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By E. van Steen, G. M. Leteba

Optimizing the catalytic performance of multimetallic nanoparticle (NP) catalysts demands a concrete understanding of their design, while preferentially deploying wet chemical synthesis procedures to precisely control surface structural properties. Here we report the influence of reductants such as hydrogen-rich tetrabutylammonium borohydride (TBAB) and carbon monoxide-rich molybdenum carbonyl (Mo(CO)6) on the shape and morphological evolution of Pt-based binary (PtNi and PtCo) and ternary (PtNiAu and PtCoAu) nanostructures derived from a homogeneous solution of aminebased surface active agents (surfactants) in a high boiling point solvent. We successfully synthesized nanostructures exhibiting well-defined and composition-controlled surfaces deploying a one-pot synthetic approach. The development of the surface properties was, however, observed to be alloyspecific. The resultant highly monodisperse alloy NP with narrow size distributions and facet-oriented surfaces are expected to display enhanced functionality as catalysts for utilization in specific chemical reactions.

Jun 1, 2021

By Bruno Deves Flores, Guilherme Liziero Ruggio da Silva, Eduardo Osório, Anderson Azevedo Agra, Antônio Cezar Faria Vilella, Anderson Nicolodi

A microestrutura porosa do coque pode ser definida como a relação espacial entre a matriz carbonosa e seus poros. A formação da microestrutura ocorre durante o processo de carbonização dos carvões coqueificáveis. Portanto, o conhecimento das propriedades que governam a formação da microestrutura torna-se atrativa como uma ferramenta na escolha estratégica de carvões na composição de misturas para produção de coque. Neste trabalho coques laboratoriais foram produzidos por carvões com diferentes propriedades, visando a formação de coques com microestrutura com propriedades microestruturais distintas. A caracterização microestrutural foi realizada a partir de uma ferramenta de microscopia ótica associada a análise de imagens. A partir dos parâmetros obtidos na análise, foi estudado a influência das propriedades dos carvões nos parâmetros analisados. Além disso a convergência com outros modelos (MOF e CBI) foi estudada. Os resultados obtidos mostraram que carvões com estágio plástico desenvolvido e elevado teor de matéria volátil geram coques de alta porosidade e com poros de tamanho excessivo. Carvões ricos em componentes inertes apresentam microestrutura de baixa porosidade, composta de poros pequenos, no entanto, com poros de baixa circularidade. Os carvões com as melhores propriedades (critérios dos modelos MOF e CBI) resultaram nos coques com as microestruturas mais regulares, de baixa porosidade, com pequenos poros e com formatos adequado.

Oct 1, 2019

By Xiaobo Zhang, Panshi Xie, Xiaobo Wu, Ding Lang, Jiandong Yu, Yongping Wu, Kun Feng

In a fully mechanized top coal caving mining process, the mechanical properties of the top coal deteriorate constantly, and the stability of the support is determined by the boundary position of the top coal entering the limit equilibrium state. Top coal flaking occurs more easily along the advancing direction owing to an increase in the distance of the boundary from the wall. Moreover, the strength of the coal seam is an important factor that determines the boundary position. The equation of the top coal limit equilibrium zone boundary, used in fully mechanized top coal caving mining, was determined based on the limit equilibrium theory, continuum damage mechanics, and the Hoek–Brown rock empirical strength criterion. Using the RFPA3D and UDEC numerical analysis methods, the effect of top coal strength on the mechanical behavior during the mining process was determined; and the space–time relationship between the top coal deformation failure, damage evolution, and boundary of the limit equilibrium zone was established. The results revealed that when the coal mass entered the limit equilibrium zone, accelerated crack development, accelerated damage, and axial unloading occurred. Moreover, an increase in the coal seam strength caused the boundary of the top coal limit equilibrium zone to be closer to the wall. By comparing the numerical results with the theoretical results, the overall trend was found to be consistent, allowing the verification of the rationality and reliability of the determination equation of the boundary position of the limit equilibrium zone.

