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By F. H. Samuel, A. M. Samuel, H. R. Ammar

Casting imperfections, such as porosity, in cast aluminum components greatly influence their fatigue properties. The effect of porosity on the fatigue life of 319-F and A356-T6 aluminum alloys was studied, where the porosity characteristics on the fracture surfaces of fatigue-tested samples were examined using SEM and image analysis. The results show that porosity has the most detrimental effect on the fatigue life: 92 % of all tested samples fractured due to porosity acting as the main crack initiation site. In the absence of casting imperfections, other microstructural aspects such as slip bands can be responsible ( 4 % ). The porosity was investigated in terms of the pore size at the sample fracture surface and its location i.e. near the edge or close to the interior. It was found that porosity located far from the sample surface (edge) has less influence on the fatigue crack initiation, and the fatigue life decreases as the size of the pore located at the sample surface increases. Aluminium

Jan 1, 2006

By P. -Q. Wu

A modified electrochemical noise (EN) technique has been applied to monitor corrosion wear of TiN-coated ASP23 steel and TiN-coated AISI 316 stainless steel sliding against corundum in 0.5 M H2SO4. Experimental results show that the EN technique can sensitively detect potential and current variations during a corrosion-wear process. Corrosion-wear mechanisms of TiN coatings depend on their substrate properties. If the substrate is passive, such as AISI 316 stainless steel, the potential and current variations reflect the properties of the coating. Depassivation and repassivation alternately take place on the tribo-activated wear area during the steady-state phase. If the substrate is active, such as ASP23 tool steel, the electrochemical noise is dominated by dissolution of the substrate at the pinholes and the hydrogen evolution all over the exposed surface.

Jan 1, 2005

By H. J. McQueen

Friction stir welding (FSW) generates complex microstructures in the nugget and thermomechamically affected zones (TMAZ) that have led to diverse explanations. However, consideration as an extension of microstructure development in piercing/extrusion can lead to a better understanding of flow patterns and microstructures during FSW. Furthermore, the intense strains in the nugget/TMAZ can be interpreted by comparison with ultra-high strains in torsion that exhibit dynamic recovery as extending into regions with high angle boundaries strongly serrated with spacing near the subgrain size defined by the high temperature. The subgrain diameter and extrusion pressure have been shown to be dependent on the Zener-Hollomon parameter Z (=t exp(Q/RT), Q activation energy, R gas constant) combining temperature T and strain rate E in the same mariner as for torsion and compression. Moreover, such tests exhibited steady state stress os above a certain strain Es (rising as Z increases) in which T, , subgrain diameter and dislocation spacing remain constant. Due to the subgrain boundaries (SGB, low angle <5°, i.e.,LAB), continually rearranging by migration, decomposition and reformation, the subgrains remain equiaxed in elongating grains, whose boundaries (GB) become serrated as they migrate to absorb SGB. As confirmed by straining in torsion at constant T and Z. , more subgrains bordering the greater GB area have several high-angle facets (HAB) ; these small cellular regions with a mixture of HAB and LAB facets are designated HAB-subgrains. As serrations in neighboring grain boundaries impinge, the grains pinch off becoming shorter; this occurs at higher strains as subgrain size decreases with rising Z. The pinching-off makes the neighbors thicker so the grains never become thinner than about two subgrain diameters. In conjunction with such geometric dynamic recrystallization (gDRX), GB&apos;s undergo a net migration into grains with denser substructure, enlarging those with larger subgrains. Consequently a better name has been proposed: grain dimensioning dynamic recovery (gDRV).

Jan 1, 2007

By P. D. Hodgson, G. L. Kelly, H. Beladi

"The formation of ultrafine ferrite by strain induced transformation is assessed using rolling and hot torsion experiments. These experiments are used to examine the impact of thermomechanical processing conditions and steel chemistry on strain induced austenite to ferrite transformation and the formation of ultrafine ferrite. The critical strain for dynamic strain induced transformation increased with increasing carbon equivalence, deformation temperature and austenite grain size. The deformation structure in the austenite grains changes with the thermomechanical processing conditions.Drawing on these results and the current literature, the important factors for the production of ultrafine ferrite are described and a mechanism proposed."

