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By John B. Wright

This paper describes laboratory techniques and subsequent results of Bureau of Mines research to produce chlorination-grade feedstock from an abundant, low-grade, domestic, rock ilmenite ore. The research is part of the Bureau-effort to devise technology that may help decrease U.S. dependence on imported raw materials. A rock ilmenite containing about 46 wt pct Ti02 was smelted in an electric arc furnace with coke, woodchips, and Na2C03 to separate most of the iron as pig iron and to form a low-iron, titanium-enriched slag. The slag was ground, pelletized, oxidized, and then sulfated with mixtures of SO2 and air in a continuous 4.5- to 9.1- kg/h apparatus at 1023 to 1223 K. The sulfated slag, containing 60 to 65 pct TiO2, was reground and leached in water at ambient temperature to decrease the combined levels of the troublesome Ca, Mg, and Mn impurities from 7.0 to 1.7 wt pct. At levels of more than 3 wt pct, these impurities contribute to operating and disposal problems, The final product was upgraded to about 84 wt pct TiO2. This material potentially is suitable for chlorination in a fluidized-bed reactor. The most favorable results were achieved with leached slag sulfated at a feedrate of 4.5 kg/h and at temperatures of 1073 to 1123 K.

Jan 1, 1984

By Wallace E. Anable

This investigation by the Bureau of Mines was conducted chiefly on Cuban serpentine nickeliferous ores to determine whether these materials would be amenable to direct carbothermic reduction in an electric furnace to produce a low-carbon ferro-nickel. The project was carried out as one of several under a Memorandum of Agreement between the Bureau of Mines and the General Services Administration (Contract GS-OO-B (D)-152l). Two ore samples were received for this investigation. One was a mixture of nickeliferous serpentine from the North Ocujal, South Ocujal, and San Juan claims of the Nicaro Nickel Co. The other sample was a mixture of material from the Ramona and the Lorna Mulo claims of the Cuban Nickel Co. Most of the ore from the Ocujal-San Juan deposits and about 40 percent of the sample from the Ramona-Lorna Mulo deposits were calcined before smelting. The remainder of the sample from the Ramona-Loma Mulo deposits was smelted after drying to about 8 percent moisture. An arc-resistance, selective-reduction smelting technique was employed in these tests. Either bagasse alone or a mixture of bagasse and coke was used for reductants. No flux was used in the furnace charges.

Jan 1, 1957

By John C. Machisak

Injury data and experience, with related employment statistics, at coal mines in the United States for 1959 are presented in this publication under the following general sections: (A) General injury experience: Tables 1 to 6: Current data on number of injuries degree of injury, frequency and severity rates, average severity, and related employment and production data by work location. (B) Selected injury experience: Tables 7 to 38: Current data on principal agencies of injuries, distribution of injuries by part of body injured, days of disability, extent of hand and machine loading, experience by employment and production groups, and various other operating factors and physical conditions related to the occurrence of injuries at the Nation's coal mines.

Jan 1, 1961

By Figueroa L. Aquiles

El presente trabajo plantea el uso de la pre-concentración en la etapa de chancado de las plantas metalúrgicas polimetálicas, como método de limpieza que busca eliminar el material estéril (ganga) antes de alimentar a los molinos y así reducir los altos costos de la molienda, flotación, secado y otros. Asímismo, los procesos de concentración van desde el pallaqueo hasta procesos sofisticados como la pre-concentración por análisis de dispersión de radiación gama y aquellos de separación por medios densos.

Nov 8, 1984

This publication contains eight papers presented at a Bureau of Mines Technology Transfer Symposium in Charleston, W, on June 22, 1983, Five of the papers describe the results of Bureau-sponsored research on cabs and canopies for low-coal underground mining equipment. The other papers describe the efforts of three underground coal mining equipment manufacturers (FMC, Joy, and Lee-Norse) in the area of cab and canopy design.