Sep 21, 2021

By Bernard J. Steblay

Two instruments have been constructed that extend microseismic data collection and processing capability for Bureau of Mines research in rock burst, coal bounce and outburst, and roof fall monitoring. The first instrument is a 13-channel tape-triggering system. This system allows better utilization of instrumentation tape recorders by collecting data digitally, turning the tape on only when valid data are present, and increasing the dynamic range of the recorder by using digital data. A digital-to-analog converter is used to provide analog output of the recorded digital data. The instrument records a much larger time slice of transient events than do current commercial devices. The second instrument is a microseismic energy measurement device. This device uses recent developments In integrated circuits to overcome the dynamic range and accuracy limitations of previous instruments. The analog signal is converted to a digital one, and then high-speed multiplication techniques are used to square the amplitude value in real time and integrate it.

Jan 1, 1983

By Rafael A. Rivera

"Since the dawn of construction, there has been a need for excavations, which sometimes need to occur below the groundwater table. Excavations in themselves are difficult enough, with the myriad of requirements, such as engineered support of excavations, considerations for stability and numerous other concerns. Excavations executed in rural landscapes can be accomplished easily without significant consideration to accessibility, adjacent properties or structures, and construction limits and deformations. However, all of these factors can have an impact on excavation considerations in an urban landscape. When digging below the groundwater table, these conditions, along with concerns associated with groundwater drawdown requirements, discharge limitations, groundwater contamination, property limits, adjacent buildings and subsidence concerns, can lead an experienced dewatering contractor to consider diverse installation methodology and equipment to allow construction to occur below the groundwater table.534 W. 29th St. New York, N.Y.There are many things that must be considered when constructing a new high-rise building within a small property footprint measuring 25 ft (7.6 m) wide by 80 ft (24.4 m) in length. When you take into account that the foundation needs to go several feet below the groundwater table and that there are two existing multistory buildings with shallower foundations on either side of the proposed structure, this task now becomes much more difficult. Consideration of geology, groundwater levels, depths of excavation and shoring for the excavation becomes critical to the success of the project. On a regular basis, dewatering contractors confront similar situations in congested cities where available real estate is limited.To minimize the negative impacts of construction dewatering, it is important to mitigate the potential effects of construction dewatering to the surrounding buildings, sidewalks, underground structures, tunnels, subways and other existing infrastructure. Such an instance occurred at the project located at 534 W. 29 St. in New York City. On this particular project, the required drawdown was greater than the typical 15 ft (4.6 m) of suction lift, so a vacuumed can pump system was utilized. The tubing was connected to a vacuumed perimeter dewatering well-point system, which is a predrainage system that is installed prior to the start of excavation for the underpinning of the adjacent structures and for the overall foundation. Each well-point, which was composed of a PVC pipe that was 1.5 in (38 mm) in diameter by 25 ft (7.6 m) long, was drilled to a depth of about 23 ft (7 m) using a hollow stem auger and was installed around the perimeter at a centerto- center spacing of about 7.67 ft (2.3 m). In lieu of a traditional perimeter collection header, and to allow for greater flexibility for the contractor, the well-points were interconnected to a modified vacuum can pump system utilizing ¾ in (19 mm) drop tubes that were “spaghetti” around the perimeter."

Jan 1, 2017

By W. T. Robson

ONE of the problems encountered in any mine is the effect of increasing pressure manifested by increasing depth. Although the depth at which excessive pressure assumes serious proportion, and the manner in which it appears in underground workings, are influenced by a variety of factors, nevertheless the difficulty is present in all mines and its gravity increases with increasing depth. In the Kirkland Lake camp, as far back as seven years ago, mining had proceeded to depths sufficient to result in the formation of pressure great enough to cause violent disruption of masses of rock. It is proposed in this paper to deal with the effect of pressure caused by mining as observed at Lake Shore Mines, and to describe some of the methods which have been adopted to counteract it. There are many contributing factors in a study of the problem, and results vary widely in individual mines and in different localities. One feature common to all, however, is that there is ground subsidence, evidenced either by a gradual settling accompanied by crushing and shearing of the ore and wall-rocks, or the disruption of the ground surrounding the periphery of an excavation may take place suddenly, attended by more or less violent shattering of the rocks. Such violent failure of a mass of rock has been designated by the term rock-burst. The history of rock-bursts extends over a great number of years. They have occurred in some form or other in practically ali places where mining operations, at all but very shallow depths, have been carried out. Since the theoretical aspects of the subject have been dealt 'with at great length by capable and experienced writers (1), the present paper will give only a brief résumé of the theories propounded by those engaged in deep mining operations in various parts of the world.

