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By H Allday

The mining industry’s attention has shifted over the last decade with the recovery from the downturn resulting in greater development of innovation and new work methods in a bid to remain competitive and deliver higher productivity. The emphasis on cost reduction to improve profit margins has primarily been the focus of the “work smarter” campaigns embraced within the industry. But is this strategy holistically the best-for-business, or does it place a ceiling on revenue opportunities and inhibit mining companies from truly maximising value? Businesses need to maintain a balance between active cost management and revenue generation often resulting in cost reduction strategies at site level. These strategies have merit, assessing areas of cost wastage across operations and creating space for opportunity. However, this potentially can create distractions from the goal of enabling growth and lead to the sacrifice of quality and delivery. Focusing too heavily on cost reductions without addressing revenue generation is an unprofitable lens to look through, and the relationships between cost, revenue, quality and profit margin can often be overlooked resulting in missed opportunity to maximise value. How these relationships are effectively employed by mining companies to reap the rewards from an overarching corporate perspective down to site level remains a fluid concept depending on the nature, operating market and strategy of the business. A common directive from businesses to their operations is to strive for greater profitability and productivity. The quantification of these requirements, and the nature of the cascading message delivered, impacts the methods employed by the operational team to meet the expectations of the business. Cascaded strategies, if not delivered with appropriate participation and buy-in can often be perceived to be knee-jerk and create frustration for operations who are squeezed to deliver on expectations by slashing site costs. This squeezing is not only felt by the mining operation but at the individual level and can result in increased team stresses. In some cases, this may also steer behaviours towards activities that result in corner cutting and an elevation of operational risk, potentially increasing associated incidents and injury. Driving down costs by any means can create an unhealthy tunnel vision where value is no-longer assessed for best-forbusiness results. By flipping the viewpoint to a value-based approach revenue opportunity may be realised and potentially exceeded, however this opportunity may be missed if value is over shadowed by a cost heavy focus. By analysing a selection of real operational cases (ranging from mining contractors through to in-house mining giants), it becomes apparent that practical revenue maximisation strategies are not only key to an increase in value and cash flow but to a stronger understanding of business drivers for sites and operators alike. In the cases evaluated additional revenue opportunities are foregone in favour of cost reduction strategies resulting in negative impacts on the associated operations and wider businesses. Alignment towards value generation is king. If strategies are not implemented focusing towards value and revenue maximisation, the opportunity loss experienced by mining operations could continue be great and the question should be posed; when the next up-turn hits will operations be ready to reap the rewards or still have a glass ceiling above their heads?

Mar 15, 2021

By M. J. Adam

As part of its research programs, the Bureau of Mines is investigating the partitioning of complex sulfide minerals to simpler sulfide phases by sulfidation reactions. Partitioning in this manner can afford opportunity to improve selective extraction of mineral constituents of value. This report describes research involving the sulfidation partitioning of the mineral pentlandite, which is an important source of Ni in primary production. For the laboratory studies, the pentlandite was synthesized in nominally equiatomic proportions of Ni and Fe. Elemental Ni, Fe, and S powders were blended, compacted, and sealed under reduced He pressure in vitreous silica tubes. The tubes were heated under controlled conditions at SOD? C for 24 h. The product was verified by X-ray diffraction and chemical analysis to consist essentially of (Ni,Fe)9S8. Small samples of the (Ni,Fe) S were encapsulated with sulfur in silica tubes at reduced He pressures and heated for 1 to 24 h at specific temperatures between 400? and 600? C, both below and above the boiling point of sulfur (_445° Cl. Reaction rate increased with temperature. Within this temperature range, partitioning to individual Ni and Fe disu1fides proceeded to essential completion according to the reaction

Jan 1, 1988

By X. -G. Chen, K. Liu

Nowadays, great interests are rising on aluminum alloys for the applications at elevated temperature, driven by the automotive and aerospace industries requiring high strength, light weight and low cost engineering materials. As one of the most promising candidates, Al-Mn-Mg 3004 alloys is found to possess considerably high mechanical properties and creep resistance at elevated temperature resulted from the precipitation of a large number of thermally stable dispersoids during heat treatment. In present work, the effect of Fe contents on the evolution of microstructure as well as high temperature properties of Al-Mn-Mg 3004 alloys has been investigated. Results show that the dominant intermetallic changes from a-Al(MnFe)Si at 0.1 wt.% Fe to Al6(MnFe) at both 0.3 wt. % and 0.6 wt. % Fe. In the Fe range of 0.1 to 0.6 wt.% studied, a significant improvement on mechanical properties at elevated temperature has been observed due to the precipitation of dispersoids, and the best combination of compression strength and creep resistance at 300°C is obtained in the alloy with an intermediate Fe content (0.3 wt.%) with finest size and highest volume fraction of a-Al(MnFe)Si dispersoids. The superior properties obtained at 300°C makes 3004 alloys more promising for high temperature applications. The relationship between the Fe content and the precipitation of stable dispersoids as well as the materials properties has been discussed.

