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By L. Sun

A numerical model has been developed to study the air flow in the flow plate and gas diffusion layer assembly on the cathode side of a PEM fuel cell. The flow plate in this type of fuel cell often has serpentine channels and the porous layer is adjacent to the flow plate to diffuse the air to the catalyst layer. Flow cross-over of air through the porous diffusion layer from one part of the channel to another can occur. This flow cross¬over is a result of the pressure differences between different parts of the channel, and it causes the flow rate through the channel to vary with the distance along the channel. A numerical study of pressure distribution and flow cross-over through the gas diffusion layer (GDL) in PEMFC flow field using a serpentine channel system has therefore been undertaken to compare the cases of a single channel and two parallel channels, with the channels having a trapezoidal cross-sectional shape. The purpose of the present work was to study the effect of the flow plate geometry on the basic fluid flow through the plate. The flow here has been assumed to be three-dimensional, steady, incompressible, isothermal and single-phase. The flow through the porous diffusion layer has been described using the Darcy model. The dimensionless governing equations have been solved by using the commercial CFD solver, FIDAP. From the results obtained, it can be found that the single channel systems have greater maximum flow rate difference than the parallel channel systems under the conditions considered in the present study. Also, the size ratio R of trapezoidal cross-sectional shape has a significant effect on the flow cross-over and pressure variation in the flow field.

Jan 1, 2005

By N. B. Clarke

LIMESTONE, as a name, covers a great variety of stone consisting of varying amounts of calcium carbonate, magnesium carbonate, and impurities such as silica, alumina, and sulphate of lime. In the iron and steel industry, limestone is roughly divided into two classes, namely Calcite, when the magnesium carbonate content is below 10 per cent, and Dolomite, when the magnesium carbonate is over 10 per cent. In practically all metallurgical melting, the quality of the finished product is related to the character of the slag, and limestone is used as a flux to achieve the proper analysis and consistency. The function of the slag is to absorb the undesired elements of the bath and also to act as a protective cover over the metal. The carbonates of calcium and magnesium are the effective agents in fluxing, and the silica, alumina, sulphur, and other foreign matter are objectionable impurities which should be as low as possible, totalling not over S per cent and preferably below 3 per cent, since all of these so-called impurities must be fluxed by the lime and magnesia of the stone. When the lime and magnesia of the stone have to be used to flux its own impurities, there is that much less of these two oxides left for fluxing the impurities from the balance of the charge, and, as a result, more lime-stone must be used than is desirable with good practice.

Jan 1, 1939

By D. W. Heard

Electrospark Deposition (ESD) is a low heat-input, high energy density, micro-welding process. The short pulse duration and high-pulse frequency, in combination with the small amount of material transferred during each pulse, results in the evolution of extremely rapid cooling rates, believed to approach 105-106 °C/s [1]. This rapid solidification event results in the refinement of the microstructure to the nanostructured or amorphous level [2, 3]. Figure 1 displays the resultant microstructure of an Al-17%Si alloy deposited by the ESD process. Furthermore, it was determined that the microstructure of the deposit remained unchanged after subsequent layers were welded onto the presented layer. Freeforming of materials is a rapid prototyping process in which the deposited feedstock is built-up to the desired geometry in a near-net shape manner. Figure 2 displays the automated set-up employed produce three dimensional freeformed objects via multiple deposition trials of the ESD process. The automated XYZ table is equipped with CNC software to transform CAD renderings into three dimensional tool paths. Figure 3 displays an Al-12Si freeformed gear (2" diameter, 12 teeth) produced by the ESD process, prior to removal from the substrate. An SEM analysis of the freeformed component showed that the microstructure did not coarsen during the deposition of subsequent layers during the freeforming process, as depicted in Figure 4, resulting in the production of a bulk nanostructured component. This paper represents a summary of the capabilities of ESD to fabricate advanced materials possessing refined microstructure. In particular, results on the microstructural evolution obtainable for various wear-related systems will be presented. In addition, the feasibility of using the ESD process to freeform three-dimensional objects via multiple deposition passes will be presented and accompanied by a characterization of the properties of the freeformed component. [1] R. N. Johnson, "ElectroSpark Deposition: Principles and Applications," in Society of Vacuum Coaters, 2002, pp. 87-92. [2] J. Milligan, D. W. Heard, and M. Brochu, "Formation of nanostructured weldments in the Al-Si system using electrospark welding," Applied Surface Science, vol. 256, pp. 4009-4016. [3] S. Cadney and M. Brochu, "Formation of amorphous Zr41.2Ti13.8NilOCul2.5Be22.5 coatings via the ElectroSpark Deposition process," Intermetallics, vol. 16, pp. 518-523, 2008.

