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By Gabriel Riveros

Fire refining of copper consists of two stages copper oxidation and copper reduction. Very frequently the capacity of the anode furnace is determined by the rate of copper reduction, The analysis of factors affecting the rate of the oxygen reduction from a liquid copper with solid carbon or injected hydrocarbons pointed out the role of the mass transfer in a liquid copper in final stage of the reduction. Experimental results of copper reduction with graphite and injected natural gas in laboratory-scale crucibles showed two stages of the reduction process with a sharp change of the controlling mechanism. The estimated dynamic surface area of gas bubbles based on the measured bubble frequency and the gas flowrate allowed for the determination of the reaction constant as a degree of the partial pre-combustion of the air/natural gas mix. The variation of the used reductant as a function of the oxygen concentration and temperature has been evaluated based on the determined kinetic model. The intensification of copper reduction in fire refining has been discusses on the basis of obtained kinetic data and analysis of various factors determining the time of reduction.

Jan 1, 2003

By N Swiegelaar

Loubert Witbank is a defunct coal mine situated near Ermelo in South Africa. Mining ceased in 1992, and within a short period acidic decant occurred, with a significant impact on the regional catchment. The problem was studied during 1996/1997, and the site remediated in 2001/2002 by the Department of Water Affairs and Forestry. Remediation involved primarily submerging of carbonaceous material, backfilling of voids, and capping of the site. Acidic water with high iron levels was also neutralised and discharged. The project was used to assess the cost benefit of different options to the downstream users, from which target expenditure was derived for the various improvements. The cost benefit analysis for neutralisation provided a basis for the investigation of low-cost neutralisation options that are robust enough to be applied in a remote environment.

Jan 1, 2003

By Tzung-mow Yao, S Ki, J Word, J Vinson

Properly designed evapotranspirative (ET) cover systems can greatly reduce the amount of infiltration and groundwater recharge (deep percolation) into potential acid generating mine waste. In arid and semi-arid environments, infrequent precipitation, low measurable subsurface fluxes, spatial variability within mine waste and cover material, and evapotranspiration from below the cover system create challenges to monitoring moisture flux in these systems. Sloped ET single-layer (monolayer) cover depths and a variety of reclamation treatments are being studied at a copper tailing impoundment in Arizona, USA. To monitor the performance of different ET cover systems in response to precipitation patterns, four different test plots consisting of two different cover depths and two different vegetation densities were instrumented with heat dissipation sensor nests. The sensors measure the soil water pressure potential and allow hydraulic gradients to be determined within and below the cover systems to depths of 180 cm. Three replicate sensor nests were installed in each test plot to account for variability in materials and test plot treatments. Data collection occurs twice daily and is ongoing. Weather during the 26-month monitoring period was characterised by two months of greater than normal precipitation followed by nine months of normal precipitation and 15 months of abnormally dry conditions. Monitoring data indicate that deep percolation occurs in response to periods of extended precipitation, however, drying was observed to depths of six feet below the surface in all test plots. Using conservative assumptions regarding tailing hydraulic properties, one-dimensional downward flux predictions based on the monitoring data indicate very low (Additional long-term monitoring and installation of deeper and replicate monitoring sensors into tailings without cover systems are recommended to evaluate the long-term ET cover system performance and develop a better understanding of deep percolation rates at the sites.

Jan 1, 2003

By Berndt Moeller

Mercury-cell chlor-alkali production plants generate mercury contaminated wastewater streams from which mercury must be precipitated and filtered, resulting in a sludge containing 2% mercury (designated KI06) that cannot be landfilled in the United States without treatment. REMERC is a chemical treatment process used to recover 99% of the mercury from wastewater sludge generated at these plants. The process uses leaching to oxidize mercury compounds to mercuric chloride, washing and filtration to separate mercuric chloride from the treated sludge, and cementation to reduce the mercuric chloride to metallic mercury. Mercury not recovered in cementation is recycled to the wastewater process for precipitation and filtration. Treated sludge contains less than 260 ppm total mercury and 0.2 ppm TCLP, meeting the USEPA low mercury subcategory specifications that allow landfill disposal. REMERC uses readily available chemicals, is straightforward to control and inexpensive to operate, has no mercury emissions to air, and recovers metallic mercury. REMERC enabled significant cost savings including lower solids disposal costs, recovery and reuse of metallic mercury in the chlor-alkali process, and ability to treat non-wastewater sludge. No new EPA permits were required. REMERC was shown to be a viable process for recovery of metallic mercury from K106 designated sludge.

Jan 1, 2003

By E. V. Lilford

The South African Minerals Development Act (?the Act?) has been promulgated and will come into full force and effect once it is gazetted. Thereafter, all Old Order mineral rights will have to be converted into New Order mineral rights within a 5-year period, probably by the end of 2008. The conversion of rights will be achieved only with the demonstrated inclusion of empowerment groups in the conversion applications. In addition to the Act, the first draft of the proposed Royalty Bill (?the Bill?) was released during the week beginning 17 March 2003. Comments on the Bill?s contents had to be submitted before 30 April 2003. The contents were to be considered in terms of applicability and acceptability to the South African minerals industry, where after proposed comments and suggested amendments were to be submitted to the relevant State Treasury office. Specifically referring to the Bill, the general response from the industry is one of concern. Since any royalty is tantamount to a tax, the general feeling is that the current mining taxation rates are already internationally competitive and to increase these effective rates, notably at differing rates depending on commodity type, will have an adverse impact on the South African mining industry. A number of these impacts can be mitigated to some degree, depending on the flexibility of the State to address the major concerns.