Jan 1, 2015

By W. G. Davenport

Chapters 7,8and 9 calculated three combinations of: blast composition (mass% O2, mass% N2) oil quantity per tonne of concentrate blast temperature that will steadily produce molten 65% Cu matte from pure chalcopyrite-concentrate. The combinations are:

Jan 1, 2001

By P. R. Sahm, T. V. Pruss

Mixtures of fine GaSb and Gds as well as preal-loyed GaSbl,As, powders were hot-pressed at 690°C and 25,000 psi. Dense alloys with compositional gradients of less than 5 pct were obtained from mixtures containing about 20 mol pct GaAs. For x < 0.2, there were increasing compositional gradients, and for x > 0.2 a GaAs-rich second phase appeared in the microstructure. Densification as well as alloying wlechanisms were enhanced by dissociation and, possibly, oxidation reactions of the powders. Densification of coarse prealloyed material, however, primarily depended on plastic flow phenomena and required temperatures just below solidus and pressures of 50,000 psi Thermal and electrical properties were measured. Although in no case was the figure of merit of melt growth materials approached closer than to within 25 pct, the better overall thermoelectric properties were found in coarse-grained, prealloyed materzals which had been compacted to near theoretical density and where grain regrowth had been induced. Similar results are believed to hold in other binary 111-V compound systems if processed under similar conditions. The densification of unalloyed GaSb powders during pressure sintering (= hot pressing) was shown to depend strongly on powder particle size.&apos; Fine powders displayed a "liquid skin effect" that enhanced compaction through the presence of liquid gallium, whereas coarse powders compacted predominantly by plastic flow. The liquid skin effect, in particular, appeared attractive for alloying GaSb with other, higher-melting, III-V compounds, and to densify these in a one-step operation. This is of special interest in the case of III-V compound alloys as the conventional techniques of melt growth or long-time annealing of powders2 is very time-consuming, especially in cases where a large separation of liquidus and solidus can be expected, such as in GaSbl alloys.2 It was felt that experimentation with this system, a particularly unfavorable example, would allow us to extrapolate to several other, more favorable, cases. Uses of Ill-V alloys are most evident in thermoelectric energy conversion devices.&apos; For this reason certain thermal and electrical properties were measured and compared to those of melt-grown material and to hot-pressed prealloyed powders. EXPERIMENTAL PROCEDURE The pressure-sintering apparatus has been previously described.&apos; Using this equipment, both powder mixtures of GaSb with GaAs and prealloyed GaSbl-,As, powders were hot-pressed. The mixtures were pre- pared from cast GaSb and melt-grown GaAs. The prealloyed material was obtained from stoichiometric melts, initially heated to 1200°C in an evacuated quartz ampoule, and then annealed in the solidus-liquidus interval. A typical annealing cycle consisted of a heating to 850°C (1 hr), extended successive annealing at 750°C (65 hr), and slow stepwise cooling (25 hr) to below solidus. The GaSb, GaAs, and GaSbl-,As, materials were ground in a vibrational mill to particle sizes below 500 . A jet mill reduced these further where necessary. Fine powders were analyzed by Coulter counting for their size distribution. Average sizes by volume were calculated from the data. Mixing of the powders, where necessary, was carried out through rapid vibrational motion. The hot-pressing operation consisted of a degassing period of 15 hr, in most cases at 690°C, followed by several hours of compression, normally 25,000 psi at 690°C for powder mixtures and 50,000 psi at 710°C for prealloyed powders. The chemical compositions were confirmed by X-ray fluorescence analysis. To estimate the degree of solid solution achieved, lattice parameters were determined and interpreted according to Vegard&apos;s rule. In addition, optical microscopy helped to correlate the relative amounts of the phases present as well as the degree of porosity to the measured density. To reveal grain boundaries, polished surfaces were etched4 with H 2 O:H 2 O:HCl = 2:l:l. In several cases microscopic concentration gradients were monitored by electron-probe analysis-. RESULTS AND DISCUSSION Alloying and Densification of GaSn-GaAs Powder Mixtures. After preliminary experiments showed that no appreciable alloying took place in mixtures of coarse GaSb (22.5 p) and fine GaAs (2.5 p) powders, hot pressing of mixtures was confined to fine powders only (3.1 and 2.4 p, respectively). Alloying and densification apparently occurred simultaneously with a grain regrowth mechanism which depended on the presence of a liquid phase.&apos; The liquid phase was provided by the dissociation of GasbS particles into liquid gallium and antimony above 555°C. This not only enhanced grain regrowth and densification, as in unalloyed GaSb,&apos; but took on additional importance here for the alloying process. Alloying was speeded up by the resulting liquid-solid interaction as compared to the very slow solid-state diffusion process normally expected at these temperatures.&apos; The results obtained with a series of powder mixtures have been compiled in Table I. It is seen that for mixtures with less than 20 mol pct GaAs, x < 0.2, the compositional ranges increased and for x > 0.2 a GaAs-rich phase and free antimony appeared in the microstructure in sizable amounts.