Jan 1, 1940

By J. A. Herbst

Until the past decade, the energy-size reduction relationship was the dominant form of mathematical model used in the description of tumbling mill grinding processes (1,2). Typically, in these models some single measure of product fineness (e.g. the 80% passing size, the size modules, the specific surface area) is chosen as the dependent variable and the energy input per unit mass of material being ground acts as the independent variable. In some instances these models have been useful for the correlation of experimental data, but, invariably, they have been found to be inadequate for meaningful process simulation. During the last decade considerable advances have been made in the development of phenomenological grinding models derived from population balance considerations (3-7). In these models a set of dependent variables is employed, corresponding to the set of mass fractions which constitute the product size distribution, and energy input is abandoned in favor of "time in the mill" as the independent variable. The phenomenological models have been shown to provide accurate simulations of the entire size distribution of ground products produced in batch (8-10), locked cycle(11)and steady and unsteady state, open and closed circuit continuous grinding(12,13).

Jan 1, 1973

By Lillian Erskine

While brass and other copper alloys have long been listed as offering health hazards to their workers, it is questionable if the metals involved are alone responsible for the trades' records of morbidity. The entire science of foundry sanitation is the product of the past two decades; and the best standards now operative would have been regarded as little short of revolutionary prior to 1910. The special handicap to the conservation of the health of the brass founder's employees has been the fact that, unlike the iron founder, his business could be profitably carried on in almost any small and unsanitary quarters. As a result, writers on occupational disease have accepted brass chills or brass founders' ague as an inevitable feature of the trade; and respiratory disabilities, as well as phthisis and disturbances of the nervous system, are also included as prevalent among those employed. While there can be no question as to the basic accuracy of past investigations, there is every reason to doubt the necessity for an undue percentage of ill health among brass molders and casters who are safeguarded by scientific ventilating standards and by improving personal habits of sobriety. There is, however, need for a campaign of education as to the most approved practices and equipment whereby the employer may safeguard the health of his workers, and thereby reduce his labor turnover and increase his productive efficiency. Broadly speaking, copper, tin, and aluminum carry negligible health hazards. The toxic qualities of lead, however, are a menace; especially if scrap lead is recovered or bought for foundry processes. The rapid volatilization of zinc renders its fumes and flocculent condensation the chief problems in conserving the health of the brass worker. The frequent presence in the foundry air of traces of arsenic compounds, lead

Jan 1, 1919

By A. U. Seybolt

DURING the course of experiments involving oxygen equilibrations with a high-purity Pd-5 at. pct Rh alloy, the appearance of a subscale was noted. Most of the heat treatments in a pure oxygen atmosphere were performed at 900°C. The presence of the subscale was noted when the oxygen partial pressure was in excess of approximately 95 mm, up to 1 atm, the highest pressure used. According to available thermodynamic information' on the free energy of formation of Rh2O3 (the only reliably reported solid oxide of rhodium), this oxide should not be stable under these conditions, nor, of course, any oxide of palladium. Extraction of the subscale from the matrix was affected by treatment with aqua regia, and the resulting X-ray diffraction powder pattern is shown in Table I. This pattern is not that of Rh2O3, nor that of any known rhodium or palladium oxide. It can be indexed on a hexagonal lattice with a. = 5.22Å and co = 6.0Å. In addition to this unknown material, there was a weak Rh2O3 pattern. An X-ray fluorescence analysis of the powder gave 3214 palladium counts per sec and 5381 rhodium counts per sec, thus indicating the likelihood of a double oxide of palladium and rhodium. In view of the fact that the above result was obtained on a single sample, it is perhaps best not to insist upon the above ratio of about 0.6, but possibly to tentatively assume 0.5 or 1/1. The small amount of Rh2O3 in the X-ray pattern might have occurred on cooling, and it seems possible that the double oxide, below some temperature level, is not as stable as Rh2O3. To examine this point, some of the extracted double oxide was heated on a sheet of pure palladium in air at 900°C, and allowed to furnace-cool over a period of several hours. The X-ray diffraction pattern of the powder showed approximately the same intensity of Rh2O3 and the "hexagonal" oxide as before, but, in addition, a rather faint pattern of another crystalline species made its appearance. This finding again suggests partial transformation of the major (double) oxide to other oxides on cooling from 900°C. Application of the phase rule shows that only one equilibrium oxide (subscale) could have been present at temperature. Vacuum-fusion, oxygen analysis of the extracted subscale showed 7.7 ± 0.7 pct O. Combining this information with that of the X-ray fluorescence analysis suggests the formula PdRhO. This compound should have an oxygen content of 7.07 pct, which is within the range of error of the oxygen analysis. However, until a more careful stoichiometric study is made, it is suggested that the formula be written

