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By Manuel Gomez

This report presents prediction equations for eleven factors indicative of metallurgical coal quality which have been developed from data obtainable during exploration. Five coke strength parameters and six carbonization product yields have been predicted for coking coals having volatile matter contents in the range 16.3 to 42.1 percent, dry basis. The prediction models developed contain information from the proximate and ultimate analyses, the size consist, and the petrographic composition of coking coals carbonized in BM-AGA retorts at 800°, 900°, and 1,000°C. The equations reported have been evaluated with independent data derived from the 900°C carbonization of 33 binary blends. Present results show that metallurgical coal quality can be predicted ahead of mining. Capability to forecast coal quality is useful in mine planning and should provide basic information for optimization of blending and crushing techniques, leading to the production of uniform coke.

Jan 1, 1968

By G. D. Sandrock

The science and technology of roan temperature rechargeable metal hydrides began about 1969 with the discoveries that the intermetallic Compounds LaNi5 and TiFe could be, conveniently hydrided and dehydrided at roan temperature and modest H2 pressures. Subsequently, this lead to the development of a broad family of REE-containing AB5 hydrides and numerous applications that make use of the extraordinary H2-absorption and reaction-heat properties of these materials. Some of the applications include H2 storage, compression and separation, as well as heat pumping, heat to mechanical energy conversion and electric energy storage. This paper briefly reviews the fundamental phenomenology of metal hydrides, the history of the use of REE's in rechargeable metal hydrides, the practical engineering properties of these materials and the applications that have evolved around them. The rechargeable nickel metal hydride battery, a new vial alternative to NiCd cells, stands at the forefront of the applications.

Jan 1, 1992

By Pierre Antoine Dhaiti, Gilbert Sergerie, Michel Dagbert, Jean-Maurice Brodeur

"Quality of iron ore is generally determined by several factors which can be correlated or independent. Among these f actors, we generally find per cent iron, silica, magnetite or hardness. Forecasting the short- and long-term fluctuations of these f actors in the future pit is an important feature of mine planning in these deposits. Computer simulation provides a realistic answer to these questions. It allows to generate values for the most important quality features of each shovel load with the proper correlations between them as well as between one load and the next being fully reproduced. Then different sampling schemes f or grade control or blending facilities can be examined on the simulated data. The mechanics of the simulation procedure and its potential applications are described in an example.IntroductionThe purpose of this paper is to illustrate the use of in-situ grade simulation in the planning o f the grade control in an iron ore min e. More precisely, given a production unit of given size, we need to know how many samples have to be collected in that unit so that we ca n recognize its grade with a reasonable precision. Conclusions that we would like to arrive at are of the type: with 4 blasthole samples we ca n get the iron grade of a 10,000 ton bloc k with less than a ± 2% Fe error 95% of the time.The approach t hat we take to solve this problem is simulation. We simulate the grade of samples and the grade of the block that contains these samples. We repeat the simulation for hundred s o f blocks. By comparing the sample grade with the block grade in each case, we determine the actual number o f blocks where the difference sample-bloc k is less than a given limit."

Jan 1, 1983

By Herty, C. H.

One of the numerous requirements of many grades of present- day steel is that the steel shall be free from non-metallic inclusions. These inclusions may be composed of oxides, sulphides, complex oxy- sulphides, and nitrides, which enter the steel with the furnace charge, result from sulphur absorption from the furnace gases, or are formed in the steel during the deoxidation process. Although few' data are available which indicate in any quantitative manner the specific effects of inclusions in steel, there is a large mass of circumstantial evidence which points to the advisability of producing steel free from these impurities for many purposes. At the present time there is a growing feeling among metallurgists that non-metallic inclusions should be divided into two distinct types: (I) those readily visible under the microscope at ordinary magnifications; and (2) those in colloidal suspension or in solid solution. Both types are profoundly influenced by the character of the charge, the manipulation of the furnace slag, and the method of deoxidation. The work described in this bulletin deals primarily with inclusions visible under the microscope at ordinary magnifications, but the steels made by the various methods of deoxidation are being used LO study certain effects which may be ascribed to the second classification, named above. This latter work will be the subject of further bulletins on the effect of deoxidation practice on the physical properties of the steels involved.

