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By V. Casaletto, L. Widdifield

"Equipment capable of higher production requires more sophisticated maintenance programs. Reduction in fleet size through use of modern technology requires higher utilization and greater availability.Caterpillar's maintenance control system program will display the capabilities of computer technology in a maintenance environment. Utilizing such resources will provide increased availability, lower inventory requirements, fewer last minute disasters, and lower cost per ton for maintenance. High production from premium quality equipment can only be realized by good planning and care, executed by maintenance and operating personnel acting cooperatively.IntroductionAccurate information is the key to accurate decision making. In today' s competitive industry, mines' teeter on the brink between profit and loss. Their survival will be predicated on their ability to retrieve, analyze, and formulate accurate information regarding the operating costs of mobile equipment. This paper deals with the impact of managing equipment operating costs and introduces a computerized control system designed for monitoring and controlling these costs.Caterpillar has produced several computerized modelling programs designed at taking the guesswork out of equipment selection and management. The most basic of these is Equipment Investment Analysis (E.LA.). This model compares two or more alternatives over the projected life of the machine. It deals with comparisons in the owning and operating costs of equipment, as well as, their productivity over a specified period of time.In order for a computer model to be credible as a decision making tool, it must be simple to use and the results measurable and accountable . Caterpillar has introduced several computer models to assist the industry in selecting and managing an equipment fleet. These programs allow the user to predict and monitor the operating costs and production capability of mobile equipment. They are often used in the machine selection process to select equipment which best suits a mine's long-term cost per tonne objectives. After the optimum selection is made, Caterpillar's Maintenance Control System provides an efficient management tool to monitor and verify the data used in the selection model."

Jan 1, 1992

By Sungdon Kim, Chuljoo Kim, Joonsoo Kim, Hosung Yoon

"This study was performed to establish the optimum leaching condition through the experiments for the oxidized roasting followed by leaching of fluorocarbonate rare earth mineral (bastnasite) using sulfuric acid, and to establish the optimum condition for the recovery of cerium by ion- sieve method from the leached solution of bastnasite. The optimum conditions for the sulfuric acid leaching by the oxidizing roasting of bastnasite concentrates are that the roasting temperature is 550 -600 °C, the roasting time is 2 hrs, the concentration of sulfuric acid is 6N, the leaching temperature is S0°C and the leaching time is 3 hrs. At this time, the leaching yield of total rare earth oxides in the leaching of bastnasite concentrates is about 91%. When cerium is recovered by ion-sieve method from the solution obtained by the sulfuric acid leaching of the roasted bastnasite, the optimum conditions are that the TREO(total rare earth oxide) of leached solution is below 70 g/l, the flow rate of leached solution is 9.6 ml/min and the ratio of height to diameter of resin packed in column is above 9. In these conditions, the recovery of cerium of yield 85% and purity 96% is possible.IntroductionThe rare earths are generally called to Lanthanides, which are totally 17 elements including Scandium of atomic number 21 and Yttrium of atomic number 39 in addition to 1 S elements from Lanthanum of atomic number 57 to Lutetium of atomic number 71. Since the separation to each element is very difficult because of their similar chemical properties, the rare earths were used as the mixed rare earths and the mischmetal without separating to each element. However, the high purity rare earths are recently produced commercially to each element so that they are used as the materials for high tech. industry such as electric and electronic materials, catalysts, optical materials, special alloy and 8Uperconductive materials, and their consumption is rapidly increasing. Therefore, the purpose of this study is firstly to prepare leached solution by using the series of process of the oxidation-roasting and leaching by sulfuric acid. Next, second purpose is the separation and recovery of cerium by ion-sieve method."