Jan 1, 1965

By Alexandre Keunecke Hardt

A alta competitividade no setor siderúrgico aliada ao dinamismo crescente do mercado internacional tem forçado as empresas a estarem mais preparadas para eventuais necessidades de mudanças em seus processos e produtos. Em muitas situações, o tempo de resposta de uma empresa para adaptar-se a uma nova necessidade, estratégia ou tecnologia determina o sucesso ou fracasso da iniciativa. As soluções MOM, como responsáveis pelo gerenciamento da produção, possuem um papel fundamental no intuito de facilitar a adaptação da empresa a uma nova realidade. Nesse contexto, a adaptabilidade e a flexibilidade das ferramentas MOM tornam-se fatores extremamente relevantes no momento de definição de um produto ou concepção de uma solução. Este trabalho tem como objetivo refletir sobre o papel das soluções MOM como acelerador de mudanças dentro das indústrias. Serão apresentadas as características principais de um sistema MOM preparado para o cenário dinâmico atual, bem como alguns critérios para avaliação da adaptabilidade e flexibilidade de uma solução MOM.

Jul 30, 2018

By K. Huttu, A. van Wageningen

"The Kittilä underground mine in northern Finland is extracting one of the largest known gold deposits in Europe. Kittilä achieved commercial production on May 1, 2009, becoming Agnico Eagle’s first mine to open outside of Canada. The Kittilä orebodies were initially mined from two openpits – Suuri and Roura – and underground operations were added in October 2010. The pits were mined out in November 2012, so mining is now entirely underground in the Suuri and Roura deposits. Additional, small openpits will mine any remaining near-surface reserves in the future.The Kittilä Mine is located in the Lapland region of northern Finland, approximately 900 km (560 miles) north of Helsinki and 150 km (93 miles) north of the Arctic Circle. With a mine life estimated through 2034, Kittilä is Agnico’s longest-life mine.The mine’s proven and probable reserves contain 32 Mt (4.7 million oz) at 4.6 g/t (0.13 oz/ st) gold. Ore has been mined from underground since 2010. The original 3 kt/d (3,300 stpd) operation underwent an expansion project to increase the throughput capacity of the mill by 1 kt/d (1,100 stpd), starting by the end of 2014.The region around the Kittilä Mine is underlain by mafic volcanic and sedimentary rocks of the Kittilä Greenstone Belt oriented nearly vertical. This greenstone belt is similar to those hosting Agnico Eagle’s Canadian deposits in Quebec’s Abitibi region and Nunavut. At the contact point between ironrich and magnesium-rich rocks lies a 100- to 200- m (330- to 660-ft) thick structural zone known as the Suurikuusikko Trend. This trend hosts the Kittilä deposit, where multiple mineralized zones have been traced over a strike length of more than 25 km (15 miles).Most of Agnico Eagle’s work has focused on a 4.5-km (2-mile) segment of the Suurikuusikko Trend that hosts the five main zones of the known gold reserves and resources. From south to north they are: Ketola, Etela, Suuri, Roura and Rimpi.The ore at the Kittilä Mine is refractory, making gold extraction relatively difficult because the gold is generally locked inside the two main sulfide minerals – arsenopyrite and arsenic-rich pyrite. Only about 4 percent is very fine-grained “free gold” (not locked in sulfide grains) and easier to extract. Most of this free gold is found in the outer, oxidized or eroded sections of the ore."

Jan 1, 2015

By C. G. Carlström

The total iron ore production in Sweden in 1969 was 33.3 million metric tons. 31.7 million tons were exported mainly to Western European countries. 27.8 million tons (87 per cent) originated from the mines at Kiruna, Svappavaara and Malmberget, located just north of the Arctic Circle in Sweden. Planned production for 1970 is 25 million tons during 10 months, due to a strike at the beginning of the year. Present production plans for the next five years expect an annual export capacity around 33 million tons in 1975, including 5.7 million tons of pellets. The mining and shipping at the loading terminals of Narvik on the Atlantic coast and Luleå at the Gulf of Bothnia are managed by LKAB - a 96 per cent state-owned company. 4 per cent of the share capital is owned by the private Grängesberg Company. The railway - 106 miles from Kiruna to Narvik and 130 miles from Malmberget to Luleå - is operated by the State Railways in Sweden and Norway. Comprehensive expansion of the Narvik ore port will be carried through during the next five years to increase the annual shipping capacity to at least 35 million tons and meet the development of rapidly growing ship sizes.

