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By K. Heatwole, D. Shier, A. Davis, J. Kidder, S. Sunkavalli

"Acid rock drainage (ARD) is produced when sulfides are exposed to oxygen and water. Oxidation reactions typically result in a depression of pH and leaching of solutes and metals. Many oxidation models have been developed based on oxygen diffusion, but in environments with high permeability, other transport processes (i.e., convection and advection) can play an important role. Multiple sulfide mineral phases with differing oxidation rates should also be incorporated. WROC, a finite-difference model, was developed to account for these factors in predicting ARD. The program includes sulfide mineral oxidation using a shrinking core mechanism, heat transfer by conduction, heat of reaction and oxygen transport by diffusion and advection. The model was validated using data from the literature. After validation, the WROC model was used to simulate several different waste rock scenarios, including different forms of sulfide mineralization and the effect of implementing a waste rock cover. The results demonstrate that including specific sulfide mineral phases can have a significant effect on oxidation and that implementation of a cover can also aid in reducing waste rock oxidation.IntroductionAcid rock drainage (ARD) is a notable environmental concern in areas where rock or other material with acid generation potential is disturbed. ARD is defined as drainage that occurs as a result of sulfide oxidation in rock exposed to air and water. ARD is characterized by low pH, elevated metals concentration (especially aluminum, iron and manganese), sulfate and high total dissolved solids. The low-pH water that results from acid generation is capable of solubilizing heavy metals contained within the rock. The principal sulfide mineral in mine wastes is pyrite (FeS2). Pyrite oxidation is complex and can involve chemical and biological reactions. Oxidation of pyrite by atmospheric oxygen produces one mole of Fe2+, two moles of SO4 2- and two moles of H+ for every mole of pyrite oxidized, as described by Eq. (1)."

Jan 1, 2015

By G du Toit, P L. Gillot, M Swanepoel

Randgold Resources’ Loulo-Gounkoto Complex is one of the largest gold mining operations in Mali, West Africa. The mine, which is situated on the western border with Senegal, treats more than 4 Mt/a of ore through a conventional three-stage crushing and ball milling circuit followed by a carbon-in-leach plant. Ore supply is achieved by a combination of open pit and underground mining, with the majority of the ore supply sourced from the Gara and Yalea underground mines situated approximately 2 km and 6 km respectively from the gold plant.In 2011, Randgold Resources commissioned Golder Associates to perform an evaluation study for providing structural backfill to both the Gara and Yalea underground mines using the current gold plant tailings. The test work performed as part of the evaluation study concluded the need for a tailings cycloning and dewatering facility capable of producing slurry at a solids concentration of 65 per cent with a particle size distribution that had minimum 25 per cent passing 20 µm and less than 5 per cent of -5 µm material. Tailings desliming was required to ensure a consistent feed quality to the paste preparation plants and to ensure that the system would be capable of handling variation in the feed composition from the gold plant.WorleyParsons, previously TWP Projects, was contracted by Randgold Resources to complete the engineering design for the slurry preparation plant, whilst Golder Associates was retained to complete the engineering design of the two paste preparation plants.This paper discusses the test work, design considerations and engineering design of the slurry preparation plant, termed the ‘intermediate plant’, as well as all ancillary facilities required for the delivery of the deslimed slurry to the paste preparation plants located at the two underground mines.CITATION:Swanepoel, M, du Toit, G and Gillot, P L, 2014. Case study – engineering design for a slurry preparation plant for a paste application in West Africa, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 477–486 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By H. E. Hirsch

Propelled by the invention of the transistor at Bell Laboratories, germanium's unique properties have advanced our electronic world by many years. Germanium has found major uses in infrared optics, fiber optics and a revised vigor as a catalyst for PET plastic production. Other advanced applications are in various stages of development. The solid state electronics industry has been the driving force behind the accelerating demand for gallium since the late sixties. Past developments of substrates for light emitting diodes, lasers and magnetic bubble memories are paling in view of the current excitement over the use of semi-insulating gallium arsenide for high performance integrated circuits. This application requires gallium metal and gallium compounds of extraordinary purity.

Jan 1, 1986

By Bora Derin

The partial pressure ratios of sulfur and oxygen for several copper flash smelting plants were derived using the Reddy-Blander (RB) model and predicted dissolved sulfur contents available in the literature. The sulfide capacities (Cs) of six different flash smelting plants (FeO-CuOo.5- CaO-MgO-FeOu-AlO15-SiO2) slags were calculated. The log (PO2/PS2) versus matte grades of various industrial processes was determined. The PO2/PS2 ratio increased with an increase of copper grade. The calculated partial pressure ratios for the copper flash smelting are in good agreement with those of the experimental data.

