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By S. C. Grand, T. J. Auping, K. Born

Process control, environmental monitoring, budgeting and accounting are based on process data. Without appropriate tools for data analysis, the process data could remain unused and wasted. This paper demonstrates how data reconciliation can be used as a tool to develop closed mass balances. Mass balances are the initial step in plant optimisation (technical, economical or environmental). From mass balances, fundamental process models can be developed. These balances link process parameters (e.g., feed materials) to process performance (e.g., recovery of valuable elements). Some of these models could find their way into simulators useful to plant operators. Classical regression methods regularly fail when they are applied to complex non-linear problems involving a large number of variables. Alternatively, multiparametrical regression analysis can be successfully applied with the aid of neural networks based on reconciled data. Both methods have been applied to plant data originating from the hydrometallurgical zinc plant at Ruhr-Zink, which in this paper serves as a case study. Very promising and useful results were obtained from this study.

Jan 1, 2000

By V. Petr, G. G. W. Mustoe, T. G. Rozgonyi

We introduced a numerical method that is applicable for the analysis of static and dynamic deformations of elastic media. In this numerical study, each elastic body is modeled with a system of several hundred rigid particles that are joined together elastically. Maximum shear stress fields due to external loading are obtained and compared with those obtained by photoelastic experiment. Preliminary results are presented for the stresses generated in circular disk shaped bodies idealized with connected systems of particles. Extension of this simulation method to fragmentation of brittle materials is also illustrated in an example.

Jan 1, 2000

One of the problems with mining projects is the setting of the design criteria that will best match the requirements. Normally this is expressed in economic terms but can be other factors. With massive orebodies these problems are often compounded by the general lack of distinct mining boundaries. A technique using evaluation surfaces was developed at Palabora for the underground mine design. This technique has subsequently been applied on several other mining projects to assist in the determination of the design criteria. This paper discusses the method, illustrated by some of the results of these studies.

Jan 1, 2000

By J. F. Lupo

Leaching operations combine both metallurgical and hydraulic processes to extract metals from the ore heap. In the design of leaching operations, metallurgical tests and simple hydraulic tests are often conducted to define operational parameters such as leach cycle time, application rate, lift height, and effective leach area. While metallurgical constraints are often the primary focus on leach facility design, the hydraulic factors are also critical to the overall success of the operation. Some of the hydraulic factors that are known to impact solution flow through heaps include: • Ore physical and hydraulic properties, • Variation in ore properties under heap loading, • Ore mineralogy and its susceptibility to chemical and/or mechanical degradation, and • Heterogeneities within the heap. This paper presents a discussion on hydraulic factors that may impact the effectiveness of leaching operations. In addition, methods are presented which may be used to assess flow conditions within active and inactive heaps.

Jan 1, 2000

By T. C. Pool

Physical and chemical conditions permitting, in-situ leaching (ISL) of uranium offers a variety of advantages over conventional production methods including less surface disturbance and less solid waste. Commercial production of uranium by in-situ leaching techniques was initiated in 1963 in the Shirley Basin of Wyoming by Utah Construction. On a world-wide basis, ISL uranium production amounted to about 13.2 million pounds U3O8 in1999, approximately 16% of world output. Both acid and alkaline systems are used, the selection of which is primarily dependent upon groundwater quality and related reclamation requirements. ISL offers low capital costs per unit of annual capacity and is particularly flexible in adapting to changing market conditions.

Jan 1, 2000

By S. Sarac

In this study, graphical and mathematical methods used to determine operating points in single or multiple fan ventilation systems are summarized. The problem is mathematically formulized for parallel connected fans in which analytical solutions are not possible. For n number of parallel connected fans, a non-linear equation system that consists of n number of non-linear equation sis derived. The Newton-Raphson method, which is a numerical analysis method, is adapted to solve this non-linear equation system and the solution steps are given as an algorithm. A computer program based on this algorithm is written and its applicability is proved.