Jan 1, 1957

By J. C. Judd

The Bureau of Mines investigated the recovery of vanadium, uranium, and phosphorus from low-grade phosphorite ores and concentrate by leach-ing with H2S04. Samples containing 0.12 to 0.23 pct V20S, 0.009 to 0.012 pct U30S and 18 to 30 pct P20S were treated by batch-agitation leaching, roasting followed by acid leaching, salt-roasting followed by acid leaching, and leaching under pressure. Maximum recoveries using leaching alone ranged from 78 to 98 pct of the V20S and 74 to 88 pct of the U30S-Leaching under pressure resulted in extractions of 88 to 95 pct of the V20S and 84 to 89 pct of the U30S. Leaching following roasting--with or without NaCI--produced extractions of 97 to 99 pct of the V20S and 86 to 91 pct of the U30a. Depending on the technique(s) employed, phosphate extractions ranged from 89 to 99 pct. Solvent extraction laboratory tests were conducted to selectively re-cover vanadium and uranium values from acid leach solutions. An average of 95 pct -of the U30a was recovered using di(2-ethylhexyl) phosphoric acid, plus trioctylphosphinic oxide. Essentially all of the V20S was recovered with octylphenyl acid phosphate plus isodecanol. The phosphate remained in the raffinate.

Jan 1, 1986

By David Scott, Denis V. Lachance, Daniel Marcotie

"LocationThe Heath Steele mine is located 50 km northwest of Miramichi, New Brunswick.Brief DescriptionHeath Steele is a 2700 t/d, copper-lead-zinc operation which employs conventional crushing, grinding, and differential flotation.HistoryThe Heath Steele mine is located in northeastern New Brunswick approximately 50 km northwest of the city of Miramichi and 65 km southwest of Bathurst. The massive sulphides containing ore values in zinc, lead, copper and silver were discovered in 1953 as a result of a joint venture between the American Metal Company and the International Nickel Company of Canada. The discovery was named after Mr. Heath Steele, manager of exploration for Amco at the time of the discovery.Mill production began in February 1957; however, the mine was forced to shutdown in 1958 due to depressed metal prices and metallurgical problems. It was re-opened in 1962 and milling operations resumed at 725 t/d until 1968 when the milling capacity was boosted to 1450 t/d and then to 2700 t/d in 1969.OreThe main ore zones are massive sulphides with very fine mineral grain. The chalcopyrite, galena and marmatitesphalerite occurrences are finely disseminated.Liberation is accomplished by grinding to 68% to 72% <400 mesh. Average mill feed assays are 0.8% to 1.2% copper, 1.8% to 2.5% lead, and 5.5% to 6.5% zinc, with 60 to 75 g/t silver."

Jan 1, 2000

By Colin D. Jardine

Rapidly increasing energy costs and more rigid customer quality requirements necessitate improved control of pelletizing processes. With the introduction of dedicated microprocessor-based controllers, sophisticated control strategies are now possible. A recent application of this technology at Carol Project has resulted in fuel savings, improved pellet quality, and standardization of operating procedures. This was accomplished with no production loss by the use of a "building block" approach to design and equipment selection. Details of this approach and the results obtained are described.

