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By Robert E. (Bob) Brown

Magnesium was discovered by Davy in 1808. The production processes as they exist are not economically competitive with aluminum The electrolytic magnesium process is divided into two steps; one to make the MgCh feed and the other to apply large amounts of electric current to dissociate the feed into magnesium (450 g) and chlorine (1200 g). The production of fuJIy anhydrous, pure cell feed is a major problem Recently, there has been a growth of thermal processes, mainly the Pidgeon silicothermic production process using FeSi to reduce dolomite in horizontal retorts. Pechiney has a large vertical electrical furnace process that also uses FeSi to reduce calcined dolomite in a molten bath containing alumina. Work is proceeding to develop new or modified processes that will greatly improve magnesium production. The present methods and the research and R&D will be reviewed in this paper.

Jan 1, 2001

By D. J. Kunz

Myanmar Ivanhoe Copper Company Ltd. (MICCL) has been operating the Sabetaung- Kyisintaung (S&K) Project producing LME Grade A Copper Cathode using the Heap Leach-SX-EW Process since 1998. The mineralization is mainly Chalcocite and the mine has a life of 20 years at the designed annual production of 25,000 tonnes of cathode copper. Design capacity was achieved within two of months of start-up. The mine is among the world’s lowest cost, Heap Leach-SX-EW operations. Information regarding plant design and operation are presented along with the challenges lying ahead and the latest developments. Daniel Kunz is President and Chief Operating Officer of Ivanhoe Mines, and a director of MICCL. He has more than 20 years’ experience in mining, construction and engineering. Prior to joining Ivanhoe Mines in 1996, Mr. Kunz was Vice President and Controller of Morrison Knudsen Corporation, a major international mining and construction company. He was also President and Chief Executive Officer of MK Gold Company, a public mining company listed on NASDAQ.

Jan 1, 2001

At the 25th Peruvian Mining Convention, the start-up of Antamina was called ?the mining event of the year.? Antamina, one of the largestcopper-zinc mines in the world, began operations in May 2001.Augusto Baertl is Executive Chairman of Compañía Minera Antamina, the operating company. He said in a convention address that Antamina would be in full production in 2002. ?I would like to stress that Antamina is, in every respect, a highly stringent operation, as it intends to be the Peruvianmine of the future,? Baertl said. ?Antamina has set the target of being, and remaining throughout time, a model mine as to technology, environmental practices and social responsibility.? [ ] In the areas of technology and operations, Baertl noted that ?we have incorporated the best engineering design available and state-of-the art technology for mining, grinding and transportation processes, among others.? In the environmental area, he said that ?we have carried out careful environ-mental impact studies and have incorporated modern technologies and methods to control and minimize any environmental impact.? In the social field, Baertl noted that ?our relationship with neighboring communities is being developed under the premises of the social responsibility philosophy.? These include popular consultation processes, environmental committees and conciliation discussion committees. The purpose, he said, is to encourage communities located within the area of influence of the project to find and lead by themselves their path toward sustainable development, beyond the life of the operation itself.?

Jan 1, 2001

By Matthew John M. Krane, Christopher J. Vreeman, J. David Schloz

"A continuum mixture model of the direct chill casting process is used to model the transport phenomena and solidification behavior in the Direct Chill casting of an Al - 6 wt% Cu billet using Wagstaffs AirslipTM process. The model, which includes the transport of free-floating solid particles, can simulate the effect of a grain refiner on macrosegregation and fluid flow. Numerical predictions of sump profiles and composition and temperature fields are presented. Two 45 cm diameter billets were cast under production conditions with and without grain refiner. Temperature and composition measurements and sump profiles are compared to the numerical results. The comparison shows excellent agreement for the grain refined case. It is believed that an incorrect model assumption prevents good agreement in the non-grain refined billet. IntroductionDirect chill casting is a semi-continuous process in which molten aluminum enters the top of a water-cooled mold, is cooled, and forms a solid ingot drawn out below (Figure l(b)). The molten aluminum begins to solidify due to the cooling effect of the mold wall. As the ingot is withdrawn from the bottom of the mold, water jets impinge on the surface, directly cooling the billet and forming a solid layer around a liquid melt, commonly referred to as the sump.A particular defect that occurs in a wide range of casting processes, including the direct chill (DC) casting of aluminum alloys, is macrosegregation, the uncontrolled redistribution of alloying elements on the scale of the ingot during solidification. Macrosegregation in DC cast ingots can produce non-uniform mechanical properties [l], which affects the behavior of the metal during downstream forming and heat treat operations."

