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By R. G. Meara, O&apos

The land-pebble district of Florida, wnich in 1928 supplied 96.7 per cent of the phosphate production of that State and 82 per cent of the domestic requirements of the United States, is centered in Polk and Hillsboro Counties about 30 miles east of Tampa The deposits are unconsolidated sediments occurring as beds of phosphate matrix overlain by a mantle of barren sands and clays. The matrix consists of a mixture of sand (quartz grains), clay, and phosphate rock in which the coarsest sand is much finer than the coarsest phosphate; that is, the sand is segregated in the fine material. Before the introduction of classifiers the concentration consisted of log washing, and screening at about 20-mesh, which was usually the finest size that could be taken to maintain commercial grade, 66 per cent B. P. L. (bone phosphate of lime) or more. When classifiers were introduced some of the fines that had escaped at the head of the washery and some of the minus 20-mesh material isolated during the washing and formerly lost supplied the feed. During October, 1927, the United States Bureau of Mines in cooperation with the University of Alabama and the Missouri School of Mines and Metallurgy began to investigate the amenability of phosphatic sands to gravity methods of concentration. The work was under the immediate supervision of B. W. Gandrud, acting supervising engineer of the Southern Experiment Station of the U. S. Bureau of Mines at Tuscaloosa, Ala., and Will H. Coghill, supervising engineer of the ore dressing section of the U. S. Bureau of Mines. More comprehensive testing followed and in the early part of 1930 some of the companies cooperated with the bureau and the above-mentioned institutions in conducting a series of tests on hydraulic classification and tabling. The results indicated that marketable concentrates could be obtained with a recovery of 25 to 45 per cent of the phosphate formerly lost. As a result two companies have introduced hydraulic classification to treat the current tailings, and one of them has substituted classifiers for the 20-mesh screens which had been unsatisfactory. Because the phosphate grains and quartz grains have nearly the same specific gravity, the use of concentrating tables by the customary methods is not applicable. The washeries included in the following report are designated as Nos. 1, 2, and 3.

Jan 1, 1931

By L. J. Kane

While analyzing synthesis gas produced from coal, the Bureau of Mines found that conventional procedures for naphthalene determination were difficult and time consuming. The Bureau developed a rapid and sensitive turbidimetric procedure, which requires only simple instruments and hence can be used in plant-control laboratories. The gas is passed through a saturated aqueous solution of picric acid at 3° to 4° C. whose turbidity is then measured at room temperature. A dispersing agent is added to prevent coagulation of the suspension on warming. Only about 1 mg. (0.015 grain) of naphthalene need be absorbed, and precision and sensitivity are a few ten-thousandths of a grain, or a few hundredths of a grain per 100 cubic feet. The determination can be completed less than 10 minutes after absorption. INTRODUCTION One of the functions of the Branch of Coal Gasification, Bureau of Mines, Morgantown, W. Va., is to develop economical methods for manufacturing, from coal, a mixture of hydrogen and carbon monoxide for producing hydrogen, methane, and other gaseous fuels. This raw gas may contain many impurities, including naphthalene. This impurity is usually determined by first forming naphthalene picrate in a water solution of picric acid, separating the picrate, and titrating the unreacted picric acid or the picrate itself.

Jan 1, 1957

By W. H. Young

PRODUCTION of bituminous coal and lignite increased substantially in 1963 compared with 1962 figures. The major items of production, consumption, exports, and productivity increased. However, certain key items declined. For the fourth year there was no upward trend in mechanization; the percentage of total tonnage mechanically loaded remained the same as in the 3 previous years and the percentage of total tonnage mechanically cleaned was smaller than in the previous year. Furthermore, the percentage of total production mined by stripping and by augers increased. Most significant was the continued decline in average value and employment. Production.-The output of bituminous coal and lignite in the United States in 1963--459 million tons-was 9 percent greater than the 422 million tons produced in 1962. Production was greater in 1963, largely because of expanded consumption by the electric utilities and an increase in exports.

Jan 1, 1964

By John E. Hamak

The U.S. Bureau of Mines estimates the identified helium resources of the United States at 630 Bcf as of December 31, 1990. This includes 295 Bcf of demonstrated reserves, 87 Bcf of demonstrated marginal reserves, and 42 Bcf of demonstrated subeconomic resources. The identified resources include 161 Bcf of helium in inferred and marginal reserves and 45 Bcf in inferred subeconomic resources. The identified helium resources contained on Federal lands are approximately 170 Bcf, including 32 Bcf in underground storage in the Cliffside Gasfield near Amarillo, TX. In addition to the identified helium resources, undiscovered helium resources in the United States are estimated at a most likely volume of 103 Bcf, with a maximum volume of 259 Bcf and a minimum volume of 41 Bcf. Also reported are 43 Bcf of helium in nonconventional and low-helium-content natural gases. Current extraction of helium in the United States occurs mostly from natural gases produced from the Hugoton gas area in Kansas, Oklahoma, and Texas, and the Riley Ridge area in southwest Wyoming. Helium extracted from natural gas in the United States in 1990 was 2.5 Bef. If current trends continue, some shortfalls in helium supply may occur in about 5 to 10 years.

