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By Carl Rampacek

Recent research by the Bureau of Mines has demonstrated that the segregation process has merit for treating oxidized and mixed oxide-sulfide copper ores. The process comprises heating the crushed ore with salt and coke or other carbonaceous materials at about 700° C. to produce fine flake copper, which then is recovered by conventional copper-flotation methods. Bench-scale laboratory tests of a number of oxidized and mixed copper ores assaying 0.78 to 5 percent Cu gave copper recoveries of 73 to 96 percent. The flotation concentrates assayed 21 to 76 percent Cu, depending on the ore being treated.

Jan 1, 1959

During 1940, the Bahrein Island field produced a total of 7,073,919 bbl. of crude oil- an average of 19,328 bbl. per day. This is a decline of 514,635 bbl. from the I939 production of 7,588,554 bbl. At the end of 1940, there were 70 producing wells.

Jan 1, 1941

During 1940, the Bahrein Island field produced a total of 7,073,919 bbl. of crude oil- an average of 19,328 bbl. per day. This is a decline of 514,635 bbl. from the I939 production of 7,588,554 bbl. At the end of 1940, there were 70 producing wells.

Jan 1, 1941

By L. A. Creglow

IN common with many other companies engaged in the mining and processing of ores, research has always been an important activity of the United States Smelting Refining and Mining Company. Much of this research has been carried on at the various plants of the Company by the operating staffs, and over the years has been an essential factor in developing new methods and improving existing methods of operation. In 1917 arrangements were made with the Massachusetts Institute of Technology under which the Company had the exclusive use of one or two small laboratories in the then newly constructed MIT buildings and the use of the metallurgical laboratories, subject of course to the Institute's needs. After about two years this work was temporarily discontinued but was resumed in 1920 under the direction of G. H. Clevenger, consulting metallurgist for the Company, who recently retired. Becoming cramped for space, the laboratory was moved to a location near MIT on Amherst Street, Cambridge, in 1924. Establishment of a general research laboratory in metropolitan Boston naturally followed from the fact that the head office of the Company was located there and that the library facilities available for all types of research were, and are, unsurpassed. The disadvantages in carrying on research at great distances from the operating units of the Company were always apparent, but with widely scattered plants this disadvantage could not he overcome. With

Jan 1, 1948

By Elmer R. Kaiser

Industry Adopts Research: Seventy-Ave years ago Thomas A. Edison began in a modest way and with limited funds to gather about him men of various talents to form the first industrial research laboratory. His laboratory at Menlo Park, N. J., became famous for many discoveries and inventions, but possibly the most important of all may yet be the industrial research laboratory itself. Today, private industry operates 2500 research laboratories in which 135,000 persons' are directly and indirectly creating new processes and products and improving old ones, as well as developing new information to help keep the fountain of knowledge from running dry. In this change-making function, the scientific personnel comprises 41 pct; the technical personnel 26 pct; and the balance, 33 pct, nontechnical. The term "industrial research" has become so broad as to include almost everything beginning with the search for and discovery of the laws governing the properties of matter and energy to the development and testing of processes, methods, and equipment. These classes of investigation commonly merge so that no sharp boundary can be traced between them. The National Research Council therefore defines industrial research as "the endeavor to learn how to apply scientific facts to the service of mankind."' Currently, expenditures for research by industry are variously estimated at between $450,000,000 to $700,000,000 a year,' or about twice the expenditure for 1940. The President's Scientific Research Board" estimated that the national research and development for 1947 (excluding atomic energy) was as follows: A few companies spend as much as 5 pct of their gross receipts for research, but 1% to 2 pct is considered a good proportion by many." Shortages: Commendable as is the record of growth and accomplishment of science in industry, it is only a beginning. America and the rest of the world have merely sampled the fruits of industrial research; most industries have yet to make research the key to their future. A top research consultant, T. A. Boyd, of General Motors, states ". . . perhaps 90 per cent of all companies still have no research laboratories."Y or example, of more than 17,000 manufacturing concerns whose gross sales exceed $500,000 a year, less than 2500 have research laboratories. A still smaller proportion of the 184,230 manufacturing establishments in 161 industriese have or could afford their own research facilities. Yet, the small and mediurn-sized com,panies with less than 250 employees each, produce one half of the dollar volume of manufactured products.' How are these companies to participate in and share the benefits of research? Boyd gives two reasons for the inadequate number of laboratories in industry: Many people still do not appreciate the importance of research, nor understand its tremendous potentiali-

