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By Eduardo Reis de Oliveira

As ligas fundidas de Alumínio são uma excelente opção para substituir os materiais convencionais devido às suas excelentes propriedades mecânicas. Assim, o uso destas ligas nas indústrias aeroespacial e automobilística estão em uso crescente. As propriedades mecânicas finais das peças são muito dependentes da macro e microestrutura, que são resultantes do processo de solidificação. Portanto, o controle dos processos de solidificação de ligas permite maximizar as propriedades mecânicas de um componente mecânico. Os parâmetros de processo que podem interferir na estrutura final de uma liga são amplos. Tem-se como exemplo: composição da liga, taxa de resfriamento, modo de extração de calor, condições de fusão e tratamento do metal líquido e temperaturas envolvidas durante a fundição. O objetivo deste trabalho foi estudar uma liga binária de Al-Mg usando a técnica solidificação unidirecional. As macroestruturas e microestruturas obtidas foram correlacionadas com parâmetros térmicos tais como: velocidade de deslocamento da isoterma liquidus (VL) e taxa de resfriamento (?). E os espaçamentos dendrítico secundários (?2) com a microdureza HV. A composição da liga analisada foi Al-Mg com 3% de Mg e com patamares de superaquecimento (?TV) variando em 20, 40 e 60ºC.

Oct 30, 2017

By Eduardo Macedo Junior

O presente trabalho descreve o desenvolvimento de uma nova especificação para a Linha de zincagem numero 3 (LZC#3) da Companhia siderúrgica nacional (CSN), de grande demanda e aceitação, alta produtividade e foco nos requisitos do cliente que tangem qualidade superficial e características metalúrgicas (resistência mecânica) em aços para atendimento do mercado Norte-americano. Este novo produto tem como característica o ciclo de recozimento com velocidade alta para obtenção de microestrutura 100% encruada na saída do equipamento e limites de escoamento e resistência acima de 500 MPa. A combinação dessas características do produto junto com as características do processo tornou a especificação “ASTM-A653MSS80CL1” um grande desafio para garantir qualidade superficial sem comprometer as propriedades mecânicas especificadas assim como a integridade do equipamento. O baixo custo de produção associado a alta produtividade desse produto fazem da especificação “ASTM-A653M-SS80CL1” um produto de extrema importância para a estratégia adotada pela CSN, mantendo dessa maneira sua competitividade no mercado Norte-americano e garantindo capacidade máxima de produção do seu equipamento em tempos de retração do mercado interno.

Aug 17, 2017

By Larry Hopkins

The molten metal circulation pump has become a staple for melting aluminum in reverberatory furnaces. The forced convection that is created in the melt efficiently provides circulation while dramatically improving melt rates, lowering fuel consumption, extending refractory life, and providing metallurgical homogeneity. Two metallurgical guidelines that are important to many casthouses are molten metal inclusion levels and hydrogen gas content. In order to improve molten metal quality, furnace and casting practices must 'manage these molten metal defects, Today specialized in-line degassing and filtration equipment is used downstream of the furnace to accomplish these tasks. In contrast, the molten metal gas injection pump has metallurgical contact time in the process for hours during the charging/homogenization cycle. The qualitative benefits of employing a gas injection pump to "pre-clean" are outlined and discussed against historical empirical information obtained with alternate methods. Further, a recent study quantifies the merits of this gas injection technique as an effective molten metal quality improvement tool. Specifically, the effects on inclusion level as determined by PoDFA?, gas content as determined by A1SCAN? sampling and alkali metal content as determined by spectrographic analysis are examined in relationship to various gas feed compositions and flow rates.

Jan 1, 1995

By D. D. Xu

A novel system for the depression of pyrite and the ash-forming minerals has been developed. A metal ion, including but not restricted to Fe+2, is added to form a hydroxide coating on the pyrite or ash-forming mineral. A polymeric depressant is then added to attach to this re-surfaced mineral. Nearly 200 flotation tests with a 11 different coals indicate the effectiveness of this system. Many of the important process variables such as the coal source, frother-collector system, grind size and procedure, pH, metal ion, and depressant type and concentration have been studied.

