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By Wei Zhang, Jinhong Zhang

"The adsorption of ethyl xanthate on copper sulfides, i.e., chalcopyrite, chalcocite and bornite, has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). AFM images show that xanthate, such as potassium ethyl xanthate (KEX), adsorbs strongly on chalcocite and bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is totally different from the one obtained with chalcopyrite/xanthate system, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The findings obtained from the present AFM study suggest that an AFM image analysis is a powerful tool for the study of the collector’s adsorption on mineral surface and as well the development of novel collector for copper sulfide flotation.INTRODUCTIONIn mining industry, copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite, are usually separated selectively from non-valuable gangue by froth flotation, which treats the highest throughput and produces the maximum economic outcome of any surface chemistry process. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineralbubble attachment and thus a high flotation recovery.The adsorption of collector on mineral surface, therefore, is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2016

By Erwin L. Zodrow

"For 25 chemical elements in electrostatically precipitated fly ash (Lingan coal-fired power station), concentration changes are studied as a function of increasing proportions of fines (ash particle diameter less than 45 micrometres). Elements that are involved when concentrations increase as the proportions of fines increase are likely to escape into the atmosphere. These are Th, U, As, S, P, Sb, Na, Ag, Zn, Pb, Ni, Ba, Sc, AI, Mo (and Bi, Ge, Ga, F and Li), i.e., more or less highly volatilized elements. Of the less volatilized metals such as Fe, Ca, Cu, Ti, K, Co, Mn (and lanthanides), certain portions presumably also escape as stack emissions. Diadochy and spinel formation in bottom slag is presented as an emission-reducing agent for certain metals.IntroductionThe Lingan coal-fired power generation plant, owned and operated by the Nova Scotia Power Corporation, produces annually about 140,000 metric tons of ash (the residual mineral content after burning coal). The tonnage is based on a 15 per cent average ash content of Cape Breton coal.For purposes of this report, samples of the hard, fused slag (bottom slag) that is accumulated at bottoms of boilers, and electrostatically precipitated fly ash (ep ash), were collected and investigated. Bottom slag is a minor component of the produced ashes.The ashes were surveyed and the presence of over 75 major, minor and trace elements is reported. From this survey, 25 elements were selected to establish elemental enrichment/depletion trends when the proportions of the less than 45 micrometre <45µm) fractions in ep ashes increase. The results are significant in that, taking the case of elemental enrichment, the elements involved are likely to escape into the atmosphere, i.e, highly volatilized elements. Depletion trends for elements are presumably associated with less volatilized elements during coal-firing. Quantification of the emission of atmospheric pollutants is not considered part of this work. ""Igneous"" minerals generated during coal combustion include spinels (found mainly in the bottom slag), quartz, glass and mullite."

Jan 1, 1982

By Chri Langille, Dougal McCreath, Samantha Espley

"In 1993, trials of two innovative applications of liner support involving the replacement of bolts in the ground support system were undertaken at Inco mines. The first trial involved an evaluation of the effect of dynamic loading on mesh-reinforced boltless shotcrete in a sub-level cave mining area on 2400 level at Stobie Mine. The second trial involved an evaluation of the MIROC Mineguard spray-on liner as a replacement for bolts and screen support, or as a replacement for screen support alone, in a topsoil heading of a bulk, VRM (vertical retreat mining) stope on 3240 level at Lower Coleman Mine.In the Stobie Mine trial, an uppers retreat heading was supported using a two-pass system. First, shotcrete was applied 2 inches thick, followed by pinning of mesh screen to the back and walls. A second pass of another 2 inches of shotcrete was then performed. For recovery of the ore zone, a vertical slot was created using a Borepak blind boring machine. The uppers rings were blasted, one or two rings at a time, starting at the slot and retreating out of the heading. During blasting of the production rings, blast monitoring was used to record the ppvs (peak particle velocities). For a series of 5-ring blasts, the maximum ppvs were measured to be 0.4 m/s (16 in./s) with a maximum charge weight per delay of357 kg (800 Ib). Six 5-point convergence measurement stations were set up and after each blast the total rockmass convergence was measured using a tape extensometer. Although a maximum displacement of 100 mm (4 in.) was measured, the shotcrete still managed to provide some support junction. A support damage assessment was also done to try and relate blast vibration to effectiveness of the mesh reinforced shotcrete liner. This trial demonstrated the effect that blasting has, on a support system, and it also demonstrated the necessity of having the mesh reinforcement properly placed within the shotcrete."