Jan 1, 2010

By C. Juers

Laboratory chromate coating was applied on AM50 and AZ91D alloys and compared to phosphate-permanganate one. Evaluation of the corrosion behaviour was performed using electrochemical DC and AC methods in ASTM water D1384-87. This electrolyte was chosen because it was moderately aggressive and found to give generally good correlations with long period exposure results in atmospheric conditions. Electrochemical impedance spectroscopy was used to determine more accurately the corrosion rates from the analyses of the high frequency capacitive loop. Anodic polarization was applied in order to evaluate the pitting resistance of the different coatings. These results were correlated with weight loss data evaluated from experiments performed by immersion tests in ASTM water D1384-87 and climatic cyclic chamber tests.

Jan 1, 2006

By A. S. MacNeil

In the operation of any colliery, a factor of prime importance is power, of which there are three sources available--man, horse, and mechanical. It is obvious that man-power is by far the most expensive, .and that animal-power, also, is more costly than mechanical. In recognition of this fact, mine owners must, for economical ?reasons, reduce the use of man-and horse-power to the minimum by the increased use of machinery. In other words, they must aim at as complete mechanization as conditions will permit, taking advantage of existing physical factors that are favourable and making the necessary adjustments and modifications to meet the less favourable conditions. Intensive coal-mining, or the concentrated production of coal, has two distinct objectives: First, the maximum production from a limited area, in a given time, thereby reducing the pit-room to be maintained; and second, reduction in cost. To this end the coal should be mined, loaded and delivered to the surface by mechanical means wherever possible. To do this, however, requires the solution of many problems arising out of the varying conditions that obtain underground. The system of longwall mining lends itself to a more efficient scheme of mechanization than does pillar-and-room, as, in the former, the first step has already been taken by the removal of all the coal in one operation, and the opening-out of one face, the equivalent in mining area of fifteen or more rooms. Much has been clone of late towards mechanization in the longwall mines of the Sydney coal-field, and with gratifying results, but not without great difficulties and frequent disappointments. In 1923, an attempt was made with shaker conveyors. The introduction of conveying was a step to bridge the gap between the face, where the coal is produced, and the main transportation arteries leading to the slope or shaft. The receiving of the coal at the faces and its delivery to main loading points on main haulage-ways was the part allotted to the conveyors.

Jan 1, 1932

By Kevin Azocar, Jim Hazzard

"Slope stability analysis is performed most commonly using limit equilibrium calculations or numerical models assuming a two-dimensional slice through an infinitely long slope surface. In areas such as open pit mining, where most slope surfaces are not planar, the importance of curvature becomes important due to the economic gains associated with creating a steeper slope. With advances in computing capabilities within the last decade, three-dimensional slope analysis can be performed within reasonable time frames. Some work has been done on the potential importance of curvature on slope stability, mainly assuming homogenous materials with a circular shear-failure mechanism. However, many open pit mines are excavated in jointed rock mass where a completely different set of failure mechanisms can be seen. Depending on the geometry and radius of the pit, the curved geometry may influence the factor of safety and failure behaviour compared to a two-dimensional slice.A series of numerical analyses were performed to investigate the effect of curvature on jointed rock slope stability compared to an equivalent two-dimensional slope analysis. By using discrete element method models, the influence of joint planes and interaction between distinct blocks can be seen. With a three-dimensional model, the effect of curvature can be combined with multiple joint sets at any orientation, which cannot be seen in a single slice. Numerous three-dimensional models are created, along with an equivalent unit-thick slice. The effect of curvature on a variety of different types of failure mechanisms is observed, and graphical relationships are created to quantify the difference between the three-dimensional factor of safety and the two-dimensional factor of safety based on the degree of curvature."