Jan 1, 1970

By Patrick Wong, Gareth Hatch, M. A. Halim, V. I. Lakshmanan, Darcy Tait

"This paper describes development of an integrated chloride process for separation and purification of REEs. The process includes atmospheric leaching of ore/concentrate with mixed chloride lixiviant containing HCl and MgCl2 followed by bulk recovery of REEs, dissolution of the bulk intermediate product, and separation of individual REEs by solvent extraction (SX) process steps. Mixed chloride leaching technology provides the opportunity to regenerate the lixiviant, while the addition of MgCl2 in HCl enhances the hydrogen ion activity by orders of magnitude increasing REE extraction efficiency at a lower concentration of HCl. An individual REE separation process developed by Innovation Metals Corp. is being piloted at a state-of-the-art facility at Process Research ORTECH Inc. in Mississauga, Ontario, Canada. The SX process includes the separation of light REEs (La – Nd), medium REEs (Sm – Gd) and heavy REEs (Tb – Lu plus Y) from leach liquor followed by individual REE separation. Each SX circuit proceeds by multistage extraction followed by scrubbing and stripping. The process is chloride based and reagents are recycled, reducing waste generation and optimizing water usage to reduce environmental impact.INTRODUCTIONRare earth elements (La to Lu plus Y) exhibit a range of unique magnetic, electronic, catalytic and optical properties. Due to these special properties, the application of REEs is increasing and they are found in components for wind power generation, hybrid electric cars, catalytic converters, and many electronic devices.Rare earth elements (REEs) are commonly divided in two groups: light rare earth elements (LREEs) and heavy rare earth elements (HREEs). Light rare earth elements include elements from lanthanum (La) to neodymium (Nd). Although promethium (Pm) is considered an LREE it is unstable and scarcely occurs in nature and is generally excluded. Heavy rare earth elements include elements from samarium (Sm) to lutetium (Lu) plus yttrium. Although rare earth elements are not rare and the rare earth oxides are scattered around the globe, over 95% of REEs+Y are currently produced in China (Pitts, 2011). On one hand the Chinese government is restricting the export of rare earth elements and on the other hand the demand for REEs+Y is increasing in the rest of the world. This has created an imbalance in the supply and demand of rare earth elements and has led to a rush for developing new rare earth projects."

Jan 1, 2016

By D. G. F. Hedley, F. Grant

"In 1958, the Ontario Department of Mines appointed a committee to study the accident situation and mining methods used in the uranium mines in the E1liot Lake district. This committee reviewed the existing knowledge on mine design, pillar support and roof spans and came to the conclusion that scientific knowledge had not yet reached the stage of producing rational design procedures which would reduce the dependence on trial-and-error methods. Since that time, the Mining Research Centre has made numerous stress measurements in two mines to define the pre-mining and pillar stresses. A comprehensive series of tests has been done in the laboratory to measure the compressive strength of the rock; a geological survey of the region has been made to evaluate tectonic stresses; and a survey was done on mining conditions with regard to stable and unstable pillar configurations. This information has been used to evaluate pillar design as effected by pillar width and height, depth below surface, extraction and pre-mining stress fields. The resultant design of pillar widths and corresponding extraction as the depth increased is in line with past and present experience in these mines. The information available on roof stability is still insufficient to design stable stope spans with the same degree of confidence; experience and trial-and-error methods are still required."

Jan 1, 1972

By C. C. Harvey

As we move towards the 21st Century there are several factors that will influence the markets and processing requirements for industrial minerals. Traditional markets for many industrial minerals in the developed world are frequently stagnant or decreasing because of their maturity or due to environmental factors such as reclamation, recovery of byproducts, and recycling. Some industrial minerals are greatly affected by these factors, while others are either immune to or have adapted successfully to meet these challenges. In the developing countries of the world, there is rapid market growth and resource exploitation. The future of specific mineral commodities in several markets will be discussed.