Jan 1, 1995

By Noel Billette, Jean-Luc Chouinard

"An analysis of the number of industrial injuries shows that the mining sector is particularly affected, since mining is one of the most dangerous industrial activities in Canada. This has led to numerous inquiries, and supports the need for an in-depth study aiming at the identification of factors responsible for these accidents. One possible factor often pointed at is the small crews incentives and this paper presents a scientific approach applied to check a potential link between bonus and accidents at two mining companies located in northwestern Quebec.The data required to do so were the accidents, the salaries and the number of hours worked at each mining site by the hourly paid personnel for the period from June 1979 to January 1982. The analysis of the results derived from the initial information shows different behaviours of the frequency rate vs the bonus rate at these mines. The number of days lost per accident is independent of the bonus rate at both mine sites, as shown by Khisquare tests on contingency tables.IntroductionA wide variety of opinions has been pinpointed by a survey of the literature related to individual or small crew incentives and industrial accidents in sectors of activity where it applies. In addition, various formulae of mining contracts take place in the industry on one part, and statistics from this sector indicate a high accident frequency rate on the other part. These fact s have lead to this scientific investigation which does isolate the direct impact of the bonus on workers&apos; accidents. This study was undertaken with the full support of the Quebec Metal Mining Association.The conclusions of this preliminary phase of the researchproject are presented for two mining complexes in northwestern Quebec. The procedure is somewhat similar to the approach of the Belmoral Commission, with the underlying assumption that bonus has a direct impact on accidents."

Jan 1, 1986

By Leonard A. Wolff

"The 1980sfor the mining industry can be characterized as the survival of the fittest. High interest rates, low commodity prices, foreign subsidized competition and decreasing ore grades have contributed to a streamlining of the domestic mining industry in the United States, leading to the shutdown of operations or large cutback of work forces. The purpose of this paper is to look at the impact of a layoff on the employees of what was once a major uranium producer in south central Wyoming, twenty months after the final layoff and mine shutdown. INTRODUCTIONDecember 19, 1985, was the date of the final of three successive layoffs over a two-month period, leading to the complete shutdown of Petrotomics Company, a subsidiary of Getty Minerals Company. The final shutdown was due to a combination of depressed U3O8 prices and the takeover of Getty Oil Company by Texaco in January 1984.The layoffs affected 104 employees and included mine personnel, mill personnel and staff. Both hourly and salary workers were involved. The operation was considered non-union, however, a few mill hourly employees were unionized. At the completion of the layoffs. only a handful of employees remained for administrative and miscellaneous functions.For Getty employees, the terms of the merger agreement provided a generous level of separation benefits. The terms that were insisted upon by Mr. Petersen, Chairman of the Board for Getty Oil, stipulated that employees receive one month of severance pay, for each full calendar year of employment up to a maximum of two year&apos;s pay. This was the forerunner of what is now commonly known as the ""tin parachute”. All but the union employees of Petrotomics received these separation benefits. Union employees were covered by their separate, less generous, contract.Much of the literature that has been published in recent months has centred around the effects of layoffs on remaining employees, or the psychological effects on the severed employee. This study will emphasize the economic impact and ramifications due to a layoff, using the Petrotomics employees as a case example."