Jan 1, 1982

By P. C. Lightfoot, J. M. Duke, A. J. Naldrett

"The segregation of magmatic sulphides from mafic and ultramafic silicate magmas, in many circumstances, leaves the magma with a lower-than-normal Ni/MgO ratio, which is characteristic of both lavas erupted from the magma chamber and olivine crystallizing within it. Two end members of the segregation process are discussed; i) batch segregation and ii) fractional segregation.In the former, the critical factor is the magma/sulphide ratio. Computer modelling suggests that where this ratio has been less than 1000, the magma will be recognizable as anomalously low in Ni, due to sulphide segregation, and thus a good target for exploration. In fractional segregation, the critical factors are the proportion of sulphide to silicate being segregated and the degree of fractionation.Samples believed to represent the liquid portion of komatiitic lava f lows from a series of unmineralized sequences in the Abitibi greenstone belt, Canada. Belingwe belt, Zimbabwe, and Barberton Mountainland, South Africa coincide with the sulphide-free fractionation model. They are in marked contrast to samples from the ore-bearing districts of Kambalda and Scotia. Western Australia in which distinct Ni depletion, corresponding to fractionation of olivine plus sulphide in a ratio of between 100 and 200:1 is recognizable. Ni-depleted olivines also mark the sulphide-bearing Dumont intrusion of the Abitibi belt.The Moxie intrusion of northern Maine has distinctly Nidepleted olivines, as does the nearby and petrologically related Katahdin body. In both of these intrusions, the composition of the olivine allows reasonable predictions to be made of the Ni tenors of sulphide showings within them. At Katahdin, the Ni depletion is so widespread that little hope is help out for the presence of economic concentrations of sulphide. At Moxie. the olivine compositions suggest that the best chance of economic sulphides lies in the southern lobe of the intrusion.Ni-depleted olivines also characterize certain rock units within intrusions of the Insizwa complex, Transkei, Southern Africa. Many millions of tonnes of Ni have apparently been removed by sulphides from these rock units, many more than are contained within the single mineralized occurrence so far identified at Waterfall Gorge."

Jan 1, 1984

By William H. Mount

Since the late 19405, St. Joe has operated rubber-tired, trackless mining equipment underground in its Southeast Missouri Lead Belt operations. At first, the trackless equipment was operated in conjunction with rail haulage equipment in the room-and-pillar operations, but was to later replace rail haulage completely. The first pieces of equipment to travel on pneumatic rubber tires were short-haul shuttle cars of 12-ton capacity hauling rock from the heading to the mainline railroad. Early-model drill jumbos were the next pieces of production equipment to be carried on rubber, along with mobile slusher ramps. Mobile diesel equipment, in the form of conventional rear-dump trucks, made its appearance underground in the early 1950s, introducing the era of relatively high-speed mobile equipment as compared to the electrically powered shuttle cars. Haulage distances for rubber-tired vehicles were no longer dictated by trolley lines and trailing cables and tires were subjected to increasingly severe applications. St. Joe&apos;s first completely trackless mine, the Hayden Creek Mine, was opened in 1952, employing rubber-tired drill jumbos, electric shuttle cars, and for the first time, an articulated diesel truck consisting of the tractor unit of a conventional earthmoving scraper and a rear-dump rock wagon. Those machines rolled on the first true earthmover tires to be used underground by St. Joe. The articulated truck concept proved to be very successful, and constitutes an In- creasing portion of the underground haulage today.

Jan 1, 1975

By Rodrigo Afonso Hatwig

Os aços inoxidáveis duplex (DSS) e superduplex (SDSS) são ligas que se caracterizam por apresentar uma microestrutura composta por frações volumétricas similares das fases ferrita e austenita. Dependendo da composição química e do tratamento termomecânico aplicado, a microestrutura dos aços inoxidáveis DSS e SDSS poderá apresentar, além das fases ferrita e austenita, fases intermetálicas deletérias. Neste trabalho, um estudo termodinâmico-computacional foi realizado com o objetivo de acompanhar a evolução das fases de aços superduplex no intervalo de temperaturas entre 300°C e 1.200ºC. Para tanto, fez-se uso do software de simulação termodinâmica FactSage v. 6.4. Os resultados descrevem de forma eficaz as fases principais e secundárias em função da temperatura e composição química.