Jan 1, 2001

By M. L. Cunha

The lack of control of As and Sb compounds from copper smelters and converters has rendered some chalcopyrite containing arsenopyrite, stibnite and tetrahedrite minerals unusable for metal extraction. In the present investigation, we have studied the carbothennic reduction of Portuguese chalcopyrite mineral concentrate in the presence of lime/CaS04 and CaS04/Si02. Thermodynamic equilibrium calculations were performed to study the distribution of As and Sb between metal and the CaO-Si02-FeO slag phase. The phase equilibrium calculations also show the effect of oxygen partial pressure on the increase in the volume of the slag phase, which helps in lowering the copper metal formation temperature and facilitates a better separation between metal, matte and slag. The reduction reaction kinetics was studied between 850°C and 1100 °C, and the phases formed were identified by X-ray powder diffraction and scanning electron microscopy techniques. The importance of this research for using recycled matte, lean and rich minerals with As and Sb is also explained.

Jan 1, 2001

Portman Mining Pty Ltd very successfully operated the Ferro GullyNorth Mine in the Hamersley Province of Western Australia to satisfy a contract for the delivery of six million tonnes of iron ore in less than two years to the Mount Newman Mining Co Pty Ltd. The high-grade ore extracted from Ferro Gully North Mine was unusual in that, not only was it within the Joffre Member of the Brockman Formation, but it was rich in red ochreous hematite and martite and very low in phosphorus.

Jan 1, 2001

By R. J. McGregor

The Internet has revolutionized worldwide communications. Any real or perceived mining incident or environmental spill, no matter how small or remote, can become a disaster of "biblical proportions" through the judicious use of the Internet by environmental and anti-mining groups. In addition, mining companies' own Web sites and unofficial message boards can provide plenty of additional ammunition to the anti-mining forces. This paper explores how the Internet and readily available information are used by anti-mining groups active on the Web.

Jan 1, 2001

By Tanya Arsh, Thomas P. Kwiatkowski, Heather Marsh, Barry Doyle

The Big Walnut Sanitary Trunk Sewer Extension Project consists of two segments, the first a 10' excavated diameter tunnel in rock through the gas producing Ohio Shale formation and the second will be microtunneled through unconsolidated water-bearing deposits. Relatively large quantities of methane gas have been encountered in the Ohio Shale. In the softground segment, the sands and gravels contain large water storage capacity and contain shallow residential wells. This paper will present an evaluation of potential gas inflows in the rock tunnel, design considerations for contract documents preparation to inform bidders as to the volumes of gases which may been countered and design options for construction of an impermeable shaft excavation support system to insure residential wells remain in service.

Jan 1, 2001

By Ross Seedsman

Discussion on the design of roof support in tailgates has often been conducted without a clear statement of the stress and failure conditions acting. There is general agreement that in the tailgate the vertical stresses above the chain pillar increase. Within the stress 'bulb' associated with this vertical stress increase there will be an increase in horizontal stress. This does not mean that the horizontal stresses acting across the roof line increase. In retreat longwalling, the proximity of the tailgate to the adjacent goof results in a substantial reduction in the horizontal stress field acting in the immediate roof. Furthermore, at the face/tailgate corner the onset of significant compression of the chain pillar. if it is designed to yield, will result in a further reduction in the horizontal stresses in the immediate roof. It is suggested that this latter mechanism can cause the horizontal stresses in the immediate roof to go to zero. Whatever, the horizontal stress acting across the roof in the face/tailgate corner will be significantly lower than in the face/maingate corner. The implication of the model is that support design in tailgates should be based on the assumption of zero horizontal (in fact tensile) stresses. How the roof behaves in a tensile stress environment is a function of joint spacing and orientation compared to excavation width and direction. It is speculated that the empirical relationship between support density and roof rating results from the relationship between joint spacing and bedding spacing. The onset of stress reductions has major implications to the design of cable and bolt anchorages in the tailgate environment.

Jan 1, 2001

By Gabriel Riveros

The stags from the Teniente Converter (TC) have high copper and magnetite contents. The reduction and copper impoverishment of these slags in an electric furnace was simulated in the laboratory, as part of a conceptual study for the Ventanas smelter of ENAMI. The effect of power input, electrode immersion, temperature of the slag, coke and solid revert additions on the rate of magnetite reduction and copper recovery was investigated. It was found that the addition of solid reverts, containing copper matte, enhanced the recovery of copper. Magnetite stratification and a corresponding gradient of the copper content occurred in the slag. Microscopic examination of slag samples showed the presence of copper in the form of matte and metallic copper inclusions. The results of the experimental work combined with an analysis of the phenomena that take place in an electric furnace led to a better understanding of the slag cleaning mechanism. The successful start-up of the slag cleaning electric furnace at the Ventanas smelter resulted in good copper recovery and confirmed the beneficial effect of solid reverts addition. Electrode consumption is lower than anticipated. No bottom build-up problems have been experienced. Keywords: copper, slag, magnetite.

