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By O. Celep, T. Uslu, Savas

This study investigates the enrichment of a low-grade colemanite concentrate (-3 mm) using a Knelson centrifugal gravity concentrator. Due to its low boron content, the concentrate is unsaleable and has to be stored under appropriate conditions to avoid potential environmental problems. The low-grade colemanite concentrate was comminuted to size fractions of-1 mm, -0.5 mm, and -0.15 mm before treatment in the Knelson Concentrator. The effects of particle size, fluidizing water velocity, and bowl speed on the enrichment process were examined. The B2O3content of the concentrate was increased from 33.96% to a maximum of 45.52%. B2O3recovery increased with increasing bowl speed and particle size, and decreased with increasing fluidizing water velocity. The enrichment process also rejected arsenic and iron to some extent, with a maximum reduction of arsenic from 1360 g/t to 765 g/t and iron from 0.88% to0.33%.

Jan 1, 2015

By P. den Hoed, R. I. Rambiyana

"Four sulphide minerals - pyrite (FeS2), pyrrhotite (Fe1-xS), pentlandite ([Ni,Fe]9S8), and chalcopyrite (CuFeS2) - contain the base metals and most of the iron in concentrates of platinum group metals (PGMs). In the pyrometallurgical processing of PGM concentrates these sulphides form a matte during smelting, and iron and sulphur are removed from the matte during the converting process. This paper discusses the roasting of Merensky concentrate in air before smelting, with the purpose of reducing the matte load to the converter.Roasting tests were conducted in a bench-scale rotary kiln at temperatures from 350°C to 700°C. The concentrate tested contained 17.4% sulphur and consisted of 23% pyrrhotite, 16% pentlandite, 11% chalcopyrite, and 2% pyrite. The particles were fine (d50 = 22 µm), and all the sulphide particles were liberated. Roasting in air at 550°C and 650°C for 20 minutes removed respectively 60% and 70% of the sulphur. The iron in the sulphides was oxidized to Fe3O4 (magnetite) at temperatures below 500°C and to Fe2O3 (haematite) at temperatures above 550°C. At 700°C the bed sintered and copper oxides formed. At temperatures below 450°C oxidation was incomplete: pyrrhotite remained and only 30% of the sulphur was removed. Smelting tests were conducted to assess matte fall and the deportment of copper and nickel to matte. It was evident that roasting resulted in lower matte falls (a drop of approximately 60%) compared with matte falls from unroasted concentrate. The iron and sulphur levels in the matte were reduced to below 3.5% and 22% respectively.This paper also briefly describes the mechanisms by which pyrrhotite, chalcopyrite, and pentlandite are oxidized during roasting. For chalcopyrite, the mechanism proceeds through an intermediate solid solution phase, which extends from Cu1.02Fe1.04S2 to Cu2.04Fe0.72S2 to a copper-rich solid solution of bornite (Cu4Fe1.4S4-Cu2S). The oxidation of pentlandite proceeds through a monosulphide solid solution (Ni0.39Fe0.53S-Ni0.74Fe0.15S) to a solid solution of heazlewoodite ([Ni,Fe]3}xS2). These mechanisms are explored in relation to chemical thermodynamics and microstructures."

Jan 1, 2015

By L. A. Thompson, A. J. Linington

"Copper–cobalt extraction is a reagent-intensive process resulting in acid consumption greatly contributing towards production costs, which in the current market conditions curtail profitability. Nanofiltration (NF) membranes have become an attractive approach in the mining and minerals industry for product concentration and reagent recovery based on the ability of the membrane to separate monovalent ions from divalent ions. NF membranes can selectively separate acids from metals and salts allowing acid to be recycled as well as the concentration and purification of product streams. Membrane technology in the field of copper–cobalt processing focusses on the concentration of Cu2+ and Co2+ in the pregnant leach solution, recovery of acid from waste streams to neutralization, recovery of valuable metals from waste ponds and process water recovery. This paper aims to provide insight into the potential applications of NF membranes in copper–cobalt processing circuits as well as a brief overview of the effects of process conditions on membrane performance and process development. INTRODUCTION The copper–cobalt industry commonly uses inorganic acids, such as sulfuric acid, in large quantities for primary leaching of copper–cobalt oxide ores and releaching during product purification (Stuurman et al., 2014). This results in numerous acidic intermediate streams containing high metal concentrations and acidic waste streams with low metal concentrations. Acid consumption typically accounts for 10–15% of the operating costs of mines in the Democratic Republic of Congo (DRC) and Zambia (Acid Plant Database, 2015). Due to remote mine locations, poorly maintained roads and cross-border conflict, the cost of sulphuric acid can range between USD 300 and 400 per ton. The pivotal role of acid in the copper–cobalt extraction process has driven many mines to build sulphuric acid plants on site to ensure a reliable acid supply, however elemental sulphur still needs to be imported which faces similar logistical challenges and contributes towards operating costs."