Jan 1, 1994

By R. A. Cattell

The Bureau of Mines actively conducted a well-coordinated research pro- gram during the past fiscal year on problems dealing with the production of oil and gas, transportation of natural gas, chemistry and refining of petrole- um, thermodynamic properties of hydrocarbons, and the processing and utiliza- tion of incombustible helium gas. These particular reserach phases, compris- ing the presently scheduled activities, are integral parts of a broad program selected soon after the war as suitable for Bureau of Mines study, to meet immediate needs for specific information on petroleum and natural-gas problems of national scope. Important progress was made and many technical reports were finished during the year. Several reports were published on gas-condensate production problems, one giving the results of laboratory tests of relative merits of various steels and alloys for rosisting the corrosion that occurs in high-pressure gas- condensate wells. Research was continued, using the Bureau's windowed cell, to determine the characteristics of gas-condensate fluids, and an important paper on the phase relations of these fluids at low temperatures was published. An important part of the Bureau of Mines petroleum production research program for many yoars has been the engineering study of type oil fields. This year reports waro completed on the Lake Creek, Sheridan, and West Rod River fields, Tex.; the Atlanta field, Ark.; and the Bogge field, W.V. Othor fields under study and for which reports will be issued are the Carthage and Now Hope fields, Tex., and the Weber pool, Okla. Spocial studios to determine the characteristics of the oil-gas solutions as they exist within the native reservoir rocks have been in progress in the North Lindsay field, Okla.; the Elk Basin field, Wyo. and Mont.; and the Rangely field, Colo. The North Lindsay study brought to light several un- usual physical proporties of the oil as it is found in this deep-seated reservoir. For instance, its viscosity is less than that of water, and more than 2 barrels of the initial reservoir oil must be produced to yield 1 barrel of "stock-tank oil." In the Elk Basin and Rangoly fields the oil-gas solution varies in composition within the reservoir, depending upon structural location. Engineering studies were continued on woll spacing and on drilling fluids with special emphasis on obtaining uncontaminated cores, or coros for which the flushing action of the drilling fluid can be dotormined accurately. In connection with research on production of oil by secondary recovery methods, progress was made in studies of conditioning water for subsurface injoction, of input ratos and pressures for water-flooding oil sands, and of the selective plugging the more permeable mediurs to prevent or retard channel- ing of the injected fluid. The availability of fuels for all types of internal-combustion engines still is tho primary resoarch project in potroleum chomistry and refining. This rosearch program is subdivided into a sorios of problems under four main topics: (1) Raw-material studios; (2) relationships of fuel consumption, proporties, and performanco; (3) utilization of potroleum products; and (4) analytical mothods, which include chomical and physical property detorminations.

Dec 1, 1949

By L. F. Willmott

The Bureau of Nines at Morgantown, W. Va., has been investigating, on a pilot plant scale, various methods of gasifying bituminous coal with oxygen and superheated steam to produce synthesis gas, as part of the broader program of finding new uses for coal. Differences in the pressure gasification methods used have depended on differences in the manner in which the pulverized coal is fed to the gasifier. One of the methods of feeding the coal that was investigated was the continuous, integrated coal-water slurry system. Goal and water were first mixed to produce a slurry; then the slurry was pumped through a heated coil. to evaporate the water fraction; the resulting steam was superheated, and some of it was separated so as to adjust the ratio of the residual steam to the coal fraction and make the resulting mixture suitable for partial combustion with oxygen in a pressure gasifier. Both before and during this reported3 developmental work it was necessary to make an extensive literature search into the technology of aqueous slurries in order to establish design criteria for the pilot plant and to correlate results of various phases of the work with that of other investigators, The pilot work coincided with the commercial development of a long-distance pipe- line for the transportation of coal as a coal-water slurry, and this fact tended to broaden the scope of the pilot plant work and the extent of the literature search. This bibliography is the compilation of the material that was collected.