Jan 1, 2003

By A. E. Flynn

Introduction The purpose of this paper is to record the results of researches on anhydrite that have been undertaken at the Nova Scotia Technical College during the last two or three years. The work was carried out in the Mining Department of the College, and several investigators were engaged on the work from time to time. Messrs. R. E. Hanson and K. M. Ed devoted their mining theses to the investigation, and Messrs. J. C. Hall and G. W. Baker were engaged on the work during the summers of 1928 and 1929, respectively. The writer was responsible for the initiation and direction of these researches, which were made possible by the financial assistance of the Department of Mines of the Province of Nova Scotia. Nova Scotia is the leading Province in Canada for gypsum production, its output being about a million tons per year, or over 80 percent of the production for the whole of Canada. The commanding position of Nova Scotia in this regard is due to the abundant supply of gypsum and its proximity to areas of intense utilization in the eastern United States. The resources of gypsum are contained in a total area of 627 square miles of gypsiferous rocks, so that an enormous reserve of this mineral is available. Present operations are confined to the highest grade and most easily worked deposits close to water transportation.

Jan 1, 1930

By R. L. Summers

The tremendous engineering advances occurring during this past century are very evident within the boundaries of the Anthracite Section of AIME. The Steelton plant of Bethlehem Steel Corporation, located along the Susquehanna River just east of the Commonwealth's capital at Harrisburg, for more than 105 years has experienced a most dynamic life which has paralleled America's industrial growth. (Figure 1) In June 1865, just after the Civil War, a group of men met to organize the Pennsylvania Steel Company. The war had brought into sharp focus the vital importance of the railroads to the country's expansion. Until that time wrought iron rails were used, and the replacing of track after only several months wear had become an almost unbearable cost. The spirit of free, competitive enterprise and the prospects of a lucrative market compelled these men to form that first Pennsylvania Steel Company and to develop better rail products. They issued the following statement: "...our desire to free ourselves from dependence upon a foreign market (has) led to the organization of the Pennsylvania Steel Company, and the parties who have connected themselves with it are determined to produce upon American soil all the principal manufactures of steel that are now, at such a serious cost for freight, commission, insurance, exchange, duty, etc., and often, with so much delay and uncertainty, imported from abroad. (We) are preparing to establish near the consumer, works at which articles of accustomed pattern will be promptly produced, and from the

Jan 1, 1971

By H. A. Oaks

FROM 1921 to 1939, the aeroplane played an increasingly important role in Canadian prospecting and mine development. This service has been interrupted by the war, but undoubtedly it will be accelerated in the postwar years, if suitable aircraft are available. The purpose of this paper will be to review the uses to which the aeroplane has been put in prospecting and development in the past, and its future possibilities as an aid in prospecting. If by review, and deduction, we get a clear picture of what we expect the prospecting plane to do, we may be able to arrive at a very close approximation of its required characteristics and, from this, an idea of costs. 'Function' is defined as the mode of action by which it (the aeroplane) fulfills its purpose. We will endeavour, therefore, first to find what this purpose is, or should be, so that our expectations will not be too limited nor too great-and then find, by analysis, what performance we require in an aeroplane to meet our reasonable expectations at an economic price.

Jan 1, 1945

By Baohua Guo, Xuelin Yang, Tingkan Lu, Hailin Sun

The work presented in this paper mainly involves two parts. Firstly, the fundamental characteristics of the high pressure carbon dioxide gas fracturing technique (CO2 technique), including, a proposed method of TNT equivalence calculation, which is used to calculate the TNT equivalence of discharge of CO2 technique, and the comparison of the explosion volume generated by dynamite and expansion volume of liquid carbon dioxide is conducted to show the differences of fragmentation capacity between the two of them. Secondly, the coal seam fragmentation mechanisms of CO2 technique are proposed, including, 1) Gas jet cutting and penetration by shaped charge, 2) Gas volume expansion by changing phases of carbon dioxide, 3) Coal seam softening by destress blasting and 4) Coal seam fragmentation by discharge vibration, associating with the mechanisms, the equations for calculating fragmentation radius are developed and verified.