Jan 1, 1968

By G. Van Weert, A. van Sandwijk, O. W. J. S. Rutten

"Cathodic and anodic reactions in an acidic nitrate medium were studied in reference to the production of electrolytic manganese dioxide from pyrolusite' (Mn02) ores by reductive leaching. Two USA ores were investigated. The reductant for the pyrolusite ore is produced cathodically in an electrolytic cell and can either be nitrous acid (HN02) or nitric oxide gas (NO). In this work emphasis was placed on the nitrous acid leach. In a high-temperature leach in a nitrous/nitric acid medium, manganese and silver are solubilized and iron is not. Anodic electrowinning of manganese dioxide from the acidic manganese nitrate electrolyte yields flaky y-Mn02, similar to that produced from sulfate and chloride electrolytes. Cathodic regeneration of nitrorts acid was studied in a membrane cell in 1.0 M nitric acid and 0.0 to 0.1 M nitrous acid on a' platinized titanium cathode. At cathode potentials ranging from +950 to +700 mV (SHE), cathodic reduction to nitrous acid takes place, at cathode potentials < +700 mV, cathodic reduction of nitrous acid to nitric oxide takes place. A conceptual process is presented and discussed.IntroductionManganiferous-silver oresLarge reserves of manganiferous-silver ores are present in the Southwestern United States and Latin America. These ores are generally refractory to hydrometallurgical methods of treatment, due to the insolubility of the higher oxides of manganese (Mn 4+) in all common lixiviants such as cyanide solutions, dilute sulfuric acid, nitric acid, ammonia, salt solution, thiosulfates, etc. The silver is either bound by the insoluble manganese, or is rendered inaccessible to cyanide leach solution by the surrounding manganese mineralization.Higher oxides of manganese will dissolve if they are first reduced pyrometallurgically to manganous oxide (Mn2+). This is a widely used pretreatment for manganese dioxide ores and subsequent dissolution in sulfuric acid is common. In order to avoid the pyrometallurgical pretreatment with its large energy requirements and gaseous emissions, fully hydrometallurgical processes have been proposed. These processes are based on the presence of a reductant in solution, in order to reduce the insoluble higher oxides of manganese to soluble lower oxides. Aqueous S02 has been proposed and tested on industrial scale by the U.S. Bureau of Mines. After washing, silver could be extracted by cyanidation. The neutralization of the pulp prior to cyanidation however causes problems in filtration and the reagent consumptions are high [1]. More recently, acidified thiourea and bacteria were proposed for the solubilization of both manganese and silver in a single leach step. High extractions were obtained, but drawbacks of these methods are high reagent consumption or slow kinetics [2,3]. For the options of manganese recovery from the leach filtrate, precipitation with persulfate or ammonium carbonate and ion exchange have been proposed. The proposed options for silver reclaim are precipitation with either zinc or Na2S and adsorption onto activated carbon."

