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By P. T. Brooks

This Bureau of Mines study describes a process for recovering nickel, cobalt, molybdenum, and chromium contained in complex waste superalloy grindings that, for lack of an economical domestic recovery process, are being largely marketed abroad. The process, devised by laboratory scale operations, includes scrap preparation, dissolution of metallics in hot chlorinated acidic liquor, carbon adsorption, three successive solvent extraction separations, and selective chemical precipitations. Nearly 90 percent of the nickel, cobalt, molybdenum, and chromium were separated and recovered as oxides, carbonates, and basic sulfate products.

Jan 1, 1969

By Andrea Bernardes

Printed circuit boards (PCBs) of varying compositions have been converted by incineration and following melting into an environmental agreeable slag and a copper-nickel-tin alloy, containing the precious metals. The environmental compatibility of the slag was determined according to the German standard DIN 38414 - Part 4; pollutants' concentration in the lixiviates is smaller than the thresholds of drinking water (CE-Standards). Each experiment the charge were 500g scrap from PCBs and ca. 100g slag forming material. The products were a kind of mullite slag, poor on iron, which was recirculated, and an alloy containing up to 0.3% Gold. With a burner to the retort coal gas, the waste gas was burned without soot, and the produced mixed zinc-lead oxide containing silver was collected in the flue dust.

Jan 1, 1997

By Donald E. Redmon

This Bureau of Mines report reviews injury experience in the nonmetallic mineral industries (except stone and coal) for 1968-69. For each of the years, 23 tables summarize disabling work injuries by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By Benjamin W. Haynes

This research was conducted as part of the U.S. Department of the Interior, Bureau of Mines program to recover metals, glass, and a combustible fraction from municipal solid waste (MSW). The objective of this analytical study was to determine the concentration of antimony, arsenic, and mercury in samples taken from various sampling areas in the Bureau of Mines raw refuse recycling plant and to compare these values with those for coals used in the generation of electricity. To provide the necessary analytical data, sensitive reproducible ashing-chemical digestion-atomic absorption procedures were adapted from published procedures. It was determined that antimony and mercury concentrations in the combustible fraction of MSW are approximately an order of magnitude higher than those found in coals presently used for power generation;' the arsenic concentration is similar in both fuels.

Jan 1, 1978

By Nélida Tantavilca, Pablo Espinoza, Claudia Barreto

En el sector minero uno de los principales problemas lo constituye el drenaje ácido de mina (DAM), sobre todo en operaciones mineras abandonadas y en operaciones activas que no logran controlar adecuadamente la calidad de sus vertimientos. Se investigó el grado de remoción de metales cobre, hierro, plomo y zinc disueltos en drenaje ácido de mina por aplicación de diferentes proporciones de mezclas de reactivo neutralizante (RN) cal hidratada al 67% de óxido de calcio (CaO), con material adsorbente bentonita sódica natural (BE), comparado con la aplicación de reactivo neutralizante sin mezcla, comúnmente utilizado en la neutralización de los drenajes ácidos de mina.

Sep 30, 2022

By Jennifer A. Slatnick

Chlorofluorocarbons (CFC's), once universally accepted as ideal compounds for use in cooling and refrigeration, in foam production, and in cleaning electronic components, are being phased out and eventually banned under extensive international agreements because the chlorine in CFC's is thought to deplete the Earth's ozone layer. The industry has responded with the introduction of alternatives in the form of hydrofluorocarbons (HFC's), which contain no chlorine, and with hydrochlorofluorocarbons (HCFC's), which fill an intermediate gap in the replacement of CFC's. As a result of the elimination of chlorine in the HFC's and the reduction of it in the HCFC's, these alternatives contain more fluorine than the CFC's do. Other nonfluorocarbon substitutes, known as not-in-kind alternatives, contain no fluorine at all. As a result, the fluorspar mining industry, which is the source of fluorine in fluorocarbons through intermediate hydrofluoric acid, is being affected. Concern for this impact has led the U.S. Bureau of Mines to employ its capabilities to analyze various scenarios in the evolution of CFC replacements and substitutes to determine their effect on fluorspar mining. This report utilizes a network flow model to examine the effects of proposed replacements for CFC's, in terms of fluorine content, on fluorspar operations worldwide and on hydrofluoric acid plants in North America and Europe.

