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By S. Jordanov

The nature of processes that take place on top of copper bearing grains during the suppression of copper acid drainage from mine tailings was studied on a grain model. Cyclic voltammetry (C.V.) was employed as an experimental technique suitable for indirect measuring of copper leaching. Experiments were done in sulfuric acid (pH=2) at electrodes that progressively approach the real situation during acid main drainage, starting with Cu-metal, then with CuO and finally with CuO covered with CaSO4. Oxidation was found to be the only process that takes place on metallic copper electrode anodically polarized up to 2 V vs. Cu/CuSO4 reference electrode. Dissolution is intensive and reaches up to 50 mA.cm-2. When the same was repeated, but on CuO electrode, anodic currents were some 4 times lower than on the bare metallic surface. This indicates that the electrode material is not completely oxidized to copper(II)oxide and the Cu(O) or Cu(I) residues are oxidized during the anodic polarization. This explains the diminished dissolution. Dissolution is further restricted at electrodes covered with CaSO4. It is some 20 times lower than on the bare oxide electrode. When the second layer of CaSO4 was applied, anodic currents were another 15 times lower. Total decrease of anodic currents when transition is made from Cu-metal to CuO covered with 2 layers of CaSO4 reaches up to 7.500 times. C.V. measurements produced a proof that mechanical blockage is the way how lime prevents leaching of copper bearing grains in immobilization experiments referred elsewhere.

Jan 1, 2007

By Baisheng Nie

The process of gas diffusion through coal particles and the mathematical physical model under the third kind boundary condition was determined to obtain the rules of gas diffusion through coal particles of different sizes. The analytical solution of the equation was obtained by the Method of Mathematical Physics. The parameters of analytical solutions and the implications of parameters were analyzed. The Biot criterion (Bi) and the Fourier criterion (F0) of mass transfer can represent and reflect the features of gas diffusion field of coal particles. Moreover, the measurement method of gas diffusion coefficient and surface mass transfer coefficient is introduced and an example of measurement is given. The achievement can provide the support to prevent disasters related to methane in coal mines.

Aug 1, 2013

By C. A. Lorenson

THE Marmoraton mine is located a mile southeast of Marmora, a village in Hastings county, Ontario, 130 miles east from Toronto and 143 miles west of Ottawa. Highway No. 14 from Belleville intersects Highway No. 7 at Marmora and the branch line of the Canadian National railway between Trenton and Bancroft passes through the property just east of the open pit. HISTORY AND GEOLOGY The Marmora orebody appears as the whorls of a thumb print on the aeromagnetic survey map released by the Ontario Department of Min.es early in 1950, the survey of the district having been made in 1948 and 1949, under the joint auspices of the Department of Mines and the Geological Survey of Canada. The 'anomaly' appeared to have interesting possibilities, so Bethlehem representatives carried out a ground survey and began drilling the property in June, 1950. A total of 40 holes, aggregating 37,000 feet, were drilled to delineate the ore-body. The Marmora orebody is a re-placement of Precambrian limesto.ne with zones or bands of magnetite interlaid with metamorpl1ic rocks and cut by later intrusives. The ore and associated Precambrian rocks are overlain by 100 to 150 feet of flat-lying Palaeozoic limestone. It is a low-grade deposit averaging 33 per cent iron and requires concentration to raise it to 65 per cent iron grade.

Jan 1, 1958

By S. A. Vazhnov, A. G. Kalimov, A. A. Potienko

In this paper we describe a mathematical model of the magnetic field and magnetohydrodynamic processes simulation in aluminum reduction cells developed in St. Petersburg State Polytechnic University, Russia. The model includes: (a) calculation of the currents in the busbar system and inside the aluminum cell construction elements including cathode and anode structures, aluminum and electrolyte layers; (b) magnetic field simulation using the integral equation method; ( c) investigation of the magnetohydrodynamic characteristics on the basis of a shallow-water approach. The developed model was used to investigate operational characteristics of the different industrial aluminum cells. Calculated magnetic field distributions and MHD stability parameters were compared with the available experimental information; the comparison demonstrated a reasonably good agreement.