Jan 1, 2004

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By David S. Wong

With air emission limits for total particulates continually tightening, management of `potroom dust&apos; or airborne particulates from aluminium smelting potrooms is of increasing importance. To better understand how settled and airborne particulates are generated within a potroom, methodologies have been developed to sample and analyse the compositional signature of dust, in relation to its sources. During a smelter case study, these methods allowed tracking of mineralogical phases in dust across a range of potroom locations, showing that the mechanisms of dust generation do vary spatially and vertically in a potroom. Such methodologies may also be applicable to other metallurgical industries.

Jan 1, 2011

By D. Harrington

Ventilation of underground workings consists in establishment of such control of air currents that the underground workers may work in safety, with maximum comfort and efficiency, and without impairment of health; and requires that the mine openings may be made subject to such control of air flow as to remove from these workings at ordinary times harmful gases and dusts, and that, at time of emergency, such as fire or explosion, there may be maintained as much or as little air flow as may be desired covering portions of the mine or the mine in its entirety. Control of air flow is the keystone of any ventilating structure, and this very essential feature is obtainable only by the installation of mechanically-operated fans, together with other;. ventilating devices such as doors, over-casts, regulators, etc. Every mine, large or small, coal or metal, should from the outset be equipped with a fan. While much has been written about natural ventilation and many claims made that in specific mines there is sufficient natural air flow, there are few if any mines, coal or metal, where natural ventilation supplies anything like adequately safe or healthful conditions for underground workers even at ordinary times; and at a time of mine fire or explosion, mines depending upon natural ventilation are practically helpless, and certainly are decidedly dangerous to those unfortunates forced to be in them. While ventilation has practically always been deemed an integral part of coal mining, metal mines have rarely paid much, if any, attention to air circulation until forced to do so by occurrence of some untoward condition or accident. Yet metal mines actually have as great need of efficient circulation of air as have coal mines. The coal mine must remove the dangerous explosive gas, methane, also fumes from explosives and, in occasional places, other gases such as carbon dioxide or nitrogen.

Jan 1, 1933

By K. K. Panthi, P. K. Shrestha

"Displacement of rock mass around a tunnel opening varies according to the rock mass properties, insitu stress conditions and applied support in the tunnel. Such displacement is also altered by presence of bands of rock mass that differ in properties. This paper focuses on the deformation behavior of rock mass around tunnel openings at four tunnel sections in Kaligandaki headrace tunnel where extensive instrumentation was done. Based on the actually measured tunnel displacement records and actually measured support pressure; back analysis has been done to estimate rock mass properties and insitu stresses. Numerical analysis has been done to analyze and assess the deformation behavior of the rock mass around the tunnel sections.INTRODUCTION Instrumentation and monitoring of tunnel convergences have significant importance in evaluation of tunnel stability. One of the key aspects of monitored data is that early convergences can be used in estimation of long term convergence. In addition, these data can also be used in evaluation of rock mass parameters and in-situ stresses around the tunnel. Convergence around a tunnel periphery may vary according to rock mass quality. Presence of bands of different rock mass may hinder the displacement pattern in the tunnel. Particularly, displacement characteristic of tunnel periphery in schistose, foliated and deformed rock mass is altered by presence of bands of comparatively stronger rock mass, e.g., quartz veins or presence of shear seams or faults. Similar observations were also recorded in monitored tunnel sections in Kaligandaki headrace tunnel, located in the Nepal Himalayas. Extensive monitoring was done by installing multiple point borehole extensometers (MPBX) at three different locations of the tunnel periphery at four different tunnel sections. In addition, convergence measurements by tape extensometers and installation of pressure cells to record support pressures were also carried out at each of the tunnel sections. Observations showed that the tunnel convergences varied according to rock mass quality, in-situ stress and effective support pressure.Rock mass parameters and stresses have significant role in the extent of tunnel deformation, but these parameters are often unknown or difficult to predict. Back analysis based on actual tunnel displacement records and known support pressure is believed to be an important method in such endeavor. This paper performs back analysis to evaluate rock mass parameters and discusses correlation of rock mass behavior with tunnel deformation and applied support. For this purpose, the rock mass parameters are estimated from actual tunnel displacement records, mapped rock mass quality records and laboratory tested data. Then, numerical modelling is conducted to correlate post peak behavior of the rock mass with actual tunnel displacement."

