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LIST OF THE MEETINGS OF THE INSTITUTE AND THEIR LOCALITIES FROM ITS ORGANIZATION Transactions Number Place Date Vol Page 1 Wilkes-Barre, Pa May, ?71 1 3 2 Bethlehem, Pa August, ?71 1 10 3 Troy, N Y November, ?71 1 13 4 Philadelphia, Pa February, ?72 1 17 5 New York, N Y May, ?72 1 20 6 Pittsburg, Pa October, ?72 1 25 7 Boston, Mass February, ?73 1 28 8 Philadelphia, Pa May, ?73 2 3 9 Easton, Pa October, ?73 2 7 10 New York, N Y February, ?74 211 11 St Louis, Mo May, ?74 3 3 12 Hazleton, Pa October, ?74 3 8 13 New Haven, Conn February, ?75 3 15 14 Dover, N J May, ?75 4 3 15 Cleveland, 0 October, ?75 4 9 16 Washington, D C February, ?76 4 18 17 Philadelphia, Pat June, ?76, 5 3 18 Philadelphia, Pa October, ?76 5 9 19 New York, N Y February, ?77 5 27 20 Wilkes-Barre, Pa May, ?77 6 3 21 Amenia, N Y October, ?77 6 10 22 Philadelphia, Pa. May, ?78 6 18

Jan 1, 1923

El objetivo del presente texto es describir la geografía, petrografía, geotectónica, geología histórica y las vetas en la región minera SantoToribio, situado en Ancash. La parte occidental del cerro Santo Toribio tiene un perfil más abrupto, donde la roca volcánica aflora en grandes extensiones y en pocos lugares, la sedimentaria. Su petrografía la conforman dos tipos de rocas: las ígneas, cuya textura afanítica corresponde a una inalteración en su composición superficial, y las sedimentarias o calizas de grano fino, que se encuentran en San Juan. De otro lado, sobre la veta del túnel de Santo Toribio se desarrollan algunos fallas tectónicas, pero de menor consideración. En su geología histórica, las calizas de esta región son de origen marino y pertenecen al periodo cretácico inferior, y dentro de este, los pisos superiores al barreniano. Finalmente la descripción de las vetas tales como Santo Toribio, Soledad, Lumbrera, Pascua, San Juan, Santa Rosa, San José, San Luis, San Dimas, Yolanda, Raquel, Paquita, Blanca, ayudan a incrementar las posibilidades de afloramiento.

Jul 20, 1957

By Open-Hearth Steel

We have a very high-powered organization up here this morning, headed by Kenneth C. McCutcheon, general superintendent of the Ashland Division of the American Rolling Mill Company, and L. A. Lambing, superintendent of the open-hearth and Bessemer departments of Jones & Laughlin Steel .corporation of Aliquippa, Pa., representing the open-hearth men. Also, we have P. F. Dolan, assistant general manager of the Maryland plant of Bethlehem Steel Company, of Sparrows Point, and Harry E. McDonnell, superintendent of blast furnaces of Weirton Steel Company of Weirton, W. Va., representing the blast-furnace section.

Jan 1, 1940

By Tai Luu, Maxim C. Schisler, Yaser Taheri

The Stevens Gateway Project is an expansion of the Stevens Institute campus overlooking the Hudson River in Hoboken, NJ. The plans call for 90,000 ft2 (8360 m2) of new classroom, research, and student life facilities in new, 4-story buildings. The excavations for the building footprints were bounded by city streets and existing buildings, including the historic Carnegie Laboratory of Engineering, built in 1902. Pit underpinning was originally specified for the Carnegie building. However, given the depth of cut, construction time required for the 13 ft (4.9 m) deep pits would be substantial. The geotechnical contractor retained for the support of excavation work therefore offered an innovative active soil nail wall design that would meet project requirements in a shorter timeframe. Unlike the passive soil nail systems common in the industry that are chiefly used for soil slope stabilization, active soil nail walls contain pre-stressed anchor components to resist soil movement and limit settlement of soil and structures being contained. In addition to a discussion of the overall design approach of the active soil nail wall system, this paper will include a detailed description of its constructability and effectiveness. This project’s use of a conventional slope stabilization technique for an unconventional purpose may have positive implications going forward. INTRODUCTION Stevens Institute of Technology is a private university in Hoboken, New Jersey that sits on the cliffs of the City of Hoboken overlooking the Hudson River and Manhattan Island to the east of the campus. In recent years, the university has executed numerous plans to expand and upgrade its campus academic, student life, and residential facilities. One such project is the Academic Gateway Complex. The plan adds 90,000 ft2 (8360 m2) of new classroom, research, and residential facilities while also enhancing community connections by building a park to serve as a green corridor for the city. The proposed construction took place on the north and south side of 6th Street between Hudson Street and River Street. The project included the demolition of an existing university building followed by the construction of two, 4-story buildings on the north and south property lots. The north and south buildings will be connected by a second floor bridge spanning 6th Street. The buildings each contain a full basement extending from the proposed ground floor at approximately El. 41ft (12.5 m) to the basement subgrade at El. 26 ft (7.9 m). Each building will be constructed on respective mat foundations. Figure 1 presents an overview of the project area.

