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By J. F. Haseman, J. E. Davenport

IN the brown rock phosphate fields of Tennessee there are large deposits of phosphate matrix in which quartz is a major constituent of the gangue, and which cannot be beneficiated by the conventional washing process to yield a concentrate of suitable grade for use in the electric furnace. A huge tonnage of high-grade phosphate concentrate is produced in the Florida pebble district from low-grade siliceous feed. However, the characteristics of the low-grade siliceous Tennessee ore are such that flotation under the conditions employed in treating the Florida ore1-2 results in inadequate beneficiation. INVESTIGATION OF FLOTATION METHODS Flotation has been used in Tennessee primarily to produce a concentrate of premium grade by moderate enrichment of a marketable grade of phosphate.3,4 A secondary use was to increase the recovery of phosphate from the fines (down to approximately 200 mesh) from medium-grade ores with a concomitant moderate increase in over-all grade.3,5 It was considered desirable to investigate methods of improving the grade of washed products from low-grade siliceous Tennessee ore when these products were substantially below the requirements for use in the electric furnace. The present paper describes the results of a laboratory-scale study of factors that affect the beneficiation of such siliceous phosphate ore by flotation. The primary objective of the investigation was to ascertain the conditions under which the ore could be made to yield a concentrate suitable for reduction in the electric furnace. It was assumed that a phosphate concentrate for electrothermal reduction should contain at least 26 pct P205 and should have a weight ratio of silica to lime of not more than 0.80. Since a concentrate of moderate grade can be used in the electric furnace, and since, as Grissom4 has shown in detail, the ore will not bear the cost of expensive treatment, the study of collectors was limited to the relatively inexpensive fatty acids. A secondary objective was to determine whether a portion of the phosphate could be recovered in a grade suitable for treatment with phosphoric acid to produce 45 pct superphosphate. The ore consisted of variably cemented sand interlayered with clay. The sand layers were composed of grains of quartz, phosphate, and clay embedded in a matrix of clay and phosphate. Some clay was finely disseminated in the phosphate grains. Little massive high-grade phosphate was present. The material used in the flotation tests was a washed sand that had been separated from the ore in a bowl classifier at the TVA phosphate-washing plant. The percentage composition of the sand was as follows: P205, 20; Si02, 40; CaO, 29; Fe203, 2; A1203, 3; F, 2.3. The particle-

Jan 1, 1947

By S. G. Ozkan

Boron minerals of economic importance are primarily colemanite, tincal, and ulexite. Turkey and the United States are the leading producers of boron minerals and compounds. Other production includes datolite in Russia and synthetic colemanite in Chile. This paper will discuss various types of chemical and physical treatments of boron ores to produce the marketable minerals and compounds that are consumed in commercial products.

Jan 1, 1995

By D. E. Stone

Solid and liquid impurities must be removed almost completely from synthesis gas for the production of synthetic liquid fuels because of their effect on the synthesis catalyst and turbocompressors. The maximum permissible concentration of dust has been set at 0.05 grain per 100 cubic feet.5/ This is one part per million by weight, or about the same concentration as in average city air. The cost of synthesis gas is estimated to constitute 60 to 70 percent of the total cost of the synthetic liquid fuel. For this reason this station is developing processes using coal instead of the more valuable coke as raw material, which promises reduction in cost of the synthesis gas. This, however, increases the difficulty of attaining the above dust value. As failure of the dust-removing equipment to produce high-purity gas may ruin valuable equipment within a few minutes, it is imperative that a reliable and continuous method be obtained for determining such extremely low concentrations .of dust in the purified gas. A suitable device must also instantly sound an alarm and, if necessary, automatically actuate the proper valves to prevent damage. The Ess Instrument Co. designed and built an instrument which they believed might fulfill these specifications. It' continually compared, by means of photoelectric cells, the intensity of a light beam passing through the gas and a similar beam passing through clean air. For maximum sensitivity, the photocells were connected back to back, i.e., anode to cathode and cathode to anode. The difference in voltage produced by the two cells was amplified and operated an indicator.