Jan 1, 1963

By Zhang Chuanfu, Tan Pengfu

"A thermodynamic model is developed to predict the distribution behaviors of Ni, Co, Sn, Pb, Zn, As, Sb, Bi, Au and Ag in copper pyrometallurgical process. In this model, as more as 21 elements (Cu, S, Fe, Ni, Co, Sn, As, Sb, Bi, Pb, Zn, Au, Ag, 0, N, C, H, Ca, Mg, Al, and Si) and 72 compounds (in fayalite-slag-making system) or 74 compounds (in ferrite-slag-making system) are considered. Accessory-element behavior is studied for two types of slag , fayalite and ferrite, and two levels of oxidation. The allowance is also made to account for physical entrainment in the melts.-Model simulations are carried out to study the effects of controllable process parameters such as feed composition, smelting temperature, degree of oxygen enrichment and volume of oxygen enriched air. The model can be used in copper flash process, Mitsubishi process and Noranda process. The predictions by the present computer model are compared with the known industrial data from Gui Xi Smelter in China, Home Smelter in Canada and Naoshima Smelter in Japan and excellent agreement between calculations and industrial data is obtained. In this paper, the effects of oxygen enrichment, matte grade, smelting temperature, and types of slag on accessory-element behavior among matte, slag and gaseous phase have been elucidated.I . IntroductionThe presence of trace quantities of minor elements such as As, Sb and Bi in copper significantly reduces its ductility, electrical conductivity, and lowers its thermal conductivity. Embrittlement of copper also occurs due to impurity-phase precipitates at the copper grain boundary interfaces. They deteriorate not only the electrical conductivity of copper but its workability in hot working."

Jan 1, 1998

By A. Davis

Pit lake chemistry depends on the lithology and hydrologic characteristics of the ultimate pit surface, the availability of buffering capacity in the wall rock versus oxidizable sulfide content, and the alkalinity of recharging ground water. In this paper, we assess the geochemistry of 11 existing pit lakes, ranging from the acidic Red Hill and Berkeley pit lakes (pH 2.6 to 2.8) to the alkaline Yerington Pit lake (pH 8.45). Predicted pit lake chemistry is similar to that in existing pits with the long-term pit lake chemistry lying on a geochemical continuum between end members consisting of influent calcium bicarbonate ground water, and naturally occurring sulfate-rich evaporite playa lakes.

Jan 1, 1996

By Paul Zinner

An exhaustive program of geologic studies and mapping has been conducted by the Geological Survey in the Iron River district of Michigan since May 1943. Means of contributing to the success of these studies were sought by the Bureau of Mines, and eventually a program involving geophysical studies and core-drilling was undertaken in the area. All of the work was done either to develop data that would contribute directly to geologic studies or to investigate geophysical methods that might be used as a primary means for the discovery of minable iron ore.

Jan 1, 1949

By P. Altinkaya, O. Celep, H. Deveci, E. Y. Yazici

"Copper-bearing gold ores have proved difficult to treat in conventional cyanide leaching process owing to prohibitively high consumption of cyanide by readily soluble copper minerals interfering with gold extraction. Cyanide leaching of gold from copper-rich ores can be improved by intensive cyanidation or application of physical and chemical pre-treatment methods (e.g., ultra-fine grinding, roasting and leaching). In this study, nitric acid leaching of a copper-bearing pyritic concentrate (0.3% Cu, 62 g/t Au and 110 g/t Ag) as pre-treatment prior to cyanidation was investigated. The mineralogical analysis of the concentrate has revealed that it is composed of mainly quartz (25%), pyrite (32.7%), sphalerite (5.37 %), galena (2.12 wt %) and anglesite (1.13 %). Arsenopyrite, chalcopyrite, covellite and bournonite were also detected as minor phases present. Previous studies carried out by the authors showed that direct cyanidation (1.5 g/L NaCN) of the as-received concentrate (d80: 80 µm) produced low gold (45% Au) and silver (46% Ag) extractions. Nitric acid pretreatment of the as-received concentrate was performed for 5 hours at 1-5 M HNO3 and 80oC. In these tests, 65% Cu/Pb and 94% Zn were leached. The nitric acid pre-treatment improved the extraction of gold and silver in subsequent cyanide leaching (1.5 g/L NaCN) to 82% Au and 87.5% Ag with a concomitant decrease (up to 54%) in cyanide consumption. It can be inferred from these findings that the removal of copper from the concentrate and the liberation of the occluded gold by nitric acid leaching as pretreatments can be appropriately employed for the treatment of the copper-bearing pyritic concentrate with high gold/silver content. INTRODUCTION Refractory ores are often characterized by their low amenability to cyanide leaching resulting low (often <80%) Au/Ag extractions (Bhappu, 1990; Celep et al., 2009; Marsden and House, 2006). One of the most common causes of refractoriness is the physical or chemical encapsulation of submicroscopic or fine-grained gold in sulphide minerals such as arsenopyrite and pyrite (La Brooy et al., 1994; Vaughan, 2004). To render refractory gold ores/concentrates amenable to cyanide leaching, the decomposition of sulphide minerals within a pre-treatment process to expose the encapsulated gold grains to the action of cyanide is required. In this regard, roasting, pressure oxidation and biooxidation are commercially used processes for pretreatment of arsenopyrite/pyrite gold ores/concentrates ahead of cyanide leaching (La Brooy et al., 1994). Presence of cyanide-soluble copper minerals in the ore leads to low gold recoveries and high cyanide consumptions under conventional cyanide leaching conditions. High cyanide concentrations (CN:Cu>4) should be employed to achieve high gold recoveries from copper-rich gold ores/concentrates. This may require recovery of cyanide from effluents. In this regard, SART Process (sulphidisation-acidification-recycling-thickening) employed industrially for recovery of cyanide and copper as a by-product. This process simply relies on the addition of sulphide (as Na2S, NaSH or H2S) to the leach solution prior to the acidification to pH 4-5. This results in the precipitation of copper as Cu2S and occurrence of free cyanide which is recycled to the leaching circuit after S/L separation (Dai et al., 2012)."