Jan 1, 1985

By Hon-Yim Ko

The properties of coal from the Pittsburgh seam, procured from the Bruceton and Federal No. 2 Mines were found to be similar. Strength and stiffness properties of Beehive Mine coal were determined and the material found to be isotropic. Mechanical, index and geologic properties of roof and floor coal measure rocks from Beehive mines were measured and correlated. Analytic formulations are given for coal creep under uniaxial loading, while triaxial creep is being investigated. Results of testing of coal model structures are compared with predictions from using several material models.

Jan 1, 1976

By Luiza Cruz Guimarães

Os fabricantes de instrumentos endodônticos de NiTi têm desenvolvido diferentes estratégias para aumentar a resistência à fadiga e à ruptura torcional desses instrumentos. A tecnologia “Controlled Memory (CM)”, que envolve o emprego de tratamentos térmicos em instrumentos já usinados, é uma dessas novas estratégias. Neste trabalho, dois tipos de instrumentos CM foram avaliados em termos de sua capacidade de recuperação de forma e resistência à fadiga após ciclos de flexão até 45 graus e esterilização em autoclave, simulando o uso clínico. Os resultados obtidos em relação às temperaturas de transformação martensítica e reversa, ao momento de dobramento a 45 graus, à recuperação de forma e à resistência à fadiga após ciclos de flexão/esterilização mostraram que os tratamentos aplicados aos dois tipos de instrumentos, embora referenciados como tecnologia CM, produziram resultados diferentes em termos de microestrutura e propriedades.

Aug 17, 2017

By James H. Aase

[This study provides data on the physical and hydrological makeup of the ,t hakes waterway system and forecasts quantities, traffic patterns, and ping cost of prospective bulk mineral commerce projected to be transported it. Factors affecting the shipping cost of iron ore, bituminous coal, imestone were quantified and integrated into a computer program that can d to estimate costs under varying sets of conditions. Combined ship of iron ore, bituminous coal, and limestone in 1995 were estimated at million tons. The cost of operating the U.S. vessel fleet for trans-ng an indicated 80 percent of this traffic tonnage was projected to be $163. 5 million.]

Jan 1, 1970

By Michel Jébrak, Claude Bellehumeur

Abstract - Regional and orientation geochemical stream sediment surveys were carried out by the Quebec Department of Energy and Resources in southwestern Quebec, over a part of the Mont­ Laurier Terrane of the Grenville Province. The area contains some small stratiform zinc deposits. The response of Zn mineralization to geochemical surveys is weak; the known mineralization is not defined by anomalous samples and consistent patterns. This study uses a technique that increases the geochemical signature of Zn mineralization in filtering out geochemical background components related to lithologies and surficial conditions. The background variations were modelled using principal component analysis, and the filtering technique consists of the partial reconstruction of the data matrix from results of principal component analysis . The filtering procedure considerably enhances the Zn anomalies located in the catchment basins of Zn deposits, and defines some new anomalies in proximity to the marbles of the Mont-Laurier Terrane, the principal metallotect of Zn mineralization.

Jan 1, 1993

By A. Mitrašinovic, A. Wolf

"The aim of this investigation was to determine the most suitable additive for recovering metals from converter slags generated during Ni extraction. Fluxes analyzed were silica and lime and reductants included pig iron, ferrosilicon and copper-silicon compound. Slag was settled at 1300°C for one hour to simulate the smelting environment. The newly formed matte and slag were characterized by chemical composition and morphology. Microstructural studies showed that slag formed after adding reductants consisted of primarily fayalite, with traces of magnetite. Entrained matte was present in the slag mostly as prills of Ni3S2-FeS matrix and a Cu2S-FeS secondary phase below 10µm in diameter. Kinetic parameters of matte formation, valuable metal recovery rates and partition coefficients were deduced. Silica additions generated higher partition coefficients for copper and nickel than the addition of lime. Additives used as reducing agents had higher valuable metal recovery rates and partition coefficients. Silica additions favoured the formation a higher grade matte while lime additions will hinder metal recovery. Pig iron, ferrosilicon and Cu30Si were the most effective reductants for valuable metals recovery. Cu10Si and coke additions had little to no effect on valuable metals recovery."

