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By F. X. Spiegel, D. Bardos, Paul A. Beck

Ti6NileSi7)G is known to be cubic, with 116 atoms in the unit cell. In the present work four new G sili-cides were found with other transition elements and five G germanides. The titanium-group elements are very efficient in forming G phases. The vanadium -group elements are somewhat less efficient, and the chromium-group elements do not form any. Cobalt can replace nickel in most cases, but it is somewhat less efficient. Iron was not found to form any G phases. Germanium is somewhat less efficient than silicon. The (TiNiSi)E phase has been previously identified by Westbrook. However, its crystal structure has not been determined. In the present work the E phase was found to have an orthorhombic unit cell with lattice parameters a. = 7.02, bo = 5.18, co = 11.11A. A large number of other E phases were found at the same stoicheometric ratio in ternary systems of silicon and germanium with transition elements. Lattice parameters similar to those for TiNiSi were measured. The number of atoms per unit cell is estimated at 30 to 36. The vanadium-group elements are somewhat more efficient in forming the E phase than the titanium-group elements. Chromium-group elements were not found to form any E phases. Cobalt is somewhat less efficient than nickel, and iron is less efficient than cobalt. Germanium is not as efficient as silicon. ThE ternary silicide designated as G-phase was first identified by Beattie and versnyder1 and by Beattie and Hagel2 at the approximate composition TiNi2Si. Westbrook et al.' gave the composition as Ti2Ni7Sis. This phase was found to be fcc with a. = 11.201A and 116 atoms per unit cell. Beattie4 and more recently independently Hladishevskii, Kripyakevich, Kuzma, and Teslyuk5 were able to show that this structure is isotypic with MgeSi7CuLe and Th6Mn23. The latter structures had been determined by Florio, Rundle, and snow,' Nagorsen and Witte,7 and Bergman and Waugh.8 According to the crystal structure, Ti8Ni6Si7 may be considered as the ideal composition. The Russian investigators5 identified six additional ternary phases isotypic with Ti6Ni6Si7, in which titanium is replaced by Mn, V, Nb, Ta, Zr, and Hf, and one, namely MneNil6Ge7, in which germanium replaces silicon. They also found that Cr6Ni6Si7, which does not occur as a ternary phase, can be stabilized by replacing 1 at. pct of the Cr by V, Mn, or Ta. Another ternary silicide was found by Westbrook et al.3 at the composition TiNiSi, and it was designated by them as the E phase. The crystal structure of this phase has not been deter-

Jan 1, 1963

By A van Jaarsveld

Environmentally-friendly, safe and cost-effective technology for stope drilling has successfully been introduced at TauTona mine. It has enabled the problem of inadequate compressed air pressure and its downgrading impact on production capability to be overcome. The paper traces the development process which culminated in the conversion of the entire stoping operation at TauTona to electric drilling. Background work which took place at other mines is also described. Statistics of performance improvements are provided. 1. Introduction Holman?s Silver series and the Seco S215 were drills that had a measurable impact on the South African gold mining industry. It is too soon to say whether Hilti will join those great names. However, there is no doubt that the introduction of electric drills into the harsh and unforgiving world of deep level gold mining is a significant development. History has shown that being the first to enter a new technology is no guarantee of long-term success. The pain and suffering which accompany the birth of anything new can deplete the energy of the innovator while at the same time creating opportunities for competitors to leapfrog him. In addition to commitment and enthusiasm, the innovator must therefore also possess, or have access to stamina and resourcefulness to overcome the unexpected difficulties which will inevitably arise. All of these were needed for the Hilti project.

Jan 1, 2008

By Robert H. Ridgway

This circular outlines salient facts regarding the sulphur industry of the United States and the world. It is founded chiefly upon published information available in the literature of the subject. The Bureau of Mines has in its files additional, more detailed data upon many of the topics presented very briefly here, and will endeavor to assist the mineral industries and the public by giving further information in response to individual inquiries. It will welcome comments, criticisms, and contributions of data that may assist in making later editions of this circular more accurate, or in developing more fully the bureau's mineral files pertaining to sulphur. Throughout this paper sulphur is used to designate crude sulphur or brimstone, not sulphur produced from pyrites or' smelter gases.