Jan 1, 2015

By K. Bunney, R. Pleysier

The deportment of a suite of elements through representative gold ore processing unit operations in cyanidation has been investigated. Chromium and lead are not soluble in alkaline cyanide solutions. Arsenic, antimony, cobalt, molybdenum, selenium, tellurium and vanadium are soluble, but typically do not adsorb onto activated carbon to any appreciable extent. Silver, copper, cadmium, mercury, nickel and zinc to varying extents report along with the gold to the carbon eluate. Cadmium, mercury and zinc can report to the carbon regeneration kiln off-gases. Strontium is soluble and adsorbs on carbon where it remgins.

Jan 1, 2011

By Kristine Haug

Although most in situ operations in Alberta do not encounter significant problems during resource extraction, there have been a few documented occurrences of oil or steam releases as a result of compromised caprock seals. The objective of the Oil Sands Caprock Integrity Project (OSCRIP) is to characterize the units above and below bitumen zones to determine which geological factors affect the quality of the caprock seal. In addition, geomechanical properties and stress measurements of the bitumen reservoir and overlying units will be examined to provide a better picture of the containment conditions in which in situ operations occur. The information from this study will aid regulatory staff and industry in determining the zone-specific geological and geomechanical factors that could affect the design, operation, and feasibility of in situ recovery projects. The OSCRIP study area (Townships 87 to 99 and Ranges 1 to 13, West 4th Meridian) encompasses the surface mineable area, the northeast extent of the Wabiskaw-McMurray bitumen deposit and the Clearwater Formation, as well as a wide band of the Devonian salt-dissolution zone. Regional geological mapping of the Cretaceous strata focuses on the spatial extent and thickness of the caprock seal. Mapping of the underlying Devonian strata is targeted at better understanding the potential effects of salt dissolution and collapse of overlying strata on the integrity of the caprock seal. Examination of LiDAR (Light Detection And Ranging) bare earth DEM in the study area has revealed localized depressions that may represent sinkholes rooted in subsurface collapse features in Devonian carbonate and evaporite strata. Mapping the location and understanding the timing of salt dissolution-related features and deformation in the Devonian strata will help address questions about the possible effect that geological structures, such as sinkholes, have on the integrity of the caprock, as well as the potential for localized variations in the stress regime of the bitumen zone and overlying units. The stress regime in units above 350 m is such that any induced fractures are believed to be horizontal, and therefore, there would appear to be no mechanisms that would allow these fractures to reach the surface. However, recent incidents have shown that vertical pathways can occur, linking the subsurface to the surface. The final phase of the project will evaluate the changes that may occur in the stress regime under thermal operating conditions in the study area.

Jun 1, 2012

The tensile test results of as-cast A356.2 grain-refined alloy castings show that the tensile strength can be improved by strontium modification (`SrM'), superheating at 900°C OM, and melt thermal treatment of the Sr-modified alloy melt (`SrMTT'). Both SrM and SrMTT processes can greatly improve the ductility (percent elongation) of the as-cast alloy. During solution heat treatment at 540°C, eutectic Si particles undergo fragmentation, spheroidization, and coarsening, thereby affecting their morphology. The effects of solution heat treatment on the tensile properties of the variously treated A356.2 alloy castings can be summed up as follows: the yield strength of the castings is significantly improved after 8 h solution heat treatment due to the precipitation of Mg2Si, after which it remains more or less the same with the further increase in solution treatment time up to 80 h; the ultimate tensile strength is also greatly improved within the first 8 h of solution heat treatment and then remains at the same level thereafter, up to 80h of solution treatment. The improvement in UTS is attributed to Mg2Si precipitation, dissolution of Si within the aluminum matrix, and changes in the Si particle morphology (spheroidization). The ductility of the as-received grain refined non-modified (`NM'), grain refined and superheated at 900°C (`SH'), and melt thermal-treated grain refined (`MTT') A356.2 alloy castings can be improved considerably with solution heat treatment e.g. from ~6% in the as-cast non-modified casting to ~10% after 80 h solution treatment.

