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By Fadi Layyous Gedeon, David Hatton, Solomon Mogashoa, Tuhin Banerjee, Faisal Aljohani

The adoption of innovative technologies in mineral processing often raises concerns about complexity and integration. However, Woodgrove’s Direct Flotation Reactor (DFR) technology at Barrick’s Jabal Sayid copper concentrator provides a different perspective. This paper outlines the smooth integration of DFR technology from piloting to full-scale commissioning, showcasing how easily the cells were brought online. Installed in a cleaner scalper role, DFR cells at Jabal Sayid upgrade re-ground rougher concentrate to final concentrate in one stage. Despite processing challenging ore, the DFR cells delivered concentrate grades that consistently exceeded expectations. The commissioning process was straightforward with minimal hurdles, highlighting the technology's user-friendly nature. This paper advocates for a shift in perceptions about new technologies in mineral processing. The success of DFR technology at Jabal Sayid demonstrates that “different” doesn’t mean “difficult.” By focusing on ease of commissioning and operational integration, innovative solutions can enhance processes, improving efficiency and productivity in the mining industry.

May 4, 2025

By C. S. Liao, S. L. Wang, C. H. Yan, F. X. Cheng

A significant development in the theory of countercurrent extraction will be presented in this article. A new term in countercurrent extraction process analysis, "Adjacent Stage Impurity Ratio" (ASIR), is proposed, and its expression is deduced. Furthermore, based on the term together with mass balance and extraction equilibrium, the conditions where a given countercurrent extraction separation operation can have minimum amounts of both extracting solvent and scrubbing agent solution can be estimated, and the equations of the two minimum amounts can be deduced. It was found that the equations for a two-component separation using a single aqueous or organic feed are exactly the same as they appeared in the theory initially established in the 1970s. Unlike its earlier version, the present derivation does not involve feed-stage-composition hypothesis, and also has the advantage of dealing with a double-feed system where both aqueous and organic feeds are simultaneously employed whereas the earlier theory can only analyze a separation using a single aqueous or organic feed.

Jan 1, 2014

By Yan Qun, Chen Xiao-ming, Ma Pei-long, Luo Xian-ping, Luo Cai-gui, Feng Bo

The effect of leach promoting reagent LPF on the leaching process of a weathered crust elution-deposited rare earth ore has been investigated and the mechanism is discussed. The result shows that the leach promoting reagent LPF can enhance the leaching extraction of rare earth ore effectively. With the addition of LPF to the lixiviant at a concentration of 0.1%, the leaching extraction increased by more than 8%, the ammonium sulfate concentration could be decreased by 25%, and the leaching liquid/solid ratio reduced by 34%. The mechanism analysis shows that LPF can react with rare earth ions and form soluble coordination compounds, thus reducing the activity of the leached rare earth ions, increasing the concentration difference for ion diffusion, and promoting the rare earth leaching process. These results will hopefully help point to a new approach to making the leaching process of low-grade weathered crust elution-deposited rare earth ore more efficient and with lower lixiviant consumption.

Jan 1, 2014

By L. A. M. Castro

As Canadian mines progress to greater depths, magnitudes of induced stresses increase, becoming high enough to cause rock mass damage and failure during excavation. In addition, depending on the orientation of key geological structures in relation to the in-situ stresses, induced shear loading can be developed on these structures, creating the potential for: a) remobilization of existing geological structures, b) formation of new seismically active structural zones, created through rock mass damage and coalescence along such structural zones, and/or c) interaction between existing and newly created structures. Numerical analyses were carried out to investigate four possible factors that might cause fault slip on controlling structures, namely: (a) unclamping, (b) day-lighting, (c) stress rotation and (d) pillar shear. Application to an underground mine in the Sudbury Basin allowed verification of these factors and the proposal of two alternative mine planning methods to limit fault slip on key structures: (1) pillar clamping and (2) stope sequencing.

May 1, 2009

By T. Macpherson

Drawing on past research experience with sprayable polymer mine support agents (TSLs), Spray On Plastics Ltd. has developed a TSL ground support system called RockWeb. Using a relatively new polyurea polymer technology, RockWeb has been engineered to solve problems encountered underground with polyurethane liners by incorporating rapid curing, moisture insensitivity and superior physical performance. RockWeb possesses a unique, patented ability to be sprayed in a ?cobweb? like consistency allowing the applicator to span fissures in the rock, ensuring no initial defects in the liner, and maintaining design thickness over highly irregular surfaces. This ability, coupled with the high strength and elasticity of polyurea, allows RockWeb to mitigate rock movement through yielding, while maintaining intimate surface confinement. RockWeb provides reduction in logistics through the transport of 1/25 of the material quantities required for shotcrete, rapid deployment rates of as little as 30 minutes per round, and immediate return to the work area. This paper will discuss the technology and advantages of RockWeb as well as opportunities for overall mining cycle cost reduction. The safety benefits, as well as health and environmental considerations regarding application of isocyanate-based liners will also be discussed.