Jan 1, 1994

By Svensson J

The nickel segregation process is one of the methods for treating nickel oxide ores. In this process nickel oxide ores are heated together with a small amount of the carbonaceous reductants and halides to about 800-950¦C. The reduced nickel segregates onto the surface of the carbonaceous reductants in the form of metallic particles which are recovered by magnetic separation or flotation. Pilot plant tests for the extraction of nickel from nickel oxide ores have been made using nickel segregation process by means of a new roasting installation which is called the "Mechanical Kiln" (2.5m~ x 3m,') with autogenous heating. Nickel oxide ores containing about 2.5%Ni were mixed with 2.5%CaC12 and 2.7%coal, and continuously charged into this installation at the rate of 60kg/h in continuous operation for 30 days per trial.

Jan 1, 1980

By Kwame Awuah-Ofei, Sisi Que, Shaochun Yuan, Yumin Wang, Ziwei Ding

This research sought to facilitate improved stakeholder analysis in mining by providing further insights into the preferences of local community members using discrete choice theory. While recent research has demonstrated the usefulness of discrete choice theory in mining stakeholder analysis, no previous work has examined which discrete choice model (DCM) is most suitable. This paper provides a research note on a case study in a mining community that was performed to compare three DCMs. After a thorough examination of the benefits and deficiencies of all models, this study concludes that the conditional logit model stratified by questions is the most useful DCM for mining stakeholder analysis. The recommendation is based on the usefulness and accuracy (ability to match the survey data) of this model.

Jul 25, 2022

By A. Johnson

When are SMART transmitters the smartest choice? To answer this question requires a closer look at SMART transmitter technology. It is necessary to understand this technology in order to recognize how it can best be utilized to give the greatest value for the application. And, once the decision to buy transmitters has been made, it becomes a question of whose SMART transmitter to buy. For, although the under-lying technology is similar, the differences that exist in how the technology has been implemented can make a dramatic difference in the end result. What prudent users of SMART technology do is to analyze their needs by application before making their buying decision.

Jan 1, 1988

By D. A. Reynolds

Yields of ammonium sulfate obtained in the carbonization of coal frequently vary from plant to plant, because ammonia is an unstable compound at high temperatures and therefore sensitive, to changes in carbonizing conditions. Differences in byproduct yields of ammonium sulfate obtained at different plants generally are accounted for by variations in plant procedure, either in preparing the coal or in its carbonization. However, technicians of one large corporation,- which frequently obtained higher yields of ammonium sulfate in its Alabama plants than ever were attained in its Ohio plants, "could not reconcile the differences in yields with their plant operations. These investigators suspected that the Alabama, coal used in their southern plant yielded more ammonia because its composition differed inherently from that of the Pennsylvania and West Virginia coals fused in their Ohio plants, although this concept could not be proved readily in their large-scale operations. Their view is supported by experimental data obtained A Beau of Mines-American Gas Association (BM-AGA) carbonization tests) -21 of a large number of coals including those carbonized commercially in Alabama and Ohio.

Jan 1, 1949

By N. Sauret-Szczepanski, G. Patry, S. Gauthier, G. Potvin, C. Munger

Adsorption/thermal desorption with sorbent cartridges and analytical method using gas chromatography coupled to mass spectrometry (GC/MS) was developed for the determination of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) emitted from primary aluminum smelters. A customized cartridge was built like a packed column with a stainless steel tube filled with a specific resin. The optimization of adsorption and desorption parameters was carried out to support the PFC sampling for all aluminum production technologies. The proposed method showed good linearity for concentrations ranging from 10 to 500 ppbv for CF4 and from 5 to 500 ppbv for C2F6 with correlation coefficients above 0.999. In certain conditions, the detection limits of the analytical method reached 0.3 ppbv for CF4 and 0.15 ppbv for C2F6- Using this methodology, a field campaign was carried out using a sequential sampler allowing the simultaneous sampling of PFC with cartridges and sampling bags. The results showed no significant difference (t-test) between the two sampling technologies and no breakthrough was observed from the cartridges .