Jan 1, 1989

By J. W. M. Porritt, K. C. Cheng

Knowledge of radon emanation rates from uranium-bearing rocks is essential to the design of mine ventilation systems for uranium mines. Measurements of equilibrium ratio between radon and its daughters in mine air are important for a better control of mine radiation conditions. The concentrations of radon and daughters were monitored at cut-and-fill stopes in the Beaverlodge Mine of Eldorado Nuclear Ltd. during all phases of the mining cycle. The radon emanation rates of ore and rock samples were measured at the laboratory and the results were compared with in-situ emanation tests in an isolated ore drift. Samples of backfill solution, backfill drainage and ground seepage water were measured [or radon and analyzed for radium and uranium. The results showed that discharges of backfill solution and daily shift-end blasts were the two major sources for a rapid release of radon gas in the ventilation air. Other mining operations, such as drilling, mucking, etc., contributed little effect on radon release to the mining environment. Radon emanation rates of the Beaverlodge are samples ranged from 13 x 10-18 to 600 X 10-18 Ci/cm2/ sec and that of waste rock samples from 0.54 x 10-18 to 13.4 X 10-18 Ci/cm2/sec. The in-situ emanation rate of mine walls with ore-to-rock ratios of 1 to 7 was 60 x 10-18 Ci/cm2/sec. The average equilibrium ratio of radon and its daughters in stapes was 32.6%. Under a normal ventilation condition, the average background levels of radon concentration in cut-and-fill stopes ranged from 13 to 80 pCi/L. The discharges of backfill solution during backfill operations at 100 tons solids per hour released approximately 1.8 x 106 pCi/min of radon and elevated radon concentration in stapes 2 to 5 times above the background levels.

Jan 1, 1981

By Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

A thermodynamic description of the equilibrium in liquid and gas phases under specific conditions of refractory gold pressure oxidation was generated using the HKF theory. The gold behavior was considered at 190-225°C in the presence of 1-100 mg/L of chloride ion, and under oxidationreduction potential (ORP) of +700 to +1030 mV. The calculations show that the predominant form of gold(I) occurrence is [AuOH]° compared to [AuCl2]?. High ORP favors the formation of [AuCl4]? as a predominant form of gold(III). It is noted that this complex is responsible for the gold losses buildup during POX. Laboratory test results for double refractory concentrate POX are shown. The combined negative effect of (i) organic carbon of the concentrate and (ii) dissolved chlorides in POX slurry on gold recovery is demonstrated. The effects of carbonate blending to the POX feed concentrate and incomplete oxidation of sulfides on POX performance were studied. The pilot tests results of continuous pressure oxidation are also shown and generally confirm the laboratory results and theoretic dependencies. A comparison of the experimental data with the results of thermodynamic calculations is made. As a result of current research, an effective process for POX treatment of carbonaceous sulfide concentrates in the presence of chlorides was developed.

Jan 1, 2014

By A. Khodadadi, M. Abdolahi, P. Taimory

Cyanide is used by the mining and chemical industries in tremendous quantities without attention being given to its hazardous properties. The use of cyanide compounds in mining is one of the most important environmental issues for the mining industry due to the acutely toxic properties of many cyanide compounds to humans and aquatic life. Cyanide tends to react readily with most other chemical elements, producing a wide variety of toxic, cyanide-related compounds and because cyanide is carbon based an organic compound it reacts readily with other carbon-based matter, including living organisms. This research is aimed at investigating a feasible and economical technique for the removal of cyanide from tailing wastewater of Muteh gold mine. In this research, removal from Muteh factory&apos;s waste water, was achieved at Tarbiat Modares University&apos;s mineral processing laboratory through the oxidation of cyanide by calcium hypochlorite. Cyanide oxidizes and changes to cyanide (CNO-) which is 1000 times less environmentally hazards than cyanide. Cyanide titration was accomplished using Rhodanine solution and silver Nitrate. Cyanide concentration in the wastewater, was 270 mg/L. Cyanide removal was achieved at an optimum pH of 12.3. However, at higher temperatures, cyanide removal was complete at this pH level. Optimum Dosage for complete removal of cyanide using calcium hypochlorite was 1.43g/L.