May 1, 2009

By L. C. Hsu, H. F. Jr. Bonham, M. O. Desilets, P. J. Lechler, J. G. Price, L. J. Garside

Abstract-Geochemical background levels have been established for unmineralized sedimentary rocks that are elsewhere the hosts of Carlin-type gold deposits in the Getchell Trend. The Paleozoic rocks in the Winnemucca Quadrangle consist predominantly of the lower Paleozoic siliceous and clastic sequences that were carried eastward along the Roberts Mountains thrust during the Late Devonian and Early Mississippian Antler Orogeny and the late Paleozoic Havallah and Pumpernickel sequences brought along the Golconda thrust eastward during early Mesozoic Sonoma Orogeny. Over 260 rock samples were collected from the Paleozoic sequences. Major and trace elements were determined by instrumental methods best suited for the specific elements. The general geochemical features of the Paleozoic sedimentary rocks are discussed in detail with reference to the data of average abundances of elements in sedimentary rocks. The background and threshold values of certain trace elements in sandstone, shale, and carbonate rock of one formation, as well as back- ground levels for the entire sequence were obtained. The characteristic geochemical features of the Paleozoic rocks in this area include: consistently high Ba and low Au contents (1.1 ppb, 1.5 ppb, 1.1 ppb Au for average sandstone, shale and carbonate, respectively); generally low contents of those elements which may be of environmental concern such as As, Cd, Hg and Pb. Plots of major and trace elements suggest that the majority of the Paleozoic clastic rocks are related to a passive- margin tectonic setting. Samples with gold values higher than threshold are considered to have been affected by hydrothermal alteration related to gold mineralization. Most of these samples generally also have higher values of Sb, Hg, V and/or As. These observations support the use of such elements as pathfinders for gold, although V has not been identified as such before. Ba is not effective for gold exploration in this area due to the generally high background value of Ba, even though it may be an important pathfinder elsewhere.

Jan 1, 1995

By S. D. Normani

A Deep Geologic Repository (DGR) for Low and Intermediate Level radioactive waste has been proposed by Ontario Power Generation for the Bruce Nuclear site in Ontario, Canada. The DGR is to be constructed at a depth of about 680m below ground surface within the argillaceous Ordovician limestone of the Cobourg Formation. The objective of this paper is to apply paleoclimate boundary conditions to a regional-scale groundwater flow model for the DGR site and to describe the influence of glacial loading and unloading on flow system evolution using the FRAC3DVS-OPG flow and transport model. The regional-scale domain encompasses an area of 18,775km2 extending from Lake Huron to Georgian Bay in southwestern Ontario, Canada. From a hydrogeologic perspective, the domain can be subdivided into a shallow zone, an intermediate zone, and a deep zone comprised of the low-permeability units of Ordovician and the more permeable Cambrian where present. The deep groundwater zone is characterized by units containing stagnant water having high concentrations of total dissolved solids (TDS) that can exceed 300g=L. The high TDS values at depth require density-dependent coupled flow and transport calculations within FRAC3DVS-OPG. The computational sequence involves the calculation of steady-state density independent flow that is used as the initial condition for the determination of pseudo-equilibrium for a density-dependent flow system that has an initial TDS distribution. The 1,000,000 year pseudo-equilibrium heads and brine concentrations are used as the initial condition for the paleoclimate simulations. Over the past 900,000 years, the Canadian Shield has experienced approximately nine episodes of complete glaciation. During the glaciation cycles, the entire Canadian land mass has been covered by a series of continental ice-sheets whose maximum thickness reached 4 km and whose southern extents reached, in some cases, beyond the present-day Canada-U.S. border. The glaciation phase of a single glaciation-deglaciation episode is typically 90,000 years in duration, while the deglaciation portion proceeds relatively rapidly and has an average duration of approximately 10,000 years. Output from the University of Toronto Glacial Systems Model, a continental scale North American glacial reconstruction of the most recent 120,000 year glaciation event developed by W. R. Peltier, is used to supply the paleoclimate boundary conditions used in this paper. Permeabilty reductions due to the presence of permafrost are also considered in the paleoclimate simulations. This paper will demonstrate that the choice of rock properties can significantly affect residual pore water pressures within the rock matrix, as well as the migration of glacial meltwater.