Jan 1, 2015

By Steven A. Mathe, Seokbin Lim

Current analytical models can accurately predict the final velocity of explosively driven flyers and can somewhat predict the acceleration profile, but do little to address the deformation of the flyers. Explosive systems such as linear shaped charges and explosively formed projectiles, which can be described as multiple interacting explosively driven flyers, often involve interactions between the flyers that occur much before the flyers reach their predicted final velocity. In this regime, it is important to accurately understand both the acceleration profile and the deformation profile of the flyers, as both significantly affect the functioning of the explosive systems. Previous work proposed an analytical model to meet this need. As the expanding gas cloud of detonation products drives the flyers, rarefactions impinge upon the gas cloud from around the flyer edges, which produces a pressure difference across the back face of the flyer leading to deformation of the flyer. Previous research condensed the effects of the rarefactions into a single term, the pressure release ratio, ?, which was calculated based on hydrocode simulations of a block of explosive only and an assumption of isentropic expansion. This work intends to determine the value of ? for different explosive compounds. The results of this analysis were compared to hydrocode simulations of an open-faced sandwich configuration explosive/flyer system with an average accuracy of 15% across the tested compounds.

Jan 1, 2015

By N. W. Xu, M. D. Wei, F. Dai, B. Li

"Chevron notched samples achieve general acceptance for measuring the Mode-I (opening mode) fracture toughness of rocks. The cracked chevron notched semi-circular bending (CCNSCB) sample, which is developed from the International Society of Rock Mechanics suggested the cracked chevron notched Brazilian disc method, has recently received much attention. However, these chevron notched methods have not been fully mastered, some ideal assumptions based by their theories and formulas, such as the straight-through crack assumption (STCA), have not been verified detailedly. Fractures of CCNSCB specimens were numerically simulated considering different heterogeneities, geometrical and mechanical parameters. The results show that, the real fractures of CCNSCB specimens are never satisfied with the STCA. In fact, micro fractures not only occur in the notch tip but also the two chevron edges. Consequently, the crack front features prominently in a shape of parabolic curve, far from being straightthrough. Moreover, curvature of the crack front is only affected by shape of the chevron ligament. Cracks usually start from two sides of the notch tips rather than center of the notch width, and propagate deviating from the postulated fracture routes. These fracture mechanisms induce errors with the measurements, and thus more attentions should be paid to the real fractures of the chevron notched samples for measuring fracture toughness more accurately. INTRODUCTIONWith the increasing requirement of people for resources and energies, frequent rock engineering activities have been conducting, such as underground excavation, oil exploration and deep burial of nuclear waste. Many problems appear in rock fracture. Consequently, there are more and more attentions paid in rock fracture mechanics due to its broad application prospects for solving these engineering problems. Since Mode-I (opening mode) fracture is the most common failure mode in rocks, Mode-I fracture toughness is a primary parameter to predict rock mechanical properties in actual engineering, and thus its accurate values are necessary to the researches of rockburst, rock mass slope stability, rock cutting, hydraulic fracturing, tunneling, et al. Therefore, it is thus significant to evaluate and study relevant methods to obtain the reliable value."

Jan 1, 2015

By Ed Sullivan

"Australia is one of the richest continents when it comes to mineral extraction, ranging from exotic projects like the Olympic Dam — a copper, silver and uranium mine believed to have the world’s largest uranium resource — to the extensive iron ore, nickel, coal and gemstone formations that provide many of the country’s most rewarding exports.Among the challenges to succeed in this industry is the ability to provide efficient “pitto- port” infrastructure performance, which essentially means ensuring that minerals move seamlessly from the point of extraction to the facilities that can then move them to international market destinations.To provide such efficiencies, avoid human error and facilitate automated mining functions, producers are increasingly turning to fiber optic cable suppliers for “end-to-end” communications and control solutions. Many such solutions include ruggedized cable and connectors that ensure the survival of fiber-based DCS/PLC automation/ control architectures for various types of mining operations, even in the harshest environments.Integrating the solutionAs industrial Ethernet and fiber optic cable emerges as the medium of choice in many industrial arenas, communication and control integration using the most appropriate products for a specific application is increasingly important.“This whole ‘pit-to-port’ performance concept is focused on control and process automation,” says Boyd McDonald, Founder and Managing Director at Datalek Systems & Electrical, Rockhampton Area, Australia. “It also means bringing reliability to networks and providing the needed bandwidth. An appropriate plug-and-play solution is also important because it takes human error out of the equation.”Datalek Systems & Electrical, is responsible for the design, installation and maintenance of numerous fiber optic communications systems including those that involve automation, security, access control an CCTV systems for open-pit and underground mining operations as well as LNG and coal seam gas facilities."