Aug 8, 2018

By Henry R. Linden

The demand for natural gas continues to increase at higher than anticipated rates, partly because of its widening price advantage over most other fossil fuels when the cost of air pollution control is included. However, there are clear indications that natural gas supply from the contiguous 48 states and continental shelves will not indefinitely keep up with this rapid growth in demand. Projections are presented which define the extent of potential deficiencies from the 1970&apos;s to the year 2000. Among the sources of supplemental gas - imported pipeline natural gas from Canada and Mexico, tanker import of liquefied natural gas, and synthetic pipeline gas from coal and oil shale - by far the most abundant at potentially competitive costs is pipeline gas from coal. The state of development and relative economics of the various coal gasification processes are reviewed. It is shown that synthetic pipeline gas could become a very substantial market for bituminous coal and lignite at current minemouth prices - 60-70 million&apos; tons of coal for each trillion cubic feet of synthetic pipeline gas produced. This corresponds to only slightly more than the current annual increase is gas demand.

Jan 1, 1969

By d&apos, Dennis V. Andrea

The Bureau of Mines and El Paso Mining and Milling Co. conducted a cooperative in situ leaching research program at the Emerald Isle mine near Kingman, Ariz. The objective of this research was to develop in situ leaching methods for 200,000 tons of ore exposed in the pit bottom and also 3,000,000 tons of ore under 200 feet of overburden adjacent to the pit. The research included core drilling for fragmentation analysis, inplace permeability testing, seismic surveys, blasting tests, blast vibration measurements, inplace leaching, and ground water monitoring. A l5,000-ton test area in the pit bottom was blasted and leached inplace for 117 days. This successful test was followed by leaching 100,000 additional tons of unblasted pit bottom ore. Two test blasts, under 205 feet of overburden and extending to 290 feet, were detonated in an area near the open pit. The second blast was detonated because the first blast did not create adequate permeability for leaching. Pit bottom leaching was discontinued and the test area under 200 feet of overburden was not leached because the company terminated operations at the Emerald Isle mine. Based on the research completed, an expanded in situ leaching system was designed, but not implemented, to recover copper from a 1,500,000-ton area at the Emerald Isle mine.

Jan 1, 1977

Terminology. The term potash originated in "pot ashes" produced by burning wood to ashes in iron pots and then leaching out the soluble salts, chiefly potassium carbonate, from the residue. In modern usage potash is a generic term for various potassium salts used in agriculture and industry. More specifically, it denotes the oxide of potassium, K2O, and the content of potassium in ores and products is stated as weight percent of K2O present. Its salts are commonly referred to as muriate of potash, sulfate of potash, etc. The presence of an adequate supply of available potassium in the soil promotes the health and improves the quality of the plant. insures greater efficiency in photosynthesis, increases resistance to certain diseases, offsets the effect of an oversupply of nitrogen, and helps the plant to utilize soil moisture more advantageously. ("Soils and Men," U.S. Dept. of Agriculture Yearbook 1938.) Occurrence. Potassium ranks seventh among the elements in abundance. It is estimated to constitute some 2.6% of the lithosphere and is found in soluble forms in the oceans, lakes, rivers, and subsurface waters. It is also an important constituent of plant and animal life. Commercially significant accumulations of potassium salts occur in underground deposits formed in past geologic times by evaporation of ancient bodies of saltwater, inland drainage basins, and shallow sea lagoons. The potash content of such waters was the end result of weathering and leaching of insoluble potash-bearing aluminosilicates, such as feldspars, micas, leucitcs, and others. The concentrations of potassium salts in the natural brines of some lakes in the arid and semiarid regions of the continents are also important as sources of potash; the brines of the Dead Sea in Asia Minor, the Great Salt Lake in Utah, and Searles Lake in California typify such concentrations. Every continent has major potash deposits as listed in Table 1 adopted from Cawley.1