Jan 1, 2015

By G. H. Keith

The Bureau of Mines determined the mechanism(s) involved in observed anomalous changes in mechanical properties of vanadium-base alloys. Tensile properties of electrorefined and commercial-purity vanadium-base alloys containing up to 5 atomic percent molybdenum or titanium were measured between 77° and 673° K. Snoek oxygen and nitrogen peak heights were measured to determine the changes in dissolved interstitial content caused by increasing quantities of solute. In addition, changes in lattice parameter were followed wit: precision X-ray techniques. Softening, observed in alloys containing titanium, is explained by the formation of a second-phase titanium compound with oxygen or nitrogen. However, because of partitioning of titanium between compound formation and solid solution formation, about five times the stoichiometric amount was required for complete reaction. Addition of 1 percent titanium drastically lowered the strengthening due to strain aging, at 673° K, and 2 percent titanium essentially eliminated it. All alloys were ductile at 77° K. Variations in the tensile properties of the molybdenum-containing alloys are explained by variations in the amounts of interstitial impurities present. The molybdenum did not react with these impurities and had no effect on strengthening due to strain aging. Commercial-purity vanadium alloys containing more than 2 percent molybdenum were brittle at 77° K.

Jan 1, 1969

By Gabriela Pereira de Miranda

Os aços avançados de alta resistência do tipo dual phase (DP) são aplicados na indústria automobilística, principalmente, em componentes estruturais. Alguns desses aços são revestidos com zinco e suas ligas, visando maior resistência à corrosão. Atualmente, o processo de união de aços mais utilizado em veículos é a soldagem por pontos. O emprego inadequado de parâmetros de soldagem pode provocar trincas por fragilização por metal líquido (LME, do inglês liquid metal embrittlement) em regiões de soldas a pontos de aços de alta resistência revestidos com zinco. O metal líquido, neste caso, consiste em ligas de Zn-Cu provenientes da combinação de cobre dos eletrodos de soldagem com o zinco do revestimento, que penetra em contornos de grãos, reduzindo a sua energia coesiva. Sob solicitação mecânica, tal fragilização pode ocasionar origem às trincas. Neste trabalho foram investigadas as condições de formação de trincas por LME na soldagem de aços DP da classe de 600 MPa de limite de resistência galvanizado por imersão a quente (HDG - GI). Verificou-se, em todas as condições de soldagem avaliadas, a penetração do metal líquido na superfície da solda. A ocorrência de trincas, no entanto, só foi constatada em condições de soldagem que implicaram na geração de tensões. Tais tensões foram intensificadas com refrigeração inadequada, causada por diferentes vazões de água nos eletrodos inferior (1,5 l/min) e superior (7,5 l/min), e/ou soldagem sequencial. Não foram observados efeitos prejudiciais de trincas por LME nas resistências estática (cisalhamento por tração) e dinâmica (fadiga sob cisalhamento).

Oct 30, 2017

By R. M. G. Machunter

The presence of ultra-fine particles affects the separation performance of wet gravity separation equipment. Several studies have been undertaken to establish the maximum level of these particulates that can be tolerated by spiral separators and it has been found that unless the ultra-fine material is effectively processed, relatively low proportions in the ROM material combined with high feed rates can result in degradation in plant performance and/or excessive water consumption. The maximum level of particulate material in the process water has been determined by examination of separation performance of spiral separators under varying slime loading. This work has been conducted utilizing various feed sources and a robust ‘rule-of-thumb’ has been derived.