Jan 1, 2019

By Adusumilli M. S, Subrahmanyam T. V, Rao V. D

Chance find of an economically important mineral on the sur- face and its exploitation without proper exploration work, has become the habit of humanity since the Bronze Age. The explora- tion and exploitation techniques have, however, been substan- tially improved in the technologically developed western world and system controlled major communist countries. Nevertheless, the greatest need is felt in the Third World countries where large mineral potential exists, but with inadequate investments in exploration and exploitation techniques, a handicap that has been beneficial to the more developed countries, since long. The great number of the Third World countries which are striv- ing hard to develop, need to formulate mineral exploration and exploitation strategies which could enable them to develop their resources. This requires planning and creating new concepts of ore deposit types and genetic models, rheology, economics and their innovation and integration. The following approach could help them to be economically "more independent" by the end of this century. 1. Bridging of pure and applied geology gap, and creating con- sciousness of research and development. 2. Revision of mineral resources concepts adopted to modern technological world. 3. Improved mineralogical research, and determinative miner- alogy as an important asset. 4. Creative research and establishing know-how, with philosophical base for regional exploration projects. 5. Indepth investigation into the origin and growth of earth as a system, and its importance in the association, quality, and quantity of metallic, non-metallic and energy resources con- centrations. 6. Mineral beneficiation, targets and strateties; methods of eco- nomic and improved recovery systems. Development of alter- native technology, and utilization of mineral technology strategies. 7. Theoretical and practical modelling by conventional and com- puter techniques of the existing and expected mineral resources, and mineral development. 8. Critical analysis of the status of mineral economics of the Third World and developed world with forecasts for the year 2000 based on problems faced by the developing world. 9. Minerals at cross roads of International Interdependence. 10. Philosophical, realistic, traditional and modern strategies for mineral development. The dynamic economic system opera- tion in national mineral sector.

Jan 1, 1988

By A. Mazhary

"Although sensor-based ore sorting has gained significant attention recently, sorting gold deposits still face a high level of skepticism by gold mining companies. In order to shed some light on the matter, this article looks at two different gold deposits that were examined using X-ray Fluorescence, Electromagnetic and X-ray Transmission sensors. The heterogeneity of each sample is measured based on the assay results of each particle and is related to its sortability. Multivariate linear regression analysis was also performed on the XRF results to find potential proxy elements for detecting gold. The results from these deposits were varied and each sample showed different levels of sortability. While both X-ray sensors proved efficient for different deposits, the electromagnetic sensor failed to produce any promising results. Despite unsatisfactory result for one sample, this technology can have significant advantages in terms of lowering the operational costs and improving head grades and recoveries providing that the deposit is amenable to such separation methods. Therefore, it is important to mention that sensor-based ore sorting is ore and sensor dependent, and as a result, it cannot be applied and be beneficial to all deposits. Therefore, amenability tests are required in order to examine the potential for sensor-based ore sorting before one can reject the idea.INTRODUCTION Although sensor-based ore sorting has gained significant attention recently, sorting gold deposits still face a high level of skepticism by gold mining companies. Except for a few cases presented previously, no new case studies have been published. Previously, mines such as Kloof Gold Mine in South Africa used an optical sorter to sort their waste stockpile in 2003–2004 (Von Ketelhodt, 2009) and then again in 2009 (Von Ketelhodt, Falcon, & Falcon, 2011). More recently, Coeur Operations utilized an XRT sorter for their Kensington Mine in Alaska (Lasley, 2014) and also Anglo-American Platinum used an XRF sorter to pre-concentrate Platinum Group Metals through an algorithm that used chrome, copper and nickel as proxies (Rule, Fouchee, & Swart, 2015)."