Jan 1, 2006

By C. Hari Manoj Simha, J. Gholipour, M. J. Worswick

Due to the high pressures involved in the hydroforming process, friction and lubrication play an important role and can affect formability of the material. Tubes of A1Mg3.5Mn aluminum alloy, of 76.2 mm (3 inch) outside diameter and 2-mm thickness were considered in this study. Three kinds of lubricants, Al070, Hydrodraw711 and water, were applied to the tubes and tubes were hydroformed to burst in a square shape die cavity. The key process parameters were recorded during the tests. An in-house Gurson-Tvergaard-Needleman (GTN) damage-based material model, implemented in LS-DYNA, was used to model the process and predict the formability of this material. The applied axial loads and internal pressures recorded during the tests were used in the computations. The effect of different types of elements (solid and shell) with different constitutive models (von Mises and GTN models) in predicting the strain distribution is studied. The GTN damage-based material showed a good ability to capture necking and displacement histories in this process. Both predicted and measured results showed that the lubricant with lower coefficient of friction can effectively increase the comer expansion.

Jan 1, 2006

By David J. Forrester

Light metals, most commonly aluminum, magnesium and titanium, and alloys containing them, are used in many industrial applications where lightness, hardness, ductility and resistance to corrosion are needed. However, these metals and their alloys can be potential ignition sources in underground coal mines. There have been documented cases in the past where coal mine explosions have been attributed to firedamp/coal dust ignitions involving light metals or their alloys. When light metals and their alloys are brought into contact with oxygen bearing material, such as iron oxide (rust) in the presence of heat, then a "thermite" reaction can occur. This source of heat can be generated from frictional contact or from merely a glancing blow. This paper outlines the hazards associated with light alloys, how to address the hazard and regulatory aspects.

May 1, 2001

By Jae-Chun Lee, Sadia Ilyas

We investigate the technical feasibility of bioleaching of metals from low grade sulphidic ore. Experiments were conducted with an adapted consortium of Sulfobacillus thermosulfidooxidans and Thermoplasm acidophilum in batch bioreactors (1.5 L), small columns (10 kg ore load, 8 % S0 sludge) and large columns (80 kg ore load, 12 % S0 sludge). Approximately 83 % Ni, 85 % Cu, 55 % Fe and 81 % Zn was leached out in batch mode while 93 % Ni, 89 % Zn, 81 % Cu and 65 % Fe was leached out in column reactors. Bioleaching potential improved by acid pre-leaching, adaptation of microbial consortium and periodic bleeding of effluents.

Jan 1, 2014

By G. Ergin

The interactions taking place between Al-Mg alloys and the bed media during aluminum filtration are not yet well understood. These interactions were studied using the infiltration technique. The reaction interface was analyzed using different techniques such as SEM and TEM. Only spinel formation was observed at the interface regardless of the type of alumina and contact time. This paper discusses the results of the study.

Jan 1, 2004

By Andrew J. Freyman, Graham T. Armstrong

"In September, 1968, a survey of operating mines in the Yukon and the Northwest Territories was undertaken to determine the role of Indigenes (Indian, Metis, Eskimo) on the mines, and the attitude of mine management to these employees. The operating mines in the Territories had (at that date) a total employment of 2,002 men, of which 91 (4.5 per cent) were Indigenes. Indigenes make up 45 per cent of the Territorial population (18 per cent in the Yukon and 63 percent in the Northwest Territories). The paper documents some of the problems associated with indigenous employment in mines. A study was undertaken to determine the role of Indigenes (Indians, Metis, Eskimos) in operating mines in the Yukon and in the North-west Territories. In addition to the mines north of the 60th parallel, the experience of several other Canadian mines was examined. The general picture obtained is considered to be representative of the Canadian mining industry."

Jan 1, 1969

By L. Rahnenfuhrer

"Hoisting equipment is a vital part of the operation of most producing mines. Safety and continuation of operation necessitates ultrasonic preventive maintenance inspection on a regular basis.Ultrasonic inspection of hoist shafting, brake linkage and draw bars will contribute to a safe operation and can prevent costly unscheduled shut-down time. With little dismantling, ultrasonic testing techniques can be applied to. determine the conditions of shafting and linkage in hoisting equipment, mining equipment and other miscellaneous mining equipment."

Jan 1, 1969

The fracture behavior of second phase particles and the role of matrix material on the wear resistances of the three Al-Si alloys containing 8, 17, and 19% Si were investigated using single pass scratch testing technique by applying normal loads between 0,15 and 5,00 N, in ambient air, Optical microscopy and SEM with EDS were used to analyze microstructures and morphologies of scratch tracks of the Al-Si alloys, The results showed that needle-like Si particles fractured under a load of 0.50 N, while block-like Si particles fractured at loads above 3,00 N, The Al-17% Si alloy with large number of needle-like particles (area fraction 16,4%) exhibited the highest coefficient of friction (0,8) and the widest scratch track, The Al-19%Si alloy containing high Si percentage and larger number of block-like particles (area fraction 16%) exhibited the lowest coefficient of friction (0,37) and the narrowest scratch track width. Presence of block-like particles was effective in reducing the amount of material transfer from Al-Si alloy surfaces to the counterface.