May 1, 2009

By Ngonidzashe Chimwani, David Glasser, Diane Hildebrandt

"Milling circuits play an important role in achieving the desired product; tonnage, size distribution and properties, since they are directly linked to the comminution energy consumption for the whole process. A grinding model with a mathematical simulation was developed for an open milling circuit with a scalped feed from a hydro-cyclone. The circuit was optimized by determining the optimal conditions in terms of energy consumption which would produce a floatable product having a desired size range (i.e. -75 +9 µm) for a platinum-bearing ore. The simulation results showed an operating region comprising the best combination of the ball filling and mill speed to achieve the highest production of a floatable size class, with the minimum energy consumption.INTRODUCTIONBall milling is usually conducted in closed circuits in order to achieve a desired product size without material overgrinding. The technological importance of optimising milling circuits cannot be overemphasised (Toneva and Peukert, 2007). Previous work has brought significant insights into the benefits of modelling milling circuits (Austin et al., 1984; King, 2012; Toneva and Peukert, 2007). However, the ability to model these circuits is dependent on the performance of the classifiers and the fidelity of the grinding mill model used compared to the actual circuit (Toneva and Peukert, 2007). Austin et al. (1984) identified five types of milling circuits as shown in Figure 1 namely; the grinding circuits employing mill in an open circuit, normal closed circuit, reverse closed circuit, open circuit with scalped feed, and, the combined closed circuit. Depending on the presence of the first classifier, the second, or both as well as their corresponding loops (streams), the combined circuit (e) can reduce to; an open (d), a normal closed (b), an open circuit with scalped feed (c) or a reverse closed circuit (a). In the case of an open circuit, the mill is operated without being directly influenced by a classifier. The normal closed circuit does not have the first classifier and therefore the make-up feed is the actual feed stream. Conversely, the reverse closed circuit keeps only the first classifier. The open circuited with scalped feed has only the first classifier but does not have the second one. The overflow stream from the classifier is mixed with the mill product to form the final product for the downstream process."

Jan 1, 2016

By Alok Porwal, E. J. M. Carranza, M. Hale

Abstract- Approaches to mineral potential mapping based on weights of evidence generally use binary maps, whereas, real-world geospatial data are mostly multi-class in nature. The consequent reclassification of multi-class maps into binary maps is a simplification that might result in a loss of information. This paper describes results of using multi-class evidential maps in an extended weights-of-evidence model vis-à-vis results of using binary evidential maps in a simple-weights-ofevidence model. The study area in the south-central part of Aravalli province (western India) hosts a number of SEDEX-type base metal deposits in Proterozoic supracrustal rocks. Recognition criteria for base metal deposits were represented as both multi-class and binary evidential maps. The known mineral deposits were divided into two subsets, viz., the training and the validation subsets. The training subset was used to calculate, for the evidential maps, the weights, contrasts, and posterior probabilities and their variances. The distributions of expected frequencies of base metal deposits estimated from the posterior probabilities and the observed frequencies were compared using standard goodness-of-fit tests to verify conditional independence of the input evidential maps. The posterior probabilities from both the models were mapped and interpreted to classify the study area into zones favorable, permissive, and non-permissive for base metal deposit occurrence. As compared to the simple weights-of-evidence model, the extended weights-of-evidence model results in more robust and finely differentiated posterior probabilities in favorable and permissive zones and has a better prediction rate. The results also reveal that the statistical properties of the weights of evidence, the contrasts, and the posterior probabilities are not significantly degenerated by using multi-class evidential maps in weights-of-evidence modelling.