Jan 1, 2017

By W. H. Hannay

Introduction The subject matter of this paper will be treated under two heads: (1) experimental work and the development of the purification system, and (2) the operation of the commercial plant. During 1927-28, a two-ton slag-retreating plant was in operation at the smelter for experimental purposes. Details of this operation and of the commercial plant are presented in a paper by G. E. Murray, read before the Annual General Meeting of the Institute in April, 1933 (1). A point which has considerable bearing on the subject of the present paper, and which was not emphasized by Mr. Murray, is the concentration of volatile impurities in the zinc oxide fume produced. The result of the operation of the slag fuming furnace is largely to confine in a closed circuit all the minor constituents of the Sullivan concentrates, both lead and zinc. They pass into the feed of the zinc fuming furnace, with the result that all impurities which volatilize-such as arsenic, antimony, tin, fluorine, etc.-report in the zinc oxide product. The accompanying condensed flow-sheet (Figure 1) will illustrate this. The only outlet for impurities which is not shown is the small tonnage which passes the Cottrell plants. The flow-sheet would indicate the possibility of building up a prohibitive concentration of cathodic impurities in the oxide leaching plant feed. However, after three years' continuous operation this has not occurred. Should this condition arise at some future date, discard of some tonnage of blast furnace slag is indicated. In Mr. Murray's paper, the much greater flexibility of blast furnace operation, due to the slag fuming furnace, is stressed, particularly as to the lead content of the slag. The requirements of our lead refinery call for a bullion containing about 0.70 percent antimony.

Jan 1, 1934

By Guojun Qi

This work relates to wafer bumping technologies for flip chip packaging applications in the electronics industry. Nickel and its alloys are alternative under bump metallization (UBM) materials because of their slower reaction rates with Sn-based solder as compared to Cu-based UBMs. In this study, we compared the morphologies of the intermetallic compounds (IMC) formed between Sn-bearing solders (Sn3.5Ag and eutectic Sn-Pb) and two types of nickel- based UBMs, electroless Ni-P (EN) and sputtered nickel. Both chunky-type and needle-type of intermetallics were observed between the EN UBM and the solders. In the case of sputtered Ni UBM, there is only a layer of scallop-type intermetallics formed. The morphology change and growth kinetics of the IMC in thermal aging process were analysed. Kirkendall voids were noticed from samples of Sn3.5Ag solder vs Ni-P UBM that have undergone prolonged thermal aging at high temperature.

Jan 1, 2003

By R. M. Barker

The historic Getchell property is currently being mined from the Getchell Main Underground workings, a foot wall extension of the Getchell open pit deposits along the Getchell fault. Drift-and-fill techniques are used to extract the ore through a ramp access. The adjacent Turquoise Ridge deposit is currently under development via two vertical shafts. Together, the two mines will continue to provide feed to the Getchell's 3,200 tpd mill/autoclave circuit, taking Getchell Gold from its current production rate of 200,000 ounces (Au) per annum, to over 400,000 ounces (Au) per annum by 1999.

Jan 1, 1997

By Hanns J. Billmayer

This report, which covers the period from June 15, 1974 to May 30, 1975, describes the work performed in compliance with the requirements of Contract No. H0242065 and modifications 1, 2, and 3 thereto. The purpose of the original contract was to equip the second shuttle car in the Jewell Ridge No. 12 mine, section 6R, with a refined design canopy and seats. In addition, several refinements and improvements were to be designed and installed at the same location on the cutter and the loader. However, during October 1974 in response to a request from the Technical Project Officer, the contract was modified to eliminate all of the cutter and loader tasks and substitute the design, fabrication, and installation of an improved canopy on the no. 2 roof drill in the above mentioned section of the Jewell Ridge No. 12 mine.

Jan 1, 1975

By Gordon M. Pugh, David G. Rasmussen

INTRODUCTION Sublevel long-hole stoping is a large tonnage stoping method that may be used when there is a fairly com¬petent straight vein and the walls will stand with little support. It is a method that lends itself to a high degree of mechanization. Two variations of the method are illustrated in Figs. 1 and 2. Fig. 1 illustrates development typical for a 3-m (10-ft) wide vein. Initial development is by a lower haulageway, which may be either track or trackless. A two-compartment raise is driven in the footwall of the vein. At about 12 m (40 ft) above the main head¬ing, a footwall scram is driven and pockets through the vein are cut on 7.6-m (25-ft) centers. Each of the sub¬level blocks selected in this example is 45.7 m (150 ft) long by 12 m (40 ft) high. Stoping starts at the slot raises at stope endlines and retreats to the timbered raise. This retreat sequence starts on the lowest sublevel and the opening cut is blasted into the slot raise. This retreating system is used in order to provide a good safe back over the miners working in any given sublevel. A crawler-mounted down-the-hole or conventional pneumatic drill puts the holes down from one sublevel to the next on any desired drill pattern. Gravity flow brings the broken ore down to the scram level. The illustration shows a large slusher mounted at the timbered raise and slushing from the pockets back to the raise chute. Development of the ore block in Fig. 2 is typical for a 5.5-m (18-ft) wide vein. Initial development is by a trackless heading driven in the footwall of the vein. Pockets are then put into and through the vein on 7.6-m (25-ft) centers. For ease in using trackless rubber tired mucking equipment, these pockets are crosscut to the vein at approximately 1.04 rad (60°) rather than per¬pendicular. A two-compartment timbered raise is driven down from one level to the next. Endline slot raises are again put through from level to level. Each of the sub¬level blocks selected in this example is 40-m (130 ft) long by 33.5 m (110 ft) high. Stoping starts at the slot raises and retreats back to the timbered raise. Long holes are drilled from one sub¬level down to the next by starting between the lowest pair of sublevels and then working up the ore block. Mucking out of the pocket drawpoints is accomplished by rubber-tired load-haul-dump (LHD) units which then dump into a centrally located orepass.