Jan 1, 2005

By L. S. Brooks

TIMBER HANDLING presents a problem for any mine where appreciable amounts are used. This problem is accentuated where the shaft compartments are too small to allow a loaded timber truck to be lowered in the mine cage. When Normetal Mining Corporation, Limited, found it necessary to resort to square-set mining it faced this problem of getting large quantities of timber down a shaft that was also required for hoisting ore. A &apos;timber car&apos; that could be suspended under the cage was developed to overcome this difficulty. Production started at the Normetal mine in 1937, at the rate of 250 tons per day. In 1938 a winze, known as No. 3 shaft, was sunk from the 800-foot level ?to the 1,385-foot level. This was later raised to surface and then deepened to 3,275 feet in three stages and became the main production shaft. The portion of the mine below the 3,070-foot level is serviced by a winze, locally referred to as No. 4 shaft, which has been developed for stoping down to the 3,990-foot level and which has been deepened to the 5,365-foot level. No. 3 shaft has two hoisting compartments, each 4 ft. 6 in. by 5 ft. 0 in. inside the timbers, through which the ?ore must be hoisted and timber and supplies lowered.

Jan 1, 1956

By S. Knapp

Inconel 600 pipes welded to Carbon-Steel are used in CANDU nuclear reactors. Fracture of these welded tubes would have important consequences in term of safety, and therefore their mechanical properties need to be better understood. In this study, the weld region was analyzed at various length-scales using optical microscopy, micro hardness testing, small and large scale tensile testing and digital image correlation (DIC). Large grains were observed in the weld region and smaller grains in the Inconel and carbon steel base metals. Micro-hardness profiles showed variations across the weld and through thickness and were justified in terms of residual stresses in the sample. Large tensile samples were extracted from the welded pipe and were used to identify the material in which fracture initiates. In addition, the local strains in each material were obtained using digital image correlation. Local stress-strain curves were built from the DIC data and compared to stress-strain curves obtained from miniature tensile samples extracted from the carbon steel, Inconel and weld regions. The results demonstrate the advantage of using DIC for extracting local material properties in dissimilar weld systems. Variations in the materials stress-strain curves thought thickness are also presented and emphasize the need for obtaining a complete map of the mechanical properties in the weld region for predictive models to be accurate. Preliminary fracture studies will also be presented.

Jan 1, 2011

By M. E. Austin

Many numerical models for the tubular solid oxide fuel cell (SOFC) exist, with various degrees of sophistication. However, the question of what physics must be modelled, and what can be neglected has not been resolved. A parametric model is proposed and analyzed to quantify the influence of thermal phenomena such as reaction heat generation, cathode channel convective cooling, and thermal radiation with participating media. Currently, a three-dimensional model is used to simulate the conditions of an anode supported cell in the centre of a tube bundle. The interconnect and nickel foam spacers that bridge adjacent cells in series and parallel, respectively, are neglected thus enabling a domain consisting of a 45o azimuthal section of the tube. The conservation equations for mass, energy, and species transport are solved using commercial computational fluid dynamics software, and radiation heat transfer is also modelled using a Discrete Ordinates method. Finally, temperature-dependent material properties and reaction rates are used. The model predicts lower overall temperatures than models that do not include radiative heat exchange and more moderate temperature gradients than those that ignore participating media radiation. Further, different regimes are identified, from convection dominated heat transfer to radiation dominated heat transfer. The results can be used to aid in the selection of appropriate models for a given fuel cell operating regime.

Jan 1, 2005

By Michel Guillot

Gaz metal arc welding is commonly used for producing large frames and assemblies. Even for light aluminum and thin wall assemblies, the GMAW technique is increasingly preferred over the GTAW technique. This is particularly true where the welding gun motion is achieved accurately with automated or robotic systems and when using pulsed or regulated metal deposition. In this study, butt joints in floor welding position are tested at speed ranging from 1.5 to 16 m/min. Attempts are made of find parameters providing good and repeatable joint quality with minimal distortion and good appearance even at high travelling speeds. Taguchi experimental plans are proposed with different parameters tested with sheet metal samples. The parameters include typical GMAW machine settings, joint preparation geometries, wire gages, gun angles, wire feeds, and more. The robot motion speed and the proximity of the part are also considered. Direct monitoring of machine welding current and voltage is achieved. Once is found the best set of parameter settings, additional tests are carried out to verify the repeatability of weld quality. Secondly, these conditions are applied for joining and testing a floor panel made of several extrusions. Weld quality is established with Vickers micro-hardness measurements, cross section geometries of the weld pool including penetration, tensile tests and metallographic observations to establish the amount of porosity and weld microstructure in the HAZ.

