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By H. E. Pawson

Giant Yellowknife is located 600 air miles north of Edmonton on the north shore of Great Slave Lake in the Northwest Territories. In its 24 years of operation some 7,730,000 tons of ore have been treated to yield $175,000,000 worth of gold.The gold ore occurs at irregular intervals throughout a fold-like sericite schist zone cutting Precambrian rocks. The ore is characterized by 40 to 80% quartz - carbonate and about 10% pyrite and arsenopyrite. Considerable amounts of stibnite and antimony sulpho-salts are also present. Gold is finely divided in the native state existing in complex association with the sulphides. In most instances stibnite is barren but minor values are evident on occasion. Visible native Fold, quite prevalent in the early operating years, is, practically non-existent today. It was readily apparent from mineral dressing investigations conducted in .1944 that Giant ore would be difficult to treat. By 1948 a flow sheet had been established and operations began. In the ensuing years, changing ore characteristics necessitated modifications to some process steps and complete abandonment of others. By 1962 the major metallurgical problems were solved and all that remained was the refining of operating performance to its highest level.With one or two exceptions today's operation follows the practice established by 1962 (Fig. 1 - Flowsheet).

Jan 1, 1973

By Yuki Tsunazawa, Shuji Owada, Sho Fukui, Chiharu Tokoro

"Since the amount of e-waste has been rapidly increasing all over the world, there is a desire to develop the effective recycling process. E-waste has various kinds of electronic components with valuable and/or hazardous materials. Recycling of them is an important subject from the viewpoint of both the recovery of valuable materials and waste treatment. In common with all mineral processing, the comminution of e-waste is a key process because the liberation states after comminution determine the overall efficiency of metal recovery. Since some of useful critical metals are concentrated in a specific component, a special and selective grinding is expected to be effective. However, the knowledge about the mechanism and the effectiveness of the selective grinding is still limited and unclear.To better comprehend the mechanism, in this study, the investigation of comminution process using the particle-based simulation was conducted. Especially, this study focused on the comminution performance of printed circuit boards (PCBs), which are major components of e-waste. The behavior of PCBs and airflow in a drum typed agitation mill having flexible chains was simulated by the discrete element method (DEM) coupled with computational fluid dynamics (CFD). To model the shape of PCBs, the particle based rigid body model was introduced into the DEM. Since this model could not directly simulate the breakage phenomena, collision energy was calculated to qualitatively evaluate the comminution performance. In addition, the simulation results were compared with the experimental comminution tests using simulant PCBs where some capacitors were solder-mounted. These results indicated that comminution performance was affected by the rotation speed of the agitator. It was also demonstrated that the comminution performance was qualitatively evaluated using the particle-based simulation and this particle-based simulation made it possible to investigate the mechanism of e-waste comminution."

Jan 1, 2016

By C. Cutts, K. Wheatley

The Dragon Lake Zone (uranium prospect) comprises a N160º trending vein that is approximately 110 m long, up to 5 m wide and from 1 to 40 m high. The zone is mostly within altered sandstone of the Fair Point Formation, the basal unit of the Paleoproterozoic Athabasca Group, but it also extends downward (up to 3.5 m) into basement rocks that occupy the northerly trending Maybelle River Shear Zone (MRSZ). This subvertical shear zone separates graphitic paragneiss and weakly deformed granitoid rocks to the east from non-graphitic paragneiss and foliated granitoid rocks to the west. The Dragon Lake Zone cuts across both the MRSZ and N060º-N070º-trending cross-faults that offset the shear zone but not the mineralized vein, which contains values up to 54.5% U over 50 cm core length. Strong chloritization occurs in graphitic paragneiss and sandstone adjacent to mineralization. Silica was depleted from the basement rocks and redeposited at the borders of the 5-15-m-wide alteration zone, as well as within overlying sandstone of the Manitou Falls Formation. There are minimal alteration effects in the overlying Lazenby Lake Formation. Geochemistry shows that the alteration zone in the Fair Point Formation is highly anomalous in metals, most notably in Ni, As, U, Pb, Co, and B. Clay within this zone is illitic and Fe-rich chlorite is also present. Brittle deformation is not as widespread or as well developed in the Fair Point Formation as it is in the overlying Manitou Falls Formation, which is extensively brecciated and contains some anomalous metal values.