Jan 1, 1993

By F. H. Gibson

In recent years physico-chemical techniques have been applied for rapid analysis of coal and coke ash as replacements for classical wet-chemical methods. Although the classical methods are accurate, they are time consuming because many chemical separations are necessary to complete an analysis, and they require skilled analysts for accurate work (12).4 For the past several years the Bureau of Mines has applied some of the newer physico-chemical techniques in its continued search for new and improved methods at analysis. The methods of analyzing coal and coke ash evolved from this work include spectrophotometric methods far SiO2, A120, , Fe203 , TiO2, and P2O5; chelatometric titration for CaO and MgO; and flame photometry for Na20 and K2O. The methods are rapid and direct, are suitable for analyzing a group of samples at the same time in production work, and dire results with almost the same accuracy as classical procedures. With the new methods, complete analyses in duplicate can be obtained at a rate of 2 to 3 times that of conventional methods.

Jan 1, 1962

By George L. Gates

The Bureau of Mines studied pressure-buildup data from a number of California gas wells to determine if the reservoir properties calculated from these data correlated with field-observed reservoir properties. Pressure-buildup curves from 24 wells showed distinct changes in slope, indicating changes in permeability of the reservoir rock. Calculated distances from the wells to indicated permeability changes were in fair agreement with distances deter-mined in the field. Pressure-buildup curves from three wells had more than one distinct change in slope, indicating multiple permeability changes. Thus field data supported the theoretical relations used to calculate reservoir properties from pressure-time relations measured in gas wells.

Jan 1, 1967

By R. M. Santmeyers

This paper presents one of a series of digests of foreign mining legislation and curt decisions that is being prepared in advance of a. general report relative to the rights of American citizens to explore for minerals and own and operate mines in various foreign countries. This interpretation of the mining legislation of Madagascar was prepared from the best information (in French) available in Washington, but is released subject to correction and amplification, if necessary, by the proper American diplomatic and consular officers, to whom it dill be referred through the courtesy of the Department of State. INTRODUCTION The basic mining law of Madagascar is the decree of 1923, signed at Rambouillet by the President of France on July 19, and published in the Journal Official de Madagascar et Dependances. It has been modified by a number of subsequent laves and regulations, generally of minor importance.

Jan 1, 1933

By Charles L. Kimbell

The estimated value of world crude mineral production in 1990 exceeded $1,501.5 billion in terms of current (1990) dollars, or almost $1,160 billion in terms of constant 1983 dollars. This latter figure was 0.3% below the 1989 level and about 3.9% below the record high to date of $1,207.1 billion 1983 dollars set in 1980. Table 1 provides the latest available revised time series of the estimated value of world crude mineral production both in terms of 1983 constant dollars and in terms of current dollars. It also provides one of the two statistical bases for this estimation, this being the data on the value of production of a group of key commodities that was compiled for and published in the authoritative French language mineral industry periodical, Annales des Mines, for selected years up to 1983.1 It should be stressed that the values just discussed and those presented in the tabulation are for crude minerals only, and by no means reflect adequately the role of the entire mineral industry in the world economy. These figures represent only the value of mineral materials as they are mined or otherwise extracted from the earth. They do not reflect the value added to these materials through downstream processing within the facilities commonly accepted as mineral industry plants. That is, value added through beneficiation of ores, smelting, refining, and similar processing is not included in these figures. Comprehensive world data on the value added by such processing are not available; however, a conservative estimate of the total value of pro-cessed output from mineral industry plants derived wholly from primary (newly mined) materials would be on the order of about $2,780 billion constant 1983 dollars or $3,600 billion in terms of 1990 dollars.