Jan 1, 2015

"The Hardy Cross algorithm offers a reliable method of solving network systems of fluid flow and has become widely used for solving water and ventilation flow networks. A limitation is that computational iterations and time to solve a network rises rapidly with the size of the model and modern detailed ventilation networks have typically grown to thousands of airways. Non-linear matrix solving methods can offer improved performance, however these are more complex and may be unstable if initial estimates are poor. This paper presents improvements that can be applied to the traditional Hardy Cross algorithm to greatly reduce iterations and solving time for large ventilation models. INTRODUCTION The Hardy Cross algorithm (Cross, 1936), was originally developed to solve water flow in city and urban pipe networks. Using principles of Kirchhoff’s electricity current laws, Hardy Cross developed an iterative algorithm for solving non-linear equations associated with network water flow. Traditional network analysis research refers to the various members of system networks as branches, nodes and meshes. This terminology has been changed in this paper to airways, junctions and loops respectively which are terms more familiar to engineers in mine ventilation. When Kirchhoff’s laws are applied to fluid networks, the following assumptions can be made: •The sum of fluid flows into a junction must equal the sum of fluid flows out of the junction.•The sum of pressure losses around any loop through a network system must be equal to zero.An iterative solution can therefore be achieved by initially guessing flow in a network, calculatingthe pressure losses around the network loops (Figure 1), and applying flow corrections using Newton’s method for each loop if the sum of the pressure losses does not equal zero. To solve the system, a loop must be defined for every segment or series of segments between a junction of 3 or more airways.The Hardy Cross algorithm has been used extensively for ventilation network analysis since the introduction of the first electronic computers (Tien, 1997), however numerous other variations and methods have since been developed through the use of matrices to solve the required system of nonlinear equations. Commonly used algorithms such as the Newton Raphson method (Brown, 1969), the Gradient method (Todini & Pilati, 1988), the Linear Theory method (Gupta & Prasad, 2000), and Coupled Network Solver (G. Danko, 2008) have found general use in fluid flow network solvers (Rossman, 2000). Despite poor and sometimes unpredictable convergence performance however, the Hardy Cross algorithm still has unique properties that make it attractive for ventilation models. Some benefits are:"

Jan 1, 2019

By N. L. Richards

In manufacturing for the 21st century, the first company to market often leads the pack in product development and sales. In this respect, manufacturing processes play an important role in transforming “raw materials” into a product(s) for sale to a customer. Thus it can be seen that upfront modelling of a design concept, or modelling of manufacturing processes in a plant, can play an important role in effectively ensuring the overall design and manufacturing route is carried out in an expeditious manner. In the paper various scenarios are considered with respect to modelling the microstructure and/or process, in various manufacturing processes. Also considered are the effects of service condition on the manufactured product in terms of creep and fatigue.

Jan 1, 2010

The methods employed for the addition of uranium to steels and cast iron in the Physical Metallurgy Division are outlined. It has been found that the segregation of? uranium is a major problem in aluminum and/or silicon killed steels and that the cooling rate is important in al-lowing the segregate to settle to one area, which can subsequently be discarded. The unsegregated areas were found to be extremely low in total oxygen, acid insoluble aluminum (AizOg) and, in some cases, slightly lower in nitrogen. Uranium recoveries, based on analyses of the unsegregated areas, were quite constant, at about 45 per cent, regardless of the type of uranium master alloy used for the addition. No segregation of carbon, manganese, silicon, sulphur, phosphorous, chromium or copper was observed in these steels. In commercial heats, the recoveries ranged from 7 to? 29 per cent for ladle additions to oxygen converted steel. When the steel was fully deoxidized prior to the uranium addition, recoveries ranged from 49 to 66 per cent, regardless of the steelmaking process.