Jan 1, 2001

By Laxman M. Amaratunga, Nuri Hrnidi

"Reactive pyrrhotite tailings were agglomerated using the Cold Bond Tailings Agglomeration (CBTA) process with low cost binders; Portland Cement and fly ash. Various chemical additives, were used to retard acid mine drainage (AMD), including acid neutralizers, surfactants, sealants, and bactericides, which were encapsulated into the agglomerates. The choice of these additives was based on their low cost, low toxicity, and environmental friendliness. The main objective of the study was to examine the long term stability of these reactive tailings agglomerates towards AMD when used as aggregates for disposal in underground paste backfill.A carefully controlled kinetic stability test was carried out using specially designed humidity cells suitable for testing pellets. Using the humidity cell test method a 20-30 year AMD test may be accelerated to 50 weeks. During this period the following parameters were monitored: pH, redox potential, conductivity, sulphate, acidity, and dissolved metals.Results indicated that most of the encapsulated additives were successful in retarding AMD, while the control samples produced significant amounts of acid generation. The water soluble surfactant Enviroseal, and the sodium silicate sealant were very effective as a long term retardant for acid generation reactions in the sulphidic tailings when exposed to oxygen, water and iron-oxidizing bacteria.IntroductionThe sulphidic material discharged from concentrators becomes reactive upon exposure to air and/or water. Pyrrhotite (Fe0 S0_1) and pyrite tailings in particular which are discharged from the beneficiation process in the mining and mineral processing activities consist of finely ground particles. Upon exposure to oxygen and moisture, the tailings become reactive due to the instability of the metal sulphide minerals present which undergo spontaneous oxidation, thereby producing a weak sulphuric acid. Therefore, the long-term behaviour of the tailings can have a significant impact on the environment, due to acid mine drainage (AMD). AMD is created during natural atmospheric weathering when leaching action (natural and bacterial) conditions are present in the process wastes discarded during the mining and milling of sulphur bearing ores, and consequently it plays a major role in surface water chemistry."

Jan 1, 1998

By M. Fafard, D. Picard, J. -F. Bilodeau, G. Soucy

To simulate adequately the behaviour of a Hall-Heroult electrolysis cell, a finite element model must take into account the properties of each material. However, it has some lacking knowledge on the mechanical behaviour of materials, like the long-term visco-elastic (creep/relaxation) behaviour of cathode. A three-dimensional model is then proposed in this paper and will be ready to be implemented in the finite element code FESh++. The model was developed using the three-dimensional model based on thermodynamic of irreversible processes where the choice of the internal variables is based on a phenomenological approach. All parameters of the model are represented by constant constitutive tensors and the temperature and chemical dependencies are taking into account through scalar functions multiplying the constant constitutive tensor. The goal of the first part of this project was to determine the parameters of the threedimensional visco-elastic model at the reference state (virgin material at ambient temperature) of three different cathode materials. This paper presents the theoretical model and the results of creep tests at ambient temperature for the semi-graphitic carbon cathode.

Jan 1, 2006

By Peter Van-De-Velde

"The results of applying Japanese pumping technology to North American reclamation projects will be discussed.IntroductionEconomic high-density mineral reclamation and subsequent transportation of solids through a pipeline presents many formidable engineering problems.In North America where space has rarely been a facto r, industry has generally relied upon the traditional dumping of material into various waste ponds, etc . In Japan, where confined geographies and stringent environmental regulations are enforced, alternative solutions for disposal or reprocessing of waste material had to be found.High-density mineral reclamation system designed by theoretical formulas is almost impossible because solids composition, i.e. concentration, velocity, moisture content, solid size, etc. can only be controlled within a broad pumping range.Traditionally this has restricted dredging of material to relatively dilute slurries whereas it is usually preferred to reduce water usage with its associated power and reclamation costs to a minimum and reclaim as high a concentration as possible.At Toyo Pumps North America we recognized these pumping limitations and began to develop and manufacture a range of standard and auxiliary equipment that would exceed these technical restrictions."

