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By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

Although the cyanidation process for gold leaching has been applied for more than a hundred years, some aspects of it, such as the passivation of the gold and the depassivating action of heavy metals, are still not well understood. In this work the anodic behaviour and surface composition of gold in alkaline aqueous cyanide with lead additions were investigated using polarization experiments and XPS. It was found that lead in the solution activated the gold at low concentrations, somewhat more positive than the reversible potential for gold, but that the activity again decreased at higher concentrations of lead. The potential range for the activation of the gold coincides with that where underpotential deposition of lead occurs, i.e. –200 to –600 mV(SCE), as indicated by the surface composition of the gold, shown in figure 1. Note that the concentration of lead on the surface of the gold only increased with time in the bulk plating potential range for lead, where gold is not activated by the presence of lead. It is also shown that up to 20 mg/L of lead added to the solution will activate the gold, provided that bulk plating of the lead is avoided. It is also important to avoid reducing conditions during leaching, where bulk plating of lead may occur, if the gold is to be activated by lead to achieve a high leaching rate, as the bulk plated lead screens the surface rather than activating it.

Jan 1, 2003

By Ragnhild Aune

In fire refining of copper, the affinities of various impurity elements on dissolved oxygen is of great significance. Further, in the design of oxygen probes in liquid copper, the influence of solute interactions on the activity of oxygen need to be considered in order to evaluate the oxygen concentration in molten copper. The present paper presents a series of measurements of the activities of oxygen in liquid Cu-M-o alloys (where M stands for Mn, Zn, As, Se or Te) carned out by the present group employing the solid electrolyte galvanic cell technique. Extreme care was taken to control the oxygen potentials in the inert gas atmosphere, and to keep the oxygen levels very low in the molten metal. The oxygen content was determined by analysis of the samples taken out from the melt. The results obtained showed that Mn has a strong negative influence on the activity coefficient of oxygen in liquid copper. A similar, but less prominent effect was observed in the case of Zn. Arsenic had no influence on the activity of oxygen in Cu (liq.). Se and Te had slight negative effect on oxygen activities in copper at XQ >10-5, while at lower oxygen levels the interaction coefficients were found to be positive. The results obtained were compared with empirical models for the calculation of interaction coefficients available in literature.

Jan 1, 2003

By A. D. Davis, C. J. Webb

Brohm Mining Co.'s Gilt Edge Mine in the northern Black Hills was a surface heap-leach operation that was active from the 1980s until 1999. Financing problems and acid drainage concerns at the mine were reported in the late 1990s. In February 1999 the Governor of South Dakota announced plans to request the US Environmental Protection Agency to help clean up acidic water at the mine and reclaim the site. In July 1999 the parent company of Brohm, Dakota Mining, filed for bankruptcy in Canada. Because of the bankruptcy and environmental problems, the State of South Dakota intervened and began water treatment. The mine was declared a Superfund site in 2000. Hydrologic issues include the potential for acidic drainage from the site. The mine is at the headwaters of Strawberry Creek, which drains into Bear Butte Creek. About four miles downstream, Bear Butte Creek loses its discharge to swallow holes in the karstic Madison Limestone aquifer, a regionally extensive and valuable groundwater reservoir. Other concerns at the site include treatment of acidic water in mine pits and a waste rock dump.

Jan 1, 2003

Slake durability of rocks is an important property of rock-mass and rock-materials in geotechnical practice. The slake durability of rocks is closely related to their mechanical properties. In this paper, mechanical properties and slake durability tests for weak and clay-bearing rocks from Beypazari Trona Bed in Ankara, were performed in order to assess the slake durability and mechanical properties (especially rock strength) of these rocks as well as to understand the relationship between mechanical properties and slake durability. In performing this relationship, statistical based correlation has been applied.

Jan 1, 2003

Simulator technology has advanced to the point where the cost of mining equipment simulators is beginning to make commercial sense. Simulator-based evaluation allows operators or potential employees to be assessed in a pseudo-real environment under surface and underground mining conditions. Simulator training also allows operators to be exposed to emergency and advanced situations such as brake or steering failure or a tireblowout. ThoroughTec, of South Africa, provides simulator equipment to the mining industry. The company’s various packages of simulator products provide an unbiased evaluation score that removes human error from the assessment process. This same evaluation score is also presented at the end of normal training or refresher training sessions. In this way, the simulator helps eliminate bad habits and improve efficiencies.