Jan 1, 2015

By C. Gravel, A. Fathi, P. Rivard, G. Ballivy, Z. Moradian, M. Quirion

Numerous schemes have been proposed in the past to evaluate the shear strength of rock discontinuities based on in situ and laboratory testing. Due to scale effects, in situ testing is the most reliable way to assess the shear strength parameters. However, practical reasons often impede this kind of testing. This is unfortunate because advances in theoretical rock mechanics are still dependant on qualitative experimental works. This paper presents a mobile high capacity shear apparatus developed for in situ direct shear testing of discontinuities along with testing methodology. The apparatus has the advantage of being simple, although of high capacity, and can be moved to different site locations for other tests. The in situ test was performed on a natural rock outcrop of schist with subvertical schistosity. A concrete block 50 x 50 cm with a base layer of high strength mortar was cast on the rock surface. Prior to the test, the concrete block was lifted and repositioned to have an unbonded joint but with interlocking asperities. The shear load was applied perpendicularly to the schistosity direction. The test was conducted in a constant normal load (CNL) condition. Both normal and shear loads were applied manually. The instrumentation consisted of two load cells for shear and normal loading, eight displacement laser extensometers for shear, normal, and lateral displacements and fourteen acoustic emission sensors for monitoring evolution of asperities’ degradation during the test. The friction angle obtained is 72° for the peak and 58° for the residual. The high values of friction angle indicates that first-order roughness and good interlocking of the joint surfaces can result in high shear strength parameter values in a rock generally regarded to have low values.

Jan 1, 2015

By S. J. Lötter, J. T. Nel, W. Purcell

"SynopsisGlow discharge optical emission spectroscopy (GD-OES) is an analytical technique used in the analysis of solid, conducting materials. Though primarily of interest as a depth profiling technique on samples with varying layers of both conducting and non-conducting materials, it is also capable of rapid bulk analysis of homogenous, solid samples. GD-OES combines the advantages of ICP-OES (wide detection range, speed, and lack of interferences) with the solid sampling of XRF techniques. This allows the analyst to not only quantify the elemental composition of a sample, but to evaluate it in terms of homogeneity with depth, a field in which auger electron spectroscopy (AES) and secondary ion mass spectrometry (SIMS) have traditionally been the primary techniques. Although GD-OES does not replace these useful techniques, it does offer various advantages over them, making it an excellent complementary analytical tool.In GD-OES analysis, a low-pressure glow discharge plasma is generated with the sample material acting as a cathode, accelerating the cations in the plasma towards the sample surface. This bombardment causes the sample material to ‘sputter’, essentially knocking free atoms or molecules of analyte material, which are then drawn into the plasma where they are excited. The light emitted by this excitation is then diffracted to separate the wavelengths emitted by the specific elements and detected by a spectrophotometer. The intensity of the signal is directly proportional to the quantity of analyte element present in the sample, allowing simple calibration and quantitative determination of the elements. Technological improvements made in the past twenty years or so have significantly increased the usefulness of GD-OES for surface analysis. Faster plasma stabilization and start-up allow for the quantification of surface layers as thin as 1 nm. Sputter rates have been accurately measured for many common materials, allowing them to be built into software libraries in the instrument’s control software. This dramatically expands the usefulness of this software and the ease of performing analyses.GD-OES analysis of nuclear materials allows for the rapid determination of the elemental composition without the requirement of initial dissolution. The thickness of any corrosion layers on nuclear materials can also be determined."