Jan 1, 1998

By F. F. Peng

A unique collector dispersion techniques was developed and used to improve the flotation rate and recovery of coarser and ultrafine coal-rich particles in the froth flotation processes. In this novel collector dispersion method, the collector such as hydrocarbon-oil is gasified and transported by gas phase (air stream) into the pulp. In addition to the excellent mode of collector dispersion, the collector-encapsulated air bubbles are generated in the pulp. This approach alters the surface properties of air bubbles and provides the fast rate of flotation compared to that of direct liquid collector addition froth flotation. Using gasified kerosene as the collector, the effect of altering surface properties of bubbles on the recovery of larger and finer coal-rich particles of -1.7 mm (-12 mesh) and -600 µ m (-30 mesh) raw coal samples were studied. The Redstone seam coal obtained from Northern Central region of West Virginia was used in this work. The effect of particle size on oil-coated bubble flotation rate and recovery were also evaluated. The conventional froth flotation test with a liquid form of kerosene addition was also conducted for comparison purpose.

Jan 1, 1991

By Sanjay Chaudhuri, V. K. Kalyani, Pradeep Kumar Singh, T. Gouri Charan

"Indian coal industry is the world's third largest in terms of production and fourth largest in terms of proven coal resources. Indian coal deposits are generally of high ash content varying from 24 to 50%. The coking coal reserves of India constitute about 12% of the total coal inventory, and the coals are washed in washeries, before being used for metallurgical purposes. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells. Extensive studies were carried out for understanding the performance of an operating conventional flotation plant. The performance studies revealed that appreciable quantity of clean coal is being lost in the tailings due to varied reasons and the required quantity and quality was not achieved. In this study, laboratory Flotation experiments were carried out to examine the cleaning characteristics of the said tailing and to determine the effective process parameters for recovery of clean coal at desired ash level ( 16-17%). Response Surface Methodology was applied to investigate the operating conditions of the Froth Flotation for modeling and optimization. Primary study reflects that there is a possibility to recover clean coal at 16-17% ash level with a yield of about 60-70% from that Flotation tailing of feed ash about 28%.INTRODUCTIONMost of the Indian coking coals are difficult in cleaning characteristics and high ash content due to its drift origin and its age of formation for more than 225 million years. Indian coking coal reserve is limited about 12% of total coal reserve. The minerals are homogeneously mixed with the coal macerals. The open cast mining practice and mechanized mining methods are being adopted to meet the increasing demands of coals resulting in generation of more coal fines and subsequently the quality is deteriorated. Indian good quality coking coal reserves of higher seams are fast depleting and hence coking coals of difficult cleaning characteristics of lower seams (LVC) are being now explored. Due to increased mechanization of coal mines to cope up the increased demand and followed by size reduction of lower seam coals in search of better liberation , the coal fines are increasing by leaps and bounds. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells."

Jan 1, 2018

By A. Luszczkiewicz

An innovative hybrid technology for beneficiation of difficult-to-process sedimentary copper ores comprising acidic leaching stage of the feed combined with subsequent flotation has been presented. Acidic leaching, preceding the flotation process, plays a beneficial role of efficient chemical grinding for liberation of copper sulphide minerals finely disseminated in the copper-bearing carbonate-shale rocks. The process was applied on a fully industrial scale. Flotation results were analysed for both chemically modified and unmodified flotation feeds. After several months of industrial scale operation, it was found that both metals recovery and concentrate grade remarkably increased as a result of application of chemical modification of the flotation feed. Beneficial effects of chemical pre-treatment of flotation middlings on selectivity at a comparable concentrate yield in industrial flotation scale, revealed a considerable increase of the total copper recovery by 3.5percent. Based on the industrial and laboratory investigations we consider a further development of the process and introduction of hydrometallurgy for better recovering of metals from low-grade copper concentrates

Sep 1, 2012

By Joseph O. Cook

I know this is, at best, a frustrating period for the coal mining industry. About 20,000 miners have been laid off, mostly in the Appalachian and mid-western areas, and several mines are working less than 5 days a week; however, the industry is experiencing modern growth and, at least, there is the potential for future growth. The coal industry is probably only operating at about 80 percent of its present capacity, and it is certainly capable of helping this country solve its energy problems. Growth, as a rule, does not come easy, and growth in the coal industry is no exception to this rule. Many formidable challenges have to be overcome. As we all know, mining relies very heavily on the earth sciences, which have advanced significantly in the past few years, but we are always working in a changing environment which in most cases is a hostile environment. Large quantities of material are quickly extracted and rapidly moved in, generally speaking, a very confined area. The very nature of the mining business directly and constantly impacts our environment during this period in which the Nation and the world has become increasingly smaller and more concerned about protecting our environment. In addition, growth brings about an expanding work force which is increasingly younger and less experienced.