Jan 1, 1951

By N. R. Andrade-Gonzalez

In this paper, the effect of magnesium and strontium additions on the heat treatment behaviour of cast A319,2 alloy was investigated, Permanent mold samples were heat treated at 495 °C for 4 and 24 h, then quenched in hot water and aged at 180 °C and 220 °C for different temperatures, It is found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu alloys, mainly when Mg and Mg-Sr are added, The results of electron probe microanalysis (EPMA) observations reveal that the age-hardening behaviour is related to the precipitation sequence of alloys, For the Al-Si-Cu alloy, the first aging peak is the result of the high-density GP zones, while the subsequent peaks arise from metastable phases, Obvious intervals during the transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks, It is seen that addition of Mg (-0,40 wt %) leads to the precipitation of coarse Al5Mg8SioCu2 particles. When modifying the high Mg alloys, Cu-intermetallics segregate in areas away from the growing Al-Si eutectic regions, Modification with strontium retards the precipitation of the silicon out of the matrix.

Jan 1, 2005

By Volkan Arslan

This study aimed to remove the contaminants in quartz sand by using an eco-friendly method and to obtain high-purity quartz. For this purpose, ultrasound-assisted acid leaching was applied. Equal amounts of a mixture of diluted hydrochloric and oxalic acids were used as the solvent. Response surface methodology (RSM) was used for optimizing, modeling, and predicting the experimental parameters. The correlation coefficient ( R2) of the proposed quadratic model for the relationship between iron removal yield and test parameters was calculated as 0.9731 and it was determined that the predicted and actual values were compatible. Finally, optimization experiments were made and optimum experiment conditions were revised and determined as 83.38 °C of leaching temperature, 196.35 min of leaching time, 2.86 M of acid concentration, and 202.24 W of ultrasound power. Under the optimum conditions determined after optimization, the highest yield of iron removal was determined as 95.08%. Under the optimal parameters, the SiO2 content of the concentrates increased from 97.841 to 99.907% and the Fe2O3 content reduced from 0.225 to 0.011%.

Jul 12, 2021

By M. I. Kalashnikova, Y. M. Shneerson, E. E. Zhmarin, Y. V. Degtiarev, E. M. Vigdorchik

Separation of a magnetic fraction from nickel concentrate following matte flotation, and its treatment in a separate circuit enable reduces precious metals losses. The magnetic fraction is treated in two stages of oxidative leaching: atmospheric and pressure leaching. A study of the atmospheric stage, using mathematical modelling, is described in this paper. The mathematical model and experimental data were used to carry out industrial process calculations. The model enabled extrapolation of the results of batch laboratory test to industrial-scale continuous processing and the selection of optimal process conditions and large-scale equipment. In December 2004, commercial oxidative leaching tests were performed on the magnetic fraction at the Severonickel Plant (Monchegorsk, Russia). A comparative analysis of the mathematical modelling results and the actual process parameters is presented.

Jan 1, 2005

By D T. Ribeiro, J F. C L Costa, J C. Koppe

Drilling and sampling are responsible for most of the costs during mineral exploration, especially in multi-elements and polymetallic deposits, such as iron, manganese and bauxite deposits. On these deposits, often it is necessary to estimate multiple attributes at several granulometric fractions, ie distinct particle sizes. This paper investigates the effect of sampling at a close spacing grid only the head grades for the multiple chemical species in iron ore deposits. The remaining required data at the various grain sizes are sampled at a sparse grid. The derived geological model is checked for precision and accuracy comparing the output obtained against a model obtained using a complete isotopic data set including head grades and chemical analysis at each granulometric fraction analysed at all sampled positions. Among the several tested alternatives, the best procedure for dealing with the posed problem involved utilising the correlation coefficients between the grades at distinct fractions to obtain an isotopic database prior to interpolation. Cokriging was the method used, based on the intrinsic coregionalisation model. Estimates were obtained with the quality needed for the proposal of the study. Results showed that at least 50 per cent of the blocks were estimated with errors less than ten per cent relative to the grades obtained at the reference model, using only 15 per cent of the granulochemical data employed to obtain the reference model. The methodology also preserved the correlations between the attributes in their several granulometric fractions on the estimated model.