Jan 1, 1982

By J. A. S. Tenorio, K. S. Barros, D. C. R. Espinosa

In the last decades, authors have been focused in the development of a cyanide-free bath for the electroplating industry of brass due to the risks that involves the use of cyanide and they have been evaluated the electrodialysis as an alternativemethodforthetreatmentoftheeffluentgeneratedinthistypeofindustry because ofthe limitationscaused bythe chemical precipitation. Hence, thepresent paperaimedtodeterminethelimitingcurrentdensityoftheeffluentgeneratedinthe free-cyanide electrodeposition of copper and zinc using EDTA as chelating agent for the treatment of the effluent by electrodialysis. The synthesized solutions were preparedwith copper sulfate andzinc sulfate indifferent conditionsofpH (10–12) and proportion of cupric ions (30%, 50%, 70%). According to the results, the increase of pH and the cupric ions proportion caused an increase in the limiting current density because of the larger amount of anionic species in solution and the consequent difficult to achieve the concentration polarization phenomenon. (cid:1) (cid:1) (cid:1)

Mar 1, 2018

By A R. Bullis

Metal Mines Limited (Bancroft Division) was incorporated m 1964 to take over the assets of Faraday Uranium Mines Ltd., including their uranium deposit near Bancroft. Ontario. This paper outlines the geology of the Bancroft area, and. then go on to describe the principle rock types m the mine workings, especially the pegmatite, which is the host rock for the uranium mineralization. The structure and mineralogy of the orebodies are thoroughly covered, and, after a summary of the production and ore re-serve figures, the paper concludes with suggestions for further exploration work. Location and History M ETAL Mines Limited, Bancroft Division, is located in Faraday township, Hastings county, Ontario. The main production shaft and concentrator are about: Y2 mile north of Highway 28 and about 5 miles west of the village of Bancroft (Figure 1). The presence of radioactive minerals in the Ban-croft-Wilberforce area has been known since the early 1920's. Uraninite was found at the Richardson deposit near Wilberforce in 1922, and some attempts were made to produce radium from the deposits of the area between 1929 and 1931.

Jan 1, 1965

By Isabella Lancellotti, Fabrizio Passarini, Luisa Barbieri, Fernanda Andreola, Ivano Vassura, Luciano Morselli

"The techniques able to incorporate wastes by means of a heat treatment present the advantage to fix the residue with chemical bonds. Among these techniques there are vitrification and sintering which are characterised by different operating temperatures in the range of 950-1500°C and the involved raw materials develop silicatic crystalline phases and glassy matrices capable to immobilize heavy metal contents in the waste matrix. In this work incinerator bottom ash, polishing and glazing ceramic sludges have undergone to thermal treatments in order to valorise the waste as secondary raw material for the obtainment of re-products. The chemical efficiency of the process adopted has been evaluated by comparing the results of release tests applied to the as-received wastes and to the thermally treated materials in order to verify the effectiveness of the different matrices to fix the waste components.IntroductionVitrification is one of the most promising technological options for the treatment of some kinds of waste. The high temperature involved in the process (1200-1500°C) leads to the complete destruction of organic pollutants, such as dioxins, and glassy network formed can incorporate heavy metals. Some vitrification processes naturally occur: glasses produced by volcanic eruptions, such as obsidians (Na2O-K2O-Al2O3-SiO2) and basaltic (CaO-MgO-Al2O3-SiO2) rocks, are basically inert materials even when they contain toxic elements, because these are embedded in an extremely stable glassy matrix. The disadvantage of vitrification is that it is an energy-intensive process involving relatively high costs, therefore its use is better justified if a high-quality product with optimised properties can be fabricated. The most effective way to improve the properties of the vitrified material is the transformation into glass ceramic. This is a fine-grained polycrystalline material (typically from 50% to 98% of the volume may be crystalline) formed when a glass of suitable composition is heat treated and hence undergone to controlled crystallisation (phenomenon named devitrification). The three key variables in the design of a glass-ceramic are: glass composition which controls glass viscosity related to the effectiveness of nucleation and rapidity of crystallisation; glass-ceramic phase assemblage (that is, the types of crystals and the proportion of crystals to glass) which is responsible for many of the physical and chemical properties; nature of the crystalline microstructure (crystal size and morphology and the textural relationship among the crystals and glass) which is the key to many mechanical and optical properties. In particular, a partly crystalline material can be obtained by powder sintering."