Jan 1, 1930

By Wilton Johnson

Native asphalt was produced in 1982 by five companies in two States, Texas and Utah. Bituminous limestone, used primarily as a paving material for street and road repair, was produced by White Uvalde Mines and by Azrock Industries, Inc., Uvalde County, Tex. Historically, gilsonite, a solidified hydrocarbon found only in Utah and Colorado, had been mined by American Gilsonite Co. and by Ziegler Chemical and Mineral Corp. from properties near Bonanza, Uintah County, Utah. During 1982, Hydrocarbon Mining Co., a subsidiary of the Oberon Oil Co., entered into a joint venture with Miocene Resources Inc. of Novato, Calif, to form Hydrocarbon Resources Co. for the purpose of mining gilsonite about 50 miles south of Vernal, Uintah County, Utah. Under the agreement, Hydrocarbon Mining contributed gilsonite-bearing properties held by lease or sublease as well as mining equipment to the venture. The property contained leases totaling 760 acres with probable reserves of 268,000 tons of gilsonite. Miocene Resources provided the partnership with a minimum of $200,000 to develop two of the leases and were to be responsible for management of the mining operations.2

Jan 1, 1983

By R. A. Franks, G. F. Friel, J. C. Edwards, L. Yuan

Two mine-fire experiments were conducted in the National Institute for Occupational Safety and Health's (NIOSH) Safety Research Coal Mine (SRCM) at the Pittsburgh Research Laboratory (PRL) which demonstrated that smoke from diesel-fuel fires of 500 kW and 660 kW heat-release rates in a return airway can develop, without causing a complete air flow reversal, into a roof layer that can migrate upwind forming a counter flow to the primary airflow in a crosscut. Subsequently, smoke can penetrate into an intake airway and create a hazardous atmosphere in the intake airway upwind from the fire. Visibility conditions less than 13 m were created by the smoke in the intake airway downwind from the crosscut. Modeling of the event with a three-dimensional, time-dependent, computational fluid dynamics (CFD) program correctly represented the smoke movement.

By S. Y. Tan

As continual complementary metal?oxide?semiconductor (CMOS) scaling requirements, metal gate/high-k dielectric/Si gate stacks are expected to replace poly-Si/SiO2/Si gate stacks in the future CMOS sub-45 nm technology node. Hafnium based oxide is a promising candidate to replace SiO2 as a gate dielectric, due to its much higher dielectric constant (high-k) and stability. The key challenges of successfully adopting the high-k dielectric/Si gate stack into advanced CMOS technology mostly come from the interfacial properties. The origins of the electrical and physical characteristics of the dielectric oxide/bulk interface were studied in detail. The leakage current density-voltage (J-V) and capacitance-voltage (C-V) measurement techniques were employed to study the dielectric oxide/Si interface. The effects of the post-deposition annealing (PDA) treatment on the interface charges of dielectric oxides were studied. We found that the PDA can effectively reduce the trapping density and leakage current, and eliminate hysteresis in the C?V curves. Besides, the changes in chemical bonding features at HfO2/Si, HfSiO/Si and HfSiON/Si interfaces due to PDA treatment were evaluated by XPS measurements. The XPS analysis provides a better interpretation of the electrical outcomes. As a result, both HfSiO and HfSiON films have exhibited superior performance in terms of thermal stability and electrical characteristics.

Jan 1, 2010

By G. E. Vaninetti

During its modem era, the southern Powder River Basin (PRB) in Wyoming has grown from meager origins in the early 1970s to become one of the most important coal-producing regions in the United States. In 1993, production and sales of southern Powder River Basin coal exceeded 190 Mt (209 million st), or about 20% of the US coal industry. Despite the remote location of the PRB relative to its potential markets, most coal industry observers anticipate continued strong growth to meet utility compliance plans for Phases I and II of the Clean Air Act Amendments (CAAA). This article is an overview of supply and demand issues concerning the marketing of southern PRB coal. It reviews the events leading up to the recent run on spot coal and offers a forecast of demand and prices.