Jan 1, 2001

By Alan DonaldsoN

Plasma Quench production of titanium is the thermal dissociation of titanium tetrachloride into gaseous titanium and chlorine followed by rapid quenching to prevent back reactions. Titanium tetrachloride dissociates into titanium and chlorine atoms at 5000 K. Expansion through a Delaval nozzle accelerates the gas to supersonic speed cooling it very rapidly. Cooling rates are as high as 7exp 1 0 Kelvins per second. Injected hydrogen reacts with condensed titanium particles to form titanium hydride and with the chlorine to form hydrogen chloride. We have produced titanium powder at 20 kglh in a continuous reactor. Costs are projected to be lower than the Kroll Process at large enough scale. Most of the cost reduction would result from elimination of magnesium as a reducing agent and much lower capital costs.

Jan 1, 2001

By John Vynne

Too often, a mine’s operations, including drilling, blasting, loading, hauling, crushing, processing, etc., are considered independent steps, rather then a continuous process. In fact, these are interdependent operations with each step in the process having an impact on subsequent operations. If the effectiveness of the drilling and blasting operations can be improved, they will impact the entire mining process. Some of the resulting improvements include: level benches on grade; fragmentation and diggability with the result being reduced loading times; haul cycles improvements; and the crushing and milling operations will be more efficient and less energy consumed. Thunderbird refers to this as “Drill to Mill” information cycle or process. This paper focuses on two of the technological enhancements Thunderbird has added to its drill monitors that allow the mines to impact the “Drill to Mill” concept. These enhancements are: incorporating global positioning satellites into drill monitors; and radio off-loading of data.

Jan 1, 2001

By M P. Simpson

Forty one whole rock samples from the Gold Cross low-sulfidation epithermal Au-Ag deposit have d18O values that range from 4.4 to 9.3 per mil, with an average value of 7.0 per mil. Unaltered and weakly altered rocks have d18O values greater than eight per mil, and the orebody is surrounded by samples that are depleted in 18O. A strongly silicified sample adjacent to the Empire Vein System has a d18O value of 9.0 per mil, similar to previously reported analyses of vein quartz (7.0 to 11.7ë, average 9.4ë). This suggests that, in detail, Golden Cross may have a zone of 18O-enriched wall rocks in the core of the deposit, adjacent to the main underground veins. Although some workers have suggested that stable isotope geochemistry may provide useful information for epithermal mineral deposit exploration, at Golden Cross this is not the case. Alteration minerals, major elements and trace elements all define larger, less ambiguous halos than the zone of 18O-depleted wall rocks.

Jan 1, 2001

By Mark Cross, Andrew P. Campbell, Koulis A. Pericleous

"Computational Fluid Dynamics (CFD) modelling is being used to simulate the freeze layers formed within direct smelting processes. There has been some concern whether water-cooled elements can withstand the p~ocess conditions and in particular abnormal cases where they may be splashed in molten metal.To validate the models being developed, two cases from literature have been modelled for solidification and stress analysis. The solidification case is presented in detail and is for hot molten metal flowing through a cylindrical pipe. The walls are at a temperature below the melting point for the metal. The resulting solid (or freeze) layer is within 3% of the value calculated by Sampson & Gibson9 •Preliminary modelling of the refractory-slag interactions is presented. Although three basic mechanisms: Penetration; Corrosion; and Erosion will eventually be modelled, only the penetration is considered here. The corrosion mechanism is to be modelled by tracking the time that the penetrated refractory is at the required temperature.Future work, after adding all the required physics, will focus on the modelling of a water-cooled element placed lower in the smelter. Process perturbations will be simulated to examine what these elements will withstand."