Jan 1, 1997

By Jorge F. Ponciano

El presente texto plantea una forma de tratamiento de lodos anódicos en la fundición de La Oroya a través de una individualización de los residuos de cobre y plomo, con la finalidad de recuperar los elementos valiosos. También, se analizan los resultados experimentales del esquema propuesto (tratamiento térmico-fusión-reducción) para los lodos anódicos de plomo, así como las ventajas que el nuevo diagrama de flujo aporta. Finalmente se plantean alternativas que procesen los residuos anódicos de cobre, complementando el esquema de los lodos nódicos de plomo, y se dan conclusiones técnico-económico del método innovador en relación al sistema actual.

Apr 1, 1991

By J. P. Gouvea, T. R. Stacey

A research project was carried out on a gold mine in the Vaal River region of South Africa (Witwatersrand Basin) to evaluate the effect of two particular aspects of rockbolt installation – the angle of inclination of the bolt relative to the orientation of the rock surface, and the protruding length of the bolt – on the mine’s gully support system. A keyblock analysis approach indicated that these factors do not have an adverse impact on the stability of the strike gullies. This was confirmed by extensive empirical data collected from the case study mine. While safety is the primary concern, cost saving opportunities can be realized through reconsidering historically inherited support standards that are perceived to be correct and appropriate. The research described in this paper sets forth a practical approach, that is easy to implement and repeatable, to evaluate the role of rockbolts in stoping gullies.

Feb 12, 2024

By D. Bienstock

The Fischer-Tropsch synthesis is practicable in a reactor where the exothermic heat of reaction is removed by circulating large quantities of recycle gas through a catalyst bed of high-voids content. At an hourly space velocity of 1100, the feed gas, a mixture of 1.5 parts hydrogen to 1 of carbon monoxide, was converted 90 percent, producing hydrocarbons predominantly in the gasoline range. At these conditions a recycle-to-fresh gas ratio of 40:1 was enough to give excellent temperature control with a pressure drop of 1.5 p.s.i. per foot of bed using a steel catalyst in the form of lathe turnings. Steel parallel plates, although offering lower resistance to gasflow, were less reactive and less durable. INTRODUCTION The Federal Bureau of Mines has been engaged in a research and development program since 1944 on the synthesis of gasoline from coal. Gasification of coal with steam and oxygen to yield a synthesis gas--a mixture of carbon monoxide and hydrogen--is being investigated at Morgantown, W. Va.; and the synthesis of gasoline by catalytically reacting the carbon monoxide and hydrogen over iron by the Fischer-Tropsch reaction is being investigated at Bruceton, Pa.

Jan 1, 1960

By Henry E. Perlee

Air compressor explosions that are caused by the ignition of combustible vapor mixtures cannot be explained by a single reaction mechanism or sequence of events. Explosions have been caused by the sudden release of large quantities of lubricating oil, by the rapid vaporization of oil that had accumulated slowly in high-pressure piping, and by the production of decomposition products from carbonaceous deposits. Ignitions can be caused by the heat produced in a catalytic reaction, in a compression process, or when a shock wave is propagated through a combustible vapor-air mixture. The frequency of these ignitions can be minimized by establishing proper maintenance and cleaning schedules. Further study is needed to satisfactorily correlate the various factors involved in compressor explosions.

Jan 1, 1963

By H. D. Kessler, Joseph B. McAndrew

WHEN there is occasion to make structural use of metals at temperatures above 900°C (1652°F), the choice of alloys is severely limited, and those materials which meet special requirements as to density, strength, toughness, and resistance to creep, oxidation, or fatigue at such temperatures are at a premium. Any new type of high temperature alloy which is found to be outstanding with respect to several of these properties is therefore likely to find special applications for which it is uniquely advantageous as compared to other alloys. Such is the case with the 7 titanium-aluminum alloys. This y phase is an intermediate phase based on the composition TiAl, and extends from about 35.5 to 44.5 wt pct Al at temperatures up to 1000°C, above which the field broadens to include 60 pct A1 at 1340°C.' The alloys of principal interest have a narrow melting range, with 7 forming by the peri-tectic reaction, melt + ß=y at about 1460°C. Unlike most intermediate phases, the binary alloys containing titanium and aluminum in approximately equiatomic proportion possess low room temperature hardness,' in addition to which they have low density, good resistance to oxidation, and relatively high modulus of elasticity.' Unpublished work done at Armour Research Foundation showed

Jan 1, 1957