Jan 1, 2000

By Mark Fritzen

Drilling and blasting near residential or business inhabited areas may expose people to blast induced vibration. Many of these people have never been exposed to blast vibration and airblast which can cause a variety of reactions ranging from indifference to anger. Blasting contractors seeking to minimize the impact of blasting to neighbors of the project will plan for a public relation plan which begins at bid time. The public relations plan cost will be included in their proposal and a variety of methods may be included including, door to door contact, letters, pamphlets, telephone calls, and the use of an independent consultant to conduct a pre-blast survey. By raising the awareness of neighbors to a blasting project the blasting contractor may reduce the anxiety and stress of unannounced blasting vibration and airblast. This helps everyone associated with the project from the project owner(s) to the blasting contractor.

Jan 1, 2000

By O Ostrovski

Direct iron smelting reduction has been examined using a modified 50 kg induction furnace. The furnace was equipped with continuous raw material feeding, a top oxygen lance, argon bottom bubbling, and sensors for measurement of gas and bath temperatures, gas composition and other parameters. In the base case, iron ore was charged at the rate of 1.5 kg/h, coke flowrate was adjusted to maintain a char fraction in the slag at 30 wt per cent, the oxygen flowrate was 100 Nl/min and the post-combustion ratio (PCR) was 60 per cent. The PCR was varied from 45 to 75 per cent by changing the lance height relative to the bath surface. Smelting reduction of Whaleback iron ore was investigated at different post-combustion ratios and iron ore feedrates using coke and coals with different volatile matter. The rate of iron oxide reduction increased with increasing iron oxide concentration in the slag, with a slight deviation from a linear function. The post-combustion ratio affected iron ore reduction and partitioning of elements between phases in the smelting reduction furnace. The high volatile coal investigated was found to be unsuitable for iron smelting reduction in the laboratory furnace.

Jan 1, 2000

By E Wan, K Stokes

Since 1978, the nickel concentrator at Leinster has been subject to continuous change. In 1971 a significant nickel sulphide deposit was discovered on Leinster Downs Station, within three years the extent of the deposit was determined. In 1978 the Agnew Mining Company began production of nickel concentrate from the Perseverance Mine and continued to do so until production ceased in 1986. In 1988 WMC purchased the mothballed project and began the first phase of many expansion initiatives. Milestones in the life of Leinster have included:open cut mining of the Perseverance orebody and the discovery of the RockyÆs Reward orebody, as well as the metallurgical challenges in treating each of these; underground mining at both Perseverance and RockyÆs Reward; construction and commissioning of the WMC grinding and flotation circuits; variations in the reagent schemes, including the introduction of æliquidÆ reagents; development of mill linings to reduce maintenance; circuit re-configuration and simplification; development of Harmony open cut; strategies for increasing throughput at the drier; and changes to tailings facilities to cope with increased throughput. This paper outlines the steps which have been required to expand the Leinster Nickel Concentrator from 650 000 tpa to 2.5 Mtpa and those steps which will be required in the future.

Jan 1, 2000

By D. Diering

Having agreed to perform this task, I naturally started to wonder what on earth I was going to talk about, and on reviewing the literature I was surprised at how little I knew and how much I?d forgotten about the origins of this industry. For example: ?I?d forgotten that the Chinese invented black powder at least 1 000 years ago, back in the 10th century (although some say this invention occurred 2 000years ago). ?I didn?t know that Roger Bacon was the first person in the Western World to give exact directions for the making of gunpowder in 1242 and to understand its potential. Pepper?s Playbook of Metals quotes:?...above all, he is named as the discoverer of gun-powder, a material which has brought more wonderful changes in the great family of man than the most potent elixir that could have been devised to prolong life?.