Jan 1, 1994

By Harry R. Price, Bharat Doshi, Awni Qaqish, Abdul-Ghani Mekkaoui, Thaddeus Znoy, Ramesh Shukla

In 1992, a detailed inspection of the Southfield Sewer revealed a reach of approximately 0.8 kilometers in length, located directly below the freeway lanes, which was severely distressed. Failure of this section of the sewer would result in the closing of the busiest roadway in the state as well as the potential backup of sewage into homes and spilling into nearby surface waters. As such, repair of the distressed section required development of a procedure that would not jeopardize the conveyance of flow through the existing sewer nor impede travel on the overlying freeway. Based on these constraints, the DWSD and NTH team developed a repair concept that entailed the mining of a new, 3.05-meter (10-foot) diameter bypass away from the traffic lanes. The new bypass section was connected to the existing sewer, up stream and down stream of the distressed area, using a “top down” construction approach, that required only minimal freeway closures during weekend periods. This paper, prepared jointly by the Owner, Consultant and Contractor will describe existing conditions, design considerations and construction methods.

Jan 1, 2001

Ore sorting is a high capacity, low cost method of pre concentrating ores and in some cases of producing a marketable concentrate. In most cases it is applied to run of mine material, immediately after primary crushing and screening in sizes ranging from 10 mm to 150 mm. Recent developments in bulk sorting of friable uranium deposits have resulted in machines capable of handling fine materials with sensing and separation being achieved on a zone by zone basis. Modern ore sorting machines rely on the synchronous operation of four internal subsystems, feed presentation, sensing, data processing and separation. A variety of different sub systems is available which can be combined in various forms to produce sorters capable of handling a wide variety of mineral types. The benefits in using ore sorting cover a wide range of situations and are applicable to both established mines as well as new mining ventures. Reduced operating costs, increased productivity, capital savings, energy and resource conservation and environmental issues are all part of the reason why ore sorting is finding rapid acceptance in today's mining industry. The suitability of different ore types for pre-concentration using anyone of the variety of ore sorting systems can be quickly established using computer based techniques which require only small samples of the materials under investigation.

Jan 1, 1980

By C. R. Austin

Tan investigation described in this paper deals with the development of high-temperature alloys of the Konel series over a considerable period of time at the Research Laboratories of the Westinghouse Electric and Manufacturing Co. The word "Konel" has been coined to designate a class of alloys which are essentially nickel-cobalt-iron with other elements added, usually in small quantities. Most of these alloys contain titanium, usually about 2.5 per cent. The main consideration related to strength at high temperatures but the thermionic characteristics of the alloys was also of considerable importance. It is, however, with the mechanical properties at elevated temperatures that we are herein concerned. Much attention has also been devoted to their age-hardening characteristics. There is little need to stress the utilitarian aspect of this subject, as it has been discussed frequently. Alloys exhibiting superior properties at normal or elevated temperatures rapidly find many suitable applications. There may be some question, however, as to what constitutes a "superior alloy, " or an alloy that may have good service possibilities at high temperatures. The problem is complex and various means have been employed to predict the useful life that may be expected of a material. In recent years the "creep limit" has been used as the best means of evaluation. Such tests necessarily are prolonged and hence collection of data is very slow. In a general survey of many alloys therefore the creep test is not desirable and recourse must be had to much shorter time tests in order more rapidly to select alloys which appear to show promise. For this reason the present survey has been made using the high-temperature tensile test and a bend test developed by Howard Scott.1 In the tensile test the conditions have been standardized for all tests, so that values obtained are at least comparable, one alloy with another, although the absolute values recorded merely indicate the mechanical properties at the given temperature under a definite rate of loading.

Jan 1, 1931

By Sadettin Bagdatli, Ali Kahriman, Umit Ozer, Alper Celtikci, Yucel Karakus

Due to population growth and rapid urbanization in Turkey, the need for the construction of residential units, transportation and infrastructure facilities has become increasingly more pressing. Since rock units encountered in the surface and underground in the construction of the subway, infrastructure and housing facilities, it is a necessity to use blast excavation methods. In recent years, large housing construction projects have been carried out especially in Turkish metropolitan areas, involving foundation excavations giving rise to great amounts of earthmoving. Since rock units encountered during foundation excavations are usually hard and solid, excavation with conventional machinery proves to be inadequate and unproductive, hence the necessity for the application of blasting technology.