Jan 1, 2003

By A. I. A. Salama

The CANMET Western Research Centre (CWRC) has developed a hydrocyclone model simulation of dewatering and fine particle separation circuits. The simulation is based on an existing empirical model. Utilizing a cyclone manufacturer’s published data, some modifications have been developed and integrated into the model. Feed stream characteristics, cyclone mechanical dimensions, and operating conditions are used in the CWRC modelling simulation. The computer results are presented in 3D graphs and corresponding 2D maps showing the cyclone mass recovery, percent solids by mass in underflow and overflow, and cut size as functions of the cyclone apex diameter and cyclone throughput (i.e., inlet pressure or pressure drop). Results of the computer simulation have been used in the economic feasibility and design of several dewatering circuits in oil sand plants.

Jan 1, 2003

By Osvaldo A. Bascur, J. Pat Kennedy

"The profitability of mining and metallurgical operations continues to lag behind that of other industries despite the technical advances that have occurred in recent years. A primary reason for poor performing in this economic sector is the lack of integration of mining and metallurgical information. The mine cut-off grade can be optimized if mining and metallurgical engineers have the data to optimize milling for the type of ore in hand.Integration of mine transactions, stockpile inventories, process flows and assays is the key to determining the economics for each blast strategy in a mining site. Real-time information from manufacturing assets greatly affects the profitability and flexibility of a company, but gross errors from faulty sensors, inaccurate instrument calibration, or incorrect process models may corrupt actionable information. New software tools can model the process, sift through available data to identify and eliminate gross errors, and use statistical data reconciliation to create materially balanced and consistent readings. The reconciled data is unified for use by both monitoring and decision making processes.Creating a real-time information environment where upgrade and change are allowed is becoming an accepted methodology to accelerate and simplify the integration of applications such as production monitoring, equipment performance management and yield and inventory management.This paper describes the data integration requirements in a mine, concentrator and port for unification of the redundant data. The capture of the mining events, stock pile management and the metallurgical information is the base requirements for a dynamic environment to reduce the overwhelming amount of information to unified set of information. Part of any decision support program should entail these results to continuously improve the measurement system to address the costs in mine and milling the ore."

Jan 1, 2003

By R. Ribacchi, P. Tommasi, C. Consorti, P. Campedel

The runout of dry blocky rock avalanches produced by planar rockslides affecting a limestone formation with clayey interbeds is analysed by means of distinct element modelling. Numerical analyses are validated by means of the back analysis of a historical rockslide occurred in the investigated area and physical aspects of the phenomenon evidenced by modelling are discussed. On analyse par la méthode aux élements distincts la distance de parcours des avalanches rocheuses sèches produites par des glissements plan interessant une formation de calcaire à intercalaires argilleux. Les analyses numeriques sont validées à l’aide de la back-analysis d’un glissement historique survenue dans le site en examen. On décrit les aspects physiques su phénomène mis en évidence par la modélisation efféctuée. In diesem Beitrag wird die Reichweite von Steinlawinen besthend aus trockenem blockhaftem Fels mittels der Distinct Element Methode untersucht. Die Steinlawinen werden erzeugt von Rutschungen in einer Kalkstein-Formation mit tonhaltige Schichten betreffen. Die numerischen Berechnungen wurden anhand einer Simulation einer historischen Bergsturzen verifiziert, der sich auf den untersuchten Gebiet ereignete. Auf der Basis der erhaltenen Ergebnisse wurden die physikalischen Aspekte der untersuchten Steinlawinen analysiert.