Jan 1, 2000

By Toshiaki Nakai, Kunihiko Takeda, Kimio Imaizumi, Hiroaki Shirasaka

"The new type of nano-porous silica particle was considered to be constructed by the spinodal decomposition-type process which was found to have narrower pores than those of conventional porous silica prepared from boron silicate or ""Shirasu"" balloon. Nano-porous silica particles were fabricated by the calcination of silica gel mixed with well-dispersed complex salts composed of phosphorous and molybdenum compounds. Both silica and inorganic salts were not perfectly dissolved in the suspension solution. After removing of the water, the silica-inorganic salts complex was volatized and successively calcinated at a temperature ranging from 650 °C to 800 °C. Then, the inorganic salts were removed by dissolving in hot water. Other inorganic salts such as potassium halides were also found to be effective as a pore-size controller.IntroductionControl of structure has an important role in the field of industry as well as in the separation and purification technology for metals and organic syntheses. Many studies on the control of material structures have been reported regarding porous materials with pores ranging from nanometer to micrometer scale. 1 ) One example is zeolite as a naturally yielded porous inorganic material. Various types of synthetic zeolites have been studied as ""molecular sieve"" materials with ordinary pore-size of less than one nanometer. In 1992, crystalline meso-porous material with a large surface area named MCM-41 was synthesized through the use of template synthesis. 2) In direct relation to our study, amorphous borate glass having 4 to 100 nm of fine pores known as Corning glass 3l or SiO2-Al2OrB2O 3-CaO porous glass having large pore dispersity ranging from 4 to 10,000 nm have been reported. 4 ) S) 6 ) Some examples of several reported studies are as follows: phase-separated porous glass consisting of B2OrAl2O3-ZrO2-RO-R2O complex oxide 7 ) glass with finer pore induced from hydrolysis of silane alkoxide, porous material attained by condensation polymerization through the use of sol-gel process 8), alumina meso-porous material 9 ) 10), silica-zirconia material 11), carbon porous material 12), etc.."

Jan 1, 2000

By Kouji Mimura, Tamas Kekesi, Yongfu Zhu, Masahito Uchikoshi, Minoru Isshiki

"The formation and anion exchange sorption of chloro complex ions can offer a great potential to be utilized for the separation and purification of metals in aqueous solutions. Available stability data were primarily used to estimate the predominance of chloro complex species, indicating the feasibility of such separations. Anion-exchange sorption functions, describing the equilibrium distribution of a number of important elements have been determined by the batch equilibrating method in the practical HC1 concentration range. Various oxidation states were stabilized by the addition of appropriate agents. Tendencies in oxidation, complex formation and anion exchange sorption were confirmed by spectrophotometric investigations. Based on the fundamental results, anion exchange processes have been developed for the purification of iron, cobalt, copper and zinc. The efficiency of separation was assessed and the procedure optimized by the analysis of experimental elution curves. Results have demonstrated that by properly controlling the oxidation states and HC1 concentrations, practically all the impurities can be eliminated. Computer programs have been developed to estimate complex formation and redox equilibria, to screen and correct analytical data, to determine distribution coefficients and to evaluate efficiencies of separation.IntroductionBase transition metals have long been used as the staple materials in various fields of industry. In general, there has been an increasing tendency in purity requirements but recent advances have created a rapidly increasing demand for ultra-high purity metals. To give a few examples, ultra high purity copper can be used as bonding wire and interconnection in integrated circuits, or as material for superconductor stabilizing, high-field magnets, beside its use in cryogenics and ultra high vacuum technology [1]. Iron holds promises as a constituent element in the ß-FeSi2 material to be applied in new opto-electronic devices [2] and it is currently used, together with chromium and manganese, in the production of special magneto-optical materials for digital recording. The use of ultra high purity manganese and chromium in semiconductor technology is evolving. Although not considered a transition metal, zinc is also treated here because of the major significance in compound ZnSe semiconductors [3], and the possibility to purify it by the anion exchange method."

Jan 1, 2000

By C Torrisi, J Andreatidis, M Duffy

BHPÆs Cannington process plant was commissioned in October 1997. The Cannington ore contains high grades of silver, lead and zinc but also contains high levels of fluorine which must be removed to produce a marketable concentrate. As a consequence the plant is more complex than the typical base metal concentrator. Some of the features of the Cannington operation include a single stage autogenous mill, multiple stages of flotation cleaning, two leach circuits, pressure filtration and a paste fill plant. The start-up and achievement of design performance for new lead/zinc operations has traditionally taken much longer than for gold or copper operation and is littered with many tales of woe with feasibility targets often not achieved (Agarwal, Brown and Katrak, 1984; Bulatovic and Wyslouzil, 1999; Leung, Andreatidis, Woodall and Alford, 1996; Sherman, 1999; Ward, 1998).

Jan 1, 2000

By Steve Kral

MINExpo INTERNATIONL 2000 was a good place for companies to introduce new products, technologies and services to the mining industry. Caterpillar took that a step further. The company hosted a one-day preview of its mining products at its Tinaja Hills Training and Demonstration Center near Tucson, AZ. About 30 members of the trade press spent the day at Tinaja Hills before heading on to Las Vegas for MINExpo INTERNATIONAL 2000. Dozens of Caterpillar professionals provided the editors with a first-hand look at Caterpillar’s mining trucks, loaders, excavators, road graders, water trucks and engines. In addition, these Cat experts explained the intricacies of each piece of equipment, the latest technology that led their improvement and their value to the company’s mining customers.