Jan 1, 2005

By P. Fellner, A. Sýkorová, J. Thonstad, J. Jurišová, V. Khandl

Adsorption of S02 on alumina used in the aluminium industry, so-called smelter grade alumina, was studied in the temperature range 15 C-120 C. The specific surface area of the smelter grade alumina was 88 m2/g. It was found that at temperatures lower than 40 C, sulphur dioxide is bonded to alumina reversibly by physical forces, and the adsorption can be described satisfactorily by the Langmuir adsorption isotherm. The heat of adsorption was estimated to be -33 kJ.mor1. At temperatures in the range 80 C- 120 C, which prevail in dry scrubbers in the aluminium industry, the heat of adsorption was determined to be -56 kJ.mor1. When S02 was adsorbed at temperatures higher than 80 C, about 30 % of the S02 could not be desorbed when heating the samples up to 250 C. In the presence of S02 and oxygen, the formation of sulphate was determined at temperatures above 90 C.

Jan 1, 2006

By D. Perednis

Fuel cells with thin samaria-doped ceria (SDC) electrolyte films deposited onto an anode support using spray pyrolysis were fabricated. The SDC films were deposited onto porous NiO-YSZ substrates at deposition temperatures between 400°C and 450°C. The influence of process parameters such as deposition temperature, flow rate, type of salt and salt concentration on the quality of the film was studied. A smooth dense film was successfully deposited using the precursor cerium ammonium nitrate and samarium nitrate dissolved in butyl carbitol (33.3 vol.%), 2-methoxy-l-propanol (33.3 vol.%), and ethanol (33.3 vol.%) solvent mixture. A deposition rate of 125 nm/h was achieved.

Jan 1, 2005

By L. Fernandes

A two level factorial study was undertaken to investigate the relative impacts of factors affecting the kinetics of polytetrafluoroethylene, PTFE, assisted pressure oxidation of chalcopyrite. A copper flotation concentrate, principally composed of chalcopyrite, was leached in 850 mL of leach solution under conditions similar to those of the CESL process. The factors manipulated were: the amount of 1/8" PTFE beads added (100 g or 650 g), oxygen pressure (690 kPa or 1030 kPa), and concentrate addition (10 grams or 65 grams). Copper extraction data, which indicated complete leaching under certain conditions, were fit using a shrinking core model from which rate constants were estimated and further used to generate a statistical model containing only the factors of significance and their interactions. Results indicated a strong positive effect of PTFE addition and a strong negative effect of increasing pulp density. A weak negative interaction between increasing PTFE addition and pulp density was attributed to PTFE/concentrate agglomeration.

Jan 1, 2014

By J. G. Peacey, G. Csicsovszki

The target of this study was to clarify the role of lead on the dissolution of gold in the (NH4)2S2O3-Cu leaching system via chronopotentiometry, linear sweep voltammetry and chronoamperometry. It was found that the dissolution of gold was significantly increased with lead concentration up to 10 mg/1 Pb in the system of 0.1 M (NH4)2S2O3 and 50 mg/1 Cu. \/oltammograms suggested that the anodic dissolution of gold was virtually independent of lead concentration in the range of 1-10 mg/1 in 0.1 M (NH4)2S2O3 solution while in solutions containing copper as well, addition of lead increased the anodic dissolution of gold.

Jan 1, 2011

By Janet S. Springer

Anomalous gold concentrations in carbonaceous material have given rise to misconceptions about the role of carbon in gold depo its. Some hydrocarbon and carbon-rich black muds may how gold contents raised to 100 time above background by mechanical entrapment. urface effect in fine ediments. and metabolic fixing of gold by micro-organisms. Such concentrates, however, are 10 times too low to be economic. Studie in the Archean of Ontario show that graphite schi t are not the protore to an economically workable gold deposit. A later event of gold introduction ha been uperimposed on the initial low concentrations. Gold enrichment i localized by reduction at vein margins where hear plane . the conduits of mineralization, cut carbonaceou horizons.