Jan 1, 2003

By A. W. Stradling, M. J. Fairweather

"The selective flotation of lead, zinc and iron sulphide minerals is key to the economic performance of concentrators treating zinc-lead ores. Diagnostic metallurgy is a tool to quantify mineral behaviour as a function of particle size and liberation. The result of such analysis may be used to select preferred strategies to improve metallurgical performance. The zinc flotation circuits at three Teck Cominco operations: Sullivan, Polaris and Red Dog are compared here. This paper analyses operating data from each of these circuits. The effects of mineralogy and performance by particle size are emphasized. Metallurgical performance at these three concentrators varies substantially. Liberation size is the major factor in determining metallurgical performance. Complex mineralogy requires a fine grind to achieve effective liberation. Fine grinding results in offsetting decreases in concentrate grade through entrainment. The economic treatment of complex fine-grained deposits requires optimisation of regrind size for liberation without unduly compromising concentrate grade through gangue entrainment.INTRODUCTIONUntil recently Teck Cominco Metals Ltd. operated three mines treating zinc-lead ore. In order of increasing mineralogical complexity they are: the Polaris Mine on Little Cornwallis Island in Nunavut in the eastern Arctic, the Sullivan Mine in southeastern British Columbia and the Red Dog Mine in northwestern Alaska. Both the Polaris and Sullivan Mines have recently ceased to operate due to depletion of ore reserves.The ore type and associated gangue, mineralogy and iron solid solution vary significantly between these deposits. Table 1 summarizes some of the important differences"

Jan 1, 2003

By J N. Moncrieff

The resource estimation process for the underground Mount Isa Copper Mine has undergone significant change. Block models are now created using a commercial software package as opposed to the in-house software that was previously used. With mineralisation occurring over a strike length of more than 4 km, Mineral Resources for all categories totalled 190 Mt at 2.7 per cent Cu at 31 December 2002. Estimation is by ordinary kriging with two separate models generated to cover the X41 and Enterprise orebodies respectively. The underlying Upper Basement Contact and the silica-dolomite alteration envelope are both used as hard boundaries to constrain the modelling. From a validated block model, grade shells are generated at the appropriate cut-off grade for a given area. The grade shells are depleted for mined voids and subdivided into 30 metre strike length blocks. Application of a SMU criteria and crown and pillar constraints results in failed blocks being culled from the resource inventory. Mineral Resource blocks are further subdivided into resource categories (Measured, Indicated, Inferred) by the Competent Person on the basis of geological confidence, taking account of geological and grade continuity, drillhole spacing and structural complexity (JORC, 1999). A geostatistical æconfidenceÆ category is incorporated into the block model as an additional tool for the categorisation process. The shapes are assessed in concert with a mining engineer to determine whether a reasonable expectation of mining potential exists and if not they are removed from the resource. The final categorised blocks constitute the Mineral Resource inventory and form the basis for conversion to Ore Reserves. The resultant Mineral Resources and Ore Reserves are reported on an æinclusive ofÆ basis.

Jan 1, 2003

By Gift Makusha

The Witbank Coalfield in South Africa contains up to five economically viable coal seams. These seams have been mined continuously for over 100 years and the reserve in now becoming depleted. The normal mining method has been bord and pillar with examples of stooping. The situation now occurs where the formed pillars, left to maintain stability, have a higher quality than the coal that is left in the unmined reserves. Where the reserves are less than 70m deep and continuous over several kilometers, opencast mining is being successfully applied. After several years of investigation, Anglo Coal has identified blocks of coal that warrant investigation with regard to pillar extraction by underground methods The proposed method is pillar extraction using Mobile Roof Supports (MRS) It is proposed to mine three panels at a depth of 120m, by keeping the panels narrow and sub-critical. The sub-critical layout does not allow caving to surface and more stress is thrown onto the barrier pillar rather than the face pillars. The sub-critical span is anticipated to be 100m. The paper describes the full geotechnical investigation, including numerical modelling, instrumentation and drawing on the local South African experience of shortwall mining. The project will be unique in that pillars were not designed for pillar extraction and have low factors of safety (l.4 - 1.8) and width to height ratios of less than 4. The mining height will be approximately 4-4 5m, and this represents "new" operating heights for Mining Roof Supports. The required equipment was ordered in late 2002 and pillar extraction is anticipated to begin in June 2003.