Jan 1, 2013

By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By V. I. Lakshmanan

Recycling helps to save energy and is good for the environment. It is also important for preserving the limited natural resources. In addition, recycling creates economic benefits and frees up space at the landfill sites. Process Research Ortech Inc. (PRO) has conducted extensive testwork in the area of waste processing and recycling. A process was developed for the recovery of Zinc from galvanized steel by alkaline leaching followed by solvent extraction and electrowinning. Extensive testwork has been conducted at PRO to obtain a useful by-product from rice husk. Rice husk was combusted in a gas/solid reactor to obtain an environmentally acceptable amorphous silica ash suitable for use in high strength concrete. In another development, vanadium was recovered from fly ash by separating carbon first, followed by alkaline pressure leaching, solvent extraction and precipitation. PRO has also developed an environment friendly process for treatment of industrial wastewater for its reuse to obtain zero or minimal effluent discharge. In this paper, four case studies related to recycling of zinc scrap, controlled combustion of rice husk, processing of fly ash, and reuse of waste water will be discussed.

Jan 1, 2011

By Raja V. Ramani, Sukumar Bandopadhyay

"The dispersion of diesel contaminants into the mine atmosphere is a variant of general class of diffusion-dilution problems relevant to underground mining practice. The equipment operations in underground mining are characterized by different activities with different time duration s, i.e. varying duty cycles. Therefore the volume and quality of diesel emissions and consequently, instantaneous concentrations are quite variable. Design of mine ventilation systems under these conditions becomes complex. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport in the design of ventilation system are discussed.IntroductionThe turbulent diffusion of suspended matter in an atmosphere is not only a topic of considerable intrinsic interest to the mathematical physicist and meteorologist, but also a problem of great practical interest. Release of particulate matter into the atmosphere at large has created o ne of the acute problems of the present day. Pollution of environment by industrial and domestic smoke, fumes and grit is widespread and has necessitated extensive studies in order to determine the concentration and distribution of pollutants in various areas. Pollutants discharge from stacks, whether chemical or radioactive, give rise to similar, but more localized, problems. The laws which govern turbulent diffusion in the atmosphere are also applicable to the study of the diffusion of toxic gases and the deposition of radioactive dust from nuclear explosion.The dispersion of diesel contaminants into the mine atmosphere is but a variant of a general class of diffusion-dilution problems relevant to underground mining practice. Most of the mine air pollutants, such as respirable dust, methane, diesel exhaust, and blasting fumes are produced in the face areas and haulage ways. Understanding of their dispersion in the mine airways is important to calculate their concentrations. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport are discussed. The over-all objective of this research effort is to evaluate the impacts of dieselization on production and ventilation systems and to aid in mine planning and design, as shown in the flow model in Figure I."

Jan 1, 1983

By R. W. Boyle

"PREFACEThis paper comprises two parts. The first part discusses lithochemical surveys based on major, minor and trace elements in whole-rock samples from primary enveloping halos. The second part continues with discussions of surveys based on leakage halos, zonation of elements, stable and radioactive isotopic distributions, geothermometric, geobarometric, thermolumin escent, pedochemical, hydrochemical, atmochemical and biogeochemical methods. A selected bibliography follows the second part of the paper.ABSTRACTAreal (two-dimensional) geochemical surveys, based mainly on secondary dispersion halos and trains in media such as surface waters, soils and drainage sediments, have proven particularly successful in recent years and have greatly assisted in the discovery of a large number of varied mineral deposits. Three-dimensional surveys based on primary halos and leakage halos have received relatively little attention by research organizations and the mineral industry. Such surveys offer many novel approaches for discovering blind mineral deposits deeply buried below overburden or within their host bedrocks. This paper reviews detailed methods for the discovery of blind mineral deposits based on sampling rocks (lithochemical methods), soils and other types of overburden (pedochemical methods), waters (hydrochemical methods), gases (atmochemical methods) and biological materials (biogeochemical methods) . All are applicable to the discovery of blind deposits; the efficacy of each or in combination depends essentially on the type of mineralization, the extent of the development of the primary and secondary dispersion halos, and the finances available for sampling techniques employing overburden drilling, bedrock drilling, and sophisticated water, gas and vegetation collection."