Sep 26, 2011

By G. Prabhulingaiah, D. M. R. Sekhar

"A phosphate deposit of estimated 6 billion tons of P2O5 is located 180 to 300 meters below the sea level, 185 kilometers north of port Luderitz, Namibia. The ore bed is 6 kilometers wide and 220 kilometers long. The ore deposit analyzing 16% P2O5 is loose sediment of 1.5 meters thick without over burden. Sizing of the ore to - 1.4 mm + 0.150 mm improves the grade to 23.54% P2O5 with a P2O5 recovery at 83.75% containing phosphate pellets and flakes of sea shells. Clay, bacterial debris as organic matter, flakes of broken sea shells and fine phosphate containing particles report to - 0.150 mm fraction and + 1.4 mm fraction contains sea shells and few phosphate containing pellets. The mineralogical composition of phosphate containing pellets is estimated (Droste, T.C., 2004) 80% frankolite, 6% pyrite, 4% illite, 3% quartz, 3% amorphous SiO2, 1% carbonates, 1% organic carbon and = 1% ilmenite, magnetite, zircon etc. The phosphate content in the pellets is around 27.7% P2O5. Trials to separate by gravity or flotation processes were not successful. Leaching of carbonates (sea shell flakes) under mild acidic condition (= 2% acetic acid or HCl solutions) or calcinations followed by leaching however yielded residues (concentrates) of grades 27.85 - 32.74% P2O5 at P2O5 recoveries ranging from 78.45 - 96.8% P2O5."

Jan 1, 2014

By F. E. Millett

The following notes deal chiefly with changes from steam to electric drives, or, in the case of the Bellevue pumps, from air to electric. Where electric power can be purchased or generated cheaply it can be used to advantage and is generally more economical than steam, especially in places remote from the central power-plant. Nothing could be more simple than the operation of electrical gear. It does not require a competent engineer constantly on the alert, oiling and watching bearings, and maintenance is at a minimum. The ease with which the current is transmitted from its source to where it must do its work is one of its greatest advantages. Transmission losses are very low. Generally speaking, the smaller the plant the lower the loss and 90 per cent, and better, efficiency is easily attained. In and around Bellevue 2300-volt, three-phase, is the standard distributing pressure; our power requirements and the distances transmitted, for the present, do not require more than this. Most of the heavier motors are 2300-volt .machines, which eliminates the cost and possible troubles of step-down transformers, and makes for a cheaper and less bulky motor. This applies to two fan, two hoist, and two compressor motors, the smallest being 75 and the largest 520 horse power. The standard pressure on power lines to all inside pumps is 550 volts, and 220 volts is general for the the tipple. While 110 volts is used for house and office lighting service, it is not economical around and in the mine. No matter what kind of device is used to lock and protect the lamps, they are invariably missing.

Jan 1, 1926

Miners really are an optimistic bunch. Even with the dark clouds hanging over the global industry, mining professionals still turn out in droves at industry conferences. In February, more than 7,200 professionals attended SME?s Annual Meeting in Denver, CO, a record. And the following week, more than 30,000 people converged on Toronto, ON, Canada for the Prospectors and Developers Association of Canada (PDAC) meeting. For many small and junior mining and exploration companies the PDAC conference is a place to find potential investors in their projects. The Investors Exchange attracts several hundred companies, each showing off their properties to the many money types who wander the hall during the four-day conference.