Jan 1, 2005

By Francis Church Lincoln, Paul Zinner

"Attention of the Bureau of Mines was first directed to the Gray farm area by the results of several exploratory churn-drill holes completed by the New Jersey Zinc Co., and later by Roland J. Teske and by Judge H. L. Heer.When the Bureau of Mines initiated its investigation of the area, all drilling on the Gray farm had been discontinued, and no mining had resulted from the exploratory work. However, in the opinion of the Illinois Geological Survey, the Federal Geological Survey, and the Federal Bureau of Mines, this drilling,with the preliminary geological studies, was considered sufficient evidence to justify continued exploration to the southeast along a projection of the trend of mineralization developed in the mines to the northwest, or the so-called Black Jack Trough.This report describes the work done and presents the data obtained during the period of Bureau of Mines exploratory work.In its program of exploration of mineral deposits, the Bureau of Mines has as its Primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision or Dr. R. S. Dean, assistant director.Special acknowledgment is due Paul Herbert, geologist, Illinois Geological Survey, for his studies of cores, which greatly influenced the planning and progress of the exploratory work. Acknowledgment is also made to A. F. Agnew and A. V. Heyl, geologists, Federal Geological Survey, for their invaluable aid; to 0. W. Terry, F. C. Lincoln, M. H. Berliner, A. M. Cummings, project engineers; and to E. P. Barrett, district engineer, Minneapolis, and E. D. Gardner, regional engineer, Rolla, Mo., for supervising the program.The Gray ore body is on the Gray farm 5 miles south of Galena in Jo Daviess County, northwestern Illinois. The location with respect to adjoining properties is shown on figure 1. Galena is a city of 4,000 population on the banks of the Galena River, a stream that was formerly navigable by Mississippi River steamers but has now shrunk to the dimensions of a small creek. A gravel road leads from the city to the Gray farm and onward to the Bautsch and Boevers farms to the south of it."

Sep 1, 1946

By Rodney P. Smith

The diffusivity of carbon (0.1 wt pct C) in Fe-Nz alloys (0 to 100 pct Ni) has been determined for the temperature range 860° to 1100°C. As a function of nickel content, the diffusivity has a maximum near 60 pct Ni (the maximum diffusivity being about 1.3 times that in the absence of nickel); the activation energy has a maximum between 40 and 50 pct Ni and a maximum between 80 and 90 pct Ni. The difference between the minimum activation energy and that in iron is about 3000 cal pev g-atom; Do has a minimum between 40 and 50 pct Ni and a maximum between 80 and 90 pct Ni. The results cannot be rationalized by an approximate thermodynamic treatment. THE diffusivity of carbon has been determined in a number of iron alloys over a limited concentration range. It seemed desirable to investigate a system which allows an extended range of alloy composition within a single-phase region. The Fe-Ni system is ideal in this respect, in that all alloys from 100 pct Fe to 100 pct Ni are fee in a convenient temperature range.&apos; The carbon diffusivity was determined by a decar-burization method. The experimental procedure was identical with that used to determine the diffusivity of carbon in y Fe-Co alloys.2 The experimental data are given in Table I. A small correction (order of a few percent) has been made to the measured carbon loss to correct for the carbon lost from the ends of the cylinders.&apos; Since the diffusivity of carbon varies with carbon content the measured diffusivity is an average value for a carbon content between zero (surface) and that at the center of the sample at the end of the decarburization periods. In making the correction in D to 0.1 wt pct C it is assumed that the measured D corresponds to the arithmetical mean of the carbon content at the surface and at the center of the sample at the end of the decarburization period.3 Since this correction is small (<4 pct in D) and since for our decarburization times the changes in carbon content at the center of the sample was small the mean carbon content could have been taken as half the initial value. It is further assumed that the change in D with carbon content for the alloys is the same as that for the diffusion of carbon in iron. From the data of Wells, Batz, and Mehl4 and of smith5 the correction of D from the mean carbon content to 0.1 wt pct C is 0.3 (0.1 - mean wt pct C). The results for iron are given in Ref. 2. Within the experimental error log Do.l%C for each alloy is a linear function of 1/T; the constants for the equation determined by the method of least squares are given in Table I. The deviations of the experimental points from the least-squares line are of the order of 2 pct in D. A comparison of our results for the diffusivity of carbon in nickel with those of other investigations is shown in Fig. 1. The lower curve in Fig. 1 is a linear extrapolation of values calculated* from the equation of Diamond6 for the relaxation time (temperature range 100° to 500°C). The results indicate a small increase in the activation energy over the temperature range 100° to 1400°C; however, it is difficult to say whether the change in Q is real or experimental error. Certainly the change in Q is less than the variation of 5 kcal per g-atom in the diffusivity of carbon in a iron.6 The experimental data for all the alloys are plotted in Fig. 2. As a function of nickel content the diffusivity has a maximum near 60 wt pct Ni at all temperatures investigated and possibly a minimum between 80 and 90 wt pct Ni for temperatures below 1000°C. The activation energy, Q, and log Do are plotted as a function of the nickel content in Fig. 3. Due to the limited temperature range of our experiments neither Q nor Do can be determined precisely; the activation energies appear to be consistent to ±0.3 kcal per g-atom; however the deviation from the absolute values may be considerably larger, see Table II. The Do values probably have little significance. The solid line for Do in Fig. 3 represents the values required to reproduce the experimental values for D when Q has values represented by the upper solid line The diffusivity of carbon may be expressed in terms of the mobility B22, the activity coefficient r2,