Jan 1, 1997

By AIME AIME

THANKS to the excellent preliminary work of: the Division officers and the local committee the fall meeting of the Coal Division at Bluefields was a brilliant success. West Virginia was at its best with its beautiful mountains, good roads and foliage, just beginning to turn to autumn colors. The meeting began on time and was kept on time throughout. The papers were-well prepared and, being on subjects of live interest, provoked &apos;lively discussion. One factor in bringing this about was that they were not too numerous and that with one exception copies had been submitted in advance a sufficient time to permit of them having been studied. The Friday morning session was presided over by John .J. Lincoln of the Crozier Coal and Coke Co. and president of the Pocahontas Coal Operators Association. After brief announcements by Thomas H. Clagett, chairman of the local committee, regarding plans for the two day&apos;s involved, and by Howard N. Eavenson, chairman of the Division, the reading of papers was taken up.

Jan 1, 1931

By T. DebRoy

In recent years rapid technological advances have been achieved in the application of high energy density heat sources such as lasers and electron beams in diverse metals processing operations such as metal refining, fabrication, coating, surface modification and alloying. However, our phenomenological understanding of these new and emerging processes has not kept pace with the technological achievements. Inadequate understanding of plasma-metal interactions, the complexity of the component physical processes, and the scarcity of thermophysical data at temperatures much higher than the melting points of metals are the main difficulties in the comprehensive analysis of these processes. Several unique contemporary issues related to metals processing with high energy density beams such as rapid evaporation of alloying elements during processing and the role of plasma in influencing vaporization rate interfacial tension and species solubility in metals are discussed in this paper.

Jan 1, 1993

By Benjamin P. Hay

Complexation of a metal ion to a ligand often results in structural changes that introduce steric strain within the ligand. A design criterior:1 for ligands that will complex metal ions more strongly is to choose Iigar:1d architecture, that minimizes this strain. This paper describes how molecular mechanics models can be used to define the degree of ligand binding site organization in terms of&apos; ,strain energies associated with conformational reorganization and distortion of the binding conformer. This approach yields a method to predict how modifications to ligand structure will affect metal binding affinity.

Jan 1, 1999

By A. J. Paul Laprairie

The process for which it is to be used is too often the only consideration in the design of a vessel. A de-sign allowing for practical manufacture and erection, as well as for proper maintenance, can often give over-all economies. Most platework in-stalled today is of welded construction. Therefore, metallurgical control is important in its manufacture. Also, because many concentrating and re-fining processes tend to be corrosive, the subject of protective coatings as a part of the manufacturing process is extremely important. The plant de-signer should know how to evaluate and specify controls for the metallurgy and for the coatings. Mining operations are becoming more sophisticated in the field of mechanical engineering. More and more emphasis is being given to preventive maintenance. The first step in any maintenance program, however, is good inspection service. This paper will suggest methods for the inspection of platework, and outline methods for repair and replacement.

Jan 1, 1963

By Richard M. Chamberlin

Perlite is an altered rhyolitic glass with 2 to 5 wt % water that expands or "pops" when heated quickly to plasticity while evolving steam to form lightweight, glass foam. Commercial perlite deposits in New Mexico are well-developed zones of chemical weathering (hydration) superimposed on highly permeable and thick glassy zones at the chilled upper surface and toes of high-silica-rhyolite lava flows and lava domes. The maximum tonnage of glass in these volcanoes was predetermined by their unique eruptive histories. New Mexico perlite production (80% of US production of 571,00 st) is mostly from the 3.9 Ma high-silica-rhyolite lava flows at the No Agua Peaks volcanic center. The primary vent at No Agua is defined by a 900 ft-high rubidium-rich composite lava dome, known as West Peak, that contains minor perlite reserves. Slightly less rubidium-rich lava squeezed out from under the west flank of the dome to form relatively thin (250 ft) but highly vesicular lobate flows that now consist of about 50 % recoverable perlite. Finally, rubidium-poor lavas were extruded from a radial dike on the northeast flank of the dome. These thicker (400 ft) flow lobes contain about 20 % recoverable perlite. The largest mass of lava does not always contain the most perlite. The thinner (west) flow at No Agua yields the largest perlite reserves rather than the large composite lava dome or thicker (east) flow.

Jan 1, 1994

By AIME AIME

THE 1944 Chairman of the Institute of Metals Division might be classed as metallurgically ambidextrous ; he is teacher of theory and practice of both nonferrous and ferrous metallurgy, and he is consultant on brass and on highspred steel. Arthur Phillips was born in Troy N.Y. and attended the New Haven Connecticut high school. Upon graduation he entered Yale, receiving a degree in metallurgy in 1913. At that time Professor Mathewson was starting his plan of &apos;"co-operation with the metal industries in metallographic work at the Hammond Laboratory of the Sheffield Scientific School, Yale University, and Arthur Phillip, became the first co-operative graduate student, working in the laboratory of the Bridgeport Brass Co., and receiving his Masters of Science degree in 1915. A little later, when the department of metallurgy at Yale was expanded. Me. Phillips was appointed assistant professor. In 1928 he was made associate professor, and in 1934 he was promoted to full professor.