Jan 1, 2015

By J. Dubbert, T. H. Jones

"This paper describes a rib-control methodology that uses standing support to provide most of the lateral resistance to the rib. The method is analyzed, and its boundary conditions for rib control are described. In this method, an animal-fencing mesh product covers 80 percent of the rib surface and is sparsely bolted to the rib. Can supports or other similar stiff supports are installed primarily as roof support for the entry. As the rib spalls and dilates, the mesh catches the material and expands, pressing against the standing support. Mining proceeds, and vertical roof loads increase the normal force on the Can supports, causing friction at the top and bottom of the support to go up, thereby improving lateral resistance to rib swelling.At one mine in the western United States, this method has proved excellent at preventing the buildup of rib spall. It substantially reduces the number of bolts used for screen installation, improves installation efficiency, reduces manual labor and provides more rib coverage than many screening methods. Because standing support is typically part of the roof-control plan in longwall tailgates, no additional standing-support costs are incurred. IntroductionRib safety in underground coal mines is an oft-studied topic because ribs are high-hazard areas. An overview of early rib safety research can be found in Jones and Mohammed (2014). There is a significant difference between rib support and rib control. Support improves safety through the installation of strengthening elements, such as bolts and dowels, designed to reduce rib spalling. Although spall reduction is preferred, controlling how the rib fails is enough to ensure safety in some situations. Rib control uses external elements to provide confinement, thereby holding sloughed material in place, or to prevent falling rib material from striking mine personnel. This paper presents a study of a control method used on the pillar side of a longwall coal mine tailgate in the western United States."

Jan 1, 2015

By L. Galarza

"INTRODUCTION Beneficiation of ores and minerals in a concentrator plant requires a significant amount of water [1] for the grinding and particle separation processes; most of it ends up being recirculated for reuse, slurry pumps are used after crushing and grinding feeding the ore to a classifier to separate fine-grained material (less than 5 mm) from coarse-grained material requiring further grinding. The lower ore grades [2] in the past couple of decades have demanded an increase on power size and efficiency of process machines to maintain a competitive plant throughput; Hydro-cyclone feed pumps to control both under and over milling or grinding are not the exception; Fig. 1 shows a conventional drive train [3] comprising an (1) asynchronous motor (also known as squirrel cage induction motor = SCIM), a high speed coupling (2), a gear reducer (3) and a low speed coupling (4) attached to the shaft of the pump (5), to accommodate the motor rated speed (typically 1800 rpm) to the process requirements (in the range of 250 rpm to 350 rpm), requiring additional components related to the gearbox: instrumentation, maintenance, disposable lubricants and filters, spare parts, thus reduces the overall system efficiency ultimately reflected into CAPEX and OPEX.WHY VARIABLE SPEED DRIVES FOR CYCLONE FEED PUMPS Hydrocyclones or commonly referred as “cyclones” are one of the most important devices in the minerals industry [4]; almost universally used in close-circuit grinding because of their high capacity and relative efficiency, the evolution of Power Electronics made affordable the use of Medium Voltage - Variable Frequency Converters (VFC) for Cyclone Feed pumps in combination with induction motors larger than 500hp (373kW) to gain multiple benefits: - Soft start with minimum electrical utility disturbance = inrush current mitigation - Full Torque available at zero speed for overload startup with pulp solidification after long still stand periods, superior to any other reduced voltage starting method. - Optimum and constant pump speed (independent of the electrical network or load condition), compared to across the line SCIM operation - Flexible Motor Voltage and Speed regardless of the power distribution Voltage and Frequency - Improved Power Factor (close to unitary), over the entire operating speed range"

Jan 1, 2015

By Shengwu Song, Xuemin Feng

Jinping I hydropower station is located in Sichuan Province in Southwest China. It is built on the Yalong River as a controlling cascade hydropower station in the middle and lower reaches, with power generation as its major function. Jinping I arch dam concerns many engineering issues and has attracted worldwide attentions due to its huge scale and unique settings. It is one of the most challenging projects in China with its 305 meters high arch dam and complex geological conditions for construction, including large-scale tectonic faults, intensively unloaded rock masses and geological asymmetry in its foundation. At present, the concrete arch dam construction has been completed and preliminarily impounded, most of the foundation treatments have been implemented, and four of six generator units had been put into operation in July 2014. In this paper, the analytical methods, design concepts, treatment measures and technical features of strengthening the geological defects in the dam foundation will be presented. Upon geological investigation into the dam foundation, a few large-scale weak discontinuities are observed. The rock masses in the left dam foundation are intensively unloaded, approximately to the horizontal depth of 150–300 m. These serious geological defects lead to a geological asymmetry on the left and right banks, and thus some major difficulties of dam construction are encountered. The influences of geological defects on the dam construction and safety are analyzed comprehensively, followed by the concepts and methods of treatment design. Based on this, the treatment methods of the weak rock masses and discontinuities are carefully determined by numerical analysis and scheme optimization, including the concrete cushion, concrete replacement grids, drainage system, anti-seepage curtains and consolidation grouting, which work together to enhance the strength and integrity of the dam foundation. Evaluations and calibrations through geo-mechanical model tests in combination with field monitoring results in early impoundment period show that the arch dam and its foundation are generally stable and function normally, which suggests that the research methods and treatment design schemes are reasonable and effective. The proposed treatment methods and concepts in the context are helpful for similar complex rock projects.