Jan 1, 1993

By H. R. Batchelder

Much information on oxygen production and the manufacture of synthetic liquid fuels has been published during the past several years. From time to tine the investment and operating cost of oxygen plants of various sizes has been estimated. Surveys have been made so that the various processes by which oxygen is produced commercially might be compared. The gas-making processes in which oxygen is employed, which wore used in Germany during the war, have been described in T.O.M. reels, and this information has been published. Descriptions of pilot-scale or proposed commercial plants for the production of synthesis gas or hydrogen and their conversion to synthetic liquid fuels also have been published. In general, each of these publications has dealt with a particular phase of the over-all problem. The present paper will discuss the relationship between these phases: The factors that affect oxygen manufacture and costs, the methods for the use of oxygen and for the production of synthetic liquid fuels, and, to some extent, the economic factors that must be considered.

Jan 1, 1951

By G. S. Scott

The investigation of the causes, behavior, and control of anthracite mine fires, which the Bureau of Mines has been carrying on has yielded several publications directly applicable to mine-fire problems. 3/, 4/, 5/, 6/, 7/, 8/ As a further step in elucidating the causes of heating in certain anthracites subjected to oxidation, reliable information vial needed relative to the actual amount of heat that is liberated when a unit volume of oxygen combines with anthracite at varying temperatures.

Jan 1, 1939

By E. D. Gardner

This paper discusses prospecting for lode gold and lists the principal lags and. regulations pertaining to locating; lode claims on public lands. It is a preprint of a part of a bulletin being prepared by the United States Bureau o Mines entitled "Equipping, Developing and Operating Small Gold Mines". The increased interest in gold mining manifested during the past few years (1932-1935) bas stimulated prospecting. Many adventurers have taken to the field to search for now gold deposits. A. large percentage of them have had no previous experience in prospecting for lode gold; this paper has been written with the tope that it might assist these newcomers.

Jan 1, 1935

By Seth C. Schaefer

The Federal Bureau of Mines studied the Gibbs free energies of formation of chromous fluoride (CrF2), chromic fluoride (CrF3), and chromium (II,III) fluorides (CrF2.40 and CrF2.45) with high-temperature galvanic cells employing calcium fluoride doped with 1 mole-pct yttrium fluoride as the electrolyte. Free-energy changes were obtained from open-circuit potential measurements for the following cells: Cr, CrF2 // CaF2 // NiF2, Ni (a) NiO, NiF2 // CaF2 // CrF3 , Cr203 (b) CrF2 , CrF2.40 // CaF2 // NiF2, Ni (c) and CrF2 ?45 , CrF3 // CaF2 // NiF2, Ni (d) with the following overall reactions Cr(s) + NiF2 (s) = Ni(s) + CrF2 (s) (1) 3NiO(s) + 2CrF3 (s) = 3NiF2 (s) + Cr203 (s) (2) 5CrF2 (s) + NiF2 (s) = 5CrF2.4O (s) + Ni(s) (3) and 3.64CrF2.45 + NiF2 (s) = 3.64CrF3 (s) + Ni (s) . (4) These results were combined with the best available literature values of ?Gf° of NiF2, NiO, and Cr203 to deduce Gibbs free energies of formation for the chromium fluorides expressed as follows: ?Gf°(CrF2) = -179.31 + 24.33 X 10-3T ± 0.43 kcal-mole. (5) (858.1 - 964.9 K) ?Gf° (CrF3) _ -226.16 + 1.82 X 10-3T ± 0.79 kcal/mole (6) (880.8 - 957.8 K) ?Gf°(CrF2.40) _ -213.65 + 32.14 X 10-3T ± 0.44 kcal/mole (7) (0053.9 - 936.8 K) and ?Gf°(CrF2.45) _ -176.17 - 12.67 X 10-3T ± 0.80 kcal/mole (8) (875.1 - 937.6 K). Free energies and equilibrium fluorine pressures for three univariant and one bivariant equilibria are illustrated.

Jan 1, 1976

By D. S. Colby

Statistics on the volume of natural gas produced in the United States were first collected for 1906. A summary of those statistics covering 1906-35 was incorporated in the 1937 Minerals Yearbook. This summary, covering 1936-50 presents, by States, a number of the more important statistics that have appeared in the natural-gas chapter of the Minerals Yearbooks. The period covered has been one of rapid expansion, especially of long-distance transmission lines. Natural gas was made available to some States for the first time; in other States the degree of dependence upon supplies transported from outside their boundaries changed rapidly. Thus, an isolated series of statistics cannot be studied without considering other regional influences that reflect in the overall operations of the industry. These tables accordingly have been designed to show for each State the simultaneous changes taking place in the various sectors surveyed. The tables show production data in the upper portion and consumption data in the lower portion. They are arranged alphabetically, by States. A copy of the 1906-35 production summary from the 1937 Minerals Yearbook has been included.