Jan 1, 1944

By Ailton Lopes Junior

O projeto desenvolvido na ITM Samambaia – Itatiaiuçu – MG, de propriedade da Mineração Usiminas, teve como objetivo a implantação de um Sistema de Controle e Supervisão através do fornecimento de todo o equipamento de automação e desenvolvimento dos aplicativos de controle e supervisão. Este projeto torna possível a operação remota de toda a planta, através de uma sala de controle central, bem como, a automatização de processos como sequenciamento de partida e parada, e o monitoramento do funcionamento de todos os equipamentos da planta, além de ferramenta de acesso remoto via internet para monitoração e comando da planta, mediante política de segurança de acesso.

Jul 30, 2018

By C Bellia, A Maldonado, S Strong, H Baxter

This paper discusses the technical and cost benefits of alternative data collection techniques used to collect lithological information, obtain laboratory testing samples and perform in situ testing. A comparison between diamond coring and sonic coring techniques is made using data from a recent geotechnical investigation for a final pit slope cut-back. The impacts of the coring method on laboratory strength testing results, material character testing and, ultimately, the mass strength parameters and subsequent slope design adopted are compared. The sonic coring method was chosen out of necessity and enabled the collection of tube samples of a clay unit of interest as well as bulk samples for material character and geochemical testing. The sonic coring generated unexpected degradation of clastic units, while cohesive clay-dominated units were recovered well. The likelihood that disturbance due to the coring method would result in lower than expected triaxial strength results was recognised ahead of time, with surplus samples collected and single-stage triaxial strength testing undertaken. This testing compared favourably with historic three-stage testing, where sample degradation occurred during the later stages. Material character testing of fine-grained, clay-dominated units was comparable with historic diamond core testing, while grain size estimates for more clastic units tended to be finer than previous results. The use of sonic coring over non-cored methods enabled the collection of material texture data, geotechnical properties and a full suite of geochemical analyses. This provided a comprehensive understanding of the lithological and geotechnical character of the rock and soil mass. A high-confidence geotechnical model was developed. The end result was the development of a slope design that was more aggressive than was previously designed (5&#176; steeper inter-ramp angle), which has proven to be appropriate to the conditions following excavation. Overall, sonic coring was a cost-effective means of obtaining additional geotechnical data for the site.CITATION:Baxter, H, Bellia, C, Maldonado, A and Strong, S, 2015. Case study assessing alternative data collection techniques and analysis methods to assist with geotechnical slope design, in Proceedings Iron Ore 2015, pp 419–428 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By A. B. Coates, J. E. Crawshaw

"The use of such methods and apparatus as the Dautriche method and the Mettegang recorder for the determination of the rate of burning of black blasting powder and other strictly burning explosives has been found to give such erratic results that no reliance can be placed on the data thus obtained. Consequently, investigators of those factors which may affect the burning rate, such as size of grain, absolute density, chemical composition, and means of ignition have had to rely mainly on observations made during practical use for determination of the part played by each. Such tests are very difficult of interpretation.The purpose of this paper is to describe a method used by the explosives division of the Bureau of Mines for the investigation of such explosives and to present the results of an investigation using that method.The investigation was concerned with the effect of grain size, initial pressure, and means of ignition on the rate of burning or rate of pressure development of black blasting powder as compared with pellet powder.The Bichel pressure gauge was used for these tests, with the slight modification to the apparatus and method described in U. S. Bureau of Mines Bulletin 15.4 These modifications consisted of reducing the speed of the revolving drum on which the time-pressure record is taken, measuring the speed of the drum by a belt-driven tachometer, and introducing an induction coil in series with the electric squib or electric detonator to mark on the time pressure record the instant at which the squib or detonator was fired."