Jan 1, 2018

By Kamilla Giló Santiago

Nesse trabalho para caracterização metalúrgica dos revestimentos compostos pela mistura das ligas AWS ERNiCrMo - 3 E AWS ERNiCrMo - 4 soldados pelo processo MIG/MAG duplo arame foram realizadas análises micrográficas por meio de microscopia eletrônica de varredura. Observou-se semelhança entre os precipitados do topo e da interface do metal de solda com o substrato e que a microestrutura obtida com a soldagem das duas ligas, simultaneamente, resultou na mistura das microestruturas, obtidas a partir das soldagens com cada uma das ligas de forma isolada. O ensaio para avaliação do desempenho da mistura quanto à resistência a corrosão foi realizado conforme a norma ASTM - G 48, método C para determinação da temperatura crítica de pite da mistura das ligas. Foram utilizadas amostras dos revestimentos com maior e menor diluição. O resultado do ensaio apontou que os revestimentos soldados apresentaram temperatura crítica de pite superior ao da liga AWS ERNiCrMo-3 e semelhante ao da liga AWS ERNiCrMo-4.

Aug 7, 2018

By Z. Jin, D. DePaoli, P. Zhang

"Phosphorite, or phosphate rock, is the most significant secondary rare-earth resource. It contains high amounts of phosphate-bearing minerals along with low contents of rare earth elements (REEs). In Florida, about 19 Mt of phosphate rock are mined annually and most are used to manufacture fertilizers using a wet process, in which sulfuric acid reacts with phosphates to produce phosphoric acid and phosphogypsum. In the wet process, REEs are also leached out into solution and eventually get lost in the leaching residue and phosphate fertilizer. Recovering REEs from Florida phosphate rock in the wet process will be beneficial to broadening rare-earth availability, improving the quality of phosphoric acid product and protecting the environment.This study focuses on the influences of wet-process operating conditions on REE leaching efficiency. The results indicate that REE leaching efficiency increases with phosphoric acid addition in the initial pulp. At a temperature of 75 °C, a stoichiometric ratio of sulfuric acid (H2 SO4 ) to calcium oxide (CaO) of 1.05 and a weight ratio of liquid to solid of 3.5, REE leaching efficiency reached a relatively high value of 52.82 percent. The trends of REE leaching efficiency were similar to those for phosphoric acid (P2O5 ). Extensive tests on the leaching residue showed that during leaching, about 90 percent of the REEs were released from the phosphate rock but only 52.82 percent ended up in the leaching solution. This phenomenon can be attributed to two factors: (1) the effect of phosphate ions (PO4 3-) in the solution, which caused REE ions to form REE phosphates and be precipitated into the leaching residue, and (2) the influence of large amounts of anions such as sulfate (SO4 2-), dihydrogen phosphate (H2 PO4 -) and hydrogen phosphate (HPO4 2-) anions as well as the polar molecule H3 PO4 , which surrounded the REE cations and formed an ion atmosphere that prevented the PO4 3- from contacting and combining with REE cations. Interaction of these two opposite effects determined the REE distribution between leaching solution and residue."