Jan 1, 2008

By R. J. Pugh

In addition to directly analyzing the surfaces of minerals using high vacuum instrumentation methods, some important surface properties of mineral fillers can be determined indirectly by using reactive chemical probe molecules. This technique enables the strength and the number of the surface reactive sites to evaluation and this type of information is useful in predicting interfacial behaviour of minerals. One method of classifying these surface sites is by using Lewis acid/base theory and this type of approach could enable one to predict the adsorption of functional groups in dispersants, thickeners, pigments, etc. Also the adhesion of polymer matrices to the filler surface may be improved.

Jan 1, 1992

By D. M. Clippinger, J. J. Eidel, J. E. Frost

At Ithaca Peak, one of three peaks situated on Duval Corporation's Mineral Park property, a 'Single pulse of quartz monzonite magma intruded the isoclinally folded Precambrian Cerbat complex consisting of schist, quartzfeldspar gneiss, and amphibolite. The magma reacted with the Precambrian rocks, yielding a quartz-diorite rim. As the magma crystallized within the rim, it produced, progressing in'ward, annular bodies of quartz monzonite porphyry, quartz porphyry, and a distinctive quartz porphyry containing abundant podiform, tabular, and irregular quartz masses. These quartz masses are spatially associated with discontinuous crenulate and tabular quartz veinlets. Following crystallization, the Ithaca Peak stock and part of the surrounding Cerbat complex were fractured, producing a stockwork of predominantly northwest and northeast-trending fractures. The stockwork was then mineralized during a period of decreasing temperature by: ( 1) quartz-pyritechalcopyrite veinlets without distinct selvages and with distinct alteration envelopes in which orthoclase was altered to quartz and sericite; (2) quartz-pyrite-chalcopyrite veins and veinlets with distinct selvages and without distinct alteration envelopes; and (3) pyrite-chalcopyrite- galena-sphalerite veins. The Ithaca Peak stock was pervasively sericitized or argillized. The Mineral Park property is surrounded by a zone of propylitization Alteration and mineralization are coextensive in space and were, at least in part, coincident in time. The Mineral Park property possibly was elevated and exposed twice prior to its present exposure. The protore has been enriched by a factor of three. The Ithaca Peak supergene ore body is conformable with present topography and lies above the present water table. The shape of the ore body was controlled by erosion and oxidation of the previously enriched mineralization. Hematite, goethite, and jarosite present at the surface indicate a high primary pyrite environment, but it is possible to recognize that a small proportion of veins and veinlets contained greater amounts of chalcocite and chalcopyrite than pyrite. The igneous facies on Ithaca Peak are the products of differentiation within a solidifying rim according to Bowen's Reaction series. The innermost facies contain more quartz and orthoclase than the outer facies. Late magmatic quartz in the case of Ithaca Peak contains small amounts of pyrite and molybdenite. It is suggested that this quartz-sulfide mineralization, may also have been the product of differentiation the product of differentiation, may indicate that the later hydrothermal mineralization may also have been the product of differentiation.

Jan 1, 1968

By Y. Guan

The adsorption of zinc species onto silica in ammonical solutions has been studied. Adsorption isotherms reveal that increasing adsorption occurs as the solution pH is made more alkaline. Fr-IR spectroscopy revealed that the adsorbed species is a zinc ammine complex.

Jan 1, 1993

By B C. McLellan

The decline of ore grades on land, increasing demand and high prices for various minerals have led to an increased interest in mining the deep ocean sea floor. The potential deep ocean reserves are vast and in some circumstances the grades are high enough to consider mining. However, the consequences of such mining are as yet uncertain. This paper will present the results of a comparative assessment of life cycle impacts of deep ocean minerals. Two alternative extraction technologies from different deep ocean resource types were examined and key commodities are considered. Initial results indicate that the energy requirements will be higher than the average land-based resources, but may fall within the range of the deepest terrestrial mines.CITATION:McLellan, B C, 2015. Comparative life cycle impacts of deep ocean minerals and land-based counterparts, in Proceedings Third International Future Mining Conference, pp 253–260 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015