Jan 1, 1982

By Y. Tang

"Rare earth elements (REEs) have many key applications in traditional and advanced technologies. A shortage of several critical REEs is expected due to the discrepancy between the availability of REEs from REE deposits and the REE demand from the market. REE recovery and separation from secondary resources such as uranium wastes and recycled materials might help balance the shortfall in a cost-effective way. This paper presents data concerning the recovery of heavy REEs (HREEs) from uranium raffinate. It also discusses the design, commissioning, and operation of a solvent extraction pilot plant for the separation of REEs.RÉSUMÉ Les éléments des terres rares (ÉTR) trouvent de nombreuses applications importantes dans les technologies classiques et de pointe. On prévoit une pénurie de plusieurs ÉTR critiques en raison des divergences constatées entre la disponibilité des ÉTR provenant de gisement d’éléments des terres rares, et la demande d’ÉTR sur le marché. La récupération et la séparation des ÉTR à partir de ressources secondaires telles que les déchets générés par le traitement du minerai d’uranium et les matériaux recyclés pourraient contribuer à équilibrer cette pénurie de manière rentable. Cet article présente des données relatives à la récupération des ÉTR lourds (HREE, de l’anglais heavy REEs) à partir de raffinat d’uranium. Il aborde également la question de la conception, de la mise en service et de l’exploitation d’une usine pilote d’extraction par solvants pour la séparation des ÉTR INTRODUCTIONSignificant amounts of strategic specialty heavy rare earth elements (HREEs) are present in waste streams in Saskatchewan uranium operations. Selective precipitation including neutralization, oxalate, and double-salt precipitation, as well as sulfide precipitation, ion exchange (IX), and solvent extraction (SX) are commonly used technologies for the recovery and purification of rare earth element (REE) solutions. REE oxalate precipitation can effectively remove Fe, Al, Ca, Si, and other impurities by taking advantage of the solubility difference between REE oxalates and impurities in the acidic solution (Xu, 2005)."

Jan 1, 2018

By N. Aslin, R. Clark, G. Heferen

The methods of harvesting copper from stainless steel mother plates has been investigated from fundamental and operational experience perspectives. At least five different harvesting techniques have been identified that have different effects on product quality, current efficiency, current distribution, growth morphology and ease of stripping. Each method is examined from fundamental principles to understand what occurs during the harvesting process and why the particular effects are manifested. Experience from plants operating the harvesting method is provided to show that the fundamental understanding is relevant. Best practice harvesting method and harvesting management are described.

Jan 1, 2014

By S. Banisi, J. Marois, A. R. Laplante

"This paper compares the behaviour of gold and ore in the grinding circuit of Hemlo Mines Ltd. Particular attention is given to grinding kinetics, classification behaviour, and liberation. For grinding kinetics, laboratory grinding of gold flakes and silica, 840 µm to 1200 µm in size (14/20 mesh), was also performed to provide a standard for comparison and to study in a controlled environment the mechanisms of breakage, folding , smearing and impacting.Grinding kinetics were characterized at laboratory scale with breakage and selection functions. The breakage function showed that 75% of gold disappearing from the 840 µm to 1200 µm class reported to the 600 µm to 840 µm; this figure is much higher than for silica (46%) or most other minerals, and implies that comparatively fewer fine fragments are produced from the breakage of gold flakes, on account of gold's malleability. The selection function of silica was four times that of gold. At plant scale, the ratio of the selection function of ore and gold increased from 6 for at 50 urn to JOO pm to 20 at 500 um to 1000µm.Observation of original flakes and their fragments with the scanning electron microscope showed that the main mechanism of ""grinding"" from the 840 µm to 1200 µm to the 600 µm to 840 µm class was folding rather than actual breakage. This was confirmed by a measure of individual flake weight. The postulated breakage cycle is that relatively globular flakes become increasingly serrated through grinding; they can then regain their original shape through folding and reflattening into cylindrical and spherical shapes, as the majority does; however, some fragments will at this point undergo actual breakage. Photograhic evidence is presented to support the proposed mechanisms.Smearing of gold unto silica was observed when silica was ground after a gold, and embedding of silica into gold flakes when gold was ground after a silica. Both mechanisms occur whenever gold and harder minerals are jointly ground, and result in ""unliberation"" of gold. It is postulated that smearing of gold onto other minerals plays an important role in explaining how gravity recovery can increase over-all gold metallurgy, especially when used ahead of flotation.Classification of gold in the primary hydro cyclones takes place at a much finer cut-size than ore, 20 µm vs 57 µm. This and the slower grinding kinetics result in high gold circulating loads in the primary loop, 6700%, and a gold content in the primary cyclone underflow (PCUF) is twenty-four times that of the ore. The gold size distribution for primary cyclone overflow is much finer than that of the ore, although they are essentially similar in the PCUF.Liberation, or more accurately ""gravity recoverability"", was assessed with a 7.5 cm (3 in.) Knelson concentrator. It varied between the thirties for the primary mill discharge and two cyclone overflows, to highs of 89% and 92% for the PCUF and secondary mill discharge."