Jan 1, 2011

By Jorge M. C. Soares

The CO oxidation reaction has been studied on Au/TiO2 catalysts prepared by incipient wetness (IW) and deposition-precipitation (DP) methods. Additionally the assessment of activity was also conducted on simple gold compounds (Au2O3 and Au(OH)3) and their physical mixtures with TiO2. We have found that there are three types of CO2 production from fresh catalysts, which are only dried, namely: Non-catalytic Type I (low temperature CO2 production); Non-catalytic Type II (higher temperature CO2 production) and Catalytic Type III. The DP catalysts are far more active for Type III reaction, showing activity already at room temperature, whereas the IW catalysts generally do not show steady state conversion until T>673 K. This is due to both large particle size and the presence of residual chlorine for the latter. No truly catalytic activity was found for low temperature CO oxidation on gold precursors on their own, although both Au2O3 and Au(OH)3 react well with CO even at room temperature in an irreversible manner (Type I reaction). Despite that, catalytic activity was obtained by mixing Au(OH)3 or Au2O3 with TiO2 which gives further emphasis on the importance of a good contact gold/support and the absence of chlorine.

Oct 1, 2003

By Pavel Vasak

Microseismic monitoring is becoming standard practice in the Canadian mining industry, particularly as mines get deeper. Full-waveform microseismic systems allow the operator to distinguish the event source mechanism, e.g., blast, shear slip or stress-induced fracture. At mine sites that heave a microseismic system operator blasts are manually identified by comparing the event waveform traces to the morning blast logs. However, this procedure is not routinely done at sites where a system operator is not present and this can lead to misinterpretation of the data at a later stage, particularly where the interpretation is outsourced, often many years later. It is critical to improve the microseismic data quality and consistency for processing and interpretation with a reliable technique to filter out blasts and blast related seismicity. This paper presents the development and implementation of a simple blast identification and filtering routine. The routine was developed specifically for Vale?s Creighton Mine about a decade ago, but is made sufficiently general so that it can be used at any mine site with an ESG (Engineering Seismology Group Canada) based full-waveform microseismic systems. The routine is strictly a post-processing procedure developed for use with the Access database data structure used by ESG. The algorithm was tested at Creighton Mine and a success rate of 80 to 90% was achieved, when compared to manual blast picks.

Oct 1, 2010

By R. H. Duval

"In May 1936, Pamour started producing gold by cyanidation of flotation concentrates, and in 1939 was milling about 1, 600 tons per day.Refining records dating from 1939 show two oil-fired furnaces in use, (Rockwell type 46 11 x 29 11 inside oval shell).Refining time averaged 7. 83 hours during the year 1939, indicating a complete refining shift of about 9. 33 hours. That year appears to be characteristic of the period with regard to time required and results obtained.For that year total fineness (gold + silver) of the bars averaged 940 (approx.), but it frequently dropped below this figure, sometimes far below.Furnace lining life varied widely from three to seven or more months. Sillimanite was the standard lining but Mullfrax 41 was frequently used.For many years refining practice remained practically unchanged, and in 1960 procedure still consisted essentially of mixing a flux(% Composition Borax 41, Silica 11, Soda-Ash 11, Nitre 15, Mn02 22) with cyanidation precipitate in the ratio of l. 2 to l and heating to a medium heat (yellowishred, 2000° F) with a low flame for a long time. Time required was about 10. 5 hours per refining. Results were still much as detailed above.At this time it was decided to revise refining procedure, in an effort to shorten refining time and obtain consistently good bullion fineness."