Jan 1, 2011

By B. Hewitt

Murrin Murrin Operations has not had a successful beginning. Numerous reliability and operability issues many of which are the result of design decisions have been addressed through mechanical and operational changes and the CCD circuit is no exception. The decision to install, the installation and the results of the CCD1 rake-lift mechanism and feedw ell dilution system are discussed in this paper. The installation was justified on improved operational robustness and an increase in the in the underflow density of 1% (per cent w/w). At approximately the same time process modifications in the solution neutralisation circuit were implemented and these changes altered the rheology of the slurry reporting to CCD1. Since the modifications to CCD1 and the solution neutralisation circuit, the CCD circuit has averaged a 2% improvement in the circuit underflow density. The CCD1 modification was completed on time and mechanically has performed well. From a risk point of view, the central rake-lift and Turbodil® dilution system add a degree of freedom and robustness to CCD1 operation that has extended the range of operational confidence. In this respect, the modification has been a success and is complementary to solution neutralisation improvements.

Jan 1, 2004

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

By Zhang. L.

Ordered intermetallic PtSb had been synthesized by arc-melted and then sintering treatment. The electro-oxidation of formic acid on PtSb was investigated at room temperature by cyclic voltammetry and chronoamperometry. The results are compared to those at a polycrystalline platinum electrode surface. It was found that PtSb intermetallic was catalytically more active than pure platinum according to the onset potential and current density. XRD and XPS technologies had been used to investigate the crystal structure and electron effect. We think formic acid decomposition on PtSb favors the reactive intermediate route and is not very much affected by the CO intermediate as compared to Pt.

Jan 1, 2005

By Arthur Brant

STEEPROCK LAKE (Figure 1) lies about two miles north of Atikokan, a village approximately one hundred and forty miles west of Fort William and one hundred miles east of Fort Frances on the Canadian National railway. The possible presence of hematite beneath the waters of Middle arm was inferred by early geological investigators (1890-1903) from the dense hematite float found on the southerly shores of this portion of the lake (1). A dip-needle survey of Middle arm, undertaken in the winter of 1930-31 by J. G. Cross, indicated two areas of high magnetic attraction which Mr. Cross thought might be due to magnetic iron oxides associated with possible hematite bodies. Bedrock could not be reached by the ineffectual hand-drilling so courageously attempted, and further work was abandoned. It was not until 1937 that Mr. Jos. Errington, of Toronto, convinced of the possibilities, determined to support Mr. Cross to the extent of several thousand feet of drilling. During the winter of 1937-38, holes Nos. 1, 3, 4, 5, and 13 were put down (see Figure 1). The first four of these holes demonstrated that the areas of magnetic attraction outlined by the dip-needle survey east of the Narrows and southwest of Elbow point were due to ash rock (2). As a result, Mr. Cross decided to investigate the bordering areas of low magnetic attraction and selected a location near the high ferruginous lime (3) point in the northeast of Middle arm. Dense, hard hematite beneath approximately 350 feet of water and clay was struck in the first hole, and, before the end of the winter&apos;s drilling, hematite had been encountered in holes Nos. 6 to 13 along a straight line 700 feet in length (see Figure 1). In the meantime, the Steerola ( 4) Exploration Company had been formed to continue development and already, in the spring of 1938, W. D. Neeland, the Company geologist, had come to the conclusion that the most probable location for possible hematite was at the ash-lime contact. Accordingly, during the summer, drilling was continued off-shore in holes Nos. 15, 25, and 27 (see Figure 2) toward possible hematite bodies inferred by Mr. Neeland.

Jan 1, 1940

By K. Tada

A surface of a magnesium slab (hereinafter, referred to as Mg slab) or magnesium alloy slab (hereinafter, referred to as Mg alloy slab) becomes black with the use of conventional manufacturing methods. The methods also involve a danger that an explosion of the molten magnesium occurs through contact with cooling water. Thus, it has been impossible to produce a slab having a smooth surface. In the present method, a molten magnesium alloy is supplied into a mold, which is sheltered from the surroundings, from a pool in tundish, which is shielded from the surroundings. AZ31B slab formed in the mold is drawn horizontally out to the outside from an outlet of the mold by revolving of the pinch rolls. A cooling water is jetted at an acute angle onto the slab on the outer side of the mold outlet. Further, an inert gas is sprayed at the inner side of the mold outlet in order to seal in a gap between a free surface of the molten magnesium alloy and a sheltered board surrounding an upper surface of the mold. As a result, oxygen and droplets of the cooling water are prevented from running back to the mold side through the gap. AZ31B slab has a smooth surface condition and high quality without a gas porosity, a segregation or the like. Further, the slab has a size of a width of 100 to 120 mm, a thickness of 5 to 20 mm and a span of 10 m or more.