Jan 1, 1991

By M. C. Ethier, A. L. Laramie

"The Granisle and Bell Copper mines were officially put into production in 1966 and 1972, respectively. The Granisle Mine was purchased in late 1979by Noranda and the two operations were amalgamated as one division. Both mines were closed in 1982after sustaining heavy financial losses during a period of low copper prices beginning in 1981.This paper describes the resumption of operations at the Bell Mine in 1985 after its shutdown period of three years and the dramatic and sustained improvements in productivity and efficiency realized as a result of a commitment by employees and management to the application of Participative Management and Employee Involvement principles. After a general description of the effects of such a philosophy on the operation as a whole, and a comparison to the operation's last full year as a producer, it deals with the practice of this philosophy in the maintenance department at the Bell Mine and the superb results realized.IntroductionThe Bell Copper deposit was discovered in 1963 and came onstream as a 10000 ton s per day open pit mine in the fall of 1972. Identified reserves at that time were 46 million tons of ore containing 0.50% copper. The mine shared facilities of the townsite of Granisle with the nearby Zapata-Granby mine which had established the community six years earlier.Because of easy grinding ore and improvements to milling circuits, Bell's throughput rate was increased to 17 000 tons per day by the late 1970s. In the open pit, improvements resulted in mining of additional reserves with higher stripping ratios. At startup, a half ton o f waste was mined for every ton of ore processed.By the end of 1982, with 48.2 million tons already mined, the Bell Mine had identified additional mineable reserves of 39.4 million tons containing 0.52% Cu.In November 1979 the Granisle Mine was purchased from Zapata-Granby. The two mines, with a total of 700 employees, were operated under common management as the Babine Division until 1982 when low copper price s forced the closure of both for an indefinite period.The outlook for copper prices remained bleak and only 50 people were retained on the payroll to maintain the two plants, most of them working on a part-time schedule.The population of the Village of Granisle dwindled from over 1500 inhabitants to under 500, as people moved away to seek other employment.Prior to the shutdown, the Bell Mine employed 370 people and pit extraction averaged nearly 50000 tons per day of which 16000 tons was mill feed, and the remainder waste. Total cost to produce a pound of copper was C$1.36 in 1982."