Jan 1, 1985

By W. B. Boggs

This is a rather comprehensive subject and cannot be thoroughly covered in the short rime allowed for its presentation. This article will touch only upon a few of the chief points of the difficulties encountered in recovering copper from brass shell cases in a primary smelter which was not designed to treat scrap metals. Owing to the fact that the plant is at present (Dec., 1946) closed, and our tests were not completed, full details of the results are not available. As is well known, most primary smelters are situated near the mines in the interior of various countries and are not close to seaports or large industrial and railway centres. Consequently, iris unusual for a primary smelter to be asked to treat scrap metal of any kind. When so required, iris obvious that the primary smelter is at a great disadvantage, for the simple reason that it probably has to pay the freight on the scrap from the seaport or industrial centre to the smelter and then also pay the freight on the recoverable metal from the smelter to the refinery, or seaport or industrial centre. Another disadvantage is that a primary smelter is not equipped to sample and unload the scrap nor bas it usually the equipment adaptable for treating the scrap efficiently, as the plant bas been designed to handle large tonnages of ores and concentrates. This short paper will describe some of our difficulties> and how they were corrected. However, it might be advisable to state briefly some of the methods used in treating brass shell cases in other plants. In the first place, a brass plant producing new brass- especially those producing brass billets for extrusion to make brass tubes or rods, or to be drawn into wire, or making brass cake to roll into brass sheets- generally insists upon using new electrolytic copper and zinc and is opposed to using any scrap or secondary brass . Consequently, such a plant usually will not treat brass shell cases. Therefore, the usual procedure is to ship brass shell cases to a secondary smelter, where it is generally sorted, melted, fire-refined, and returned to the market in the form of a high or low brass ingot which can be sold to brass foundries for making brass castings. This evidently is the cheapest and simplest method. Another method is to ship to a smelter which is a combination of a primary and secondary smelter attached to or near an electrolytic refinery. In plants of both these types, that is a primary smelter with Cottrell dust collectors or a combined primary and secondary smelter with Cottrells or a bag house, the zinc may be wasted. However, if a bag house is used, some of the zinc is recovered, but it is usually contaminated with other metals and further processing is required to recover it.

Jan 1, 1947

By F. L. Thompson

MAN has been using lubricants of one type or another for at least four thousand years, and probably for a much longer period. We have learned from the inner wall of the tomb of Tehuti-Hetep, on which is a decoration illustrating the method of moving a great stone statue, that as early as 1650 B.C. lubricants were used to facilitate the movement of heavy loads. The Egyptians had available nearly every animal oil and fat, as well as at least thirteen vegetable oils, of our time, all used for food products and in the arts. Examination of the deposit on the axle of a chariot from an Egyptian tomb of 1400 B.C. showed it to consist of animal fat, quartz, sand, iron, and compounds of aluminium and lime-indicating a manufactured lime-soap grease made with lime-soap and possibly tallow. This would not be a bad lubricant for the axles of chariots which had to travel over sandy soil in hot weather. As to the method of grease application, it is remarkable that, from the time wheels were first used in the far distant past up to the present day, no one has ever thought it necessary to design a seal to keep the lubricant in and the dirt out. While time certainly marches on, we have today, in waggons throughout the world, exactly the same form of lubrication as was used in the earliest chariots. From the early days of the chariot until shortly before 1800 A.D. (when the steam engine was introduced), the main heavy equipment required for mining purposes, for machines of war, etc., was made of wood. The bearings were rough, but usually they had metal in the lower half. Light machinery was made of bronze, brass, or iron. Large clearances and poor alignment, plus the fact that speeds were much below present-day demands, combined to provide conditions that were quite satisfactorily met by the lubricants available. These were often produced locally by the machine operator. In northern countries, lard oil, prepared from the fat of hogs, was the universal lubricant employed in machine shop, as a belt and leather dressing, and for cutting operations. Sperm oils were used for light machinery, whereas beef and mutton tallow were more generally employed for the largest bearings. For the early steam cylinders, a slug of heated beef tallow was injected wherever the cylinders gruntingly complained of a lack of lubricant. Southern countries, however, resorted to the use of vegetable oils-olive, cocoanut, etc.

Jan 1, 1940

By E. J. Marcotte

"IntroductionDevelopments in the preparation, hydraulic transportation and placement of classified mill tailing as an effective backfill and support for mining excavations, have made feasible several advancements in mining methods that are safer and more economical. Hydraulic backfill systems have played an integral part in the development of more efficient cut-and-fill and blasthole stoping.The hydraulic transportation of tailing fill has made possible the elimination of expensive and laborious transportation, placement and spreading of gravel type fills. Also, in cut-andfill stopes, the use of hydraulically placed consolidated fill has largely eliminated the need to use extensive timbering for floors and supports, previously necessary when only gravel type, waste rock or unconsolidated tailing fill was used .Another important advantage of using mill tailing as backfill is that it decreases the need to contain a large portion of the mill solids waste in a surface disposal area and thus reduces environmental and ecological problems.Tailing Fill PropertiesConsolidated tailing fill consists of deslimed mill tailing and Portland cement. These two materials are mixed together in various proportions to form a high density slurry which is transferred underground by gravity through boreholes and pipelines. After placement underground, the water is drained off and the mixture is allowed to set. The strength of the consolidated fill is dependent on the cement content, particle size distribution and curing time. A typical tailing/ cement ratio used for bulk filling in stopes requiring vertical wall support is 30:1. Ratios ranging from 8:1 to 5: 1 are used for stope floors. High pulp densities minimize segregation and loss of cement during placement as well as reduce the amount of drainage water to be handled."