Jan 1, 2017

Page The Cobaltchromium Binary System (paper by A. R. Elsea, A. B. \Yesterman, and G. K. Manning, Met. Tech. June, 1948, Mechanism of Precipitation in a Permanent Magnet Alloy (paper by A. H. Geisler and J. B. Newkirk, Met. Tech. Aug. 1948, Tp 2444)................................................................................................. 300 Some Effects of Applied Stresses on Precipitation Phenomena (~aper by W. L. Finlay and W. R. Hibbard, Jr., Met. Tech. Sept. 1948, Tp 2470)....................................................................................... 301 Diffusion of Carbon in Austenite with a Discontinuity in Composition (paper by L. S. Darken, Met. Tech. Sept. 1948, TP 2443) 304 An Electron Diffraction Study of Oxide Films Formed on Nickelchromium Alloys (paper by J. W. Hickman and E. A. Gul- bramen, Met. Tech. June 1948, Tp 2372)..................................................................... 305 An Electron Diffraction Study of Oxide Films Formed on Copper-nickel Alloys at Elevated Temperatures (paper by J. W. Hickman and E. A. Gulbransen, Met. Tech. June 1948, TP 2391)................................................ 307 Decarburization of Chrome Nickel Alloys by Their Surface Oxides in High Vacua and at Elevated Temperatures (paper by E. A. Gulbransen, W. S. Wysong, and K. Andrew, Met. Tech. Sept. 1948, TP 2438)................................ 307 Fractographic Study of Cast Molybdenum (paper by C. A. Zapffe, F. K. Landgraf and C. 0. Worden, Met. Tech. Aug. 1948, TP 2421)................................................................................................. 308 Effect of Composition on Grain Growth in Aluminum-magnesium Solid Solutions (paper by L. J. Demer and P. A. Beck. Met. Tech. June 1948, TP 2374)............................................................................. 309 Effect of a Dispersed Phase on Grain Growth in Al-Mn Alloys (paper by P. A. Beck, M. L. Holzworth and P. Sperry, Met. Tech. Sept. 1948, TP 2475)................................................................................. 310 Statistical Rate Theory of Metals—Mechanism of Flow and Application to Tensile Properties (paper by J. W. Fredrickson and H. Eyring, Met. Tech. Aug. 1948, TP 2423)............................................................... 315 Nucleation of Slip Bands (paper by J. G. Leschen, R. P. Carreker, and J. H. Hollomon, Met. Tech. Sept. 1948, TP 2476) and.. 318 Transient Plastic Deformation (paper by R. P. Carreker, J. G. Leschen, and J. D. Lubahn, Met. Tech. Sept. 1948, TP 2477).. 318 Plastic Deformation of Large Grained Copper Specimens (paper by W. R. Hibbard, Jr., Met. Tech. Sept. 1948, TP 2469). ... 323 Plastic Flow in Anisotropic Sheet Steel (paper by L. R. Jackson, K. F. Smith, and W. T. Lankford, Met. Tech. Aug. 1948, TP 2440)................................................................................................. 323 The Effect of Thermal-mechanical History on the Strain Hardening of Metals (paper by J. E. Dorn, A. Goldberg, and T. E. Tietz, Met. Tech. Sept. l948, TP 2445)....................................................................... 325 The Room and Elevated Temperature Properties of Some Sand Cast Magnesium-base Alloys Containing Zinc (paper by T. E. Leontis, Met. Tech. June 1948, TP 2371)..............................................................., 327 The Low Temperature Properties of Tin and Tin-lead Alloys (paper by H. S. Kalish and F. J. Dunkerley, Met. Tech. Sept. 1948, TP 2442)............................................................................................335 Thermal and Electrical Properties of Ductile Titanium (paper by E. S. Greiner and W. C. Ellis, Met. Tech. Sept. 1948, TP 2466).................................................................................................... 335 Property Changes during Aging (paper by A. H. Geisler, Met. Tech. Aug. 1948, TP 2436)............................... 337 Factors Affecting the Tensile Notch Sensitivity of Magnesium Alloy Extrusions (paper by I. Cornet, Met. Tech. Aug. 1948, TP 2419)................................................................................................. 338 Effect of Grain Size on Tensile Strength, Elongation and Endurance Limit of Deep Drawing Brass (paper by H. L. Walker and W. J. Craig, Met. Tech. Sept. 1948, TP 2478)............................................................. 339 A Copper-base Alloy Containing Iron as a High-strength, Highconductivity Wire Material (paper by W. Hodge, R. I. Jaffee, J. G. Dunleavy, and H. R. Ogden, Met. Tech. Aug. 1948, TP 2422).............................................. 340 A High Strength-High Conductivity Copper-silver Alloy Wire (paper by W. Hodge, R. I. Jaffee, J. G. Dunleavy, and H. R. Ogden, Mel. Tech. June 1948, TP 2366)...................................................................... 340 The Effect of Chronlium on the Ma Point (paper by J. B. Bassett and E. S. Rowland, Met. Tech. Aug. 1948, TP 2417.... 341 The Kappa Eutectoid Transformation in the Copper-silicon System (paper by W. R. Hibbard, Jr., G. H. Eichelman, Jr., and W. P. Saunders, Met. Tech. Sept. 1948, TP 2441).............................................................. 343 Stabilization of the Ausknite-martensite Transformation (paper by W. R. Harris, Jr. and M. Cohen, Met. Tech. Sept. 1948, TP 2446)................................................................................................ 344 Secondary Hardening of Tempered Martensitic Alloy Steel (paper by W. Crafts and J. L. Lamont. Mel. Tech. Sept. 194,8, TP 2439)................................................................................................. 345