Jan 1, 2003

By Steve Dillingham

Change occurs all of the time. In fact, it’s fair to say that change is a constant. Sometimes the change is inconsequential, but sometimes the change impacts us d i rectly and severely. Take regulations, for instance. Complying with regulatory requirements is just part of the job for those involved with explosives. But in recent years, it seems as if new or revised regulations in areas such as hazardous materials training, drug and alcohol testing, security issues, or local licensing/permitting standards are changing the way we operate on a recurring basis. Simply keeping track of all of these regulations has become a full-time job.

Jan 1, 2003

By M. Ng

As part of a long-term study of titanium minerals processing being undertaken by the Julius Kruttschnitt Mineral Research Centre, techniques have been developed to measure the resistivity of ilmenite, rutile, zircon and other associated minerals. The techniques have proven reproducible and have allowed the measurement of resistivity under conditions of varying temperature, surface condition and surface moisture adsorption. The measured values can be linked to the separability of the minerals in the dry plant, and hence are useful as a diagnostic test for existing plants when performance deteriorates, or for greenfield sites to investigate potential problems. One of the major problems in electrical separation of titanium minerals is surface coating on the mineral grains. Coatings can make normally conductive minerals such as ilmenite and leucoxene behave much more like non-conductors. Electrical separation of surface contaminated ilmenite from non-conductors then becomes extremely difficult unless the surface contaminant is first removed. The resistivity measurement technique was used to evaluate the effect of surface cleaning on the resistivity of ilmenite and zircon from a Western Australian deposit which will shortly be in production. Ten different attritioning methods were evaluated, ranging from simple rinsing inwater to chemical attritioning in sulphuric acid combined with ultrasonic leaching. A roasting and quenching step was also investigated. As would be expected, the gentler treatments, such as rinsing in water or Calgon, had only amoderate effect on the ilmenite surface coatings. Ilmenite resistivity decreased by about 1 order of magnitude from 5.6 x108?m to between 2.5 and 4.4 x107?m. More intense treatments had a much more pronounced effect. The most effective, reduced ilmenite resistivity to 6.5 x105?m or three orders of magnitude. Zircon was relatively unaffected by any of the attritioning methods, with only a small increase in resistivity observed from 8.0 x1012?m to 2 x1013 ?m. The results show that measurement of mineral resistivity allows the effect of surface treatments to be easily quantified in a way that has benefits for greenfield site development where only small samples are available for testing. The effect of surface moisture has also been investigated using resistivity measurements. Measurements were made on zircon in an environmental chamber in which both humidity and temperature could be closely controlled. Zircon resistivity at 60 deg C decreased from 6 x1011?m at 5% relative humidity to 8 x108?m at 95% humidity. Moisture content and moisture re-adsorption from dry of zircon and number of other minerals were measured using a Mettler moisture analyser. Zircon adsorbed the least amount of surface moisture (0.05–0.09%) but re-adsorbed moisture from dry the fastest, reaching 98% of the original level in 10 minutes. Leucoxene adsorbed the most moisture (0.67%), but was much slower re-adsorbing this moisture from the dry state, reaching only 63% of the original level in 10 minutes. The difference was attributed to the surface characteristics of the grains, the leucoxene being much more porous than the zircon examined. The resistivities and differing rates of moisture adsorption can be used to quantify the effects of changes in atmospheric conditions of the performance of electrical separation in dry plants.

Jan 1, 2003

By J. Lui

The 15m high Inco flash furnace uptake was designed as a reaction chamber with the objective of destroying the H2S contained in the furnace off-gas by combustion with oxygen at about 1300?C. Until recently, the oxygen required for this purpose was injected through afterburners located at the bottom of the uptake. An undesirable side effect of this practice was the formation of build up accretions on the inside walls of the uptake. This buildup had a negative impact on both the furnace on line time and the control of the flash smelting process. In late 200 I, the afterburners were relocated to the roof of the uptake. As a result, about 80% of the uptake accretion buildup disappeared with obvious beneficial effects for the operation of the furnace. This paper discusses key flash smelting aspects that affect the operation of the flash furnace uptake such as the dusting rate, the formation of H2S in the freeboard of the furnace, and the impact of using coke to supply some of the heat required by the process. The mechanism of buildup formation and its dependence on uptake afterburners location are also examined. Prof. Yazawa's sulfide smelting thermodynamic relationships proved instrumental in understanding the conditions that influence the formation and the elimination ofH2S and uptake buildup.