Jan 1, 1990

By Nick Vayenas, Ming Cai, Hongbin Zhang Lorrie Fava, Enrique Acuña

"A hybrid methodology is proposed to improve the accuracy of Diesel Particulate Matter (DPM) concentrations simulated in a ventilation network model by using Computational Fluid Dynamics (CFD). DPM, as a primary concern for underground hard-rock mines, has been studied in two dominant numerical models, ventilation network solvers and computational fluid dynamics. Ventilation network solvers are efficient, but they are not able to provide three-dimensional DPM concentration contours and only accept area-average DPM data as input. CFD simulations are time-consuming, but generating DPM concentration results with high accuracy. Besides, both monitoring points and planes can be created in a CFD model, which can take both point data and area-average DPM data as input. The hybrid methodology is intended to combine the advantages of the two by using the CFD results to update the network model results at key locations. A field study was conducted in a dead-end heading in an underground gold mine in the United States. Real-time DPM monitors were used to collect data. A CFD model and a network model were built for the experiment area. The CFD model was calibrated to the experimental data. In the study presented here, results from a calibrated CFD model are converted to equivalent diesel emission rates in the ventilation network model at a shared outlet. The hybrid methodology is used to provide better input for the network model. INTRODUCTION Mine ventilation system is one of the most important parts for an underground mine. It not only provides fresh air to the personnel but also helps clear the contaminants generated from the diesel-powered equipment. For most underground metal and non-metal mines, diesel particulate matter is the main contaminant. It is also the focus of this paper."

Jan 1, 2019

By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019

By H. F. Naldrett

"AbstractAt the end of May, 1950, Imperial Oil, Limited, had completed a total of 192 D-3 wells in the Leduc-Woodbend field, 62 of which lost circulation in the D-3 zone for periods ranging from two hours to fifty days. The majority of the remaining wells •lost some mud without actual loss of returns. In addition, independent operators completed 69 D-3 wells, of which 9 lost circulation. Included among the latter is the now well known Atlantic No. 3 well, which blew wild out of control for seven months. The well was finally brought under control through two directionally drilled wells, but not before the derrick fell and the well caught fire. Practically all known filler materials have been used in attempt3 to prevent or regain loss of circulation, but none has been successful, except in minor cases. Ordinary sawdust has come to be the most commonly used filler material and is added to the mud before the D-3 zone is contacted. In cases of serious loss of circulation, the on1y successful method of getting returns has been the use of a series of small cement plugs.IntroductionThe Leduc field is twenty miles southwest of Edmonton, Alberta. Geologically, it is on the east limb of the Alberta syncline, in the homoclinal belt. The main productive zones are in the Upper Devonian formation and are known locally as the D-2 zone and D-3 zone, respectively (see Figure 1).The D-3 zone is a dolomitized reef with fair average porosity and permeability, and shows considerable evidence of vertical fracturing. Porosity is mainly due to moderately uniform development of vugs which are interconnected by small crevices. However, the formation is known to be, locally, extremely vuggy and in places cavernous. These latter conditions create very serious drilling problems due to the hazard of loss of circulation, particularly in the gas cap, which has a maximum thickness of 200 feet. The D-3 zone is contacted at an average depth of 5,300 feet."

Jan 1, 1950

By G. W. Poling

Sedimentation behaviour of siliceous mill tailings derived from a magnetite-chalcopyrite ore in fresh water, fresh water - sea water mixtures and full-salinity sea waters are compared. Results of batch settling tests are presented in the form of settling curves and solids flux curves. The addition of a few per cent of sea water markedly enhanced the zone sedimentation rate due to particle agglomeration caused by a reduction in zeta potential of the suspended solids. The presence of a small amount of residual, previously magnetized magnetite in the tailings also enhanced agglomeration and sedimentation. The significance of these results to submarine disposal of mill tailings is discussed.

Jan 1, 1973

By Z. I. Zaki

Synthesis of TiC /A1203 Composite from TiO2, Al and graphite using combustion technique has been investigated at different initial temperatures; room, 400 and 600 °C. The effect of initial temperature on the composition of the product, wave velocity and combustion temperature of the reaction was studied. The measured combustion temperature and wave velocity were increased with increasing the initial temperature of the combustion reaction. The maximum wave velocity obtained was 5.9mms-1 when conducting the combustion reaction at initial temperature of 600 °C. Oxidation resistance of the obtained composite was also studied at the temperature range 300-800 °C. No oxidation is detected before 400 °C while it takes place effectively at 700 °C forming different titanium oxides. Wave velocity measurements method was used to calculate the activation energy of the reaction between the starting materials. It was found to be 316.34 kJ mol 1 at the temperature range that was studied.