Jan 1, 1950

By G. R. Smith

This report describes research carried out by the Bureau of Mines to develop new technology for electrorefining metals at much higher current densities than those normally used in commercial practice, preliminary studies using rotating-ring and cylinder electrodes to increase the mass transport of copper are discussed. Following this work, single- and multichannel cells were developed that utilized a high electrolyte flow in the channels formed by the anode-cathode pairs. Using these cells, copper was successfully refined at current densities in the range of 70 to 300 amp/ft2. The effects of flow rate, electrolyte composition, and grain-refining and leveling agents on the morphology and purity of electrodeposited copper were determined.

Jan 1, 1979

By Takaaki Wajima

The slag was attempted to be converted into the adsorbent for phosphate removal from aqueous solution using the alkali fusion method. The slag was mixed with NaOH powder (NaOH / Slag = 1.6), and then the mixture was heated at 600 ? for 6 h to prepare the precursor. The precursor was stirred at room temperature in distilled water to synthesize the adsorbent, and the removal ability of the obtained adsorbent for phosphate from aqueous solution was investigated. The products, including hydrocalumite and calcite, were synthesized, and the removal efficiencies of the adsorbent for F- and PO43- showed higher than those of raw BF slag, especially removal of PO43- are excellent (99 %), while the removal of Cl- , SO42-, NO3- and Br- was minor. The adsorbent could remove PO43- selectively in the co-existing solution of Cl-, NO3-, F-, SO42- and Br-.The equilibrium adsorption capacity of the adsorbent for PO43- was extrapolated using Langmuir and Freundlich models, and experimental data are found to fit Langmuir than Freundlich. The calculated maximum adsorption capacity of the adsorbent for PO43- is higher than other adsorbent reported previously. The high affinity of the adsorbent for PO43- in aqueous solution was caused by the formation of hydroxyapatite [Ca5(PO4)3(OH)] and brushite [CaHPO4?2H2O]. The prepared adsorbent is expected to be anew inorganic adsorbent for the removal of phosphate ion from wastewater. Keywords: Blast furnace slag, Alkali fusion, Phosphate removal, High selectivity