Jan 1, 1989

By Somasundaran P., M. Vasudevan, Z. Dai, D. R. Nagaraj, T. Bhambani, P. Patra

Historically, efficient beneficiation of ultramafic ores has been challenging, partly due to a lack of clear scientific understanding of the effects of Mg silicates, particularly fibrous serpentines, on selective Ni recovery. Recent research at Columbia-Cytec as a part of a Vale JDP project has led to new insights into the mechanistic aspects of the adverse effects of Mg silicates. Our research has provided strong evidence to support the hypothesis that the adverse effects of Mg silicates are mediated through their large influence on pulp rheological properties, far more than any other pathway. The severity of the effect of Mg silicates is predominantly dependent on the aspect ratios of Mg silicates. For example, the pulp viscosity increases dramatically with increase in the fibrous nature of the gangue mineral leading to poor Ni separation. Various ways by which the suspension rheology affects flotation sub-processes, with implications for remedy are discussed. The insights and results have served to develop (or construct) a phenomenological model to adequately explain all of the ore flotation data, particularly the Mg silicate transport to the froth phase and the concentrate.

Jan 1, 2011

By A. J. DeArdo

Linepipe steels have come a long way in the past forty years. In fact, modern, high strength steels for large diameter linepipe applications represent one of the seminal accomplishments in metallurgy of the past half-century. The synergy of advanced steelmaking, alloy design including microalloying, hot rolling, and interrupted accelerated cooling has led to the marvelous steels being used today. The drive for higher performance pipelines has been motivated by the energy sector of our global economy who wanted both higher throughput capacity, i.e., larger diameters and higher pressures, and lower material cost, i.e., relatively thinner gauge wall thicknesses. These requirements led to new steels with higher strengths, better toughness and improved weldability. The goal of this paper is to trace the evolution of linepipe steels from the X60 grades of the small diameter pipelines of the 1960s to the (X80 - X120) grades used in the large diameter pipelines of today. The metallurgical triumphs permitting this success story, e.g., clean steel practices, controlled rolling, microalloying with Nb, and using IAC to obtain low temperature transformation products, will be highlighted and discussed.

Jan 1, 2005

By Patty Simpson, Sarah Benson

In an effort to improve consistency across the nuclear industry, over the past 10 years the Canadian Standards Association has developed a series of standards related to environmental management at Class 1 nuclear facilities and uranium mines and mills. Canadian uranium mines have been required by the Canadian Nuclear Safety Commission to align their existing monitoring programs with these standards. Orano’s McClean Lake Operation’s monitoring program, which was originally presented in the Environmental Impact Statement in 1991, has evolved through regulatory change, new scientific understanding, additional projects, and experience into a comprehensive set of monitoring requirements for effluent, groundwater, air emissions, and the receiving environment. The exercise of aligning the existing practices with the standards provided an opportunity to review and rationalize the entire program. To document the process the original “Environmental Monitoring Program Design Document” was restructured and developed as both a repository for historical information and monitoring rationalization, and also to be a living document describing on-going studies and supplementary work that are outside of the regular environmental monitoring program and may justify future changes to the program.

Jan 1, 2020

By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

By D. Chadwick, J. W. Matousek

Between 1860 and 1890 -- from the time of the American Civil War to the last decade of the 19th Century -- nickel production in North America was dominated (even monopolized) by the output of the industrial complex of the Gap Nickel Mine near Lancaster, Pennsylvania and the American Nickel Works in Camden, New Jersey. In some years, from one sixth to one third of the world's metallic nickel supply came from this enterprise. Mining and smelting were conducted at Lancaster; a matte of high iron content was shipped to Camden for pyrometallurgical and hydrometallurgical refining to produce nickel metal, copper sulfate, and cobalt oxide. The high purity nickel product was rolled into sheet for marketing, primarily for coinage, as nickel had few other uses at that time. The undertaking experienced all of the problems that face the mining and metallurgical industries of today: declining reserves, high labor and fuel costs, high transportation costs, fluctuating demand and prices, pollution concerns, and foreign competition. The technical features of the geology; the mining, smelting, and refining operations; and some of the economic aspects are assessed. The view is taken from that of the present time -- seeking those lessons from history that we are supposed to learn or face the prospect of repeating the mistakes of the past.

Jan 1, 2005