Jan 1, 1951

By Elmer R. Kaiser

Industry Adopts Research: Seventy-Ave years ago Thomas A. Edison began in a modest way and with limited funds to gather about him men of various talents to form the first industrial research laboratory. His laboratory at Menlo Park, N. J., became famous for many discoveries and inventions, but possibly the most important of all may yet be the industrial research laboratory itself. Today, private industry operates 2500 research laboratories in which 135,000 persons' are directly and indirectly creating new processes and products and improving old ones, as well as developing new information to help keep the fountain of knowledge from running dry. In this change-making function, the scientific personnel comprises 41 pct; the technical personnel 26 pct; and the balance, 33 pct, nontechnical. The term "industrial research" has become so broad as to include almost everything beginning with the search for and discovery of the laws governing the properties of matter and energy to the development and testing of processes, methods, and equipment. These classes of investigation commonly merge so that no sharp boundary can be traced between them. The National Research Council therefore defines industrial research as "the endeavor to learn how to apply scientific facts to the service of mankind."' Currently, expenditures for research by industry are variously estimated at between $450,000,000 to $700,000,000 a year,' or about twice the expenditure for 1940. The President's Scientific Research Board" estimated that the national research and development for 1947 (excluding atomic energy) was as follows: A few companies spend as much as 5 pct of their gross receipts for research, but 1% to 2 pct is considered a good proportion by many." Shortages: Commendable as is the record of growth and accomplishment of science in industry, it is only a beginning. America and the rest of the world have merely sampled the fruits of industrial research; most industries have yet to make research the key to their future. A top research consultant, T. A. Boyd, of General Motors, states ". . . perhaps 90 per cent of all companies still have no research laboratories."Y or example, of more than 17,000 manufacturing concerns whose gross sales exceed $500,000 a year, less than 2500 have research laboratories. A still smaller proportion of the 184,230 manufacturing establishments in 161 industriese have or could afford their own research facilities. Yet, the small and mediurn-sized com,panies with less than 250 employees each, produce one half of the dollar volume of manufactured products.' How are these companies to participate in and share the benefits of research? Boyd gives two reasons for the inadequate number of laboratories in industry: Many people still do not appreciate the importance of research, nor understand its tremendous potentiali-

Jan 1, 1951

By J. R. Tonry

In the grinding of dry non-metallic materials such as rocks, ores, gypsum, lime, and cement clinker, it is recognized that only a relatively small portion of the energy is utilized for actual size reduction, and the major portion of the energy used is converted into heat. As a result, heat is generated inside grinding mills imparting to the ground product a higher temperature than that of the mill feed. In some cases, as for instance in grinding cement clinker and gypsum into finished cement, it may be desirable to keep this temperature increase within certain limits, to avoid any change in the properties of the product and, because consumers may specify a maximum temperature of the finished product for reasons associated, with the tulimate use of the cement. The actual proportions of heat and useful work are somewhat indefinite. Some tests have indicated that nearly all the energy is converted into heat, and. other investigators have found that they could account for "everything except the noise." Investigations sponsored by the American Institute of Mining and Metallurgical Engineers, and carried out with an adiabatic calorimeter, indicated that a surprisingly high 19 percent of the energy might actually be used for size reduc¬tion. However, for the purpose of the following discussion it will be assumed that: (Fig. 1) 10% is lost in motor and gears 10% is lost by radiation and convection from the mill body 10% is used for size reduction, and. that 70% of the energy input leaves the mill as heat in the ground. product. A typical example (Fig. 2) would be a 7x22-ft tube mill operating in open circuit, driven by a 400 hp motor, charged with 77,000 lb of grinding media and producing 70 bbl or 26,300 lb of cement per hour. Reducing this cement from a clinker size of 96 percent passing a No. 16 mesh sieve to a specific surface of 3,230 sq cm per gm (Blaine) will increase the temperature of the cement approximately 143F above the temperature of the feed, as explained later. If the tempera¬ture of the clinker therefore is 125F, the finished cement will be 268F, which in some cases may be too hot. : When cement temperatures approach a range during grinding where dehydration of the gypsum becomes a problem, a logical consideration would be some means of reducing the temperature before it attains the range conducive to gypsum dehydration. Regardless of the varying degrees of heat generated within the mill or mills during grindingto various finenesses, consideration of the maximum safe limit for any type of cement being ground, which may vary fromplant to plant, govern in refining the mill circuit to obtain a safe temperature range. All plants are not necessarily required to do the same cooling job, and may or may not use cement coolers following the grinding circuit. (Not discussed in this paper). In the past, various means have been employed for controlling this temperature increase, Such means have included water cooling of the outside of the mill shell; equipping the shell with cooling fins; injection of moisture inside the mill; ventilation through the mill; and., in cases of closed-circuit grinding, drawing cooling air through the classifier; the purpose in all such cases being to remove heat from the grinding system.