Sep 1, 2012

By S. H. Lorain

The Minah silver-lead mine in the Wickes district, Jefferson County, Mont., produced substantial quantities of silver-lead ores in the 1890&apos;s. The mine has been abandoned since the "silver panic" of the early 1900&apos;s. As a part of the Bureau of Mines: program to develop new sources of lead to overcome the growing shortages of that metal, a development project was started at the Minh mine in April 1946 and continued until June 1947, during which 5,600 feet of angledozer trenching and. 1,093 feet of core drilling were completed on the main vein and nearby parallel veins: As a result of this work, interest in the property was stimulated and private operators are now engaged in reopening the mine. This report discusses the past history, geologic setting, and the recent and early operations of the mine.

Jan 1, 1948

By W. L. Falke

This Bureau of Mines report illustrates critical path planning and scheduling techniques as applied to typical mining operations. Detailed examples of arrow diagramming and computer oriented applications of critical path methods are given. Program Evaluation and Review Technique (PERT) is discussed briefly in comparison to the Critical Path Method (CPM).

Jan 1, 1966

By J. E. Doo1ey

To process and use the heavy ends of petroleum effectively, the development of suitable separation and characterization procedures not currently available was required. A systematic procedure was developed by the Bureau of Mines using such techniques as isothermal and molecular distillation, chemical treatment, silica-alumina gel chromatography, gel permeation chromatography, and spectrometry. Using these techniques, the Bureau achieved a detailed separation and characterization of a 370° to 535° C distillate from Gach Saran, Iran, crude oil. Such a systematic procedure and the semiquantitative data resulting therefrom should be of value in selecting feedstocks and in optimizing petroleum processing operations.

Jan 1, 1973

By M. L. Whisman

Three samples of waste lubricating oil were re-refined by processes developed by the Bureau of Mines and reformulated with additives to meet designated requirements for viscosity and service. Quality-defining bench-scale tests were used to compare and evaluate the quality of these three motor oils, eight commercially re-refined lubricating oils, and three new lubricating oils. Most of the re-refined oils studied could not be distinguished from new oils by the bench tests used to define quality. There was some evidence, however, that one and perhaps more of the re-refined products investigated might not meet all of the quality standards of new lubricating oil, suggesting the need for better quality controls by re-refiners.

Jan 1, 1974

By A. C. Fraker, H. H. Stadelmaier

WIENER and Bergerl reported the existence of the nitrides Fe3NiN and Fe3PtNwith a cubic L1&apos;2 structure. The present note shows that a similar nitride Fe3PdN can be observed and that the composition range between the iron nitride Fe4N and the nitrides Fe3NiN, Fe3PdN, and Fe3PtN is occupied by single-phase cubic nitrides with structures intermediate between L1&apos; and L1&apos;2. The materials used in this investigation were electrolytic iron of 99.9 pct purity, carbonyl nickel of 99.7 pct purity, sponge platinum of 99.95 pct purity, and palladium sheet of 99.8 pct. purity. Binary alloys of the transition metals were induction-melted in a crucible of fused alumina, powdered, and screened to a particle size of - 200 mesh. The powders were nitrided at 600°C in a gas mixture of ammonia and hydrogen, and the crystal structure was determined with the aid of a Wilson powder camera. The results are compiled in Table I together with information from the paper of Wiener and Berger.1 The compound at the nominal composition Fe3PdN has a diffraction pattern with prominent reflections of a face-centered cubic lattice (h2 + k2+l2 = 3, 4, 8, 11, 12, 16) and weaker superstructure lines (h2 + k2 + 12 = 1, 2, 5, 6, 9, 10, 13, 14). With decreasing palladium content the superstructure lines become weaker and approach the intensity of those of Fe4N. No analysis was made of the intensities, but it can be assumed that the structure is that found by Wiener and Bergerl in Fe3NiN and Fe3PtN, namely L1&apos;2 (perovskite structure) with both palladium and the interstitial nitrogen fully ordered. The dependence of the lattice constant upon the solute atom (Ni, Pd, Pt) content can be explained tolerably well by simple lattice expansion due to subsequent work confirms this suggestion, it will be of significance to order-disorder theory. The author is grateful to Lester Guttman for discussions on this topic.

Jan 1, 1961