Jan 1, 2013

By Miao Tian

Large quantities of copper complex resources are produced globally and urgent to be cleanly processed. This article presents a thermodynamic analysis of mixed smelting process including low-grade polymetallic copper sulfide concentrates, high copper content sulfide concentrates, metallurgical by-products (copper removal slag from lead metallurgy), and copper powder from electronic waste. A top blown smelting reactor to simulate mixed smelting process is developed using a metallurgical process simulator, METSIM. Reactor parameters, heat loss and phase distributions are estimated from actual plant data. The proper proportion between complicated primary and secondary copper resources is determined by analyzing the influence of the feed rates of various resources, oxygen, silica flux and revert on the smelting performance. Autogenous smelting process is built by optimized matching materials of copper complex resources, in terms of the reactor temperature, copper content in matte and slag, and the percentage of magnetite in slag.

By Eugene F. Eisemann

This paper is concerned principally with the competition between fuels for industrial use in the United States. Total energy consumption in the U. S. is allocated between industrial and other uses The industrial volume is divided into two classifications (1) where-there is competition between fuels and (2) where there is no competition. The pattern of fuel consumption by electric utilities was studied because there, is competition between fuels and because it is the fastest-growing industrial market. Electric utilities fuel consumption is discussed by geographic area. The growth of each fuel in several areas is investigated. The analysis of these areas, includes the study of the relationship between prices where fuels are in, competition:- (1) on the East Coast where price competition occurs between oil and coal, and (2) in the southeastern states where competition exists between coal and gas..

Jan 1, 1961

By T. Y. Yan

A method has been developed to remove calcite from the leaching circuit in the uranium in situ leaching system. The process involves injecting the leachate and a pH control agent tangentially into an inverted cone reactor containing calcite seed catalyst. The leachate can be treated at high throughput to obtain clear effluent containing 5 ppm or lower Ca. Both lime and ammonia are effective pH control agents and consumed according to stoichiometry.

Jan 1, 1983

By Jing Li, Weiqiang Lai, Joe Zhou, Jiezhen Ma, Shuibo Chen, Ashele Copper Company, Feng Gao, Guofu Feng

"Copper-zinc ores often contain gold and silver, which can be recovered into copper concentrate by flotation as by-product. The challenges for operations that produce copper, zinc, gold and silver are the separation of copper and zinc and the low grade of precious metals. Ashele copper-zinc ore in north China contains 2.38% Cu, 0.69% Zn, 0.21 g/t Au and 18.10 g/t Ag and the plant produces copper and zinc concentrates, with gold and silver being recovered into copper concentrate. Copper occurs mainly as chalcopyrite and Zn occurs as sphalerite. Copper is well recovered with a recovery of over 94%. However, the recovery of Zn is substantially low (around 50%) due to fine grain size of sphalerite. In addition, gold recovery is much lower than expected and only 33% of gold in the flotation feed was recovered. The grade of gold in copper concentrate is also lower than the required payable grade (1.0 g/t). To determine the cause for lower Zn and Au recoveries, a plant survey program was conducted on the operation. The information acquired shows that the loss of Zn was mainly in the copper concentrates (accounting for approximately 38% of the head assay); of which, 24% was liberated, 8.5% was associated with chalcopyrite and 4.6% was associated with pyrite, indicating that the separation of copper and zinc was the main cause for the Zn loss, with liberation being the second cause for Zn loss. Future effort in improving Zn recovery should be focused on the separation of zinc from copper. Gold in the ore occurs as both microscopic gold and submicroscopic gold, accounting for 36% and 64% of the head assay, respectively. Microscopic gold occurs mainly as native gold and electrum; it is relatively coarse with a grain size of 10 to 240 µm and a large portion can be recovered by gravity. Submicroscopic gold was mainly carried by pyrite (accounting for 38%), and to a less extent, by tennantite (15%) and chalcopyrite (10%). Gold in sphalerite is nominal (1%). It is suggested that more coarse gold and tennantite be recovered and a gold recovery increase can then be achieved to obtain a copper concentrate with over 1.0 g/t Au through flowsheet optimization. Gravity concentration should be investigated and may be worth added into the existing flowsheet to maximum the gold recovery and grade.INTRODUCTIONCopper-zinc ores containing gold and silver is a subtype of polymetallic sulphide ores. Unlike porphyry copper sulphide ores and iron-oxide copper-gold ores, this type of ores often contains substantial amounts of zinc and lead. Polymetallic sulphide ores are mainly distributed in Canada, such as at the LaRonde and Horne deposits. Other examples include Mt. Morgan in Australia and Boliden in Sweden. Globally, production and reserves from gold-rich VMS deposits account for 1370 t gold. This is equivalent to 1% of the world production and reserves, whereas the Canadian total for gold-rich VMS deposits is 870 t, representing close to 10 % of Canadian production and reserves (Gosselin & Dube, 2005a, 2005b). Flotation is the principal process for processing the copper-zinc sulphides ores, for subsequent smelting, roasting, or hydrometallurgical treatment. Oxidized copper-zinc ores can also be processed using leaching technology. For example, at LaRonde operation (a Cu-Zn-Pb ore containing 3-4 g/t Au and 60-100 g/t Ag) the flowsheet consists mainly of a copper flotation circuit and a zinc flotation circuit followed by a cyanidation process of flotation tails. The precious metals are recovered with copper concentrate, zinc concentrate and cyanidation of zinc tails via Merrill Crowe precipitation (Zhou et al., 2005)."