Jan 1, 2015

By S. Tafazoli, N. Himmelman, D. Chan, E. Chow

"While Wearable Technology has been garnering attention in the consumer market, enterprise and industry have just begun exploring its potential applications. Since February 2014, Motion Metrics International has been working in collaboration with Vandrico Solutions Inc. to apply Wearable Technology to improve productivity and safety in the mining industry. This paper discusses the value proposition of using Wearable Technology to deliver critical notifications in mining. The advantages and disadvantages of various form factors are explored. The challenges, both specific to mining and in general to Wearable Technology, are defined. Finally, the concept of MetricsGear™, the first Wearable Technology platform developed for mining by Motion Metrics International in collaboration with Vandrico Solutions Inc., is described. MetricsGear™ is designed to notify the user with minimal distraction to keep the user focused on their primary task, and aware of mission-critical events. This focus and awareness allows the user to work more efficiently and safely. INTRODUCTION The mining process consists of a series of intricate stages, where certain events or conditions in one stage can have a huge impact on other stages. The notification of these critical events or conditions is vital for ensuring the overall efficiency of the mining process. Critical notifications can be classified as two types: time-critical events and contextual information. Time-critical events are situations where a timely response from a responder can have a significant impact on seizing an opportunity or mitigating cost. Some Human-Computer Interaction (HCI) experts classify notification types based on the Interruption, Reaction, and Comprehension (IRC) framework. Time-critical events are classified to have high interruption, high reaction, and low comprehension due to their urgency. The responder should have just enough information to identify the crisis and react as soon as possible (Chow, E. 2014). For example, when a tooth is lost during shovel operation, it is necessary to recover the missing tooth before it jams the primary crusher. The consequence of missing this critical time period is a jammed crusher that can cause the mine to be out of production until the jammed tooth is extracted (Baumann, M. 2013). In this case, the responder only needs to see an image to confirm if the tooth is missing, and information to identify which equipment and when the tooth went missing (see Figure 1). Contextual information is relevant information that is valuable for the receiver to be aware of as it can present an opportunity to improve efficiency or save cost. According to the IRC framework, contextual information is classified as low interruption, low reaction, and high comprehension. They are not as urgent as time-critical events, but provides more detailed and informative information to assist the receiver. For example, when a shovel’s worn tooth is predicted to require replacement soon, a notification to a GET technician can help him or her schedule a pre-emptive replacement of the tooth in an already planned maintenance to prevent having to reactively schedule another one when the tooth is critically worn. This helps reduce the amount of equipment downtime to maximize production (Baumann, M. 2013). In this case, the receiver will look at the information when he has a moment to spare to get a quick forecast, and make use of this information as needed (see Figure 2)."

Jan 1, 2015

By Stephen R. Iverson, Jeffrey C. Johnson, Donovan J. Benton, Michael J. Raffaldi, Lewis A. Martin