Jan 1, 2006

By W. Mirihange

Considerable mechanical property decline is always observed at the Heat Affected Zone (HAZ) of AA 5083, This occurred as a result of the thermal effect on the hardened material, It is highly beneficial to have a prospective metallurgical procedure to overcome this decline of properties. Therefore, experiments were set to evaluate the effectiveness of a quick post weld heat treatment process with the AA 5083, Optimum results were obtained at 473K and with approximately 600 seconds time, The interplay between the time, temperature and mechanical properties are possible to explain by the Lifshitz-Slyozov-Wagner (LSW) theory and by considering the composition of the material.

Jan 1, 2005

By D. G. Cerigo, D. M. Bryce, P. H. Jennings

This paper summarizes the results of an experimental and economic study undertaken to evaluate the feasibility of treating an oxidized orebody of about 10 million tons, grading about 0.75 per cent copper, by agitation leaching and by percolation leaching.

Jan 1, 1968

By Renato Macciotta

The argillaceous formation known as the Opalinus Clay is host to the Mont Terri Underground Research Laboratory. The URL was developed to investigate the hydrogeological, geochemical and geotechnical properties of the formation. Underground excavations at the site are characterized by non-elastic and time-dependent deformations. Excavations trending perpendicular to the strike of the bedding presented relatively minor deformations, however, tunnels parallel to the strike of the bedding showed much larger non-elastic deformations. This paper presents an analysis of the measured response of a tunnel trending parallel to the strike of the bedding in Opalinus Clay. The measured convergence is compared to tunnel experience in weak rocks to assess the tunnel stability.

Jun 1, 2012

By A. Zangooi, J. A. Finch

Flotation is a separation process based on the collection of particles on the surface of bubbles. Flotation machines disperse air into bubbles using a variety of techniques. The characteristics of the bubble population are strongly affected by the selection of frother type and concentration. As metallurgical results depend on the bubble distribution, the measurement of frother concentration is vital to understand and control performance. A previously developed colorimetric technique was refined to work with low solubility frothers and to increase daily analysis rate. Field-testing demonstrated that the method is robust, reliable and accurate. As well as relating frother concentration to gas dispersion measurements, the results can be used to answer operational questions including: how well a frother dissolves, how reliable and stable frother delivery is, how evenly frother is distributed down a bank, and whether frother distributes between the pulp and froth zones. Some of these points are illustrated from plant experiences. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists ofCIM Sudbury, Ontario, Canada Edited by

Jan 1, 2009

By C. Blawert

In spite of various corrosion studies on HPDC AZ91, there is no clear indication which microstructure gives the best corrosion performance. The skin with its fine microstructure is sometimes reported to have the best corrosion resistance, but there is no clear definition of the skin. If the skin is the outermost part of the casting and nothing is removed from it, then it is contaminated and the corrosion resistance is low. If the outermost skin is removed (about 25 µm) then a better corrosion resistance can be obtained. However this does not automatically mean that there is no other region in the bulk of the casting which could have a similar or even better corrosion resistance. Indeed, the corrosion measurements including potentiodynamic polarization and long term electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin about 100 pm thick. The thickness of this region is more or less independent from the thickness of the casting section. The surface region is free from any dendritic grain growth which influences the amount and distribution of the 13-phase and therefore the distribution of the most important alloying element Al. This could explain the different corrosion behavior. Further reason can be found in the enrichment of some impurities such as Fe in the near surface.

Jan 1, 2006

By D. Nie, M. Ren, T. Mo

This paper studied the phenomenon of room temperature creep deformation at crack tip and its effect on fatigue crack growth rate of a X-70 pipeline steel using compact-tension (CT) specimen on a MTS 810 testing machine. Time-dependent deformation at the crack tip under constant load was observed in this steel at room temperature and the amount of deformation produced was seen to depend on loading rate and the magnitude of stress intensity factor. It is found that there exists a critical stress intensity factor below which the deformation decreases with time when the applied load remains constant. It is also found that the occurrence of room temperature creep obviously affects the subsequent fatigue crack growth rate. The observed behavior was explained based on dislocation theory.

Jan 1, 2005