Jan 1, 2016

By J. H. Puffer

The copper mineralization of the Mesozoic Passaic Formation of New Jersey is typical of copper deposits in eastern North American Mesozoic sediments. Most such deposits are located at the base of the first of several basalt flows that are interbedded with continental, red-bed sediments. The copper mineralization is similar in most respects to that of the Keweenawan Basalts of the Lake Superior area. The first basaltic flow units of the eastern North American Mesozoic basins, and the Keweenawan Basalts, are continental quartz tholeiites of similar chemical composition and copper contents. The copper minerals and associated zeolite facies metamorphic mineral assemblages of these two rock units are also approximately the same. Stoiber and Davidson (1959) suggested that Keweenawan copper was mobilized and concentrated during metamorphism. The evidence pertaining to the Mesozoic copper deposits of New Jersey is consistent with such an interpretation and also with DeVore's (1955) suggestion that ore fluids commonly arise as a result of the mobility of metals under metamorphic conditions. There is additional evidence that final metamorphic concentration of Mesozoic copper was preceded by an initial stage of hydrothermal precipitation related to fluids emitted by basaltic magma.

Jan 1, 1987

By Géssica Seara Faria

Foram fabricados compósitos de matriz de cobre, reforçados com grafeno a partir da mistura de uma dispersão de óxido de grafeno com pó de cobre eletrolítico. A dispersão foi produzida pelo método de Hummers modificado e caracterizada por espectroscopia Raman e difração de raios X. Os compósitos foram fabricados pelo processo de metalurgia do pó convencional. Os pós de compósitos foram caracterizados por microscopia eletrônica de varredura, os corpos de prova consolidados foram avaliados quanto a densificação a verde e do corpo sinterizado, e os corpos sinterizados foram submetidos a ensaio de compressão a fim de verificar a resistência dos compósitos.

Oct 30, 2017

The great variety of geological conditions in French coal deposits has obliged the industry to develop different thick seam mining methods. In very steep seams in a dense deposit where stowing is necessary to avoid spontaneous combustion, surface subsidence and water problems, a rising horizontal slice method is used, the coal being hard enough and the seams regular (Lorraine). In very thick and irregular steep seams where the stowing is not necessary, a sub-level horizontal slicing is used; a third method has to be used in Dauphine.