Jan 1, 2017

By A Litwinowicz, M Laxman, A Fourie, A L. Li

This paper presents a design approach and analytical methods that were used for assessing the potential of static liquefaction and developing the mitigation measures for a tailings dams. The rigour of the design and analysis approach represented leading practise in the industry to address static liquefaction, which contributed to a robust design with high confidence and certainty. The salient features of our approach to static liquefaction included geotechnical investigation and tailings characterisation, static liquefaction screening assessment, static liquefaction triggering analysis, limit equilibrium analyses and numerical modelling of static liquefaction using the NorSand model, which was amongst the first tailings dam projects involving numerical modelling of static liquefaction using these methods.

Jul 1, 2021

By Jr. Koch

Statistical methods applied at the Bureau of Mines Denver Mining Research Center to data from metallic ore bodies were used to evaluate lignite reserves from core data and to predict the extent of lignite horizons in some Texas lignite beds. Six lignite seam units were studied using data from 361 drill holes. The data indicate a total of 214.2 million tons of lignite in the area examined, and probable reserves of 113 million tons in an area 2,000 feet beyond the limits established by the drill holes. It was demonstrated that lignite reserves present in lenticular beds could be reliably determined by statistical techniques, and that core drilling could be optimized to maximum information with minimum drill holes. The technique described is applicable to other coal beds.

Jan 1, 1966

By J Deraisme, P Epinoux, O Bertoli

"Société le Nickel exploits the Dôme lateritic nickel orebody at its Tiébaghi operations in New Caledonia. The site geology has an obvious bearing on recovery and metallurgical performance, with controls that are extremely complex at all scales, including lithology, oxydo-reduction conditions, mineralogy and multivariate geochemistry. In this context, establishing an adapted recoverable resource estimation method that is efficient and transparent proves an interesting challenge. The method must address the key notions of: support effect – the exploration data set can only warrant the estimation of large panels of 20 × 20 × 3 m3 that are much larger than the selective mining units (SMUs) of 5 × 5 × 3 m3 information effect – the selection at the production stage uses estimates based on information that is much denser than that available for mine planning.The problem is rendered more complex in this type of deposit by the fact that the additive variables used for the estimation (metal accumulation and ore tonnage) are not the ones used to establish the selection at the mining stage (ie the nickel grade of SMUs, which is the ratio of accumulation on tonnage). Eventually, the selection criteria not only involve Ni grades, but also other elements such as Al2O3, Fe2O3, MgO and SiO2.The solution presented in this paper is to construct an SMU multivariate simulation in the saprolitic horizon and construct an efficient post-processing aimed at producing multivariate recoverable resource estimates. The efficiency constraints imposed by the number of blocks to be simulated (1.5 million) lead to resorting to direct block simulations. The underlying multivariate discrete Gaussian model, which had its validity tested beforehand, is put to good use to mimic the selection process that happens at the mining stage by offering the ability to simulate a composite value located at random within each block.The paper also presents the application of a scenario reduction algorithm to pick a representative subset of a few simulations to help appraise the risk attached to the downstream (reserve optimisation and mine sequencing) phases of the project. The original version of the paper (see Deraisme, Bertoli and Epinoux, 2014) used an early version of the scenario reduction plug-in (named S2RM) built in Isatis® software, where measuring the distance between the initial set of scenarios and the reduced set was based on Ni only. The implementation presented here is for the second generation of S2RM, where measuring the distance between the initial and the reduced set of realisations is based on all study variables. The benefits of the measure adapted to the true multivariate nature of the problem are highlighted in this updated version of the paper.CITATION:Bertoli, O, Deraisme, J and Epinoux, P, 2014. Multivariate block simulations of a lateritic-type nickel deposit and post-processing of a representative subset, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 99–108 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 24, 2014

By V. E. May

Has your organization adopted Six Sigma as part of their Performance Improvement strategy? What about Lean manufacturing or Lean Six Sigma? If you already have any of these business process improvements in place where will you go next? In this article we will focus on transforming your organization beyond Lean Six Sigma to the next level of performance. In the future companies can take another quantum step forward by combining Lean Six Sigma with advanced Root Cause Analysis (RCA). The value of taking this natural progression on the way to achieving new levels of organizational excellence is presented.