"The NIOSH ground control safety research program at Spokane, Washington, is exploring applications of photogrammetry to rock mass and support monitoring. This paper describes two ways photogrammetric techniques are being used. First, photogrammetric data of laboratory testing is being used to correlate energy input and support deformation. This information can be used to infer remaining support toughness after ground deformation events. This technique is also demonstrated in a field application. Second, field photogrammetric data is compared to crackmeter data from a deep underground mine. Accuracies were found to average 8 mm, but have produced results within 0.2 mm of true displacement, as measured by crackmeters. Application of these techniques consists of monitoring overall fault activity by monitoring multiple points around the crackmeter. A case study is provided in which a crackmeter is clearly shown to have provided insufficient information regarding overall fault ground deformation. Photogrammetry is proving to be a useful ground monitoring tool due to its unobtrusiveness and ease of use.INTRODUCTIONNIOSH Mine Safety ResearchPhotogrammetry systems have been implemented by the National Institute for Occupational Safety and Health (NIOSH) as part of its ground control research to improve mine safety. Conventional monitoring of ground movement has typically focused on movement of a few discrete points that are marked or anchored to instruments. Loss of a designated point or anchor, or the ability to identify a stable point in an unstable area, have often frustrated monitoring efforts. NIOSH researchers are using photogrammetry to conduct full-field measurements of rock surfaces underground. Periodic measurements of the entire surface of a ramp allow patterns of displacement to be observed. Full-field measurements provide much more insight into ground behavior than point measurements.BackgroundPrevious work by Benton, et al. (2014) discussed laboratory calibration and verification testing of two photogrammetry systems being used by NIOSH researchers. Both systems utilize stereoscopic image pairing techniques for photogrammetric reconstruction. This paper discusses how a laboratory system was used to conduct volumetric analyses of testing of shotcrete panels with varying types of reinforcement. The laboratory system was found to be accurate to within 2 mm. Additionally, a field photogrammetry system was found to produce linear measurements within 1 mm of known lengths in laboratory conditions. This system is currently being used at a deep underground mine to observe ground support conditions and deformations that have occurred. This paper discusses comparison of preliminary volumetric measurements of rib deformation to laboratory tests, as well as comparison of the field system against a crackmeter installed across a fault surface where it intersects the ramp."

Jan 1, 2015

By F. Schreiter

"One method to increase the exploitation rate of a mine is the use of backfill with residual materials in exploited areas. The backfilled material is meant to support both, the walls of galleries and pillars as well as the roof of mining openings. With increasing depth, the exploitation rate diminishes fast, thus the application of backfill in order to change the layout of the mine is crucial for economic success. In result of using backfill, it is possible to change the layout of the working area with a higher ratio to excavated areas and less area occupied by pillars. Thus it is possible to boost the output of a mine by using backfill. Setting the criteria for the selection of the best possible materials and whose improvement, it is useful to know about their qualities and handicaps. The Mining Department at TU Bergakademie Freiberg is analyzing the parameters of residues from different processing methods, accrued in plants of different potash mines and blending different residues for optimization of material attributes. These were significantly characterized by basically parameters like the size and the distribution of different diameters of the grain material. INTRODUCTION The chair for underground mining methods at TU Bergakademie Freiberg is tasked with the sufficient and sustainable supply of economics with raw materials. The steady high demand, the rising prices and the finiteness of the deposits are reasons for the need of an optimized economic utilization of natural deposits, a continuous improvement of mining technics and technology. From an ecological and economical position the best possible utilization of the resources has to be achieved. Many mining operations are by reasons of the deposit not able to haul valuable minerals only, they have to haul a mixture of valuable minerals and waste rock. This hauled combination is given into the processing plant for separation and enrichment of the valuable mineral. The residuals of the processing are commonly dumped to a waste rock pile. For minimizing the size of such a waste rock pile and also minimizing the ecological footprint of a mining operation the only way is minimizing the quantity of accruing waste rock material. Both, optimization of economic utilization and also minimization of waste rock dumps can be realized in one by backfill with processing waste rock material in mined out areas. Especially in mines, mined by room and pillar method, smaller dimension of the pillars are sufficient for safety and stability. By the way less valuable minerals have to be leaved back in the mine and the mine outcome is increasing."

Jan 1, 2015

By Celine Y. Zhang, Chloe J. Feng, Charles Q. Jia, Donald W. Kirk

Oil sands petroleum coke (OSPC) is a by-product of coking - a high-temperature process that converts the mined bitumen to the synthetic crude oil (SCO). For every barrel of the SCO produced, about 20 kg of OSPC are generated. Over 70 million metric tons of OSPC have been produced and stockpiled as a result of the development of oil sands industry in the past few decades. Unlike conventional petroleum coke, OSPC has uniquely high impurity contents, particularly sulphur (~ 7 wt%) and metals (e.g. vanadium at ~0.15 wt%), which has hindered its large-scale applications as a solid fuel. Vanadium is a valuable metal that is widely used as an alloy for strengthening steels. The stockpiled OSPC contains about 100,000 tons of vanadium, while the world’s production in 2013 was only 75,600 tons. At the current price of $25US/kg, the OSPC-bound vanadium represents a total value of $2.5 billion US dollars. In this work, we investigate the technical feasibility of extracting vanadium from OSPC. The work focuses on the characterization of vanadium in OSPC and the conditions for effective extraction of vanadium from the OSPC.