Jan 1, 1976

By C. Xiao, R. Chi

In recent years, the biosolubilization of rock phosphates by phosphate-solubilizing microorganisms has become a major topic of research studies. However, the microorganisms used in previous studies were mostly single and known species, and studies seldom focused on mixed communities of microorganisms or microbial consortia from natural environments. In this study, a microbial consortium from rhizospheric soil was used to solubilize two different compositions of medium- to low-grade rock phosphates — designated as ore samples 1 and 2 — in a laboratory-scale bioreactor. The microbial consortium showed good growth in the bioreactor, reduced the suspension pH and released soluble phosphates from the ores. Scanning electron microscopy with energy-dispersive X-ray spectroscopy showed the action of the microbial consortium on the ore surface. There was considerable corrosion on the ore surface, and 3.42 and 4.93 percent of the element phosphorus was removed from ore samples 1 and 2, respectively. Microorganisms were sampled from the bioreactor for the analysis of their community structures by Illumina MiSeq high-throughput sequencing. The analysis show that the suspensions added with different ore samples had different microbial diversities and richness. This study provides new insight into the biosolubilization of rock phosphates by a microbial consortium directly taken from rhizospheric soils.

By M Scoble, C Hughes, M Roberts

At 14 per cent, the representation of women working in the mining industry is the lowest among primary industry categories in Canada. Despite an increase in research and industry commitment to advance and retain women in the mining industry, the gender gap in mining organisations persists.This paper is based upon a recent Canadian survey of 163 highly qualified women (HQW) working in the mining sector. For the purpose of this research, HQW were defined as women with a BachelorÆs degree or higher. This research sought to identify career progression and retention patterns of women who in theory have the educational qualifications to advance into positions of leadership in mining operations. We considered why womenÆs advancement in mining organisations has stalled; examined the career development pathways of HQW; and investigated the interactions of mining workplace culture on HQWÆs career development and retention within the Canadian mining industry. Results?indicated two distinct career pathway trends for HQW. æThe specialistÆ; a career characterised by multiple professional scientific and technical positions, and æthe corporateÆ; a career characterised by professional administrative roles and roles in mid-level management. It was found that neither æcorporatesÆ nor æspecialistsÆ systematically progressed into senior management and executive roles. These findings suggest that HQWÆs careers in mining are stalled, despite a strong indication by respondents of interest in their professional career advancement. With regards to?workplace?culture, respondents indicated that blatant forms of gender discrim-ination have been reduced in mining workplaces; however, exclusion from informal networks, implicit bias and subtler forms of workplace discrimination persist. Consistent with previous mining sector research, improving work-life balance, work flexibility and mentorship were found as key drivers for HQW to advance and remain in the industry.CITATION:Hughes, C, Scoble, M and Roberts, M, 2012. Where are the women? Highly qualified women in the mining industry, in Proceedings International Mine Management 2012, pp 23-34 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 20, 2012

By E. T. Tuzcu

In this manuscript, a new approach for modeling the rate of grinding process is explained. A review about grinding rate definitions so far is given and the possible ultimate way for grinding modeling is given as modeling the rate based on energy spectra. The traditional/phenomenological approaches for modeling size distribution of grinding mills give their place to a new generation modeling technique. Developments in the computational methods and necessity to model product size distribution of large mills, larger than ball mill size, paved the way for this novel technique. The traditional grinding rate models are mostly based on the back calculated breakage parameters from the experimental data. However, direct modeling of breakage parameters and hence the prediction of size distribution of the grinding mills may become possible with this approach. The material breakage data and discrete element method (DEM) energy spectra are the main components of this approach. Albeit the focus in this study is on modeling of breakage rate under impact mode of breakage, the abrasion mode of breakage was also tested by carrying out abrasion tests. Impact mode of breakage was analyzed using ultra-fast load cell device (UFLC) and drop weight tester. Dry tumbling test was carried out for abrasion experiments. Obtained material breakage versus energy data are combined with the collision energy spectra to obtain the breakage rate function. In addition, the material breakage versus energy information from the tests is converted into breakage distribution function. The model was verified in a lab scale mill (90 cm diameter-15 cm length). 10 to 15 kg of limestone was ground using 50 mm steel ball at varying conditions, i.e., rpm, volume loading. It is shown that the proposed model predicts all (1, 2, 4 min.) grinding intervals for all experiments highly accurate.

Sep 1, 2012