Jan 1, 2003

By P. G. Gresse

The Orange-Vaal River system is known to be the primary secondary source for alluvial diamond deposits in the northern Cape and along the west coast of Namaqualand. The higher order sources for diamonds contained within this system are still not defined entirely to satisfaction, but certainly include kimberlite pipes exposed in the catchment regions of these rivers. The focus of alluvial diamond mining along the Orange-Vaal system recently changed from the traditional areas in the upper catchment regions?the Barkly West, Christiana, Bloemhof, Wolmaranstad, Schweizer-Reineke region, and the lower regions near the mouth of the Orange River at Baken, Alexander Bay and Oranjemund, to the area between Douglas and Prieska?the so-called mid-Orange region (Figure 1).

Jan 1, 2003

Experimental results are presented that test the hypothesis that the descaling behaviour of stainless steel slabs following reheating is controlled by interfacial roughening at the scale-steel interface. In this investigation, two stainless steels were considered: type 304 (austenitic, with 18% Cr and 8% Ni) and type 412 (ferritic/martensitic, with 11.6% Cr). It was found that the entanglement that arises at the scale-steel interface was in fact effective in maintaining scale-steel adhesion, under the mechanical descaling conditions used. In the case of type 304, descaling proceeded by fracture along chromite layers, which formed (by internal oxidation) on the austenite grain boundaries; for this steel, the extent of descaling depends most strongly on austenite grain structure, and not primarily on the conditions in the reheating furnace. In contrast, type 412 samples descaled only at the edge of the entangled zone, and showed a greater sensitivity to the reheating conditions; specifically, higher free oxygen in the reheating gas and longer reheating times were found to increase the residual scale thickness. Key words: stainless steel, reheating, scale, entanglement, descaling, fayalite, internal oxidation, grain structure, free oxygen.

Jan 1, 2003

By Randall J. Essex

Public and private owners of infrastructure projects face a number of real and perceived constraints when considering design-bid-build (DBB) procurement for underground projects. Thus, they may not be considering all of the available contracting approaches available to them. To the extent that the North American tunneling industry believes improvements can be achieved through better forms of contract, we have an opportunity and responsibility to bring these ideas to the owners of our projects. This paper offers suggestions for how we can climb out of our DBB Paradigm Sinkhole—and share some of the benefits of alternative contracting methods.

Jan 1, 2003

By O. Morfín

The most probable source of Pb contamination in the perennial reach of Aravaipa Creek, Arizona, has been determined using Pb isotope ratios and total metals analyses of samples collected from the ephemeral and perennial reaches and mine wastes located in the Aravaipa Mining District . Previously, elevated levels of Pb, Cd and As in fish in the perennial reach of Aravaipa Creek, a protected wilderness area,, were assumed to be due to off-site transport from abandoned flotation tailings piles located at Klondyke, Arizona upstream of the wilderness area.Our work replaces this inference with isotopic data that allows us to confirm this hypothesis. The Pb/Zn deposits of the district were mined between the late 1890s and the late1960s, with the most significant ore production coming from one deposit in a rhyolite dike swarm on the Western front of the Santa Teresa Mountains, a granitic pluton of Cretaceous-Tertiary age (~65 ma). Mineralogy has been well constrained across the length of the lode system: Pb and Zn sulfides predominate in the NW sector, and a mixed suite of hypogene/supergene Pb sulfide and Pb oxide minerals comprises the majority of its SE corner. Total metals analyses and comparison of metals ratios serve to constrain the source and transport of certain metals within different parts of the system. Pb isotope ratios in samples, obtained by ICP-MS analysis, define two distinct contributors. The first end-member (208Pb/204Pb = 38.513 to 38.721 and 207Pb/204Pb= 15.550 to 15.598) is characteristic of the mixed, oxide/sulfide ores at the SE end of the deposit. A second end-member (208Pb/204Pb = 38.855 to 38.946 and 207Pb/204Pb = 15.610 to 15.625) characterizes samples taken from the NW, purely Pb sulfide end of the lode. Pb isotope ratios from perennial reach sediments are closely correlated with ratios given by samples from the Klondyke tailings site and by Pb sulfide samples from the NW sector, the primary source of ores processed at Klondyke.