Jan 1, 1964

By John S. Stevenson

THE Twin "J" Mine, operated by Twin "J" Mines, Limited, represents an amalgamation of the old Lenora, Tyee, and Richard III mines (see Figure 1) on mount Sicker, eight miles by road, northwesterly, from the city of Duncan, on Vancouver island. These mines produced 253,000 tons of copper-gold ore between 1898 and 1909 (see Table I). During the more recent period of production from these properties, July, 1943, to May, 1944, Twin ?J? Mines, Limited, mined and milled ore with values mainly in copper and zinc, and minor values in gold, silver, and lead. Figures are not available for this later production. Field work at the property was started by the writer in 1941 and continued in 1943 and 1944.

Jan 1, 1945

By Clifford S. Gibson

THESE troubled times suggest three reasons for maximum effort to control silicosis: (1) To keep to a minimum the ever-increasing burden occasioned by past deficiencies in this respect. (2) To effect the greatest production with maximum efficiency, which means at the least cost. (3) To preserve man-power in every way. Good control of the silicosis problem aids these aims. Inadequate control hampers all three. Insofar as our knowledge goes, silicosis in Ontario mines is caused by the inhalation of finely particulate quartz. It follows, therefore, that removal of dust containing this mineral automatically erases the cause. The achievement of this ideal is the aim of the mine operator. His best tool to this end is ventilation. This paper discusses mine ventilation from the viewpoint of dust control and it is hoped that in so doing there may result a better understanding of the part played by air in silicosis prevention. No attempt will be made to treat the subject fully. Instead, there will be presented certain salient aspects culled from field observations, the data in all cases referring to gold mines, unless mention to the contrary is made.

Jan 1, 1942

By A. H. Winckers

"The Sullivan Mine and Concentrator are owned and operated by Cominco Ltd. and are located in the Rocky Mountain Trench, in Kimberley, British Columbia.The Sullivan Concentrator commenced operation in 1923 at approximately 2,500 tons per day. The concentrator was enlarged in several stages and by 1945 was treating 8,500 tons of ore per day. In 1949, the capacity of the concentrator was expanded to 10,000 tons per day with the completion of the sink and float plant, the installation of the rod mill, an underground crushing plant and a 4-mile underground and surface electric railway from the underground crushing plant to the concentrator. Throughput now averages 7,000 tons per operating day, or 2,400,000 tons per year.The concentrator operates 7 days per week, 24 hours per day while the underground crushing station operates 5 days per week, 24 hours per day. The ore is essentially a replacement deposit in argillaceous quartzite of Precambrian age. The ore bodies are massive deposits consisting of fine grained mixtures of sulphides, sometimes interbanded with the country rock and varying widely in their content of lead, zinc, iron and silicates. The principal economic minerals are galena and marmatite (7 ZnS:FeS). Iron is mainly present as pyrrhotite, and to a much lesser extent as pyrite. The intimate association of these sulphides necessitated the development of a successful differential flotation process before the ore could be beneficiated profitably."

Jan 1, 1981

By M. Mezbahul-Islam

Thermodynamic modeling of the Mg-Cu-Ni system is carried out as a part of multi component thermodynamic database for Mg alloys. This system is being modeled for the first time using the modified quasichemical model, which considers the presence of short range ordering in the liquid. The thermodynamic descriptions of the binaries Mg-Cu, Cu-Ni and Mg-Ni have been extrapolated to the ternary Mg-Cu-Ni system using Toop geometric model. The constructed database has been used to calculate and predict thermodynamic properties, isothermal sections and liquidus projections of the Mg¬Cu-Ni system, which showed very good consistency with the experimental data.