Jan 1, 1958

By Paul Kunze

We have been told many times by legal folks and insurance types about the importance of producing accurate blast reports should you ever get dragged into court. In that venue the investigators will look at the information regarding product type and quantity, it’s distribution among the holes, and delay information in order to arrive at some judgement regarding vibrations or other blast induced phenomena

Jan 1, 2003

By E. S. Machlin, A. A. Hendrickson

Use was made of a recently developed surface-accumulation diffusion technique to measure the self-diffusivity of edge-type dislocation singular lines (Burgers vector along <110>) in a bent and polygonized single crystal of silver. Two factors are involved in obtaining a number for the diffusivity. One factor, the dislocation-line density, was measured by a microscopic technique recently developed, and the value of the other parameter, the effective "diameter" of a dislocation pipe, was estimated. With these parameters equal to 7.3 X 106 dislocations per sq cm and 10-7 cm, respectively, it was found that the self-diffusivity along edge-type dislocation lines was a factor of about two times the average grain-boundary self-diffusivity. The dislocation-pipe diffusivity is about 7x10-7 sq cm per sec at 450°C. THE possibility of short-circuit diffusion through imperfections in crystals has been recognized for some time. It was only recently, however, that concerted effort has been expended to obtain values of diffusivity for grain-boundary short circuits. The work, for example, of Hoffman and Turnbull1 on silver, Fisher&apos;s&apos; analysis of the grain-boundary dif-

Jan 1, 1955

By John D. Smith, Robert J. Mitchell

"There is a world-wide trend toward underground bulk mining methods employing hydraulically placed backfill. This trend is recent and therefore there is little in the literature to assist an operator in the design of backfill properties, the design of drainage facilities, the calculation of the operating forces on a bulkhead, and the control procedures considered necessary before, during and after pouring. This paper presents recommended procedures that are based on over to years of experience in the various aspects of backfilling large openings. Free-draining timber or concrete block bulkheads are shown to be a viable alternative to massive reinforced concrete bulkheads for the containment of backfill pours. Hydrostatic pressures cannot develop in backfills provided adquate drainage facilities are installed.IntroductionThe increasingly adverse relationship between mining costs and mineral values has led mining companies to develop more productive, lower-cost, bulk mining methods. This has led to the increasing use of large, more or less continuous, hydraulically placed backfill pours to enable the recovery of a higher proportion of pillar ore. The success of any bulk mining method depends on the degree of stability maintained during the stoping operations with reference to the mining rate, the performance of the backfill with respect to the per cent extraction of pillar ore, and the control of the mine structure with respect to safety and productivity. One such method has been previously described(I) where a steeply dipping orebody is being mined with a sub-level method that employs large, hydraulically placed tailings pours for delayed pillar recovery. The paper describes the rock mechanics analysis undertaken to establish the stope and pillar geometry and the approach taken to establish backfill strength requirements to prevent dilution during pillar recovery. Production with this method started in 1970 and because few, if any, large bulk pours had previously been used in- this way (judging by the lack of information in the literature), design data and criteria were needed for several aspects of the work. Methods to establish backfill quantities and pertinent ""in-place"" fill properties are described in 2, 3 and 4 in the list of references. Results of field measurements taken to establish fill pressures for bulkhead design purposes are described in 5 and 6. Laboratory large-scale model tests undertaken to confirm a fill strength design equation, which takes into account fill arching, have recently been completed. A paper describing these tests and the results will be forthcoming in the near future."