Jan 1, 2006

By Laurel A. Powers

The Bureau of Mines process for recovering Ni and Co from low-grade domestic laterites uses a reduction roast followed by an ammonia, ammo-nium sulfate leach. This investigation examined the waste streams of the process for their potential environmental impact and focused on the laterite residue produced. The U.S. Environmental Protection Agency's extraction procedure (EP) toxicity tests and column leaching showed that leachable metal concentrations would be low enough so that the residue would not be considered a hazardous waste under present definitions. Under nonacid leaching conditions, about the same amount of metal was extracted from laterites as from their residues, and the leachates were similar to water samples from an undisturbed laterite deposit. Washing tests on the laterite residue showed that ammonia and ammonium sulfate concentrations were reduced according to equilibrium stage calculations, resulting in residues that would be acceptable for revegetation. With water washing only, the residue would not be considered a hazardous waste even though significant amounts of Ni and Co were absorbed from entrained leach solution onto the residue. Washing first with fresh leach solution and then with water prevented this absorption and thus improved the overall metal recovery.

Jan 1, 1983

By Jorge Luiz Soares do Couto

O presente trabalho tem como objetivo realizar uma análise comparativa do comportamento de quatro metais de solda obtidos pelo processo arame tubular de forma a avaliar o efeito da relação Ni-Mn nas propriedades mecânicas. Foram soldadas juntas multipasse, com consumíveis da classe 110ksi de resistência mecânica, preaquecimento de 200°C, corrente contínua e posição plana e aporte térmico nominal de 1,2 kJ/mm. Após a soldagem, realizaram-se ensaios mecânicos e metalográficos em corpos-de-prova retirados integralmente do metal depositado, na condição de como soldado e após tratamento térmico pós-soldagem. Os resultados mostraram que as melhores propriedades mecânicas foram obtidas para uma composição contendo 1,35%Mn e 2,50%Ni. Adicionalmente, verificou-se que o tratamento térmico pós-soldagem propiciou uma redução da tenacidade ao impacto dos metais de solda de maior resistência devido à precipitação de carbetos nos contornos de grão.

Aug 7, 2018

By Marcela dos Passos Galluzzi Baltazar

Catalisador monolítico comercial de níquel foi selecionado com o objetivo de se determinar o regime cinético da reação de oxidação parcial do metano (OPM). As estruturas cristalinas deste catalisador foram identificadas por DRX. A composição química superficial e o estado químico dos elementos presentes na superfície da amostra foram determinados por EDX. A técnica de microscopia (MEV) com emissão de campo foi utilizada neste trabalho com as finalidades de análise morfológica do catalisador antes de sua utilização nas reações de oxidação parcial. Análises de TG-DTA foram realizadas com o objetivo de se estudar o comportamento térmico do catalisador. A área superficial e a área metálica foram determinadas por BET e Quimissorção, respectivamente. A temperatura de redução do catalisador foi determinada através de TPR. Foi utilizada uma unidade experimental para realização de testes catalíticos. Antes das reações, os catalisadores pulverizados na faixa granulométrica < 0,150 mm foram submetidos a uma etapa de redução para ativar os sítios de níquel metálico. As análises dos produtos de saída do reator e das cargas reagentes foram realizadas por cromatografia gasosa, utilizando-se um Cromatógrafo VARIAN CP3800. Foi determinado o regime cinético na OPM utilizando as massas de catalisador 65, 80 e 95 mg.

Oct 30, 2017

By Hiroyuki Matsuura

The effects of P2OS or Na2O addition on the reaction rate of CO2 dissociation on the surface of FexO-base molten oxides was investigated at I 773K by isotope exchange method 1-6. The rate constant decreased with increasing P2Os content of molten oxides and the residual rate constant was observed at high P2OS content. On the other hand, the rate constant increased with increasing Na20 content for FexO-SiO2 melts, The rate constant was evaluated by the composition of oxides and the rate controlling step of CO2 dissociation was discussed.