Jan 1, 2011

By Douglas B. Silver

Study Parameters (Status as of February 1993) Time Period: 1989 -1991 151 North American Public Metal Mining Companies Fiscal not calendar year basis 85+% of Canadian and U.S. Metal Production Au, Ag, Cu, Pb, Zn, Mo, Ni, W Results are Preliminary and Research Continues Chicken Little is Alive and Well

Jan 1, 1993

By C. I. Garcia, G. Zhou, W. Gao, A. J. DeArdo

The development of X-100 and X-120 linepipe steels was investigated using a series of low-carbon Mo-Nb-B steels. The laboratory steels were vacuum melted and processed using advanced thermomechanical processing (TMP) philosophies. Prior to the laboratory hot-rolling experiments, the grain coarsening temperature, the conventional T95 and T5 start-stop recrystallization temperatures and the transformation behavior of y were studied using a computer-controlled high temperature deformation MTS-458 and a Theta-IV High Speed dilatometer systems. The results from these experiments provided the guidelines for the design of the laboratory hot-rolling TMP processing experiments. The mechanical properties of the experimental steels showed yield strengths in the range 700-850 MPa and CVN impact properties of over 80 J at -20°C. The best balance of mechanical properties was obtained by using CCR+DQ+Tempering treatments. The major microstructural features responsible for the observed mechanical properties in order of importance were: a) substructural refinement associated with lower bainite, b) dislocation strengthening, c) fine recrystallized ferrite, and d) small amounts of retained austenite. Fine Nb(C,N) precipitates formed in ferrite were observed, however their contribution to the strength was minimum. Most of the Nb(C,N) precipitation took place in austenite. This precipitation was used to exert microstructural control of austenite during hot rolling. The physical metallurgy and optimum TMP to achieve the mechanical properties are detailed in this paper.

Jan 1, 2005

By H. Kenworthy

Small batches of fluorspar flotation concentrates were made into nodules and pellets on a laboratory scale. Several of these were rated acceptable by laboratory evaluation methods. The most satisfactory pellets were produced by mixing fluorspar with about 12.5 percent of water, by weight, and 4 percent of organic binders. These binders) for the most part) originated from petroleum and wood-pulp industries. They were generally difficult to handle and were not easily incorporated with the fluorspars tested. Most of them seemed to have an aversion for damp fluorspar and had to be forcibly mixed with the fluorspar; which was then formed into pellets by pressure. Substitution of fuel oil in varying amounts in the binders enhanced the mixing and penetrating qualities of these binders but at the same tire tended to make the pellets more porous. Tall oils performed the same function to a lesser degree and usually decreased the water absorbency of the finished pellets. Heat-treating temperatures to set up these binders were moderate -about 5000 F. for 30 to 50 minutes was usually enough for both drying and heat treating. Nodules made with 1-1/2 to 2 percent of bentonite as a binder were easily mixed and formed. They required a high degree of heat (about 1,500° F.) to develop their strength and were quite water-absorbent when finished. Two fluorspars were examined for weight and fluorite loss after heat treatment at similar temperatures. Both showed a definite wej.ght and analytical loss of fluorite. Bentonite was used also as a binder to successfully nodulize finely ground oxides of iron, manganese, and nickel.