Jan 1, 2011

By J. M. Réjean Gagnon

"Quebec Cartier Mining Company is currently mining a low-grade iron ore deposit in northeastern Quebec. The Company is producing some 8,000,000 dry gross tons of concentrates per year, grading about 66 per cent iron. The pit, which is located on the keel or hinge line of a fold, will eventually be about 1,000 feet deep with a surface area of 8,000 by 2,600 feet. The most significant structural discontinuities in the mine are the natural bedding planes and secondary perpendicular joints. The exposed walls are subjected to a sub-Arctic climate and heavy blasting occurs approximately six times a month.QCM utilizes design and operating techniques to control rock fall. Steps are also being taken to analyze the ultimate over-all pit slope stability."

Jan 1, 1968

By Ltd. (CYMCO) Technology Center Yunnan Metallurgical Group Co., S. Jian, T. Song, J. D. Miller

"As sulfide zinc ore deposits become exhausted, nonsulfide zinc ore deposits become the other resource for zinc production. However, flotation for zinc recovery from nonsulfide deposits is much more difficult than the flotation of sphalerite from sulfide deposits and may become an option for zinc production only if a suitable processing technology is developed. In this regard, research efforts are being devoted to the flotation of nonsulfide zinc oxide minerals. Some common methods which have been used for the flotation of zinc oxide minerals include sulfidization-flotation, activation, and direct flotation with anionic and cationic collectors. The traditional flotation techniques have low efficiency and difficulty in separation and recovery of the zinc minerals from gangue minerals, for example, smithsonite (ZnCO3) from other carbonate gangue minerals and hemimorphite (Zn4Si2O7 (OH)2·H2O) from silicate gangue minerals. In this study potassium lauryl phosphate was evaluated as a collector for the flotation of nonsulfide zinc minerals. Results from contact angle and microflotation experiments at pH 6–9 show that hemimorphite (Zn4Si2O7 (OH)2·H2O) can be floated from quartz and that smithsonite (ZnCO3) can be floated from calcite. However, when dodecylamine, which is a common collector reported in literature for the flotation of nonsulfide zinc minerals, was used as collector, no significant difference between nonsulfide zinc minerals and gangue minerals was observed at any pH value. Initial evaluation suggests that potassium lauryl phosphate is effective at low concentration and may be a promising collector for zinc oxide mineral flotation.INTRODUCTIONBefore the twentieth century, zinc was mainly produced from nonsulfide ores (Large, 2001; Gilg, Boni, & Cook, 2008). With the development of differential flotation processes in the late 19th century major production switched from nonsulfide zinc sources to sulfide zinc ores (Hitzman, Reynolds, Sangster, Allen, & Carman, 2003; Gilg et al., 2008). However, as it is becoming more difficult to find new sulfide ores, recovery from nonsulfide deposits is being considered. Nonsulfide flotation for zinc recovery is much more difficult than the flotation recovery of sphalerite from sulfide deposits and may become an option for zinc production if a suitable technology is developed. Zinc and lead oxide ores are difficult to beneficiate ores due to their similar floatability with gangue, high solubility in water, and the influence of slimes (Fa, Miller, Tao, & Li, 2005). In order to improve the performance of oxidized minerals, lots of effort is being devoted to this field of study (Ejtemaei & Mahdi, 2014)."