Jan 1, 2014

By G. Graves, J. A. Walker

"Abstract - The Mount Fronsac North volcanogenic massive sulfide deposit is the most recently discovered massive sulfide body in the Bathurst Mining Camp. The deposit occurs within a sequence of intercalated fine-grained felsic tuff and sedimentary rocks (Little Falls member), at the top of the Nepisiguit Falls Formation. Aphyric to sparsely feldspar-phyric rhyolite and related volcanic rocks of the Flat Landing Brook Formation overlie the host sequence. The massive and semimassive parts of the deposit have a north-south strike length of 525 m and a dip of ~45°E; the deposit is continuous downdip for 600 m, and thickness varies from 2 to 20 m. The deposit contains an estimated geologic resource of 14 Mt of low-grade, semimassive (>60%) to locally massive sulfides, and includes a high-grade zone of 1.26 Mt grading 7.65% Zn, 2.18% Pb, 0.14% Cu, 40.3 g/t Ag, and 0.40 g/t Au. The semimassive to massive sulfide intersections occur in an envelope of quartz-sericite±chlorite schist, which is interpreted to be intensely deformed felsic tuff. This sequence has a maximum thickness of 140 m and contains significant (up to 50%) fine- to coarse-grained disseminated pyrite. The pyritic envelope has a strike length of 900 m and extends over 1000 m downdip. Massive sulfides are found throughout this alteration envelope, but more commonly occur at or near the upper contact. The significance of the discovery of this deposit is that it represents a near surface discovery of a large tonnage sulfide body in a mature mining camp, one in which the possibility of discovery of a new shallow deposit had been all but discounted. This opens the possibility for future discoveries in this part of the Bathurst Mining Camp. Sommaire - Le gîte de sulfures massifs volcanogènes du Mont Fronsac Nord est la découverte de sulfures massifs la plus récente dans le Camp Minier de Bathurst. Le gisement est situé dans une séquence de tufs felsiques à grains fins interlités de roches sédimentaires (membre de Little Falls, au sommet de la Formation de Nepisiguit Falls. La partie massive et la semimassive s’étendent du nord au sud sur 525 m et ont un pendage de ~45°E; le gisement est continu sur 600 m en angle de chute et son épaisseur varie de 2 à 20 m. Le gisement contient une ressource géologique évaluée à 14 Mt de sulfures semimassifs (>60%) localement massifs à basse teneur, incluant une zone à haute teneur de 1.26 Mt titrant 7.65% Zn, 2.18% Pb, 0.14% Cu, 40.3 g/t Ag, et 0.40 g/t Au. Les intersections de sulfures semimassifs à massifs se situent dans une enveloppe de schiste à quartz-sericite ± chlorite interprétée comme un tuf felsique intensément déformé. Cette séquence contient une quantité importante (jusqu’à 50%) de pyrite disséminée dont le grain varie de fin à grossier et son épaisseur maximale est de 140 m. L’enveloppe pyriteuse s’étend latéralement sur 900 m et a été tracée jusqu’à 1000 m en angle de chute. Des sulfures massifs sont trouvés partout à l’intérieur de cette enveloppe d’altération, mais ils sont plus fréquents près du contact supérieur. L’importance de cette découverte tient à ce qu’elle est un exemple d’un gisement à fort tonnage nouvellement découvert à une faible profondeur dans un camp minier mature, i.e., un camp ou l’on ne croyait plus qu’il était possible de trouver un gisement près de la surface. Ceci ouvre la porte à la possibilité d’autres découvertes dans cette partie du Camp Minier de Bathurst."

Jan 1, 2006

By W. E. Cassan, W. L. Eaton, James Westfield, W. M. Romisher, Karl Hughes, S. H. Ash