Jan 1, 1985

By S. J. Swainson

PHOSPHATE ROCK is a low- priced commodity. This fact has influenced the choice of mining and beneficiating methods to a greater degree, perhaps, than in most other low-grade mining operations. The fact that many yards of everburden and matrix must be stripped and mined per ton of salable "rock" produced and sold has necessitated he development of relatively simple btneficiating plants having high capacity and low capital and operating costs. The law of diminishing returns must always be reckoned with in phosphate mining and washing, and often recovery must be sacrificed in favor of costs in order to achieve the highest over-all economic efficiency. The phosphate-bearing formation, known as "matrix," is composed of (1) phosphate pebbles, which are somewhat rounded in shape and which vary in size from 1-in, to micron sizes, (2) rounded quartz grains usually smaller than 10 mesh, and (3) clay, of varying "stiffness," which is the binder of the matrix. The phosphate pebbles vary in hardness. Their color, which varies from white to black, is not a reliable indicator of the Bone Phosphate of Lime (B.P.L.) content of the

Jan 1, 1944

By d&apos, I. J. Agati

The stockpiling and reclaiming of bulk materials can be a challenging task for engineers seeking the optimum solution for plant needs, reliability, and at lowest unit cost. The objective of this paper will be to expose advantages, disadvantages and limitations of many storage and reclaiming systems to the responsible engineer and management. The paper will emphasize the practical aspect of stockpiling and reclaiming methods. Many valuable and interesting papers are available dealing with the theoretical viewpoint and application of a particular manufacturer&apos;s machine. Several of these are mentioned in the bibliography. As many practical parameters as possible will be given. After twenty years in the field of designing and selling bulk materials handling systems, the needs of the user and the plant are recognized and reasonably understood. This paper cannot give solutions to all problems In this vast field but will stress practical applications and examples of various installations. The evolution of advancements in materials handling is based upon not only technological innovations, but learning from many experiences of others and utilizing them as stepping stones to improved installations.

Jan 1, 1969

By W. H. Oppelt

A small, annular-retort gasifier having a nominal capacity of 40 pounds of lignite per hour was designed and constructed at the Lignite Experiment Station, Grand Forks, N. Dak. The purpose of the investigation was to increase the capacity of an annular-retort gasifier by better temperature distribution in the heating chamber (adjacent to the annulus) and by supplemental internal heating with controlled amounts of air. Correct control of air admission should yield crude ammonia-synthesis gas having a (H2+CO)-N2 ratio of 3. Dakota Star stoker-size lignite was used during the exploratory experimental program. The effects of temperature level and distribution in the heating chamber and of addition of air to the reactor were investigated. Hydrogen - carbon monoxide ratios ranged from 1.9 to 2.5, and (H2+C0)-N2 ratios were as low as 2.9. Hourly gas production ranged from 970 to 2,580 cu. ft., or 62.0 to 164 cu. ft. per sq. ft. of heated surface, or 350 to 940 cu. ft. per cu. ft. of reactor volume. Data from the small gasifier could be readily correlated with those previously obtained in the commercial-scale unit under comparable experimental conditions.

Jan 1, 1957

By Willy Ank de Morais, Márcio de Morais Tavares, Mateus Araújo e Silva, Érika Elis Kuo, Cícero Lopes de Souza

Estruturas de aço são utilizadas em diversas aplicações na construção civil, com vantagens relativas a outros tipos de construções, tais como leveza e rapidez na execução da obra. Porém um dos maiores problemas neste tipo de sistema construtivo é a corrosão atmosférica a que estará sujeita o aço estrutural utilizado. Com o objetivo de se avaliar a resistência à corrosão atmosférica, neste trabalho, foram construídos painéis expositores, conforme a NBR 6209, para manter corpos de prova de aço estrutural comum e patinável, por um período inicial de setenta dias em dois locais distintos, categorizados com de agressividade ambiental I e III, respectivamente interior e litoral do estado de São Paulo. Superficialmente o processo de degradação foi nitidamente diferenciado, com o mesmo resultado sendo apontado pela alteração da massa das amostras, que se elevou durante a exposição ao ambiente de agressividade III, já que os produtos de corrosão formados não se desprenderam no curto período de tempo do teste. Mesmo considerado que a norma estipula um tempo mínimo de dois anos de duração para o ensaio, que ainda está em andamento, o presente estudo aponta a necessidade de adotar mecanismos de proteção contra a corrosão muito mais severos nas regiões litorâneas.