Jan 1, 1980

By Andreas Volkert

Energy efficiency, equipment reliability and cost reduction are of the key factors in any efficient plant. Badische Stahlwerke (BSW) started using its own burner technology in 2001, this was developed by Badische Stahl-Engineering (BSE). Over the past 15 years, Badische improved all aspects of its Virtual Lance Burner (VLB), to perfectly fit all steelmaking requirements. This tiltable VLB was first tested at BSW’s electric arc furnace no. 2 in 2012. Promising results like reduction of refractory wear, energy efficiency, reliability, etc., were obtained. At the same time the existing VLB system was further improved with regards to the design of the water-cooled copper box. Today in 2016 both EAFs at BSW are equipped with the new patented tiltable system and the new copper box design. The paper will describe the results of the past years at Badische, but will also show the performance at other installations.

Aug 17, 2017

By G. Derge, W. Peifer, J. H. Richards

INTRODUCTION A WIDE variety of metallurgical defects in steel have commonly been attributed to the presence of excessive amounts of hydrogen. These defects include flakes in rails and forgings, cracks in welds, and blisters in enameled ware. They have been related to hydrogen largely by circumstantial evidence because the proper sampling and analysis of steel for hydrogen has been known to be difficult and because no general agreement has existed with regard to the relative suitability and accuracy of available methods. The need for a direct approach to these problems has been widely recognized. This general situation has been well described in the publications of the British Committee on the Heterogeneity of Steel Ingots,1 and current approaches to the problem were reviewed in a recent symposium of the AIME.12 The plans described by the present authors at that meeting have now matured satisfactorily and will form the basis of this paper. The principle object of this paper will be to describe the methods of sampling and analysis which have been developed and to illustrate the usefulness and limitations of these methods by citing their application to a specific problem. The first problem selected for investigation was the behavior of hydrogen in rail steel. This was chosen because the occurrence of shatter cracks in rails has received a great deal of study over a long period of time. The defect can be controlled by the expensive procedure of slow cooling. However, it may be hoped that a better understanding of the factors influencing the hydrogen content of rails will lead to a more efficient control of this problem. Rails provide a good starting point for a more general study of hydrogen in steel because they provide a cross section large enough to develop cracks, yet small enough for convenient handling and sampling. Rails were also selected because they are made from plain carbon steel and it was felt that the initial work should not be complicated by the effects introduced by alloying elements. The considerations which determined the original planning of this study should be reviewed. The inherently complex nature of most hydrogen problems requires that a large amount of data must be collected for any particular case. This in turn means that any analytical procedure should be as rapid and simple as possible. The same objective of speed is indicated by the fact that it may finally become desirable to use hydrogen analysis in process control. It is also known that hydrogen is highly fugitive and that any procedure which facilitates early analysis of the sample without prolonged or irregular storage has distinct advantages. The most important previously reported methods of analysis may be classified into three general groups: (I) Vacuum fusion. (2) Vacuum extraction (without melting). (3) Total combustion.

Jan 1, 1948

By P. J. Noakes

Remote and isolated, located in a frigid, hostile environment, the Black Angel mine in Greenland had to create a warm social environment which would help attract and retain a stable work force of miners and support staff. The high cost of personnel turnover plagues many mines and, when the mine is inside the Arctic Circle, accessible by helicopters which are highly vulnerable to unpredictable weather conditions during the long, dark winters, the potential costs of personnel turnover become critical factors in the success or failure of the mining venture. Manpower planning should start from the date the engineers begin the technical design of the new mine. The plan should include provisions not only to ensure an adequate, skilled work force, but also to ensure a stable work force of people who are happy enough in the mining environment to want to remain, take their vacation and return to work at the mine. The skilled work force was assured with training courses of four months, designed to produce highly specialized underground workers from unskilled Danes and Greenlanders supported by trained Swedish and other Scandinavian miners. The stable social unit was assured by plans the primary attribute of which had to be flexibility. The accommodation changed from shared accommodation with communal washroom facilities to single accommodation with private washroom facilities. A recreational director was hired to help the workers make use of elaborate recreational facilities. A closed-circuit TV and radio system was installed to operate as a private broadcasting system using taped programs originally broadcast on European TV networks or developed by the mine personnel themselves. The liquor rules were changed and the mine manager became a licensed innkeeper responsible for the orderly operation of the Black Angel Bar in accordance with the Danish laws governing the services of a public bar. The result is a relatively stable work force. Some 35% of the people have more than two years' service with the company, Greenex A/S, and some 62% complete 10 months of service.

