite is referred to as bruennerite. The mineral bruennerite has become of commercial importance only in Austria. The important deposits are found in Styria, lower Austria and northern Hungary. It is of interest to know that the world's largest deposit of spathic iron ores or iron carbonate (FeCO3), occurs at Eisenerz, Styria, while the world's largest deposit of spathic bruennerite is found at Veitsch in the same province.The Styrian and lower Austrian deposits are located much nearer the Adriatic sea than are the deposits of northern Hungary; and it is from the former that most of the exported magnesite has come. They are located south-west of Vienna, and extend west from Semmering thru the Murz Valley to Tyrol. The chief deposits reckoning from east to west are those of Semmering, Veitsch, Breitenau, Trieben, Radenthein, and Dienten.The largest and most important deposit is that at Veitsch located near Mitterdorf, on the South Austrian railroad in the Murz Valley, Styria. Here the magnesite, which occurs in the form of a lens is quarried on the slope of a hill in a series of terraces about 50 feet apart. The entire work extends thru a vertical distance of 500 feet. The huge magnesite lens is nearly 4 of a mile long and over 1,000 feet in width, and probably extends to a considerable depth.The formation containing the magnesite extends eastward beyond Vienna into Northern Hungary where magnesite is quarried beyond Jolsva and Nyustya in the Gomor district. In spite of the remote location of these deposits as compared with those in Styria, magnesite was shipped from them before the war a distance of 360 miles to the port of Fiume for overseas shipments to other parts of Europe and to America.The average analysis showing the composition of the Austria-Hungary mineral is as follows:The magnesite occurs as lenticular masses in a belt of Carboniferous rocks consisting mainly of metamorphosed Shales, sandstones, conglomerates,,and limestone, It is grayish in color when fresh, and contains sufficient ferrous carbonate to blacken it when calcined. It turns brown owing to the oxide ion of the ferrous carbonate when exposed to the air. The quantity of carbonate of iron is ariable and different analyses show that it ranges up to 13 or 14%For the most part, only the sintered article has been imported into The United States. This material has achieved an enviable reputation for its uniformity both as to chemical and physical characteristics. The homogeneity of the sintered Austrian magnesite is doubtless due in part to the averaging effect of the different operations, such as crushing, dressing, sintering, And mixing, n effect which is not obtainable in mere hand samples.There is comparatively little variability in the sintered magnesite as marketed, and five analyses of this sintered magnesite as quoted by Cornu* are gas follows:"

Aug 1, 1919

By Sidney Katell

An economic analysis of underground gasification of coal, based on experimental results obtained by the Bureau of Mines, indicates that a gas suitable for use in a power plant might be produced for approximately $.62 to $.77 per million British thermal units. This estimate does not include cost of land purchase. The gasification experiments were conducted in a 3-ft. seam of high volatile A bituminous coal. The major factors which can influence a change in operating costs are height of overburden, power costs, thermal efficiency, and the gasification air inlet pressure. The following equations show the relationship of these factors to operating costs:

Jan 1, 1961

By L. C. IlsLey, R. A. Kearns

"The electrical section of the Bureau of Mines has obtained copies of all available State safety rules and regulations in order to make a study of those portions of the codes relating to electrical equipment. While it has been found almost impossible to compare the several codes as a whole, comparison of those regulations dealing with a single subject has proved both interesting and instructive.Sixteen states have rules or enactments having reference to telephones and the present paper covers a compilation of these references. It is believed that data of this kind will be of service to commissions or other bodies contemplating the revision of existing codes.The compilation taken from the various codes follows: State Rules and Regulations.California.Sec. 5 (Par. c) Telephone communication shall be maintained between a co-operative station and each mine which it supplies. If the foreman in charge of a station does not reside thereat, his residence also shall be in telephone communication with each mine supplied by his station.Sec. 8 (Par. a) Whenever a fatal accident occurs in or about any mine, notice thereof shall be given promptly by telephone or telegraph if possible, followed by a notice in writing to the chief inspector, by the superintendent or other person having immediate charge of the work at the time of the accident."

Jun 1, 1921

By L. B. Pankratz

High-temperature heat-content values of gallium and scandium sesquioxides were measured over the temperature range from 298° to 1,800° K. The results fill gaps in the thermodynamic information for these compounds; no previous similar data existed. The heat-content values were combined with heats and entropies of formation to obtain free energies of formation of gallium and scandium sesquioxides to 2,000° K. The thermodynamic stabilities of the sesquioxides of aluminum, gallium, scandim, and yttrium were compared.