Jan 1, 1951

By Roy G. Stott, John A. Johnson, Floyd G. Anderson

"This information circular discusses drilling and blasting in open-cut iron-ore mines and is one of a series of papers describing iron-ore mining practices in the Lake Superior district to aid in preventing accidents in that industry.The Lake Superior district consists of the Marquette and Menominee ranges of Michigan, the Gogebic range of Michigan and Wisconsin, and the Vermilion, Mesabi, and Cuyuna range of Minnesota. Open-cut mines produce 8o percent of the iron ore mined in the district; 98 percent of the total Lake Superior district open-cut ore is produced in Minnesota and 2 percent in Michigan. The entire Wisconsin iron-ore production is from underground nines. The Mesabi range in Minnesota produced 93 percent of the open-cut iron ore and 76 percent of the total iron ore in the district in 1947.During the 8-year period 1940-47, 619,000,000 gross tons of iron ore were shipped from mines of the district, or 85 percent of the United States output. Approximately 78,000,000 gross tons of iron ore were shipped from the mines of Minnesota, Michigan, and Wisconsin in 1947.This paper is based primarily on observations daring the period July 1947 to March 1948. Thirty-two open-cut mines were visited; 28 on the Mesabi range, 3 on the Cuyuna range, and 1 on the Marquette range. In 1947, 36,100,000 tons of iron ore was shipped from these 32 mines, or 59 percent of the open-cut ore and 46 percent of the total iron ore shipped from the district. During 1947 about 90 open-cut iron-ore mines were operating in the district, and the annual production of each ranged from 25,000 to 10,000,000 tons.Many recommendations included in this paper for improving safety and preventing injuries to employees were taken from Bureau of Mines Information Circular 7387.Data were collected under the direction of Frank E. Cash, former supervising engineer, Health and Safety Division, Bureau of Nines, Duluth, Minnesota. E. W. Felegy, mining engineer, Safety Branch, gave valuable assistance in reviewing and editing the manuscript.The authors gratefully acknowledge the information and assistance given and the numerous courtesies extended to them by officials of the following mining companies:All the Lake Superior iron ores occur in bedded formations that range from less than 100 feet to over 2,000 feet in thickness. These formations are designated by one commonly applied name, ""iron formations.""4/The Mesabi range in northern Minnesota, about 70 miles northwest of Duluth, was opened to mining in 1892; it is the largest single source of iron ore in the United States. It is 75 miles long and, because of the gentle dip of the ore formation, it ranges in width from 1-1/2 to 3 miles.5/ The ore formation, which is nearly horizontal, has a maximum thickness of about 450 feet and is covered by a glacial drift that ranges from 10 to over 100 feet in thickness. Most of the ore is near the surface and adaptable to open-cut mining."

Mar 1, 1950

By A. Demers, M. Chapman, N. Reynier, R. Lastra, M. Courchesne, C. Laviolette

Historic medical isotope production at Canadian Nuclear Laboratories (CNL) in Chalk River involved the dissolution of irradiated isotope targets prior to extraction of Mo-99. This process generated liquid waste that was cemented in 5-gallon containers and transferred to an outdoor waste-management facility for intermediate storage. Research was undertaken to develop an innovative method for uranium, mercury and cesium recovery from the radioactive cemented waste (RCW). Regulations prohibit the removal of active radioactive waste from the Chalk River facility. Thus, CanmetMINING produced surrogate material following the same procedures and conditions to those used at CNL. The selective recovery of the uranium from the surrogate radioactive cemented waste (SRCW) could offer CNL more disposition options for the resulting wastes. Leaching tests were performed using four different SRCW at 1 kg scale. Different conditions, operating parameters, and the presence of plastic and corrosion products were evaluated on solubilization. The research investigated the use of potassium iodide with the sulphuric acid leach to increase metals recovery. Iodine improves the solubilisation of metals and the U dissolution reached 99%. The increase of leaching time reduces the U solubilization due to silica gel formation. Therefore, it will be important to control leaching time to avoid the loss of U during the pilot scale experiments. For Hg, the solubilization ranged from 60 to 80% due to the presence of metallic mercury and mercury sulphide found in SRCW cured at 60°C and/or aged for 30 months. Ion exchange (IX) was found the best method to separate the uranium from the impurities and produce a purified and concentrated uranium solution suitable for yielding a uranium product (yellow cake).

Jan 1, 2020

By W. G. Hopkins

The development of systems for location of miners who have become entrapped following a mine disaster has been one of the major research goals in the Bureau of Mines. This study details the preliminary development of such a system. Current technologies for locating trapped miners from the surface are either simple direction finders or time difference pulse systems that have accuracy limitations. Developing technologies using full vector field measurements at several receiving points are currently being studied. The necessity of measuring field strength with great accuracy can be a drawback in these systems. A system that operates with continuous wave radio signals, whose phase differences can be measured accurately even in weak signal conditions, greatly improves the location accuracy. A microcomputer would be used in conjunction with the system, to gather and manipulate the data to automatically pinpoint the location of the trapped miner. Comparison of this system with existing technology indicates a favorable accuracy/complexity ratio for the phase difference of arrival technique.