Jan 1, 2015

By C. Garcia, A. Potulska, J. J. Opazo, T. Comi

"The Sierra Gorda SCM sulfide ore processing plant began commissioning in the third quarter of 2014. Located in the Atacama Desert in northern Chile, the project is an open pit mine and Copper-Molybdenum processing plant is one of the most highly-instrumented operations in the world. It is the first hard rock operation in Chile and the second in South America to utilize HPGR technology. It is a significant Molybdenum resource especially in the first five years and the Molybdenum separation plant is complex. Designed to process up to 60 million lbs. of fine Molybdenum per year, it uses the latest technology and equipment to ensure superior recovery and product quality. It also has gas handling and alarm systems to fulfil the Company’s vision of “Zero Harm”. This paper discusses the overall operation and issues relating to the concentrator start-up. These include a review of the mineral processing design, the unified process control center and management information systems, and the correlation of geological and metallurgical performance data (mine-to-mill) for use in anticipating and preparing for treatment of diverse ore deliveries. INTRODUCTION Sierra Gorda SCM is a joint venture partnership with KGHM International (owned by KGHM SA, Poland), Sumitomo Metal Mining, and Sumitomo Corporation (Japan) operating in northern Chile. The Sierra Gorda open pit mine and Copper-Molybdenum processing plant will become one of the largest mines in the world. The need for optimum production efficiency and sustainability has driven the creation of the most modern, well-instrumented mine in Chile. This paper contains a general review of the project including geology and history. This was a very fast-track project going from greenfield site acquisition to mill start-up in 10 years. Highly-experienced and motivated engineers and technical staff have overcome many significant challenges resulting in a rapid ramp-up of production capacity. A potential expansion to double the production rate in the fourth year of operation has also been intensely studied. The Sierra Gorda property is located in the Atacama Desert of northern Chile, in the District of Sierra Gorda, Region II of Antofagasta, Chile (see Figure 1). There is almost no precipitation in this area. The mine site is generally flat with some rolling hills. The project is located about 5 km from the village of Sierra Gorda at an elevation of approximately 1,700 m above mean sea level. The village is near a highway and railway line. The city of Calama, home of the famous Chuquicamata Mine, is located about 60 km northeast of Sierra Gorda. In addition, the SG mine is in the midst of numerous other mines including Spence, Esperanza, Mantos Blancos, El Tesoro, Lomas Bayas, Gabriela Mistral, El Abra, Radomiro Tomic, and Escondida, to name a few."

Jan 1, 2015

By K. G. Matshika

"Nickel electroplating from sulphate electrolyte is an efficient process. To achieve good quality cathode, however, parameters such as temperature, nickel concentration, pH, electrode alignment, electrolyte flowrate and additives must be optimised, because these affect cathode morphology and current efficiency. It is also important to control the clarity and contamination of the electrolyte, as these have a considerable effect on the quality of the cathode surface. Delamination, surface roughness and pitting on the cathode surface can be caused by incorporation of solid particles or impurities form the electrolyte. Three types of solid particles were investigated: cuprous selenide, barium/ lead sulphate (co-precipitated) and ferric hydroxide. These particles can be found in industrial electrolytes, especially if there is a problem with the filtration step or contaminants have reacted to form insoluble particles. A rotating cylinder Hull cell was used for this investigation. It is found that the effects on morphology depend on the type of solid, concentration, particle size, current density and electrolyte flowrate. Cuprous selenide is the most detrimental, especially at higher concentrations, higher current densities and low flowrates. Increased rotational speed offers a uniform sheet of fine gas bubbles across the surface of the cathode which reduces the thickness of the diffusion layer of liquid adjacent to the cathode and increases the rate of mass transport to the cathode from the bulk liquid. INTRODUCTION Electrowinning operations are important when recovering associated by-products of nickel production, such as copper, cobalt and zinc, from pressure leach solutions. The base metal mineralization associated with platinum-group metal (PGM) production yields significant quantities of copper and nickel as by-products. The base metal refinery is vital in PGM processing as it increases the PGM concentration from mined ore by a factor of 400, in comparison with concentration by flotation (20 times) and pyrometallurgical processing (20 times) (Crundwell et al., 2011). Anglo American Platinum Ltd produces nickel cathodes by electrowinning and purges sodium from the base metal refinery in the form of sodium sulphate at the Rustenburg Base Metals Refinery (RBMR), as shown in Figure 1. This is the Sherritt acid leach process used in most base metal refineries to ensure no loss of PGMs and shows the subsequent purification steps for copper and nickel. Other refineries in Zimbabwe, such as Bindura and Empress, use the Outokumpu leach process (Pavlides, 2001)."