Jan 1, 1963

By R. V. Lundquist

The Bureau of Mines made a laboratory study of the amenability of anorthosite rock ( from the San Gabriel Mountains , Los Angeles County , Calif . ) to treatment by the lime soda sinter process for the extraction of alumina . The study was done under a cooperative agreement with the California Division of Mines and Geology . This report presents the results of the investigation , and it includes a review of the geology of the deposit ( 7 ) by Dr. Gordon B. Oakeshott . Interest in the recovery of alumina from submarginal aluminum silicate ores is stimulated by the fact that the domestic aluminum industry depends on imports of bauxite for its alumina requirements . Of the 8.0 million long dry tons of high - grade bauxite consumed in 1961 for producing metallurgicalgrade alumina , only 0.9 million long tons , or 11 percent , was mined in this country . During past years many organizations have carried out research programs to determine if alumina could be extracted economically from such domestic ores as clays ( 3 , 4 ) , anorthosite ( 8 ) , and other silicate sources . Successful alumina extraction is the ultimate objective of the Bureau of Mines program.

Jan 1, 1963

By R. S. Dean

The principle of explosive crushing depends upon the fact that an expandable substance contained within the pores of a solid body will disrupt such a body upon expansion. Such expansion may be obtained by the detonation of an explosive or by the sudden release of pressure of a superheated liquid. That this principle of disruption may be applied to minerals rests on the fact that cracks, cleavage planes, and pores exist in all mineral to an extent hardly conceived possible heretofore. Crushing by this method takes advantage of force applied from within the mineral rather than from forces applied from without. The application of a force from within would appear to be more effective. A consideration of the possibilities of such a method for crushing led to some experimental work of a preliminary nature, the results of which are embodied in this paper. No systematic program was followed in the work and the results are, therefore, not final and far from complete. The success attained so far, with the mediocre apparatus available seems to warrant a preliminary report, with the expressed hope that the work may be carried on as well-outline program covering such phases as have been impossible to investigate at this time.

Jan 1, 1931

By T. A. Hendrickson

The Bohemia district, situated about 30 miles southeast of Cottage Grove, Oreg., in the Calapooia Range, has been the major producer of lead and zinc in Oregon. Sporadic production has been Maintained from the district since its early discovery about 1858. In 1942, a selective-flotation mill was built at the Champien mine, which operated for only a short time and was forced to close because of the war and lack of labor. The Champion mill reportedly has been operated as a custom mill for the treatment of ore from the Musick and Helena mines, located in the district sometime in the past. This report summarizes the results of laboratory ore-dressing studies made on ore samples from the Musick and Helena Mines.

Jan 1, 1951

By F. E. Cash

The Holmes Safety Association , organized and named in honor of the late Dr. Joseph A. Holmes , first director of the United States Bureau of Mines , has for its object the prevention cf accidents , the improvement of health conditions at work, in the home , and in public places , and the promotion of the general welfare of its members . As a means of preventing accidents and advancing health and safety , the Holmes Safety Association disseminates information , gives instructions on subjects related to safety , and promotes first -aid and other forms of protective and accident - prevention training . This organization is intended to work and cooperate in the closest possible way with existing mine or plant safety organizations in conducting educational , social , and recreational activities for the promotion of health , safety , and efficiency .

Jan 1, 1929

By Richard D. Graves

Pitch from low-temperature carbonization of bituminous coal was hydrogenated at cracking conditions in a continuous bench-scale unit to produce low-molecular-weight oils and tar acids. The pitch contained 15.6 pct benzene-insoluble material, 4.0 pct hexane-soluble oil, and 80.4 pct asphaltene by weight. At 475° C, 7,500 psig, and 1.5 hours residence time, hydrogenation products, based on the weight of pitch, were about 36 pct oil boiling below 325° C, 24 pct hexane-soluble heavy oil, 17 pct asphaltene, 1 pct benzene insolubles, and 12 pct hydrocarbon gases. The yield of tar acids boiling below 250° C was 4.3 pct, and the yields of C6 to C8 paraffins, naphthenes, and aromatics were each less than 1.0 pct. The yield of tar acids was within the range of yields obtained by hydrogenation or high-temperature carbonization of bituminous coal (2 to 5 wt pct). Yields of oil boiling below 325° C increased with increased residence time or temperature. There was little or no effect of residence time on yields of alkali- soluble material which contained tar acids. Yields of hydro-carbon gases increased markedly with an increase in temperature from 475° to 500° C. Lowering the hydrogen pressure to 4,500 psig resulted in yields similar to those obtained at 7,500 psig.

Jan 1, 1962

By Chas. G. Maier

The bright annealing of copper is an industrial practice of considerable importance. In connection with this process, equilibrium concentrations of carbon monoxide and dioxide, which may exist in contact with copper and cuprous oxide at elevated temperatures, are of interest. Data obtained at the Pacific Experiment Station of the U. S. Bureau of Mines enable estimates of these equilibrium concentrations to be made in two independent ways. Although the publication of final data on one method can not take place until certain further experimental work is accomplished, repeated requests which the Bureau of Minus has had for data relative to the annealing and deoxidation of copper justify the present preliminary report. This paper deals with the calculation of gas concentrations in the reduction of cuprous oxide, using more scientific data which will be published later, and refers especially to those conditions of temperature and concentration of practical implication, and from which critical limits ensue.