"INTRODUCTION Funds were made available to the Bureau of Mines, United States Department of the Interior, for anthracite investigations during the fiscal year ended June 30, 1945. One of the approved projects was to conduct inquiries and scientific and technologic investigations having a bearing on the anthradite mine-flood problem. The investigative work done from July 1,1944, to June 30, 1946, is described in previous reports (5, 8, 10, 24, 28). 6/Purpose of Report The purpose of this report is to describe the investigative work conucted by the Anthracite Food-Prevention Section, Safety Branch, Bureau of Mines, during the period July 1, 1946, to June 30, 1947,Scope of WorkInvestigative work during the fiscal year ended June 30, 1947, was conducted under the direction of D. Harrington, chief, Health and Safety Division, and S. H. Ash, chief, Safety Branch, Bureau of Mines, Washington, D. C.The broad objective of the investigative work was to obtain factual day on: 1. Anthracite reserves of Pennsylvania.2. Underground water pools.3. Barrier pillars.4. The ""buried valley"" of the Susquehanna River.5. Infiltration of surface water into underground mine workings.The above-mentioned investigations are being continued during the fiscal year July 1, 1947, to Juno 30, 1948.In addition to the investigative work covered in this report, Ash end Eaton presented a paper on barrier pillars, which proposes a method for designing barrier pillars and has been Published by the American Institute of Mining and Metallurgical Engineers (5);"

Apr 1, 1948

By Rob Farnfield, Ben Williams, Ashley Haslett, Diane Cartledge

Major accidents that occur within our industry are often tragic and expensive, damaging reputation and threaten the livelihood of the business. There isn’t anything in them that can be seen as positive for those that experience them. They undertake what are usually very painful, detailed and time consuming investigations to discover how the incident occurred and what needs to be done in the future to prevent similar incidents occurring. Many admirably choose to share the lessons learnt through industry organizations such as SAFEX International so that we can all have the opportunity of preventing similar incidents from occurring within our own organizations.

Jan 1, 2016

By S. Junnikkala, K. Föhr

"Experiments were performed with plant feeds with a continuous 1,8 m3 cell at Pyhasalmi mine with Cu flotation feed in order to test the applicability of the bubble surface area flux as an indicator of the flotation rate constant. It was found that bubble surface area flux could not predict the rate constants of coarse Cu containing fractions. In the middle size fraction, the correlation coefficient in the rate coefficient estimation was higher but not statistically significant. Only the fine fraction showed a linear relationship with a moderate correlation coefficient.The bubble surface area flux was shown not to be a function of the impeller velocity above a threshold value. The flux was an almost linear function of the superficial gas rate enabling to use the superficial gas rate instead of flux if the operation of an existing cell is to be estimated.INTRODUCTIONBubble area flux seems to offer a simple way of modeling flotation. It relates the flotation rate constant with the bubble surface area flux by a simple linear equation. Due to this, there has been a considerable interest in using the bubble area flux for flotation computations. It has even caused claims that a cell producing a high bubble surface area flux automatically produces a high rate constant and therefore a high recovery.This paper discusses some of the assumptions of the relationship and gives some plant results during two sampling campaigns.The bubble surface area flux s b is describing the area of bubbles available for flotation in a cell per unit area. The bubble surface area flux is related to the superficial gas rate J, by the Sauter mean diameter as follows"

Jan 1, 2001

By Douglas Bartley, Brian Wingfield, Robert McClure

Recent studies and limited tests indicate favorable results utilizing high accuracy electronic detonator technology over conventional non-electric pyrotechnic systems. This study discusses the application of this technology using the Daveytronic programmable system in an on-going production basis. The study quantifies the performance as it relates to fragmentation, excavation, vibration and productivity in an eastern U.S. aggregate mining operation.