Jan 1, 1982

By Felipe E. Olivares S

"El presente texto revisa el origen y distribución de los metales raros como parte de un proyecto de recuperación de subproductos de valor comercial en la fundición de La Oroya. Para ello se reeexaminan ocho minerales raros (bismuto, selenio, teluro, cadmio, talio, indio, bismuto, indio de alta pureza), cuya composición de elementos raros se registra en la concentración de algunos productos o residuos. Estos minerales son del grupo del cobre Chalcópirita, Enargita, Tetrahedrita, Bornita y Chalcosita; del plomo: la Galena, Jamesonita y Gratonita, y la Esfalerita que proporciona el zinc. Los concentrados y minerales que entran al proceso de fundición se reparten en tres circuitos principales: cobre, plomo y zinc. Los circuitos de los primeros están ligados entre sí por el sistema de Cottrelles y los procedimientos de las mismas fundiciones, mientras que el último actúa de forma independiente. Por último, es competencia del Departamento de Investigaciones, la recuperación de dichos subproductos a través del proceso de concentración y fundición, como de a búsqueda nuevos métodos en el campo minero y metalúrgico. "

Jul 20, 1956

By Frederick P. Agterberg

It can be useful to model the mean grade values for a metal in mineral deposits containing that metal as representing the extreme value tail of a lognormal frequency distribution for the concentration values of the metal in rocks of all types. Results for copper and zinc in the Abitibi area of the Canadian Shield are compared to results previously obtained for the Canadian Appalachian Region. The lognormal model is also applied to a set of 162 large gold deposits in the Abitibi area. In the second part of the paper, 1311 large and small gold deposits in the Abitibi area are modelled as discrete events. By means of a newly developed spatial clustering model it is possible to predict the variances of random variables for frequencies of deposits in cells of different sizes.

Jan 1, 1979

By Arthur L. Murray

"While serving as surgeon with rescue car No 11 of the U. S. Bureau of Mines, the writer visited the principal metal-mining camps of Utah during the latter part of 1919. In visiting the mines, meeting and conversing with miners, and talking over the medical situation with physicians in the various camps, the number of cases of lead poisoning encountered was great enough to attract attention.With a view to procuring more definite information as to the number and distribution of cases of lead poisoning throughout the State, a study of the records of the State Board of Health was undertaken. Utah had no ordinance re¬quiring the reporting of occupational diseases, so it was not possible to secure data an cases A study of the mortality records by years gave the following results.:Year Deaths from lead poisoning.1910,11911,01912,21913,11914,61915,41916,11917,31918,11919,2These few deaths would seem to indicate a fairly low case rate, but when it is realized that lead poisoning is rarely an immediate cause of death and that the train of sequelae in this disease frequently leads to chronic involvemeets of the digestive, nervous, circulatory or genito-urinary systems, it is apparent that the number of deaths showing lead poisoning as the cause can not be taken as an index of the cases prevalent. The time elapsing between the presence of the active signs of lead poisoning and the terminal illness from pathologic conditions excited by lead absorption may be years, and the initial cause, lead poisoning, is frequently lost sight if entirely, hence the death certificate shows no evidence of the primary cause."

Aug 1, 1921

By D. G. E. Kerfoot

In September 1945, when the Lynn Lake nickel orebody was discovered Sherritt Gordon Mines was a small copper mining company with rapidly depleting ore reserves at its single producing mine at Sherridon in the Cold Lake area of Manitoba, 100 miles north of The Pas. The company has been formed in 1927, largely through the efforts of Eldon L. Brown, a 27-year old mining engineer, with the financial backing of Thayer and Halstead Lindsley and the Gordon family. The Lindsleys were American mine promoters who had been successful in the Sudbury area, and the Gordons had extensive interests in the lumber industry in northern Ontario. Carl Sherritt, who gave his name to the company, was an American trapper and prospector who had staked the copper property and sold his interest to the new company. Carl Sherritt died in a flying accident at The Pas in 1928. The Sherritt Gordon Mine started production in 1931, shipping copper concentrate to the new Hudson Bay copper smelter at Flin Flon, Manitoba. In 1931 the price of copper was 18¢/lb. Within a year the price had fallen to 5¢ /lb and the mine was forced to close. It remained closed through the Depression years.