Jan 1, 1929

By Jack D. Ramsdell

The objective of this investigation was to make a preliminary evaluation of titanium-vanadium-zirconium, alloys using room-temperature tensile properties as criteria for selecting promising alloys for future critical studies. Arc-melted titanium-vanadium-zirconium alloys ranging in composition from 5 to 20 a/o (atomic-percent) vanadium and 5 to 30 a/o zirconium, were investigated to evaluate hardness, hot workability, and room-temperature tensile properties. Metallographic examination coupled with hardness measurements were used to follow structural changes and aging response. Room-temperature tensile properties were criteria for evaluating mechanical and engineering properties of the alloys.

Jan 1, 1960

By Andrew B. Cecala

The U.S. Bureau of Mines has designed and tested a system called the Bag and Belt Cleaner Device (B&BCD) to reduce dust levels in and around the bag conveying and stacking process. The device physically cleans either 22.7 kg (50 lb) or 45.4 kg (100 lb) paper bags by using a combination of brushes and air jets. It is completely self-contained and is kept under negative pressure by a baghouse to ensure that dust and product removed from the bags during cleaning does not flow into the work environment and contaminate workers. The bags travel through the device on a chain conveyor, which permits any product or dust cleaned from the bags to fall into a hopper at the bottom of the device and be recycled back into the process via a screw conveyor. Once exiting the B&BCD, the outside of the bags and the conveyor are essentially product and dust free. The B&BCD was evaluated at two mineral processing plants to determine reductions with the device in use. The results of both field evaluations showed that the amount of product removed from the outside of the bags varied from 77 to 93 pet.

Jan 1, 2010

By A. S. Prokopovitsh

A spectrophotometric method for the determination of small amounts of copper in tungsten metal powder using the principle of solvent extraction has been developed by the Federal Bureau of Mines. The metallic sample is dissolved in hydrogen peroxide, tartaric acid added, the pH adjusted, and the excess peroxide destroyed by boiling. Copper is reduced to the cuprous state, and the reagent neocuproine (2,9-dimethy1-1,10-phenanthroline) is added to form a colored complex with the copper. This colored complex is then extracted into chloroform and the absorbance of the separated chloroform layer measured on a spectrophotometer. Copper contents as low as 1 p.p.m. (parts per million) can be determined. The method is limited to finely divided tungsten powder. The interest of the Bureau of Mines in developing more sensitive methods for the determination of trace impurities in high-purity tungsten prompted an investigation of the possibility of using solvent extraction-colorimetric methods. The organic reagents now commercially available make possible many extremely sensitive colorimetric methods for the determination of metallic ions. Extraction of the colored complex into a small volume of organic phase can be used to further increase sensitivity (4) .4/ This general approach has the added advantage that no special equipment beyond that normally found in an analytical laboratory is required.

Jan 1, 1961

By G. R. Hopkins

[ ]

Jan 1, 1927

By Welby Courtney

Because of the inherent safety problem associated with the deposition of airborne respirable dust onto the floor and other airway surfaces, the Bureau of Mines investigated the rate of reduction of airborne respirable dust in an airway due to deposition of the particles onto the surfaces of the airway. The effects of relative humidity and air velocity on the deposition rate were examined. It was found that the deposition rate was comparable in magnitude with the Stokes sedimentation rate and that it was independent of relative humidity. However, near the dust source the deposition rate depended significantly upon the air velocity, with such dependence decreasing with increasing distance from the dust source. In addition, the size distribution of the airborne particles was approximately constant along the first 300 ft of the airway, indicating that it was not merely the larger (heavier) particles that were being deposited. These results suggest that deposition, though comparable with the Stokes sedimentation rate in magnitude, does not follow a simple Stokes-type process, and that the process of deposition remains to be explained.

Jan 1, 1986

By C. F. McCarroll

[Laboratory research and, control in the production an. utilization of petroleum and it 3 products have expanded greatly during the past decade, and much of the routine control and experimental equipment now rewires the constant daily use of liquid mercury. In spite of this ;;renter use, very little consideration has been given to the hazard that might be occasioned by the toxic vapors of mercury unavoidably spilled' of otherwise exposed to the atmosphere during the normal procedure of laboratory open at ions. A simple visual examination ).'.' son-,, r° the laboratories reveal the presence of a considerable quantity of mercury in the cracks of floors, on work tables, and on ark, around equipment stands. Usually this mercury is contaminated with oil3/ and dirt so that it remaining in a finely divided state and a ;mall amount pre presents a relatively large surface for evaporation. Since :mercury shows measurable volatility at a temperature v,.^ lo.! 5o F., mercury vapor will be present in, the mercury _3 exposed promiscuously.]