Jan 1, 1967

By J. J. Demeter

As part of its work on converting coal to fluid fuels, the Federal Bureau of Mines has been studying the synthesis of liquid fuels from carbon monoxide and hydrogen by Fischer-Tropsch synthesis. A fluidized bed of nitrided, fused-iron catalyst has been operated successfully to produce high yields of oxygenated compounds. Trouble-free operation continued for over 800 hours, and the test was terminated voluntarily. About 85 percent of the fresh feed was converted when the unit was operated at a space velocity of 500 hr.-1, a 12:1 recycle-to-fresh-feed-gas ratio, a 300-p. s. i. g. pressure, and a temperature of 252° C. When operating at a fresh-feed-gas space velocity of 1,000 hr.-l and a 9:1 ratio of recycle to fresh gas, conversion of fresh feed was 68 percent, and the product yield was 235.9 grams per cubic meter of synthesis gas converted. The oxygenate and C5 and heavier hydrocarbon yield was 110.6 grams per cubic meter of gas converted, 83 percent of this was oxygenates. The atom ratio of N:Fe of the catalyst, initially 0.455, decreased to 0.288 by the end of the 800-hour experiment. Nevertheless, the yield of oxygenated compounds per cubic meter of H2 + CO converted at the end of the run was approximately the same as that obtained 500 hours earlier with identical operating conditions. X-ray analysis of the discharged catalyst indicated that only ?-iron carbonitride was present. Sieve analysis of the discharged catalyst indicated that only 2 percent of fines was produced during the reduction, nitriding, and synthesis.

Jan 1, 1959

By L. C. IlsLey

Permissible electric nine lamps are approved with the. understanding that if actively marketed they will be listed in Bureau of Mines publications so that state mine departments, compensation bureaus, mine operators, miners, and others interested in safety equipment for mines may know the permissible lamps available and the important safety features of each. The last list of permissible electric mine lamps was issued as Report of Investigations 33045 in June 1936, a supplement to Bulletin 332.6 All lamps described in Bulletin 332 are either obsolete or have been materially modified, as covered by extensions of the original approvals. These modified lamps and the new designs approved since 1930-totaling 12 cap lamps and 23 lamps of miscellaneous types-comprise the present list of actively marketed permissible electric mine lamps. This bulletin presents the Bureau&apos;s test requirements and procedure relative to permissible electric mine lamps and describes briefly the lamps, giving tabulated details of each.