Jan 1, 1999

By T. Wallmach, S. B. Blancher, A. Delaporte, P. Goncalves

"Fe-Ti oxides concentrates produced from heavy mineral sand deposits are widely used for the production of titanium dioxide pigments that are critical components of white paint, plastics and paper. According to mining industry, the Fe-Ti concentrates mostly consists of three phases: ilmenite, leucoxene and rutile. However, a few mineralogical studies have shown that the variety of Fe-Ti oxides found in sand deposits is far more complex, mostly due to alteration processes. The aim of this contribution is to characterize in detail by means of Qemscan analyses the mineralogy of the three main concentrates (ilmenite, leucoxene and rutile) produced by the Grande Côte Operation (GCO) mineralurgical plant in Senegal. The ultimate goal is to characterize the different products and textures formed during the natural ilmenite alteration processes, to localize the phases carrying the main impurities (Cr and P), and finally to determine the physical properties of each mineral component to improve metal recoveries. Along alteration processes, Ti content increase. Ilmenite (FeTiO3) is progressively transformed into pseudorutile (Fe2Ti3O9) particles which could also be altered and transformed into hydroxylian pseudorutile [FeTi6O12(OH)3.3H2O] or complex blends of anatase microcrystals (TiO2). These transformations are accompanied by significant changes in particle textures. Microporosity and fractures appear and the impurity content also increases. Anatase rich microcrystal assemblages, so far described as Leucoxene, could be identified to consist of grains with higher porosities, water contents and higher intrapore impurities. These particles are the main carriers of chromium and phosphorus. The observed mineral transition textures have a significant impact on the ore dressing processes. During these transformations, the physical properties of these phases change, the magnetic susceptibility as well as densities decreases, due to the increase in porosity. The separation of particles, especially those with high porosity will help improving the GCO mineralurgical plant performance and to reduce the impurity contents in finals products."

Jan 1, 2018

By John S. Carman

Our industry is in trouble. Real trouble. It has never been an easy, secure business. But to-day it is engulfed in revolutionary currents. No longer can there be reliance upon the checks and balances of market forces. Supply and demand largely dictated the economics of business enterprise in simpler days. To-day politics, in particular nationalism become increasingly dominant. And as governments expand and put out tentacles of interference in the direction of the mining industry, far too little understanding is evidenced as to how that industry works. Then there is something which is relatively new -stagflation. As the prices of minerals falls, the capital investment required for new extractive facilities soars at rates which far outdistance those which are cited by governments to indicate the magnitude of inflation. To illustrate; 1) In 1971 it was calculated that $355 million would be required to bring the Cuajone property in Peru into production. Five years later that stage was reached at a cost of $680 million. 2) With the Caridad mine in Mexico, estimated capital investment doubled between 1971 and 1976. 3) The requirements calculated for Cerro Colorado in Panama have risen in two years from $560 to $800. 4) The budget of $240 million for Sar Chesmeh in Iran in 1971 had become $500 million by 1976.

Jan 1, 1977

In the last 40 years, New Zealand has developed a number of liquid- dominated geothermal steam fields, for electricity generation and indus- trial process steam. New technologies were developed, and in this work, New Zealand led the world. The policy of full publication of the results, in a wide range of sciences, provided a reservoir of detailed data defin- ing the geology, size and shape, and the chemical and physical regime, of many geothermal fields and their constituent parts. The discovery of precious and base metal deposits /precipitates in geothermal drill cores and steamfield equipment, suggested a clear link- age with epithermal mineral fields in general, and with that of the Coromandel (Hauraki) Region in particular. Further work on geothermal/ epithermal relationships have implied that the techniques, developed to obtain an understanding of geothermal fields, could be applied also to epithermal mineral exploration. This work is developing fast, and is now proceeding in many coun- tries. Future work may show that the presumed relationship between geothermal and epithermal deposits may be applicable in the wider con- texts of all hydrothermal deposits, and possibly in many other minera- lised areas with volcanic "country rocks".

Jan 1, 1988

By Kenneth N. Han

The effect of anions such as sulfate, chloride and nitrate on the solubility of rare earth element (REE)-bearing phosphates and fluoro-carbonates was examined using relevant thermodynamic data. The study found that these anions have significant influences on the overall dissolution of REEs from various sources in the aqueous media.