Jan 1, 2015

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By D. Kimball, P. Chambers

"BACKGROUND In the event of an explosion or fire in an underground mine, workers can be exposed to a deficiency of oxygen, an excess of carbon monoxide, or both. These threats can occur as separate conditions or simultaneously. A lack of oxygen in the breathing air can only be addressed via the use of a self-contained breathing apparatus (SCBA) acting as a source of oxygen. An excess of carbon monoxide can also be addressed via the use of an SCBA, but if the threat occurs in isolation (that is, the atmosphere still contains sufficient oxygen to support life) and the concentration of the threat gas is not extreme (< 2%) then the carbon monoxide threat can also be addressed by the use of a filter self-rescuer (FSR). Used together, the SCBA and FSR offer a far more efficient and universally capable life support system than when used in isolation. However, the SCBA does not take advantage of the fact that the surrounding atmosphere likely contains some level of useable oxygen; i.e., the SCBA always supplies the total required oxygen from its limited supply, resulting in a ceiling on its useful life regardless of the level of oxygen in the surrounding air. To address this technology gap, what is needed is a ""smart"" SCBA that provides filtration and catalytic protection against threat gasses and has an extended duration life-sustaining oxygen inhale stream independent of the threat content and oxygen deficiency of the surrounding atmosphere. DEVELOPMENT Developed under contract with NIOSH the Smart Escape SCBA is comprised of three major components including; 1) oxygen supply, 2) oxygen sensing & dosing electronics and, 3) a CO catalyst and carbon bed broad spectrum FSR. The SCBA is designed as a hybrid system that provides non-toxic breathing air by using an approved Chemical, Biological, Radiological and Nuclear filter self-rescuer and a catalyst to convert high levels of carbon monoxide to harmless carbon dioxide (CBRN FSR/CO). In addition, the Oxygen Sensing & Dosing Electronics (OSDE) package adds sufficient oxygen to make up for deficiencies detected in the ambient air (Figure 1). By making use of the ambient oxygen, less oxygen is required for a one-hour unit life. This means that the Smart Escape SCBA fits in a smaller and lighter package than a similar-duration conventional Self-Contained Self-Rescuers (SCSR). Alternatively, taking advantage of available ambient oxygen could offer a significant increase in working duration in a unit with the same size as current SCSRs. The research performed under this NIOSH contract involved numerous tasks including: (1) definition of performance and system requirements for the Smart Escape SCBA, including keeping environmental stressors within acceptable ranges, providing at least one hour of breathable oxygen supply, and using a mask or hood that allows high-quality voice communication; (2) designing, building, and evaluating prototype units to support extensive bench top testing at Avon Protection and third party labs to demonstrate the device’s capabilities; (3) building sufficient quantity of Smart Escape SCBAs designed to be intrinsically safe (per MSHA criteria); (4) testing and evaluation by the National Personal Protective Technology Laboratory (NPPTL)."

Jan 1, 2015

By Calvin Konya, Anthony Konya

State and Federal construction specifications require the Blasting Contractor to prepare a Master Blasting Plan which is reviewed by the Owner’s Representative. The Master Blasting Plan requires the Contractor to submit the design of a typical blast. Most blasting specifications also require the Blasting Contractor to submit Daily Blasting Plans. The Master Blasting Plan and the Daily Blasting Plan require that the Blasting Contractor also submit the types and quantities of explosives and initiators used. The specifications also request that the Blasting Contractor submit the pounds of explosive used per delay for both production and presplit blasts. The Blasting Contractor may also be required to predict the anticipated ground vibration and air overpressure levels for the proposed blasts. There are equations that can be used to predict the ground vibration. There are also equations that can be used to predict the air overpressure levels. The data for these equations were primarily derived from quarry and surface coal mine and some construction blasts. Data from major construction projects were analyzed in this study to determine new air overpressure propagation equations for construction blasting. These new prediction equations compare calculated results analyzed from field data with other existing air overpressure prediction equations. Production blasting air overpressure values are also compared to air overpressure from presplitting

Jan 1, 2015