Jan 1, 1942

By N. S. Spence

INTRODUCTION WHILE TITANIUM, the element, has been known for over 150 years, titanium, the metal, is a relative newcomer to the metallurgical and industrial scene. The reasons for this chiefly lie in the refract1Hy nature of titanium compounds; the high melting point of the metal; the great activity of elemental titanium, particularly at temperatures close to .and above the melting point; and the pronounced deleterious influence of certain impurities on its mechanical proper-ties. Early efforts at production of the metal were, consequently, either unsuccessful or resulted in products having sub-metallic properties. With the considerable improvement in equipment, materials, and skills that have developed within the past twenty-five years, later investigators have had a better opportunity to overcome some of the inherent practical obstacles and to come to grips with the essential technical problems. NATURAL ABUNDANCE OF TITANIUM Titanium is one of the most abundant metallic elements. It has been estimated (1) that titanium comp-rises about 0.65 per cent of the earth&apos;s crust, and therefore ranks fourth among the structurally useful metals in the order: aluminum, iron, magnesium, titanium. It must be appreciated that the relative abundance of the element is only a crude indication of its potential availability, since a very substantial proportion is present as a minor constituent in practically all igneous rocks. By comparison, present-day ores of titanium are relatively few and are but a minor fraction of the estimated total titanium contained in the earth&apos; s crust.

Jan 1, 1951

By Fabiano Soares

Strand guide rolls in continuous casters are crucial components for guaranteeing an optimum process for the production of high-quality steel grades. The properties of these rolls greatly influence the quality of the slab produced. The most commonly used designs so far have been the axle roll and the solid roll. A quite new roll concept is the STEC-Roll®. It combines the advantages of the axle roll with those of the solid roll. This paper explains the development of this roll type and shows the current design. The characteristics of the STEC-Roll® are presented in greater detail and are underlined by a number of simulation results. Beside the design itself, the benefits for casting and maintenance are explained, including for example the easy assembly and dismantling or the use of the roll for dry casting. A brief examination is made of the TCO for the STEC-Roll® and an estimation is provided of the exchangeability of this roll. To conclude, an overview on the current applications is presented.

Aug 17, 2017

By Keith A. Heasley

At this point in time, approximately 800 M tonnes (880 M tons) of coal are mined each year in the United States. Forty percent of this coal or approximately 320 M tonnes (350 M tons) is taken from underground coal mines, and from this subtotal 16% or 50 M tonnes (55 M tons) is from longwall panels (1). If, for the sake of argument, an aver- age extraction thickness of 1.5 m (5 ft), an aver- age extraction ratio of 50 percent and an in situ density of 1360 kg/ms (85 lb/ft3) for this coal are assumed, then the 320 M tonnes (350 M tons) of underground coal translates to over 310 km2 (76,000 acres) that is undermined each year. Con- sidering that the total U.S. production of under- ground longwall coal to date is approximately 345 M tonnes (380 M tons), then a total of approximately 165 km2 (41,000 acres) (considering 100% extraction) has been directly undermined by longwall coal production in the United States. If the angle-of- draw is considered, the total area affected by longwall subsidence in the United States is probably twice the above value or 330 km2 (82,000 acres) . In the future, a number of other miscellaneous factors seem likely to multiply the number of potentially damaging situations that occur due to longwall coal mining. First, the overall production of coal in the United States is expected to gradually increase. This factor is further com- pounded by both the fact that the percentage of the overall production due to underground mining is bound to increase, since the vast majority of U.S. reserves (68%) are only recoverable by underground methods, and the fact that the percentage of the underground production of coal that is recovered by longwall mining is drastically increasing (1). Finally, as the nicest underground reserves are depleted, the remaining reserves will tend to be deeper, which increases the affected surface area, and under denser population concentrations, which increases the likelihood and severity of possible damages. Overall, considering the number of factor which are biased towards increasing the amount of undermined acreage, it appears that there must certainly be a corresponding increase in the number of possible damaging situations due to longwall-induced, ground subsidence.

Jan 1, 1986