Jan 1, 2000

By D. M. Abbott, H. J. Sandri

The geoscience matrix method has proven useful for valuing metallic mineral properties lacking delineated mineral resources or reserves. However, the method explicitly excludes commodity markets from the factors considered; marketability is assumed. When valuing industrial mineral properties, marketability cannot be assumed, it must considered. Market considerations may also significantly affect the standard weightings of geoscience matrix parameters such as the proximity to known deposits. In some cases, such proximity is desirable but in many cases it is undesirable. Application of the geoscience matrix method to industrial mineral properties therefore requires thoughtful, market-related adjustments to the basic geoscience matrix methodology.

Jan 1, 2000

By M Skead, H Michael, R Chase, A Davidson

Ashanti Goldfields CompanyÆs (AshantiÆs) most recent development is the Geita Project in the Lake Victoria Goldfield of NW Tanzania. It comprises six distinct gold deposits within two mineralised trends: Nyankanga, Lone Cone, Geita Hill (Geita trend) and Matandani, Kukuluma and Area 3 West (Kukuluma trend). Between 1936 and 1966, the Geita area produced an estimated 5.5 M tonnes of ore from five underground deposits at an average recovered grade of 5.3 g/t. The discovery of Nyankanga was made by Ashanti in 1996 from RAB drilling of a +100 ppb Au anomaly in laterite soil above ferricrete cover. The Kukuluma trend was discovered by SAMAX Resources (taken over by Ashanti in 1998) between 1996 and 1997 from RC drilling of a +80 ppb Au laterite soil anomaly. Oxide facies banded iron formation (BIF) of the Upper Nyanzian System forms prominent topographic ridges and is the dominant host lithology for gold mineralisation. The ridges are flanked by felsic tuff units which lie stratigraphically above. Syn-genetic lamprophyre (vogesite) and post-genetic felsic dykes are also seen in the Geita trend. At Nyankanga a granodiorite-diorite suite has intruded as dykes and sills into BIF from a plug centred on a WNW fault and has produced wallrock alteration assemblages similar to those seen in Cu-porphyry systems (potassic, propylitic, etc) as well as sulphide and gold deposition. However, the main ore-grade mineralisation (as in the rest of the Geita trend) is controlled by low-to-medium angle structures dipping north-west and north with numerous splays in the hanging wall. High-grade shoots at Nyankanga plunge to the west and to the north-west, being lithologically and fault-controlled respectively. At Geita Hill the higher grade shoots are controlled by fold noses in BIF dipping to the north. Free gold occurs within fractures of sulphides. The deposits of Kukuluma and Matandani occur on an ancient (possibly Cretaceous) erosional plateau and are related to two WNW to NW trending shear zones, discordant to the local strike of the BIF sequence. Complete oxidation occurs up to 120 m depth and there is a strong supergene component to the gold distribution. Primary gold mineralisation is divisible into two distinct assemblages: arsenopyriteûpyrrhotiteûmagnetiteûchlorite associated with brecciated cherts and pyrite associated with shaley banded ironstones. Area 3W is most likely the fault-displaced extension of the same mineralised trend and comprises thin, intermittent zones of high-grade gold mineralisation occurring adjacent to a ridge in banded cherts and minor BIF. Current resources (measured, indicated and inferred) for the project are estimated at 89.24 Mt at an average grade of 4.17 g/t (11.97 Moz of contained gold) at a 1.0 g/t cut-off grade. Of this 9.83 Moz is within the Geita trend and 2.14 Moz is within the Kukuluma trend. A resource of 2.74 Moz is from an inferred resource at depth at Nyankanga where the viability of an underground operation is being studied. Proven and probable reserves are 49.77 Mt @ 3.46 g/t (5.54 Moz) based on a $325/oz gold price providing a mine life of ten years at an average production rate of 500 000 oz per year. Reserve estimation was carried out using mineable polygons to select resource blocks based on a series of mining and costs parameters. In addition key cost parameters were tested to provide sensitivities for pit optimisations and pathfinders for negotiations with suppliers and contractors. Construction began in March 1999 and first gold is expected to be poured in the second-quarter 2000.