Jan 1, 1939

By Robert E. Meredith, Thomas T. Campbell

An investigation was undertaken to examine the feasibility of employing low- temperature nonaqueous baths for electrodepositing some of the refractory metals of the ferroalloy group . To date , such metals as tungsten , molybdenum , and vanadium have been produced only by high - temperature processes that are technically difficult and sometimes cumbersome in operation . Deposition studies were performed in a wide variety of organic solvents , including amides , ammonia derivatives , ketones , polyhydroxy alcohols , and ethers . Compounds prepared and used as solutes included the chloride and bromide salts of vanadium , tungsten , and molybdenum . Studies were conducted over a temperature range of 20 ° to 200 ° C under inert atmosphere . Conductivity and current potential data were obtained for all baths that contained reasonable solute concentrations . Qualitative solubility data were obtained for compounds of ferroalloy metals in a variety of solvents . In general , all solutes showed low solubility in ethers and ketones but reasonable solubility ( in excess of 20 grams per liter ) in alcohols , amides , and ammonia derivatives . No successful metallic deposits that would encourage further study were obtained with any of the systems that were examined .

Jan 1, 1963

By M. S. Seehra, V. S. Babu, L. Farinash

"The diesel particulate matter (DPM), a constituent of the diesel engine exhausts, is known to be a potential carcinogen. 1- 3 Consequently, suitable methods to control/eliminate DPM have ·been under investigation in recent years. The DPM can be controlled by using fibrous ceramic traps. However, clogging of traps by DPM requires the impractical periodic trap replacement. Following the recent work by Garner and Dent,4,5 we are investigating the in situ use of microwaves to regenerate the ceramic traps, thereby eliminating the trap replacement step in this process. The use of microwaves instead of conventional heating for trap regeneration has the advantage of selective heating of the DPM instead of the trap, if the trap absorbs insignificant microwave power relative to the DPM. Also, the oxidation characteristics of the DPM are needed to understand fully this regeneration process.The rate of energy absorption P per unit volume of a sample is given byP = wE"" |Eo|2 • (1 )where w is the angular frequency, |E0|2 is the intensity of the microwave radiation, and E” is the imaginary part of the dielectric constant (E = E’ + iE”) . Thus measurements of E11 for DPM and ceramic trap material are needed to determine their capacities for microwave absorption. In this paper, we report these measurements carried out at · a frequency of 8.7 GHz. Following microwave absorption, the DPM is expected to oxidize. The oxidation characteristics of the DPM have been investigated using Fourier transform infrared (FTIR) spectroscopy of the evolved gases CO2 and CO and using thermogravimetric analysis (TGA). Finally, some information on the structure of carbon in DPM has emerged from the analysis of its x-ray diffraction spectra. Results of these experiments are reported in the following pages."

Dec 1, 1996

By S. H. Lorain

This paper is one of a series on mining and milling method and costs being published by the United States Bureau of Mines. The Golden Messenger mine, operated by the United Gold Mines Corporation, is in the York-Confederate Gulch mining region in Luis and Clark County, Mont., 22 miles northeast of the city limits of Helena and about 1 mile north of the town of York. It is the first operation to exploit successfully the low-grade ores of the York-Confederate Gulch area. The unusual vein structure presents some mining problems that have been solved in ail interesting manner.

Jan 1, 1937

By William H. Schiffbauer, Ph. D. Mowrey

Proximity warning devices can improve workplace safety by alerting workers when they are in a hazardous area near moving equipment. Industrial work sites often present extreme challenges to safety-based proximity warning devices. Many commercially available types of proximity warning sensors and systems can be rendered useless when covered with mud, ice, snow, ore, rock, and other material. The list includes radar, ultrasonic, capacitive, and visual types of sensors and systems. Addressing these shortcomings, NIOSH personnel have developed a patented active proximity warning system called HASARD (Hazardous Area Signaling and Ranging Device) which employs lowfrequency, low-power magnetic fields which are quite impervious to severe environmental conditions. A shapeable wire loop antenna which provides the marker of dangerous work areas, has been mounted on a continuous mining machine and was mounted inside 1.3-cm thick angle iron. This loop antenna was exposed to more than six months of active underground coal production, which included being covered by and scraped over with tons of rock, sprayed by a continuous stream of water, and immersed in thick mud. After six months the loop antenna showed signs of wear, but was still capable of performing its intended function. The HASARD system is now being applied to other industrial applications and is showing much promise, especially in harsh environments. This paper details the system, describes the tests that have been done, and mentions other areas where it can benefit the safety of industrial workers.