Jan 1, 1978

By Brandon Buschmeier, Frederic Masse

"Inclusions are a type of ground improvement that provide an improvement of a soil mass by insertion of a material with better characteristics than the surrounding soils. There are primarily two types of inclusions: “Soft” inclusions which are constructed of granular material (Stone Columns, Rammed Aggregate Piers, VibroPiers...), and “rigid” inclusions which are constructed of grout inserted with or without pressure (VibroConcrete Columns, Controlled Modulus Columns, Soil Mixing Columns).While the central principle of the inclusions is similar (i.e., overall improvement of characteristics of the soil mass below the structure), the load transfer mechanism is radically different for each technique. Therefore, the applicable design methodology is specific to the type of inclusions and there exists no universal method of design which spans across all inclusions.This paper will present an in-depth comparison between the standard design methods used for “soft” granular-type inclusions (Priebe modified, Balaam & Booker, Goughnour & Bayuk...) and the methods used for “rigid” inclusions which mainly rely on finite element analysis. The paper will explain why the design for soft inclusion methods cannot be applied to rigid inclusions and vice-versa. Each design method will be reviewed in detail to better emphasize its limitations and advantages.Two case histories will also be presented; one for each type of inclusions in order to illustrate the concepts developed in the first part of the paper.1 INTRODUCTION1.1 GENERAL OVERVIEW OF GROUND IMPROVEMENT WITH INCLUSIONSThe use of ground improvement methods to provide the appropriate amount of foundation support is a growing and constantly evolving industry. Traditional structural foundation methods including ‘shallow’ and ‘deep’ foundations do not adequately address the wide range of settlement tolerances, soil conditions, and loading considerations inherent to each unique potential project. In some instances, ‘shallow’ foundation solutions are simply not feasible due to soil and loading constraints. Furthermore, ‘deep’ foundation solutions are used to ‘bridge’ the soft compressible soils, ensuring that the entirety of the load in the structure is transmitted through individual elements into competent layers below the ground surface (bedrock, dense residual soils). Highly concentrated structural loads are transferred into the individual elements by means of direct contact requiring the use of structurally rigid surficial components (structural slabs, grade beams, and pile caps).Ground improvement bridges the gap between these two traditional methods, offering adequate foundation support while using more costeffective techniques and design methodologies. Inclusions are a type of ground improvement used to provide a reinforcement of the soil mass through the vertical insertion of a material with better characteristics than the surrounding soils. Much like deep foundations, inclusions are installed through soil layers with high compressibility and/or low bearing capacity and terminated in a suitable bearing stratum. However, unlike deep foundations, ground improvement inclusions rely on a distribution of load between the soil and the inclusions. By doing so, some of the structural load is applied directly to the soil in a proportion equal to its bearing capacity and compressibility limits, while the rest of the load is shed into the vertical inclusions down to the bearing stratum. Load sharing is a critical aspect in the performance and design of the various ground improvement methods."

Jan 1, 2015

By James Douglas

IN discussing the waste upon which hinges, or is supposed to hinge, so largely the preservation of our national resources, the conclusions reached would be more reliable if actual ex¬perience were consulted, and fewer deductions were drawn from general statements, which are often the product of the imagination. It cannot be questioned that the value of by-products has not been sufficiently appreciated by us, and that our, tardiness in recovering the useful ingredients of the escaping gas of our coke-ovens is one of the most glaring instances of shortcoming in that direction. And yet even for that sin there is some palliation in the immature condition of affiliated industries. I presume that it is admitted, without argument, that, except under very exceptional conditions, all the elements cannot be recovered from most of the ores or natural products. which we treat. While it is a shame that the by-products from our coke-ovens should be dissipated, Edward W. Parker's report to the U. S. Geological Survey for 1906' supplies a fairly good excuse in justification of this appalling waste. He says (pp. 773 to 774.)