Jan 1, 2001

By Ehsan Vahidi, Fereshteh Rashchi, Ataollah Babakhani, Alireza Zakeri

"The synergistic effect of Cyanex 302 on solvent extraction of nickel and cadmium from sulfate solution with D2EHPA diluted in kerosene was investigated with the aim of increasing separation efficiency. Experiments were carried out within a pH range of 0.1-5.0 using sole D2EHPA and D2EHPA-Cyanex 302 mixtures in different ratios. Increasing Cyanex 302 to D2EHPA ratios in the organic phase caused a left shifting of the extraction isotherm of cadmium and a right shifting of the extraction isotherm of nickel. As a result, optimum separation was found with a Cyanex 302 to D2EHPA ratio of 0.1M:0.5M. In the present system, effect of a modifying reagent such as TBP was studied. The influence of various diluents including kerosene and carbon tetrachloride was also investigated.IntroductionBatteries are popular sources of portable energy. Ni-Cd batteries are manufactured in two main groups of small domestic cells and large industrial batteries with 80% being in domestic use. Ni-Cd cells have various uses, for example in cordless electric utensils, cordless telephones, airplane engine starters, and communicational distribution systems [1].Depleted Ni-Cd batteries are classified as hazardous waste since nickel and cadmium are heavy metals and suspected carcinogens. Given the risk associated with uncontrolled disposal, directions for issuing legislation on disposal and recycling of used batteries have been made in industrialized countries [2]. Recycling of Ni-Cd batteries is important from both economic and environmental points of view. Different methods have been used for recycling these wastes through pyrometallurgy [3], biotechnology [4,5], and hydrometallurgy [1,2].Due to the advantages of hydrometallurgical processes, several studies have been implemented on leaching and solvent extraction (SX) of the used Ni-Cd batteries. Leaching of batteries is usually done in sulfate or chloride media; while solvent extraction has been used in different extractants: two-stage solvent extraction by D2EHPA and Cyanex 272 [6]. Solvent extraction of Cd from leach solutions has been studied using various extractants; Cyanex 301 [1], D2EHPA [7], Cyanex 302 [8], Cyanex 923 [9], Cyanex 272, Tops 99, PC88A [10]. Application of phosphorus based extractants for the solvent extraction studies of Ni such as TOPS 99 [11], D2EHPA [12], Cyanex 272 [2], has been investigated. Separation of Cd(ll), Ni(II), and Co(ll) from chloride leach liquor of spent batteries [13], were explored in the earlier studies. Cd extraction with D2EHPA involves co-extraction of both Ni and Co [14], which causes issues in the separation process efficiency."

Jan 1, 2012

By E. J. Gleim

An important phase in the Bureau of Mines investigation of electrical machines designed for operation in gassy coal mines is testing enclosures of electrical components for explosion-proof qualities. In brief, this testing consists of filling and surrounding the enclosure with an explosive atmosphere of methane and air and then igniting the atmosphere within the enclosure to determine (1) Whether the resulting explosion is confined without discharge of flame; (2) whether the enclosure walls are permanently distorted; and (3) whether excessive pressures are developed within the enclosure. Ordinarily, the pressures encountered in routine testing do not exceed 100 pounds per square inch gage. Hence, the designer of the machine does not have too much difficulty in taking corrective measures to prevent flame discharge and distortion of the enclosure. Occasionally, however, the explosion pressures greatly exceed 100 pounds. Then the goblet of the designer may not be solved so readily, From experience over the year 0, the testing personnel often can predict that certain construction will result in high. Pressures, but, only in a very general way, has it been possible to advise designers what modifications might be made to reduce the explosion pressures to normal values. For example, if high pressures were developed in a motor starter having a partition with an opening through it, some enlargement of the opening may appear to be the logical procedure, but it has not been- possible to give information concerning the exact amount the opening should be enlarged to prevent development of high pressures .

Jan 1, 1952

By Makoto Kimura

Failure tests on laterally loaded single and pile group are analyzed with a 3-dimensional elasto-plastic finite element program. In the analysis, the mechanical behavior of the ground is supposed to be elasto-perfect plastic with Drucker-Prager's yielding criterion. The nonlinearity of the piles is simulated by assuming a hyperbolic relation between the bending moment and the curvature of the piles. The influence of the axial stress on the cast-in-place concrete piles is also considered in the numerical analysis. It is found that the mechanical behavior of the piles subjected to lateral loading, such as the load-displacement relation up to an ultimately large deformation, and the distribution of bending moment in the pile group can be well simulated.

Jan 1, 1996

By AMIRA P588 Research Team

This contribution summarises new knowledge and data, obtained during a three year ARCAMIRA funded research project, on the mineralogical and geochemical characteristics of hydrothermal alteration associated with low sulfidation, gold-silver epithermal deposits. These data are used to develop exploration vectors for use at both deposit and district scales, plus techniques have been established to distinguish ore grade epithermal systems from barren or low grade systems. Deposits investigated were Ladolam, Papua New Guinea, Gosowong and Mt Muro, Indonesia, Cerro Vaguardia, Argentina and Bimurra and Twin Hills, Australia.

Jan 1, 2005