Just as geophysics, in the form of 3D seismic and wireline logging, plays a key role in petroleum reservoir management, so too will geophysics play an important role in mining of coal, metals, and minerals in the 21 st century. The commercial and social imperatives driving greater use of geophysics are reduced costs, increased revenues, and enhanced safety. In short, superior utilisation of capital and management of risks. In relatively undeformed sedimentary environments it is possible to adapt petroleum-style 3D reflection seismic to image mines. This has been demonstrated most impressively in the Witwatersrand. Anglo-American, for example, completed a $1 million 3D seismic survey at Western Deeps in order to site a new $300 million shaft with confidence. Likewise, 3D seismic has gained rapid acceptance at Australian coal mines in recent years. Encouraged by these successes, metalliferous mining companies are supporting research in Canada and Australia, as well as South Africa, to adapt 3D seismic for more highly structured, metamorphic terranes. Because the mining industry is far more diverse than the petroleum industry in terms of commodities and geological environments, 3D seismic is not always cost-effective. A plethora of other geophysical techniques can be applied, many of which are employed in mineral exploration. Mine applications of geophysics differ from traditional exploration applications in two main ways: time scales and length scales are shorter, and boreholes are more plentiful. Borehole geophysical techniques therefore play a more significant role, both for logging and imaging. Logging systems detail the variations of in situ physical properties down the borehole at scales measured in centimetres, while geophysical imaging techniques can map features located tens or even hundreds of metres from the sensors. While geologists tend to think of boreholes in terms of chips and core, geophysicists perceive them first and foremost as access paths for instruments. Borehole logging has been employed at iron and coal mines for decades, mainly to accurately define ore boundaries in delineation holes. In base metal mines, Outokumpu implemented logging widely for orebody delineation in percussion holes in the 1980s. The benefit was a direct cost-saving, arising from substitution of core drilling with percussion drilling plus borehole logging. The practice has since spread to other companies. INCO, for example, defines nickel boundaries in blast holes at Sudbury using conductivity logs. The benefits are in the form of reduced dilution and enhanced ore recovery, flowing from a more accurate mine model. Density, natural gamma radiation, magnetic susceptibility, and conductivity are the principal metalliferous mine logging parameters because they can be recorded in both dry and water-filled holes. Sonic velocity is the premier geotechnical logging parameter, given its sensitivity to rock strength, stress, porosity, and degree of fracturing. Sonic is recorded routinely in exploration and geotechnical holes at coal mines. With the advent of slimline dipmeter, full waveform sonic, and optical and acoustic scanner tools, the role of borehole logging in geotechnical evaluations is expanding. Monitoring of strain and micro-seismic activity enhances safety during mine production. While qualitative interpretation of logs is adequate for stratigraphic identification or definition of boundaries, a wealth of quantitative information, eg density, can be derived from properly calibrated, repeatable geophysical logs. Moreover, geophysical logs can sometimes serve as surrogates for geochemical assays, and not only for magnetite and uranium. At OutokumpuÆs Kemi chromite mine, for example, gamma-gamma logging provides the basis for grade control. By reducing reliance on assaying, three benefits can be realised: reduced reliance on core drilling; lower core handling and assaying costs; and shorter turn-around times. Conventional downhole EM and borehole magnetics are used for near-mine exploration, and for ground sterilisation. Inco has enjoyed considerable success with borehole UTEM in the Sudbury Basin, for example, and Geopeko has applied three-component borehole magnetics successfully in the Tennant Creek area. Electrical techniques such as applied potential and magnetometric resistivity (MMR) are also finding application at mines. For higher resolution, borehole seismic, radio imaging, and radar have been invoked, with varying degrees of success, to delineate orebodies and map structures, or to geotechnically characterise the rock mass and identify hazards. Success mapping nickel sulphide shoots with borehole radar has been reported by WMC at Kambalda. There are no universal geophysical panaceas, and each mine imposes different geological, logistical, and economic constraints. Geophysics will not always be cost-effective. However, the greatest single impediment to expanded use of geophysics at mines has been the low level of awareness of geophysics on the part of most mine geologists, engineers, and managers and, equally, the limited understanding of mine geology and engineering exhibited by the majority of geophysicists. This myopia will be remembered as a 20th century affliction! Blue Sky areas for mine geophysics in the next ten years include integration of geophysical data acquisition with drilling, enhanced grade estimation and rock mass characterisation, and the incorporation of geophysical information into mine models using geostatistical techniques. All these advances will be predicated on an expansion of petrophysical knowledge.