Mar 1, 2019

By Claudio Pereira Diogo

Bobinas de aço laminadas a frio galvanizadas com recobrimento do cromo foram empregadas para a produção de telhas e calhas d’água. Entretanto, o fabricante destes produtos teve problemas com as superfícies obtidas, que mostraram sinais de marcas de deformação/estiramento. O problema é que, na aplicação desejada, uma aparência superficial que não seja brilhante e lisa é muito indesejável. Este trabalho foi feito a fim de descrever as condições que levaram o material para se comportar como visto pelo usuário (fabricante de telhados e calhas de chuva) com base em sua aparência e comportamento mecânico. Foram empregadas observações em microscópio estéreo e curvas tensão-deformação, obtidas a partir de ensaios de tração. Com base nos resultados, são apresentadas algumas opções para minimizar a ocorrência de marcas citadas durante a utilização do que as bobinas.

Aug 16, 2017

By M. S. Shishvan, J. R. van Duijvenbode

The results of dig limit delineation in open pit mining are never truly optimized due to gaps in the underlying data, such as insufficient sampling. Aside from the data uncertainty, there is also an influence on the final dig limit by either humans or by the heuristic character of an optimization method like simulated annealing. Several dig limit optimizers have been published, which can replace the manual dig-limits designing process. However, these dig limit designs are generally not adapted to account for this heuristic character. In this paper we present a stochastic analysis tool that can be used with the results of heuristic dig-limit optimization to increase confidence in the obtained results. First, an enhanced simulated annealing algorithm for dig limit optimization is presented. Then, this algorithm is tested on ten different blasts at the Marigold mine, Nevada, USA, as a case study. Finally, the results are analysed with a destination-based ensemble probability map and an analysis conducted of the final solution data distribution. The generated dig-limit designs of the algorithm include high revenue areas that are excluded in comparable manual designs and show improved objective and revenue values. The analysis tool provides block destination probabilities and box plots with the distribution of opportunity value for the dig limit. Furthermore, with the analysis tool, it is possible to make well-informed design decisions in areas of uncertainty.

Dec 13, 2022

By L. R. Fisher

The purpose of this investigation was twofold: (1) To devise a rapid method for determining quantitatively the porphyrin-carboxylic acid content of a particular crude-oil porphyrin aggregate, and (2) to isolate porphyrins in the crystalline state from crude-oil porphyrin aggregates. The first purpose was accomplished by applying adsorption chromatography. In fulfillment of the second aim three different crystalline porphyries were isolated by methods which involved both adsorption chromatography and fractionation of benzene solutions with hydrochloric acid of varying strength. The three porphyrins had etio, rhodo-, and phyllo-type absorption spectra, respectively. INTRODUCTION Many samples of petroleum have, as interesting minor constituents, chemical compounds known as metalloporphyrins. Their presence in crude oil and other bituminous materials was first discovered by Treibs a quarter century ago. Much experimental work has been done on metalloporphyrins because of their importance to the petroleum industry. They have a deleterious effect on refining catalysts. The ash resulting from the burning of heavy fuel oil is very reactive, We to the presence of metallic constituents, particularly vanadium. In oil-fired gas turbines, the ash may build up on the blades, causing imbalance of the rotors and, in addition, severe corrosion. In industrial boilers, the ash residue is responsible for severe damage to boiler tubes and to the refractory brickwork (15).4 Through study of the chemical constitution of the various metalloporphyrins found in petroleum, much can be learned concerning the origin, migration, and history of crude oils.

Jan 1, 1961