Jan 1, 2016

By Hong Zhong, Shuai Wang, Fangxu Li, Guangyi Liu

"The flotation performances and adsorption mechanisms of a-hydroxyoctyl phosphinic acid (HPA) to malachite, cassiterite and wolframite were investigated by micro-flotation tests and X-ray photoelectron spectroscopy (XPS) analyses. The micro-flotation results indicated that compared with styrene phosphonic acid (SPA), diphosphonic acid (DPA), benzohydroxamic acid (BHA) and salicylhydroxamic acid (SHA), HPA exhibited excellent collecting power to the three oxide ores. In addition, HPA showed superior selectivity against hematite, tourmaline, feldspar and quartz. The results of XPS analysis demonstrated that HPA reacts with active species (M) on metal oxide by formation of P-O-M or P-M bonds.INTRODUCTIONIn mineral processing, flotation has been the main process for separation and recovery of valuable minerals from complex ores (Mei, 2013; Zhou, 2014). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by surfactant (known as collector in flotation) adsorption so that these mineral particles can preferably attach air bubbles in a slurry or pulp (Bai, 2004; Hankins, 2004). To anchor a solid surface selectively, special functional group are designed to adjust the interaction between the surfactant and the active sites of solid surfaces (Wu, 2006; Huang, 2014).Organic phosphorous compounds have strong affinity toward metals or metal oxides because they form more stable metal complexes than metal carboxylates (Pazik, 2001; Zheng, 1998). In mineral engineering, phosphorous compounds have been exploited as metal extractants and flotation collectors (Alguacil, 2002; Sun, 2008). Ni (2012) and Zhang (1998) introduced diphosphonic acid (DPA) as an effective collector for flotation of fersmite and niobite. Liu (1999) found styryl phosphonic acid (SPA) was a superior collector for flotation recovery of finely disseminated rutile ores. Gruner and Bilsing (1992) thought SPA was one of the best collectors for flotation recovery of cassiterite which could obtain a high-grade concentrates of more than 40% with high recovery values. Bulatovic (1999) investigated the flotation performances of phosphoric acid ester (PAE) to perovskite, ilmenite and rutile and found that PAE was an impactful collector for selective flotation of titanium minerals from complex ores in the presence of petroleum sulfate. However, a-hydroxyoctyl phosphinic acid (HPA) as a flotation collector for recovery of titanium ores were hardly reported in the previous literatures."

Jan 1, 2016

By T. Prietl

Metallurgical vessel linings are multilayered, consisting of refractory bodies, insulation materials, joints, and additional space to control for thermal expansion. A unique biaxial hot testing press (BHTP) was installed at the RHI Refractories Technology Center Leoben, Austria to enable the three-dimensional behaviour of complex vessel lining segments to be investigated under simulated service conditions. Using the BHTP, the heat up and thermo-mechanical behaviour of magnesia chromite brick lining segments with and without mortar filled joints were examined. The results obtained during the initial heat up provided validation of CFD modelling of the lining system. In addition, after the heat up and under steady state conditions, the lining behaviour during deformation-controlled compression and relaxation was examined. These analyses generated important data regarding the stiffness, joint compressibility, and brick damage of the lining segments after cyclic loading and unloading as well as the benefits of using mortar joints in the lining. These investigations were performed in collaboration with the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals, University of Leoben, Austria. The BHTP has been operational since November 2004 and is providing information regarding the thermo-mechanical behaviour of different lining segments.

Jan 1, 2007

By André Gobell

"La distribution des éléments majeurs dans une séquence de roches volcaniques felsiques, la formation de Waconichi, au sud de Chibougamau, indique que les roches pyroclastiques du secteur ouest de ce segment sont chimiquement anormales si on les compare à la composition moyenne des roches volcaniques de Chibougamau: elles sont caractérisées par une teneur anormalement élevée en f er, en magnésium et en potassium et une teneur anormalement basse en sodium et en calcium; ce chimisme caractérise les encaissants des dépôts de sulfures massifs d &apos;origine volcanique.Les coulées rhyolitiques massives sous-jacentes au gite de cuivre-zinc avec or et argent de Lemoine ne montrent pas ou très peu d’altération de ce genre. Le schéma de mise en place des dépôts de sulfures massifs d&apos;origine volcanique et la nature des roches en présence permettent de croire que la zone d&apos;altération mise en évidence à l&apos;ouest de la mine Lemoine puisse être reliée à la mise en place de ce gisement d&apos;ou l&apos;im portance de tenir compte des caractères texturaux des roches lors de l&apos;interprétation de données litho géochimiques."

Jan 1, 1980