Jan 1, 2000

By R. T. Southin

Cast ingots of 99.99 pct purity A1 and aluminum/copper alloys containing up to 2 pct Cu have been found to contain four zones rather than the three previously accepted, i.e., chill, colummar, and equiaxed zones. The fourth zone consists of a coarse dendritic layer across the top surface of the ingot which is open to the atmosphere. It is also found that the grains in the equiaxed region have a "cornet" shape, with a head which is coarsely dendritic and a tail which grew with the same structure as the columnar grains. Experiments using mechanical barriers, and others involving the elimination of the surface dendrile layer, have indicated that nucleation of the equiaxed zone is caused by the showering of dendritic particles from this surface dendrite layer. These particles are the dendritic heads found in the comet grains. A mechanism of nucleation and growth of these comet grains is put forward. Experiments with a number of other metals and alloys suggests that these conclusions may apply generally to ingots cast without the addition of nucleating agents, and solidified under normal conditions. THE macrostructure of cast ingots may contain the following three zones: i) a peripheral zone of fine equiaxed grains, commonly called the chill zone; ii) a zone of columnar grains extending inwards from the chill zone; iii) a central zone of equiaxed grains; these are normally larger than the chill grains. All three zones are not necessarily present in any particular ingot since their existence and magnitude depend upon the casting conditions and composition of the cast material. The mode of formation of zones i and ii is fairly well understood. However, the cause of the central equiaxed zone remains a matter of conjecture. Previous theories put forward to explain the mechanism of nucleation in the equiaxed zone have been examined by Chalmers1 and Winegard.2 At the time when the present work was carried out the most re -cent hypothesis was that due to Chalmers,1 who recognized more fully than previous workers that conditions in this zone during solidification were not conducive to nucleation. In his hypothesis, he suggested that nuclei were formed near the mould wall during the very early stages of solidification, and that they can drift into the central zone by convective motion. This was supported by evidence from experiments using mechanical barriers to stop the drift of nuclei. A similar hypothesis had previously been put forward by Genders.3 More recently, Jackson et al. 4 have observed that dendrite arms in organic compounds can melt off during solidification. They have postulated that this occurs in metals and alloys, and that the dendrite arms which have been freed from the main dendrite act as nuclei for the equiaxed zone. In the present work, critical metallographic examination has shown that there is a fourth zone in the macrostructure of cast ingots which is a dendritic layer over the top surface of the ingot. It is also shown that there is a relationship between this zone and nucleation of the equiaxed zone. EXPERIMENTAL DETAILS The alloys examined were prepared from super -purity aluminum of 99.99 pct min purity (spectro-graphically detected impurities of Cu, Fe, Si, and Mg) and copper of 99.98 pct min purity (spectrographically detected impurities of Si, Zn, As, Fe, Pb, Bi, Ni, Sn, Mn, Ag, Cr, and Al). Three compositions of ingots were examined, containing 0.0, 0.1, and 2 pct Cu, respectively. The alloys were melted in an alumina-lined salamander crucible using a medium-frequency electric induction furnace; when the appropriate casting temperature was reached, the alloys were cast without degassing or fluxing treatment. The mould used was made of electrode graphite and had the following dimensions: external diameter 6 in., height 9 in., with a mould cavity 8 in. deep and a diameter tapering from 5 in. at the top to 4 in. at the bottom. Casting temperatures used were generally in the order of 70" to 90°C above the liquidus and the mould was at room temperature before casting. Inserts kere placed in the mould cavity in some experiments. These consisted of either an 18-g stainless-steel tube of 2 in. diam held axially in the mould i in. off the bottom and extending 1 in. out of the top of the mould or a "trap-door" barrier of stainless-steel gauze of 24-mesh held horizontally in the mould 31/2 in. down from the top. The construction of this insert is shown in Fig. 1. All inserts were preheated prior to casting to prevent chilling. RESULTS The macrostructures of ingots of the three compositions are described, in terms of the three generally recognized zones, in Table I, and illustrated in Figs. 2(a) to (c). The most interesting observation in this table is that relating to the shape of the equiaxed grains, which were not in fact equiaxed but of almost tear-drop shape. Closer examination of these grains showed that each consisted of a head which had a coarse dendritic structure and a tail which always grew in the opposite direction to heat flow, and which had the same structure as that of the columnar material of the ingot concerned; i.e., in the pure aluminum and 0.1 pct Cu alloy it was cellular and in the 2 pct Cu alloy it was cellular-dendritic. Identification of original cast grains was greatly hampered in the super-purity aluminum ingots, and to a lesser degree in the 0.1 pct Cu alloy,

Jan 1, 1968