Jan 1, 1952

To develop a safety training module for surface miners and road construction workers exposed to the hazards of highwalls. Background Investigators collaborated to develop a new training module that would address the hazards of working around highwalls. Such a module would be applicable to surface mines and road construction sites, both of which require personnel to work under and on top of steep and often unstable slopes.

Aug 1, 2004

Through a contract, the Bureau of Mines has funded the development of an Automated Breathing Metabolic Simulator (ABMS). The ABMS simulates man in all of the breathing and metabolic parameters for monitoring support and resuscitation equipment. For the first time, complete breathing and metabolic simulation are incorporated in the same device. Breathing rate, breathing depth, breath velocity contour, oxygen uptake, and carbon dioxide release are all variable over wide ranges, simulating conditions from sleep to hard work with respiratory exchange ratios covering the range of hypoventilation to hyperventilation. In addition, all of these parameters are remotely controlled to facilitate the use of the device in hostile test environments. The exhaled breath is also at body temperature and completely saturated. The simulation in faith¬ful to the extent of having a variable functional residual capacity and an anatomical dead space equivalent to that of humans. The ABMS will be used as a stand-in for humans in test and validation of respiratory equipment, permitting more extensive and safer evaluation in hazardous environments where human testing would have to be limited. In addition, it will greatly reduce the cost of prolonged testing in cases where simulation chambers with human subjects require three shifts of crews, including standby physicians. Perhaps most importantly, it will provide a calculated and reproducible test and validation facility. The ABMS is under complete computer control. Through a typewriter terminal the test sequence can be input into the computer which will then automatically adjust the ABMS to simulate any desired sequence of metabolic activities for time durations up to 15 hours. The computer also monitors the test procedures and provides test results printout.

Jan 1, 1973

By Albert J. Forney

Extensive studies have been made of the various effluents found in the Synthane coal-to-gas process. Analyses have been made of the waters, gases, and trace elements present in some of the streams. Results of analyses show the water effluents are the area where extensive research is needed.

Jan 1, 1974

By C. J. Chindgren

A refractory-lined, garage-type automobile incinerator with a natural gas afterburner for air pollution control was cooperatively constructed and tested by the Bureau of Mines and the Wasatch Metal & Salvage Co. in Salt Lake City, Utah. The incinerator is capable of relatively smokeless burning of 32 to 60 cars per day, dependent on the degree to which the cars are stripped prior to incineration. Preliminary burning campaigns indicate the cost of incineration to be approximately $2.75 per car.

Jan 1, 1970

By R. R. McLellan

The Brown Derby pegmatites are in Gunnison County, Colo., about 18 miles east of Gunnison. Approximately 860 tons of lepidolite concentrates, with smaller amounts of microlite and beryl, was produced from 3 dikes of the Brown Derby group from 1943 through 1947. No mining was done from 1948 until December 1950, when production of lepidolite and beryl was resumed by the Poston Mining & Milling Co. Mining was intermittent during 1951 and 1952. The dikes were mapped and studied by the Federal Geological Survey during the field seasons of 1942 to 1944, and in May 1950 the Bureau of Mines initiated a diamond-drilling project to test the three dikes for lepidolite and beryl. After being recessed twice, the project was terminated indefinitely July 1951. Seven drill holes were completed for a total of 1,841.6 feet of drilling.

Jan 1, 1956

By J. B. Zink

The Bureau of Mines developed a spectrochemical method to determine six constituents in coal ash in the following concentration ranges: silica 9 to 63 percent, alumina 7.5 to 35 percent, ferric oxide 2 to 30 percent, calcium oxide 1 to 29 percent, magnesium oxide 0.5 to 6 percent, and titanium oxide 0.5 to 4 percent. Samples of coal ash are fused with a mixture of lithium tetraborate and vanadium pentoxide. The resulting beads are crushed, mixed with powdered graphite, and briquetted. The pellets are analyzed spectrographically, using controlled high-voltage spark excitation. Vanadium serves as the internal standard. Effects due to matrix variations are minimized by fusion with lithium tetraborate. Intensity ratios of selected analytical lines are determined photometrically, Concentrations are read from analytical curves, prepared from synthetic standards, relating log intensity ratios to log concentration. A combustion procedure is used to determine sulfur tri-oxide. The method is most useful when large numbers of coal ashes must be analyzed but a high degree of accuracy is not essential.

Jan 1, 1967

By D. F. Walsh

A study of damping capacity was made on a number of magnesium-base alloys, commercial types and experimental compositions. Hardness and tensile properties were determined, and the microstructure of each alloy was examined. Alloys of low yield strength, in general, possessed high damping ability. A correlation was established between damping capacity and composition.

Jan 1, 1962