Jan 1, 2003

This talk was delivered in Kalgoorlie in April this year, to the Kalgoorlie Branch of The Institution of Engineers, Australia. We believe it is of such interest to members of our Institute and readers of this publication we believe it important to extend the audience who have the opportunity to read it. An edited version follows:"Why should we be so concerned about Mining Related Education; after all is said and done, the mining industry is not a great employer of persons?"The mining industry is capital rather than labour intensive. It employs only 2.7 per cent of the national workforce. However; the minerals industry is Australia's major exporter accounting for over 40 per cent of the nation's total export of goods.In Western Australia the value of minerals production in 1985 was about $5,000 million and consequently mineral exports accounted for about 53 per cent of the total value of overseas exports from the State. The diversity of the mining industry is also worthy of mention and produces iron ore, alumina, gold, nickel and mineral sands. That apart, our potential to become a major producer of diamonds, rare earths and petroleum products is considerable, not to mention base metals (copper, lead and zinc) and uranium.Our mining industry is of national importance and contributes in excess of 30 per cent of the total value of Australian overseas trade. Although the mining ind ustry does not employ many people, the people it employs contribute very much more, per capita, to the wealth of the nation than do employees in any other sector of our economy.No-one would deny that during the 20th century Australians have depended on the export earnings from the sale of relatively unprocessed agricultural products and more recently the sale of relatively unprocessed minerals for their standard of living.Not surprisingly, therefore, our economy is highly vulnerable to unstable world commodity market prices.The slump in trade we are currently experiencing (in first quarter 1987-Edition) was brought about by the over supply of the raw materials we produce. However, the recent downturn in world market prices is more serious than previous slumps because in part it is due to technological advances 'in other countries which could have a permanent effect on the world trade of primary products.

Jan 1, 1987

By Mehmet Bu daycı, Onuralp Yücel, Ahmet Turan, Murat Alkan

In this study, iron based alloys (Fe, Fe-Cr-Ni-Mo, etc.) were produced by using metallothermic methods starting from Mill Scales obtained continuous casting processes. During the process, the combustion was realized by ignition and the produced wave propagates throughout the reactant mixture yielding the desired product. In this work, Mill scale used as an iron source, which includes +2, +3 values iron oxides. Aluminum, Magnesium and Silicon were used as reductants. In these metallothermic experiments, different ratios of reductants were examined, and their effects on the metal recovery and alloy compositions were investigated. The samples were characterized by using chemical analysis (AAS), XRD and XRF techniques.

Jan 1, 2016

By R. T. DeWoody, J. W. Chester, W. C. Miller

The work was done to develop a relatively efficient muffler for quieting the exhaust of a rock drill . The exhaust of a pneumatic rock drill is the source of the major part of the noise generated by the drill . The exhaust noise can be reduced in a number of different ways , but this study involved only reactive mufflers . The reactive muffler can be simulated by an electrical circuit . Information obtained from analogous electrical circuits was used to design an efficient exhaust muffler for pneumatic rock drills . Electrical analogies proved to be a valuable tool in the design of mufflers .

Jan 1, 1964

By Foster Fraas

Almost all minerals show irreversible changes in electrical conductivity after heating in the temperature range 100° to 800° C. This effect can be detected with only a limited number of minerals with the standard ionizing-electrode-type separator, which differentiates between nonconductors and conductors in the single-particle resistivity range of 1011 to 1013 ohms. Tests outside this range with other type separators, such as the static field type, increase the number of minerals with which the effect can be detected to almost all that were tested. Irreversibility may be the result of an alteration of adsorption layers, volatilization of surface cations or anions, or an oxidation or reduction. One example is limonite, which decomposes to hematite and passes through two minima and two maxima in conductivity in the temperature range 100° to 900° C.

Jan 1, 1959

By Isa Nozari, Asghar Azizi

The extraction of copper from sulfate leaching liquor was investigated using Acorga M5640 commercial extractant in kerosene diluent. The effects of important factors such as the extractant concentration, contact time, liquor pH, and temperature were examined on the separation factor Cu/Fe and the extraction efficiency of copper. The results indicated that nearly 92.32% copper was extracted from the leach liquor at 10% (v/v) Acorga M5640 concentration, 1:1 aqueous/organic phase ratio, 20 min contact time, pH 2.5, and 25 °C temperature. Also, the further increase in the values determined had no positive impact on the extraction of copper. Under these conditions, the separation factor Cu/Fe was obtained about 29.64. The extraction mechanism was studied applying the plot of log(D) – 2 pH against log [extractant] and it proved the association of two moles of Acorga M5640 for the extraction of one mole of copper. McCabe–Thiele diagram was constructed and a single-step extraction process was found to obtain themaximumextraction. Additionally, thermodynamic datawere investigated and the extraction process was endothermic and non-spontaneous at 298 K (ΔH = 27.05 and ΔG = 15.52 kJ mol−1). Moreover, the loaded organic phase was stripped and 80.94% copper was recovered after 20 min using 10% sulfuric acid concentration.

Jul 31, 2020