May 1, 1909

By Richard Akerman

At the International Sessions of the Iron and Steel Institute of Great Britain, the American Institute of Mining Engineers and the Verein Deutscher EisenhUttenleute, held in Allegheny City, Pa., in October, 1890, Sir James Kitson, then President of the Iron and Steel Institute, presented an account by Sir Henry Bessemer of the origin of the process which bears his name.? The paper graplhically told how, after the first successes immediately following the first reports given at Cheltenham of the new process, there rapidly succceded such obstacles and difficulties in its practical application, that the whole matter was nearly abandoned in 1858. Suddenly, however, the situation changed, so that at length it became possible

Jan 1, 1894

By J. Zhang, A. J. S. Spearing, L. Ma

Ore deposits are becoming more complex to mine as a result of the exhaustion of surface and other easily mined deposits. There is also increasing socio-political pressure to design more environmentally sound, sustainable, and safe mining practices. Wang and Ma designed a mining method for coal, similar to a modified drift and fill using a continuous miner to take sequential cuts (rooms) that are subsequently backfilled. The authors have modified the concept to make it more autonomous, safer, and less costly using highwall coal mining techniques, modified and adapted for underground applications. The method is more flexible than longwall mining and the percentage extraction would seem to be in the same range. In addition because of the backfilling, surface subsidence would not be a major issue and could be more effectively managed.

Feb 2, 2021

By R. G. Robins

Metal separations based on the selective precipitation of phosphates have a potential application in many hydrometallurgical processes. This paper reviews the literature on the solubility of a number of both divalent and trivalent metal phosphates and presents the result of some additional experimental measurements. The systems examined have been modelled to obtain free energy of formation data for the various species. Computer generated solubility diagrams which are described can be useful in predicting a variety of metal separations.

Jan 1, 1991

By C. B. Clark, W. H. Bruckner

Since the end of World War II interest has been increasing in the use of shaped charges in the mining industry and in other industries using explosives for blasting purposes. Shaped charges employ the principle known as the "Munroe effect," which was discovered by Charles E. Mun-roe more than 50 years ago (in 1888). Details of their design have been explained elsewhere.1,2,3 Fig I shows the essential features of design of two types of shaped charges (with conical and hemispherical cavities) and a schematic sketch of their action upon detonation. The following discussion deals with the behavior of the metal in the cavity liners when they are subjected to intense Pressures exerted when the explosive charge is detonated. Among the conclusions reached in research On shaped explosive charges, the following have been established concerning cavity liners:1'2 I. The optimum wall thickness of a conical cavity liner is dependent upon the apex angle of the 'One as well as On the base diameter of the charge. Acute apex angles require thinner walls for optimum perfmnance and more obtuse angles require thicker walls for the same base diameter' 2. Cones were more effective in forming a penetrating jet when the walls were tapered; that is, the thickness of the wall of the cone increased from the apex down. 3. The physical and mechanical properties of metals have a marked effect upon their performance as cavity-liner material. Boiling point, ductility, malleability, tensile strength, and hardness are among the properties that influence the effectiveness of a metal used as a cavity liner. Lead, for example, makes a wide, flat crater in steel plates. Aluminum makes a deeper crater than lead, and an aluminum alloy having a high tensile strength makes a deeper hole, but slightly smaller in diameter. Cast iron makes a deep, narrow hole. These findings, together with the following analysis under Metallographic Survey of slug, offer solutions to many of the problems involved in solving the mechanism of the formation of Munroe jets. It has been fairly well established that cavity liners collapse in a manner similar to that indicated in Fig 2, Conical liners are known to collapse upon themselves while hemispherical liners are believed to turn inside out in the process of jet formation. The first has been definitely proved by recovery of collapsed portions of cones, while liners from partly detonated charges show that hemispheres may turn inside out. Fig 3 shows a sketch of a recovered slug from a 6-in. shaped charge using a 45° cone made of cast iron. (This size of charge drilled holes up to 3 ft in depth in solid granodiorite.)