May 1, 1929

By Paul Torda

El presente texto analiza la posición de la institución educacional como "depósito" de talentos de ingeniería para futuras exploraciones dentro de posibles descubrimientos tecnológicos. En este sentido, la creación de un programa educacional adecuado genera el cultivo de una imagen del talento de ingeniería para los roles técnicos no tradicionales en la industria, como también para el gobierno local y el federal. El plan general involucra no solamente una ruptura con los procedimiientos tradicionales de clases, sino también origina nuevas demandas sobre los estudiantes por la independencia e iniciativa.

Nov 1, 1973

By B Twidle, D Bertoldi, J Meikle, R Dunne

The Waihi Gold Mine is situated in a high rainfall area (annual average of over 2 m) on the North Island of New Zealand. Water treatment and discharge at the mine has been ongoing for the last 25 years. The first water treatment plant consisted of a æstandardÆ water treatment facility (ferric chloride precipitation) and cyanide detoxification. With time the project has expanded and the volumes of water increased requiring additional treatment methods (reverse osmosis) to meet the water quality for discharge. This paper will provide information on the historical development of the water treatment flow sheets, performance data and operating costs.CITATION:Bertoldi, D, Dunne, R, Twidle, B and Meikle, J, 2013. Water treatment at the Waihi Gold Mine, in Proceedings World Gold 2013 , pp 503-508 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Gary B. Williamson, Barton K. Cross

Digital simulation is a modern analysis tool which allows the mine operator to evaluate the result of making a decision without actually changing the organization or buying the equipment. The purpose of this paper is to demonstrate the use of digital simulation in evaluating a decision of whether or not to introduce dispatching in an open pit mine. The analysis shows that appreciable savings can be realized by dispatching. In certain cases, an operator can reduce the number of trucks required to move a specified tonnage. A second analysis evaluates the alternatives of using one large shovel or two smaller units. In this case, the operating cost of the haulage equipment necessary to support the shovels turns out to be the critical factor in this decision.

Jan 1, 1969

By George T. Faust, S. R. B. Cooke

"The Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama, is investigating the preparation of pulverized coal for fuel. In this study the relative amount of surface in various products and samples had to be assessed. Because of the familiarity with screens and because of the simplicity of using the inverse ratio of the opening for ascertaining the amount of relative surface in the respective sizes, screens down to and including 270-mesh were used. This choice was made in full cognizance of the irregularity of screens, but it seemed that if the same screens were used throughout all the tests the relative values would be satisfactory.In dealing with the subsieve sizes, pneumatic elutriation was used to make several fractions to extend the sizing analysis into the range of hypothetical screens. This kind of a sizing analysis was thought necessary because it is familiar to all operators, and, furthermore, it is amenable to several ways of plotting curves that bring out the characteristics of various coals and various methods of grinding.The method of obtaining the data from which to set up the hypothetical screen scale is the subject of this paper. It consists in determining the average projected area of the particles in the respective elutriated products. By extending the ""area method"" to sieve sizes, a factor is found that may be applied to the subsieve sizes, and thus the scale is projected in a regular manner. This method avoids contentions about specific surface and steers clear of ""average diameter"" except as material sized on screens may be said to have an average diameter."

Aug 1, 1939

By D. J. Wesolowski, D. A. Palmer, P. Bénézeth, S. Hilic

The equilibrium solubilities of gibbsite, Al(OH)3, and boehmite, A1OOH, have been extensively studied in our laboratory from 30 to 90°C, and 100 to 300°C, respectively, to ionic strengths of 5 mol.kg-1 (NaC1) over a wide range of pH. The resulting solubility constants have been treated with consistent empirical models that incorporate appropriate experimental data taken from the literature. These studies were initiated in part to understand and quantify scale formation in geothermal fields as a result of fluid re-injection from electric power generating plants. Most of the experimental results were obtained through application of a unique potentiometric method that allows for rapid, precise measurement of the in situ pH and allows the approach to equilibrium to be monitored from under- and super-saturation. The experimental program was extended to deal with more basic solutions (e.g., five molal NaOH), in which the dissolution of boehmite was measured for application to the refining of bauxite by the Bayer process. More recent results in strong caustic solutions at temperatures below 90°C were obtained to investigate the dissolution of aluminum-containing sludge from holding tanks at the Savannah River waste reprocessing site. In this case the solubility enhancing effects (kinetic and equilibrium) of triethanolamine were also established and quantified. Finally, potentiometric solubility experiments were conducted (50°C in 0.l mol-kg-1, NaCl) on aluminum alloy sheets to identify mainly the nature of the aluminum oxide/hydroxide surface layer formed under these conditions.

Jan 1, 2004