Jan 1, 2001

By M. G. Basavaraj, S. Sarkar, G. S. Gupta, P. D. Patil

"Previous experimental study on raceway size hysteresis on two-dimensional cold model showed that the inter-particle and wall-particle friction had a very large effect on the raceway size. Existing literature correlations for raceway size ignore the frictional effects. It has also been shown in the present study that their applicability to the ironmaking blast furnace is questionable. To take into account the effect of friction on the raceway size a stress analysis has been done for the raceway region. Two-dimensional fluid flow equations under turbulent conditions have been developed and solved computationally in order to get the pressure forces. The frictional forces were obtained in terms of stresses. To predict the raceway size a force balance was done for the raceway zone considering the pressure force, the frictional force and the bed weight. The resulting equations from the force balance are able to describe the raceway hysteresis phenomena reasonably well along with the raceway size. A two dimensional experimental set up has been fabricated in order to validate the computer predictions. Predicted values agree well with the experimental values.IntroductionWhen a high velocity blast of air is introduced into a packed bed through a tuyere, a cavity is formed in front of the tuyere. This cavity, formed in the iron-making blast furnace, is called the raceway. Coke tumbles down and bums in this raceway, generating heat and reducing gases for the iron-making process. The raceway is responsible for producing most of the reducing gasses in the blast furnace. In addition, the size and shape of the raceway determines the movement of solids within the blast furnace, the distribution of gases and liquids (slag and metal), setting the location where the primary chemical reactions occur and the temperature profile in the lower part of the blast furnace.Due to the importance of the raceway, many investigators l - 6 have studied it and have predicted the raceway size using the empirical correlations based on experimental (hot & cold) and mathematical models. A number of correlations have been reported in the literature to predict the raceway size by various investigators3 - 6 which are different to each other. Each of the correlations shows a different dependence of raceway diameter (DR) on bed height, particle size, solid density, bed voidage and blast velocity. None of the correlations includes the effect of solid stresses on the raceway size and shape. The magnitude of these stresses will depend on the bulk solids properties (internal angle of friction, wall angle of friction) and the bed dimensions."

Jan 1, 2001

In November 1999 Waihi Gold Mining Company commissioned its new crushing and conveying plant used to transport both ore and waste from the Martha Mine to its ore processing plant and also its tailings dam construction area. To date, a record monthly throughput of 854 000 tonnes throughput has been achieved. This paper outlines the measures taken subsequent to the commissioning of the system to achieve greater than design throughput and to mitigate the environmental and safety issues associated with operating the system in the middle of a town.

Jan 1, 2001

By Mohammad T. Izadi

Piles are, often, used for transferring load from the super structure through soft consolidating strata onto relatively stiff uncompressible soils. Downward movement of the soft soil strata develops negative skin friction and dragload around the pile shaft, with time. Traditionally the induced dragload is considered in determining the pile bearing capacity. On the other hand, field measurements on instrumented piles show that negative skin friction is reduced by the magnitude of applied live load. A method for calculating the pile bearing capacity, driven through soft consolidating strata is presented. In this method, two allowable load-bearing capacities are calculated for each pile, live load plus dead load and dead load. The proposed method, substantially, increases the allowable load bearing capacity of piles compared to calculated values by the traditional methods.

Jan 1, 2001

A wide range of materials are used in hydraulic backfilling operations and the pipeline flow behaviour of these mixtures varies considerably. It is shown that despite the large differences in constituent materials and flow behaviour, a common approach can be applied to analysing the flow of all hydraulic backfills. This is extended to include a rational design approach for backfill distribution systems. The use and limitations of pipe loop tests as a design aid is discussed. Backfill quality control is identified as a key area where improvement needs to be made to enhance the reliability of backfill system operation.

Jan 1, 2001

By Peter B. Dowden, Robert A. Robinson

Boulders, frequently found in tunnels excavated through soils, can pose major problems for full face TBMs in terms of slowing or halting the tunnel advance, cutter damage, and abrasive wear. The paper aims to consider the problem as a whole, from the geological characteristics of boulder sites, to the appropriate physical design of theTBM, and its operation in boulder-laden soils. In addition, visualization of boulders and other subsurface obstructions by seismic methods and ground penetrating radar are reviewed. The paper will assist the construction planner in assessing the risks and preparing appropriate specifications.

Jan 1, 2001

By Charles L. Richman

The effect of the addition of Silver Sulfide on the rate of Chalcopyrite (CP) of Sulfuric acid (H2SD4 leaching is discussed, Although Ag2S in an expensive addition, a theoretical explanation of it's use will aid in the development of a economic substitution. We have used cyclic voltammography to show the presence reaction species at different potentials. Cyclic Voltammography maps the surface reaction current peaks on CP, to regions on the CP Phorbaix diagram. AC Electro-lmpedance spectroscopy (EIS) models the surface impedance properties, which control the rate of electron and ion transfer, and the surface kinetic reactions, with and with out light. EIS and other measurements show that AgCuS u Photo-reactive material- The EIS results are compared with the SEM and EDXA results to show the presence of diffusion pores, and diffusion controlled reactions during CP leaching without the addition of silver sulfate. We hypothesize that AgCuS is an ionic conductor like Ag2S. EIS shows an imposed negative leaching rate greatly. Our theory shows how the formation of Silver Copper (1) sulfide layer at open circuit potential gives an effect similar to negative potential, that is enhanced with illumination. We verify that AgCuAS is an N-type semiconductor that forms a diode type junction with the electrolyte with the Mott-Schoottly relation.

Jan 1, 2001