Jan 1, 2007

By B. M. Currell, M. J. Neate, P. W. Bowden

Historically the hydrogen fluoride laden fume emitted from the electrolytic cells in the aluminium reduction process is further treated in pulse jet dust collectors. These dust collectors act as dry scrubbers performing two duties: adsorbing the gaseous fluoride emitted from the cells onto alumina dust; and collecting the alumina dust minimising particulate and fluoride emissions to the environment.Patented StarBag (TM) technology has been used in aluminium smelters in Australia as a means of increasing the dust collection and fluoride scrubbing capacity of existing collectors. This technology provides an alternative to major capital equipment upgrade where increased capacity is required, and potentially lowers the production cost per tonne of aluminium where capacity limitations are being realised and production expansion is required. This paper presents the findings of on-site pilot scale, and full production scale comparative tests, highlighting the operational and variable differences observed utilising the Star-Bag(TM) technology at Boyne Smelters Ltd in Australia. The results illustrate how this technology can be utilised to increase the hydrogen fluoride scrubbing efficiency and dust collection capacity of existing capital equipment.

Jan 1, 2006

By J. N. Hilton, D. Moffett, E. Barnes

"A recent pilot-plant program carried out at Rio Algom's Quirke uranium mine at Elliot Lake, Ontario is described. The goal of the research was the production of tailings basin effluents which were low in total radium-226. The process tested involved precipitation of radium with barium chloride and sedimentation in plastic-lined settling ponds. Adjustment of the tailings basin overflow from its normal value of pH 9.5 by addition of sulphuric acid to about pH 7.5 was found to give approximately a five-fold improvement in total radium-226 removal. A five-month demonstration test resulted in an effluent with a mean total radium-226 activity of44 pCi/L after 2.5 days settling time and 29 pCi/L after 5 days. The results from the demonstration program are used to propose a schedule of achievable total radium-226 activities where precipitation and sedimentation are employed. The maximum suggested values for 5 days nominal settling time are: 30 pCi/L in an annual mean, 45 pCi/L in a monthly mean. 60pCiIL in a weekly mean and 80 pCi/L in any single grab sample.IntroductionRadium-226 has been removed from effluents at the Elliot Lake uranium mines since the introduction of the first barium chloride treatment system in 1965. Current practice, which has changed little over the years, consists of radium-barium sulphate precipitation by the addition of a low do se of barium chloride to the clear overflow from the tailings basin(l·2l. Provision is made for the precipitate to settle in large natural or constructed ponds and lagoons. The residence time in these ponds, which depends on the site, ranges from 3 to 35 days, with varying degrees of efficiency being achieved."

Jan 1, 1981

By R. U. Seneviratne, B. K. Ahlgren

In this paper we follow various technological discoveries and developments in the purification of minerals and metals in the mining industry by ion exchange. For approximately 100 years, ion exchange has been a known and variously applied purification and separation technology used by scientists and producers. It would seem obvious that the producer’s objectives have always been to achieve the highest quality products and the lowest operation costs, but also with the least amount of technological complexity. As a strategy to reach these goals, much effort has been expended in the quest to improve continuous ion exchange (CIX) systems by reducing utility needs and resin degradation or loss while at the same time improving productivity and reliability. Recent developments from a number of companies have pushed equipment boundaries, resulting in a variety of unique commercial equipment designs each with a varying degree of success. The challenge set forth for all new designs has been a truly continuous process with no sacrifice in the afore mentioned benefits. One very recent equipment design based on system symmetry appears to meet many of these objectives with greater flexibility and less complexity resulting in better economics for the producer.

Jan 1, 2014

The cost benefits of controlling dilution of extracted ore have been very well understood by miners and mining professionals for many years. However, as we strive towards more mechanization, the dilution factor has been compromised in order to fit ?equipment? that is better suited to provide improved safety and productivity. Alternately, the drilling and ground support is accomplished by handheld drilling. In 2007, a short study, commissioned by CAMIRO (Canadian Mining Industry Research Organization) on the safety of hand held drilling vs. mechanized drilling, concluded that the risk of injury with handheld drills was seven times greater than with mechanized drills. Armed with this data, MEDATech Engineering proposed to the CAMIRO group to fund development of a ?MICRO Bolter?.

May 1, 2009