Jan 1, 1986

By Z. Zhang, X. -G. Chen, F. Breton, A. Arici

"The microstructure of Al-10Si-0.3Mg-0.5Mn alloy with 0.27% Zr and 0.19% V addition was quantitatively analysed and compared to the base material. The addition of Zr and V in the AlSi10Mg alloy exhibit a beneficial effect on the Si modification, resulting in the reduction of the size of eutectic Si particles on both as-cast and T6 conditions. The quantitative image analysis results show that the Zr and V addition and T6 treatment can reduce the size of the intermetallic phases. In addition, the presence of Zr and V is favour to the partial dissolution of the intermetallic phases during the T6 treatment. Different heat treatment procedures were tested to optimize treatment parameters. The mechanical properties of the alloys were evaluated using hardness measurements and tensile tests. The results show that the addition of Zr and V can remarkably improve the mechanical properties on as-cast and T6-treated conditions. The correlation between the microstructure and mechanical properties of the alloys is discussed.INTRODUCTION Al-Si-Mg foundry alloys have been widely used in automotive and aerospace industries due to their high strength-to-weight ratio, heat-treatable capability and excellent castability. The alloying elements such as Cu, Mn, Fe are traditionally added into Al-Si-Mg alloys to improve their mechanical properties (Mohamed, Samuel, Samuel & Doty, 2009). In recent years, the attention has been paid to the effect of the transition elements such as Zr, V, Ti, etc, as minor alloying additives, on the properties of aluminum alloys (Elhadari, Patel, Chen, & Kasprzak, 2011; Kasprzak, Amirkhiz & Niewczas, 2014; Shaha, Czerwinski, Kasprzak, Friedman & Chen, 2015; Shaha, Czerwinski, Kasprzak & Chen, 2014; Mahmudi, Sepehrband, Ghasemi & 2006; Meng, Cui, Zhao & Zuo, 2013). Kasprzak et al., (2014) and Shaha et al., (2015) reported that additions of Zr, V, and Ti in Al-Si-Cu-Mg cast alloys can improve the alloy mechanical properties at high temperature by forming stable intermetallics and precipitates on as-cast and heat treatment conditions. On the other hand, the mechanical properties of near-eutectic and eutectic Al–Si cast alloys depend not only on the chemical composition but also, even more importantly, on microstructural features such as the morphology and size of eutectic silicon and intermetallic particles, which are present on both as-cast and heat treatment conditions (Mohamed et al., 2009). However, there is rather limited information on the effect of Zr and V on the microstructure features and mechanical properties of near-eutectic Al-Si-Mg cast alloys."

Jan 1, 2018

By C. J. Hall

This paper presents a basic motive column analysis of natural ventilation and shaft resistance, using the density depth diagram. The method makes use of tables showing the state of the air as determined by thermodynamic analysis. Several theoretical examples are given.

Jan 1, 1968

By L. Fernandes

A factorial study was performed to investigate the relative effects of temperature, copper concentration and meso-2,3-dimercaptosuccinic acid (DMSA) concentration on the performance of thiosulfate leaching of gold. A total of 24 leaching experiments were performed representing eight unique combinations of high-low levels of the three factors performed in triplicate. All investigations were performed in an electrochemical cell with an electrolyte composed of 0.1 M sodium thiosulfate with a combination of copper (either 0 mM or 1 mM) and DMSA (either 0???or 1µM). All leaching investigations were conducted under open circuit while the electrolyte, which was open to the atmosphere and mechanically stirred, was maintained at either 25°C or 50°C. After 1.5h of leaching the amount of gold in solution was quantified using ICP-MS analysis from an aliquot of the electrolyte. Results indicate that DMSA addition improved gold leaching performance, most notably at 50°C and with addition of copper. Under this unique condition, the quantity of gold in solution was reproducibly and significantly above the average response of all other factors studied.

Jan 1, 2014

By J. B. Evans

"NORMALLY the duties of the exploration engineer and geologist cover the initial, and possibly, the most important phase of mining property evaluation; that phase being the presentation of an opinion of the property's ore reserve potential in terms of tonnage and grade. The prime objective of this pa-per is to outline one method of bridging the wide gap that lies between a know ledge of a property' s tonnage and grade potential and an appreciation of the value of that property in dollars and cents.THE PRESENTATION OF PROPERTY EVALUATIONThe engineer engaged on a mining property evaluation, regardless of whether he be an independent consultant, or a company employee, has as his goal, the presentation of his appreciation of the property's potential value or worth within terms of reference acceptable to his principal.To furnish a complete evaluation report, the evaluator must firstly study all aspects pertaining to the particular property under consideration, then present his appreciation of the property's worth in some tangible form. The ultimate presentation is one giving a Present Value of the pro pert y in terms of monetary exchange. Such an idealistic presentation is not always possible; typical preventives being -insufficient reliable information, limited time, Jack of ability and absence of definite direction."

Jan 1, 1960