Jan 1, 1965

By W. R. Hopkins, J. A. Davis

"This paper presents a discussion of the mechanisms by which aerosols of the process electrolyte are entrained into the breathing environment of copper, Zinc and nickel eIectrowinning tankhouses. Literature outlining the health effects associated with worker & posure to the acidic and metallic contaminants found in the airbome aerosols is summarized and compared with existing North American regulations.A brief review of the existing technologies for the source reduction of these aerosols is presented. This paper outlines the industry experience with use of covers, balls, beads, shapes, fixtures and chemical surfaetants. Each of these devices is ranked according to its effusiveness in the process in which it is used, and rated according to its operator acceptance.The various forms of existing in-plant ventilation systems are reviewed with a discussion of their relative merits and effectiveness. Actual experience is related, detailing the methods of testing for ambient contaminant levels in a variety of tankhouse environments. Guidelines are provided for the site and process specific criteria which govern the selection and ultimate effectiveness of a particular form of ventilation system.Finally, actual project experience is cited in which hydraulic modelling is used a design tool in tankhouse ventilation design. These projects include the upgrading of existing traditional ventilation designs, and the &apos;&apos;grass roots"" design of a more efficient aerosol source control system to be used in high altitude, cold weather sites."

Jan 1, 1994

In-Situ Leaching (ISL) process plants are low cost producers for uranium deposits where the geology is suitable. In the 1970s, a three-year pilot ISL program occurred on gold ore from the Ajax Mine, Cripple Creek District, Colorado, using a chloride and iodide solution [1]. The test was halted due to poor results. With gold and silver the international ISL progress has been slow; however the potential for low capital expenditure (CAPEX) and operating expenditure (OPEX) with large low grade deposits is real. Unless the metallurgy has been demonstrated there are significant risks which could be fatal flaws to an ISL gold or silver project. The metallurgy of gold ISL projects is far from simple and it is early days with project development.

Jan 1, 2011

By H. Dundar

An extensive testwork was performed around the HPGR plant at GoldFields Ghana Limited Tarkwa Gold Mine. The HPGR was used to prepare the feed for heap leaching. The circuit was configured in such a way that the edge material from the HPGR discharge was recycled for further crushing while the product from the centre reported to the heap leach section. The set-up of the Polysius HPGR provided an opportunity to study the effect of different design and operating variables. This paper will discuss the results from the tests performed to assess the effect of rolls? speed and applied pressure on the capacity and the grinding efficiency of the HPGR. Applying different pressure values appeared to have an influence on the amount of edge material recycled.

Jan 1, 2012

By Michael Bowker

Au/TiO2 catalysts were prepared by incipient wetness impregnation and tested for the room temperature photocatalytic reforming of methanol in aqueous solution. These catalysts proved to be more active, on a molar basis, than Pd/TiO2. The dependence on loading of gold was different from that of palladium, showing a double maximum in yield at 0.1 and 2 wt. % with low rate below 0.01% and above 10%. A model is proposed for the reaction involving band gap excitation of titania electrons which are used to oxidise the methanol via adsorbed CO. With palladium, photoreforming of CO and water can be achieved, but this is much less effective on gold, presumably due to the much weaker bonding of CO on Au.

Oct 1, 2003

By H. Dundar

The first application of High Pressure Grinding Rolls was in 1985 at a cement plant, for the purpose of capacity improvement. Then various circuit configurations were derived to achieve a reduction in overall specific energy consumption, by transferring more of the grinding required to the HPGR. In most circuit configurations, the recycle of fines is required for effective breakage between the rollers. By increasing the fines amount in the feed material to a specific level within the recycling load, a uniform material bed is created and a higher pressure gradient along the roller width is obtained, resulting in compact flakes, including more fines. The fines recycle results in enhancement of the interparticle breakage. This paper will discuss the effect of the feed size distribution on HPGR performance.

Jan 1, 2012