Jan 1, 1949

By C. B. Clark, W. H. Bruckner

Since the end of World War II interest has been increasing in the use of shaped charges in the mining industry and in other industries using explosives for blasting purposes. Shaped charges employ the principle known as the "Munroe effect," which was discovered by Charles E. Mun-roe more than 50 years ago (in 1888). Details of their design have been explained elsewhere.1,2,3 Fig I shows the essential features of design of two types of shaped charges (with conical and hemispherical cavities) and a schematic sketch of their action upon detonation. The following discussion deals with the behavior of the metal in the cavity liners when they are subjected to intense Pressures exerted when the explosive charge is detonated. Among the conclusions reached in research On shaped explosive charges, the following have been established concerning cavity liners:1'2 I. The optimum wall thickness of a conical cavity liner is dependent upon the apex angle of the 'One as well as On the base diameter of the charge. Acute apex angles require thinner walls for optimum perfmnance and more obtuse angles require thicker walls for the same base diameter' 2. Cones were more effective in forming a penetrating jet when the walls were tapered; that is, the thickness of the wall of the cone increased from the apex down. 3. The physical and mechanical properties of metals have a marked effect upon their performance as cavity-liner material. Boiling point, ductility, malleability, tensile strength, and hardness are among the properties that influence the effectiveness of a metal used as a cavity liner. Lead, for example, makes a wide, flat crater in steel plates. Aluminum makes a deeper crater than lead, and an aluminum alloy having a high tensile strength makes a deeper hole, but slightly smaller in diameter. Cast iron makes a deep, narrow hole. These findings, together with the following analysis under Metallographic Survey of slug, offer solutions to many of the problems involved in solving the mechanism of the formation of Munroe jets. It has been fairly well established that cavity liners collapse in a manner similar to that indicated in Fig 2, Conical liners are known to collapse upon themselves while hemispherical liners are believed to turn inside out in the process of jet formation. The first has been definitely proved by recovery of collapsed portions of cones, while liners from partly detonated charges show that hemispheres may turn inside out. Fig 3 shows a sketch of a recovered slug from a 6-in. shaped charge using a 45° cone made of cast iron. (This size of charge drilled holes up to 3 ft in depth in solid granodiorite.)

Jan 1, 1949

By Irina Chernyshova, Erik Larsen, Hanumantha Rao Kota, Vladislav Slabov, Garima Jain

The mining industry faces pressure to provide metals for the green digital shift using sustainable technologies. This study evaluates biosurfactants as collectors for ultrafine and coarser particles of hematite and malachite, aiming to improve the flotation of ultrafine particles.

Jun 1, 2023

By H. Golzarpoor

Life Cycle Analysis (LCA) is a methodology for evaluating the environmental impacts associated with a product during its life cycle. LCA is identified as the most reliable method for verifying environmental impacts; however, current LCA-based approaches have certain limitations for environmental analysis of construction products. Integration of the LCA methodology with Discrete Event Simulation (DES) provides a sound framework for modeling and analysing the environmental impacts of construction products. LCA and DES is one possible combination for analysing the cause and effect of various scenarios where time, resources, and randomness of input variables affect the outcome and, therefore, has the potential to address the shortcomings of LCA in construction. Recent studies in disciplines other than construction such as manufacturing systems have revealed positive effects on evaluation of environmental metrics while integrating LCA with DES; however, this integration has not yet been applied for environmental analysis of construction products. By implementing LCA data in a DES model, this research proposes an environmental model of earthmoving operations in a case study. Environmental variables are simultaneously assessed with production variables in the same simulation model and the integration of DES and LCA is discussed.

Aug 1, 2013

By P. A. S. Manning

Eastern Jamaica consists predominantly of non-carbonate rocks reaching elevations of over 2200 m. The area is drained by a well established river network which supplies close to 30% of the sand and gravel used by the building and construction sector. Present high extraction rates and slow rates of replenishment will result in early exhaustion of this source of aggregate. A number of volcanic and carbonate rocks are being examined as a possible source of high quality aggregate which meet the requirements for all types of construction. Preliminary evaluations show a dacitic deposit to be the most suitable source for aggregate use.