Jan 1, 2011

By T. H. Aldrich

THE Aldrich Mining Co. holds under lease from the Illinois Central R. R. Co. about 14,000 acres, in the East half of Township 12, Range 12 `V., in Marion county, Alabama, and owns other lands, of which about 1,000 acres adjoin this leased tract, making a total area of about 15,000 acres, all of which is underlain by the coal-seam upon which the company is operating. This seam is nearly horizontal ; and a ravine, diagonally crossing the tract, exposes the outcrop on either side for about 2 miles. The territory has been so divided that nearly the whole of it can be worked out by two collieries. The mines at Brilliant were opened in the Fall of 1898, and shipments began in the following spring. The original plan was to furnish steam-coal for locomotives to the Illinois Central R. R. Co.; and upon this expectation the investment of capital was made. The field was entirely new; and the softness of the coal at the outcrop induced the belief that it could be very cheaply mined. A contract for the delivery of a large quantity of coal to the railroad was accordingly executed. But with the advance of the entries to increasing distances from the outcrop, the coal proved so hard that it could no longer be drilled with a breast-auger; and the expense of mining became so great that the contract for cheap steam-coal had to be cancelled. It became evident that the work must be done with machinery and explosives, if it could be profitably done at all. On the other hand, the excellent quality of this coal opened, at the same time, a possible market not specially contemplated at the outset-namely, that of a first-rate coal for domestic and general uses. Since no other deposit of such coal was known to exist on the line of the Illinois Central, or any other railroad

Jul 1, 1906

By A. J. Miller

Estimates of interstitial water saturation derived from capillary pres-sure data are compared with residual water saturations found by the analysis of cores out in oil-base drilling fluid. A theoretical explanation for the high-rate of water production from the Bellshill Lake Field is proposed, based on the interpretation of the capillary pressure data.

Jan 1, 1960

By Adeyemi Adesina, Subhabrata Mishra, Syed Mohammed Mustakim, Malaya Kumar Jena, Shaswat Kumar Das

Utilization of low-grade manganese ore adopting the carbothermic reduction roasting process is a proven method to produce high-grade manganese ore. To minimize industrial waste and protect the environment, gas cleaning plant sludge (GCPS), which is a solid waste from steel industries, was employed as a reductant to perform the reduction roasting process. The optimum conditions to carry out reduction roasting of the low-grade manganese ore were found to be: a roasting temperature of 950 °C, a residence time of 2 h, 40% GCPS as reductant, and magnetic separation at 5000 G for a manganese ore size of –10 mm. A lowgrade manganese ore comprising Mn grade 31.27% and Fe grade 19.78% having a Mn/Fe ratio of 1.58 containing a high silica content of 26.48% was used for the carbothermic reduction roasting having mineral phases of pyrolusite (MnO2) and hematite (Fe2O3) as found from XRD. The gangue minerals were separated during the magnetic separation, and the upgraded product was obtained, which reached a maximum value of TMn 49.5% with RMn 76.55% and TFe 62.19% with RFe 42.51%. In the study, activated charcoal (AC) was also taken as a reductant for comparative analysis; the experimental results revealed that GPCS performed better than that of the AC, showing potential to be used as a reductant in metallurgical industries. However, the resultedMn/Fe ratio was very low for the reduced sample; therefore, it can be used for smelting along with high-grade manganese ores as a feed.

Mar 5, 2021

By Erik Bengtsson

Phenol was discovered in coal tar by Runge (1)1/ in 1834 and was isolated (2) in 1841 as pure phenol by distilling the tar, extracting with caustic soda, acidifying the extract, and fractionating the tar acids. Later, o-cresol was isolated (3) through careful fractional distillation of the tar-acid mixture. The m-and p-cresols distilled within a boiling range of about 1.50 c. and had to be separated by other means. Raschig (4) fractionated the tar-acid mixture to obtain pure o-cresol, sulfonated the mixture of m-and p-cresols, and treated the cresol-sulfonic acids with superheated steam at 1200 to 1300 c. to hydrolyze the m-cresol sulfonic acid, the p-isomer was not affected at that temperature. He also attempted to make use of the different crystallizabilities of the m-and p-cresol sulfonic acids (5). When treated with sodium bisulfate and sodium pyro-sulfate at 100° to 110° C. or with sulfuric acid (90/0) at 20° C., only the m-cresol was sulfonated (6). Hoffman-La Roche (7) treated the meta-para mixture with concentrated sulfuric acid at 40° to 100° C., when m-cresol and part of the p-cresol was sulfonated, and precipitated the m-cresol sulfonic add by diluting with water. The same sort of separation may be carried out by means of 80 percent sulfuric acid at 35° C. and 35 mm pressure (8).

Jan 1, 1950