Jan 1, 2003

By Niall Weatherstone

Introduction Risks & Rewards of a Mineral Reserve Life History of a Mineral Reserve Estimate Risk Assessment & Management Mineral Resource & Reserve Estimation Good Practice Mineral Resource & Reserve Reporting Conclusions

Jan 1, 2003

By William Ewing

Copper is rapidly being adopted by the semiconductor industry as the interconnect material of choice. The aqueous processing techniques used generate wastes such as spent electrolyte from electroplating, electroplating rinse water, copper solutions from removing copper from the back of the wafer and CMP waste streams. We are examining the use of chelating resins as a means of recovering copper from these streams within the processing plant, thereby allowing recycling of process water and minimizing hazardous waste disposal costs. We have examined the effect of model plating additives (and other organic complexing agents) on the efficacy of Dowex M4195. Although these might have had a significant effect, commonly used electroplating additives polyethylene glycol (PEG), benzotriazole (BTA), thiourea, glycine, and 3-mercapto-1-propanesulfonate (MPSA) each had little or no effect on the ability of the resin to chelate copper and remove it from solution. This suggests that Dowex M4195 could be useful for treating waste solutions of rather variable compositions.

Jan 1, 2003

By F Pothitos, S Hewson

The geological and geotechnical conditions at the Cadia Hill Open Pit are very complex. This complexity coupled with high mining rates has required significant technical input into the design and optimisations of the pit slopes, accesses, cutbacks and scheduling. A multi-discipline team of NML engineers, geologists and external consultants has been conducting comprehensive geological and geotechnical programs in order to achieve an optimum design of the pit slopes. Extensive data collection, analysis and interpretation has led to the formation of working geotechnical models of large structures, rock masses, and back-analysed slope performance charts. The current Cadia Pit Optimisation Project focuses on the risk-and-return principle for pit design and on the integration of geotechnical, hydrogeological, mining engineering and scheduling. The risk management for pit design has also been incorporated into the short term and long-term operation of the pit mining to ensure safety and production.

Jan 1, 2003

By Tom A. Armour

Different variations of soil nailing techniques have been used in the United States since the late 1970's. Such techniques owe their origins to French developments, which began in the early 1970's as a spin-off from European tunneling excavation support practice. The growing demands of urban infrastructure development and rehabilitation and environmental protection have created an active and expanding soil nailing market demand for earth retention and slope stabilization in the United States since its early developmental years. There is a clear need for a fundamental review of the large number of soil nailing techniques that are currently being used in the United States. Following a brief summary tracing the historical development of soil nailing and a generic classification of applications, this paper provides a review of the different recent advances in the design and construction of soil nailed systems. Discussion topics include nail design advances, permanent "top-down", structure support/underpinning, alternative face stability measures, composite systems, hollow bar and fiberglass nails and architectural reinforced concrete/shotcrete facings. Case histories will be presented to illustrate each of these advances.

Jan 1, 2003

By C. Musingwini

Traditionally, mineral reserves management at most underground mines in Zimbabwe focus on maintaining large mineral reserves so that the time between development and production is as long as possible. Historical data at Shabanie mine, a Zimbabwean sub-level caving underground mining operation, confirms this practice. However, the high cost of underground development means that the luxury of large buffer mineral reserves cannot be justified. Furthermore significant increases in the costs of production, exacerbated by the current unfavourable economic climate, make the wisdom of extending development workings well ahead of use questionable. Poor ground conditions at Shabanie mine, mean that some development ends have to be re-mined two or three times due to partial or complete closure between the time they are mined and the time they are utilized. In order to reduce the inordinately high support costs associated with closure of development ends a new ?just-in-time? (JIT) approach that provides development ends as and when they are needed, has been adopted. Accordingly a model to determine an appropriate ?just-in-time? rate of development has been created. The JIT development model indicated that the mine could reduce development rates from 330 m/month in 2001, to 160 m/month in 2002 and achieve savings of about 50% on annual support costs, but still assure customers of a long-term product supply. The mine accepted the model in November 2001 and began implementing it in 2002. Results of the implementation will be reviewed in 2003.

Jan 1, 2003