Jan 1, 2000

By Marcela C. Santini, Luiz A. Teixeira

"Surface conditioning (also referred as etching) of plastics prior to metallization is generally conducted with sulfuric I chromic acid solutions. Although these baths perform well technically, the presence of Cr (VI) imposes serious operating problems of an environmental nature. The present work reports ·the results of a study of surface conditioning o(ABS using solutions based. on sulfuric acid, with hydrogen peroxide and/or nitric acid, replacing chromic acid, as oxidants. Process performance was evaluated by SEM and by the uniformity and adherence of electroless nickel coatings applied on selected conditioned samples. The results showed that the evaluated types of solutions could be optimized to perform as well as the chromic-based baths, with a much superior environmental quality.IntroductionMetallization of plastics is normally undertaken for either decorative or functional purposes. Through metallization, the specific properties of plastics such as light weight, design flexibility, and low-cost of manufacturing are enhanced by the addition of properties usually associated with metals. These include reflectiveness, abrasion resistance, electrical conductivity, and a variety of decorative effects (1).The available processes that can be used for metallization of plastics are vacuum metallization or vapoµr deposition; indirect metallization and plating (1). Plating can be sub-divided into electroless plating and electroplating. In electroless plating, metal ions in aqueous solution are deposited on the .activated plastic surface by oxi-reduction reactions without the aid of an external electric potential, forming a thin metallic layer. This electroless deposited film has two functions: (a) it provides an electrically conductive substrate that allows further coating by electroplating; and (b) provides a secure bond between the plastic substrate and the electroplated layer (1,2). In case the electroless metallic part requires an additional layer for finishing purposes, or just an increase in thickness, the part can be additionally electroplated with a· variety of metals - in most cases those are copper, nickel or chromium (3)."

Jan 1, 2000

By Stanley J. Michalek

Good planning is critical to operating a safe and efficient mining operation. As the shallow coal scams become depleted, attention turns toward deeper mineable seams or remnant coal reserves. It is becoming more common to place a mine in a scam that is below or adjacent to existing mine workings. Significant research has been conducted regarding the ground control issues of multiple scam mining. However, safety aspects of the operation may not be fully considered. Safety issues include working below or adjacent to a flooded mine and controlling gas Communication between the active mine and the nearby mine. This paper will discuss the safety issues a mine operator should consider when working under or adjacent to mines that may be flooded with water.

Jan 1, 2000

By Ron L. Schmiermund

The Ferris-Haggarty underground mine was abandoned circa 1910, and portal discharge has since resulted in degradation of a trout fishery in the receiving waters of Haggarty Creek. Although tunnel discharge varies dramatically in volume throughout the year due to infiltration of snowmelt, compositionally it is a nearly constant low-TDS, pH-neutral, low-sulfate, copper-silicate dominated water. Between infiltration events, components of ARD accumulate in unsaturated, oxygenated environments within upper workings and are delivered to the main haulage level by the subsequent annual snowmelt flush. Mixing with non-ARD mine waters results in neutralization, dilution, and precipitation of amorphous copper carbonate and silicate phases. These mechanisms, combined with variations in the water balance, control the composition of the portal discharge. Understanding the chemical and hydrologic control mechanisms was critical to the design of a passive treatment system to decrease effluent copper concentrations.

Jan 1, 2000

By S. Mason

Many organizations are realizing that continual improvement in health and safety relies on addressing the potential for various forms of human error. Of these, rule violations are often the most frequent form associated with accidents. These occur when an individual (or individuals) deliberately contravenes established and known safety rules. They have been associated with up to 90% of the accidents and other incidents in some industries, and yet they rarely receive the systematic attention they deserve in the promotion of safety. This paper presents underlying motives that cause violations. These can vary significantly from mine to mine and from job to job. Managers need some measure of the attitudes of the violators to determine the underlying motives behind the violations if they are to determine effective strategies for promoting safe behavior. Questionnaires form the starting point to address attitudes and the motives behind rule violations. The choice of the most suitable questionnaire, how- ever, will vary from organization to organization. Guidelines on the choice of questionnaire are offered.

Jan 1, 2000