Jan 1, 1998

By Å. Sterten, R. Tunold, J. Brun, K. Dalatun

c axis compression behavior of beryllium single crystals at three purity levels under hydrostatic pressures up to 27 kbars was determined. Extensive non-basal slip, observed by two-surface trace analysis and transmission electron microscopy, occurred under a hydrostatic pressure of about 12 kbars (175 ksi) for the high-purity (twelve-zone pass) material and at about 19 kbar (275 ksi) for the lower-purity (zone-leveled) material. Prismatic loops with a (c + a) Burgers vector were observed in association with second-phase parti- A principal factor limiting the use of beryllium is its brittle behavior when tested at the usual strain rates (E = 10-4 sec- 1) at temperatures below about 200°C and under impact conditions at temperatures in excess of 200°C. It has been proposed' that the brittle-ness of beryllium is associated with the lack of a sufficient number of independent slip modes and the absence of a slip mode with a Burgers vector out of the basal plane [presumably (c + a) pyramidal slip mode] and to the ease with which beryllium cleaves on the basal and second-order prism planes. The absence of pyramidal slip has been attributed to a high Peierls-Nabarro stress associated with the motion of dislocations with a (c + a) vector and the ease with which cleavage occurs on the basal and second-order prism planes. The experimental evidence in support of the proposed explanation for the brittleness of beryllium is far from complete; for example, that the ductile-to-brittle transition in polycrystalline beryllium is associated with the operation of profuse (C + a) slip has not been unequivocally established. The occurrence of (c + a) slip ({1122}(1123)) has been experimentally established2-5 under conditions where basal and prism cleavage are restricted in a c axis compression test. In these investigations (C +a) slip was found in high-purity beryllium single crystals tested in c axis compression* at 200°C and in Be-4.4 pct Cu and Be-5.2 pct cles in the lower-purity materials tested. The loops were related to surface "extrusions" observed on many of these same specimens. Nonbasal dislocations operating on (1122) planes with a (c + a) Burgers vector were observed. The presence of c and a dislocations together with (c + a) dislocations suggests that the (c + a) dislocations dissociate presumably on unloading or after failure of the test crystals to c and a dislocations. terial, (c + a) slip has only been observed near the the fracture4 surface in room-temperature c axis compression tests. Fracture in these tests occurs without measurable plastic flow, as determined with a strain sensitivity of 10"6. Since it has been shown for many metals that the application of hydrostatic pressure suppresses fracture,?-' it was felt that studying the behavior of unalloyed beryllium single crystals stressed in c axis compression under a hydrostatic pressure would reveal whether (c + a) can occur if fracture was prevented, and that it might elucidate the role of (c + a) slip in the ductile to brittle transition. Evidence that (C + a) slip is associated with increased ductility in a high-pressure environment has been found in stress-strain tests on poly crystalline beryllium.10 The present paper describes a study on the influence of a hydrostatic pressure environment on the occurrence of (c + a) slip in beryllium single crystals. Material of two purity levels was tested in c axis compression over the pressure range ambient to about 27.5 kbars.* 1) MATERIAL PREPARATION AND CHARACTERIZATION Two lots of low-purity single-crystal beryllium were used. The first lot was "ingot secondary refined grade" and designated lot A. The second lot (lot B) was produced by a two floating zone pass zone-leveling operation in an argon-filled sealed quartz apparatus on a 1-in.-diam by 12-in.-long bar of Pechiney secondary refined-grade vacuum-cast and hot-extruded material. The high-purity material (lot C) was made by traversing twelve floating zone passes through a similar bar of Pechiney secondary refined-grade vacuum-cast and hot-extruded material. In a series of spark cutting and lapping procedures,11 single-. crystal specimens some 0.12 in. sq by 0.30 in. high were made with the sides Parallel to the first- and second-order prism planes and the basal plane within 3' of arc of the top and bottom surfaces of the specimen. Such an accurate orientation is necessary because of the large difference in resolved shear stress

Jan 1, 1970