Jan 1, 2003

Exploring for deep shallow dipping orebodies can be very expensive and very difficult. Surface exploration is often not an option and obtaining the best location for underground drilling can cause production delays if drilling is carried out from development headings. The Otter/Juan mine has been in production for approximately 34 years. All of the production is now sourced from more than 1000 metres below the surface from an area known as the Edwards Lode. The orebody is shallow dipping and open at depth. Exploration drilling has been performed from decline stockpiles and from hangingwall drill drives. Drilling from footwall positions (eg decline stockpiles) into shallow dipping orebodies can often produce intersections which are unusually thick thus leading to optimistic resource figures. The decision to develop a dedicated hangingwall drilling position can vastly improve the quality of the data used to generate an orebody model. In 1997 a new extension to the Edwards Lode was discovered and named the æFÆ surface. In 1999 a resource calculation was performed using data obtained from drilling that was carried out from decline stockpiles. In 2002 a dedicated drill drive was developed into the hangingwall of the æFÆ surface to obtain better data to verify the previous resource calculation. For this case study obtaining more representative data reduced the resource estimate by 66 per cent. This information was obtained early enough to allow for alteration to the mine plan and without loss of capital.

Jan 1, 2003

By M. Myers, T. Oxley

Price, lead-time, efficiency, availability, maintainability. These are all the factors involved in the selection of components for a conveyor system in a mining operation. Historically, the decision-makers do not consider all these factors together when it is time to procure the equipment needed to assemble a conveyor system. The Total Cost of Ownership approach enables an operation to attain superior efficiency and desirable maintenance practices, all while minimizing the total cost to operate and maximizing the return on investment.

Jan 1, 2003

By Choi Sang-Ken, Chung Hun-Saeng, Kim Byoung-Gon, Lee Jae-Jang, Park Chong-Lyuck

"Graphite has unique properties such as high thermal resistance, low thermal expansion coefficient, and good thermal and electrical conductivity, and is often utilized as coating materials for electrical conductors, TV Brown tubes, electromagnetic shields, and so on. Additionally, its excellent lubrication property is widely used in oil and solid lubricants. Finely ground graphite particles in the sub-micron range are commonly used for these applications.Sub-micron fine graphite particles are typically prepared in liquids by vibration ball mills. However, it is known that the wet process takes long periods of grinding time like 24 hours or more and requires a series of subsequent highenergy operations such as de-watering, drying, regrinding and classification. On the other hand, there would be numerous advantages if fine grinding could be done effectively in dry atmosphere. However, since crystalline graphite has a layered structure giving a high lubrication property, its dry grinding, especially when obtaining sub-micron size particles, is extremely difficult. The shape of the graphite particles is also important for its utilization since particles with flaky shape can maintain relatively high electrical and thermal conductance as well as lubrication ability. Therefore, it would be necessary to reduce the size of graphite particles into fines with flaky shape while grinding proceeds. Dry grinding characteristics of natural graphite under various atmospheric conditions with gases using different mills were studied, and fine flaky particles by grinding the graphite intercalation compounds and the exfoliated graphite were produced. However, there were no sufficient investigations on the size reduction of natural graphite at low atmospheric pressures in attritional milling conditions. The main purpose of this paper is to provide sub-micron fine grinding characteristics of natural crystalline graphite at various degrees of low atmospheric pressure, and to discuss the size reducing models in an attrition mill"

Jan 1, 2003

By Irsan Chandra

It is generally recognized that the gold thiosulfate leaching system requires the presence of copper and ammonia in order for acceptable leaching kinetics to be observed. However, the presence of copper and ammonia complicate the chemistry of the system as thiosulfate is rapidly oxidized by oxygen under these conditions. In addition, the environmental impact of ammonia would need to be considered before the adoption of this system. This paper describes fundamental studies into the thiosulfate oxygen system. The two reagents for this system are thiosulfate and oxygen, and leaching is carried out at pH < 7. It will be shown using electrochemical techniques that both the reduction of oxygen and the oxidation of gold-to-gold thiosulfate are hindered. Thus, if leaching is to work under these conditions, then both half reactions need to be improved. The use of additives, such as thiourea and lead have been shown to dramatically improve the oxidation of gold and the reduction of oxygen respectively. The leaching of gold in the presence of such additives is discussed.

Jan 1, 2003

By Michael Traylor, Michael Jatczak, Brett Robinson

The Detroit River Outfall No. 2. is an effluent water conveyance system linking the Detroit Metropolitan Wastewater Treatment Plant to the Detroit River. The 6.4m (21ft) finished diameter tunnel extends 1,890m (6,200ft) east from the bottom of a 91m(300ft) deep, 9.2m (30ft) diameter drop shaft. At the eastern terminus of the tunnel, six Riser Shafts connect the tunnel to diffuser heads on the riverbed. The tunnel runs through a highly fractured Limestone formation capable of producing high levels of groundwater in?ows and Hydrogen Sul?de gas. Control of this water and gas was a theme which ran through the entire Project’s design and construction. This paper will provide an overview of each portion of the Project’s construction, including the Entrance Shaft, Precast Concrete Segments, TBM Tunnel, Pre-Excavation Grouting Methods, and the Riser Shafts.

Jan 1, 2003

The standard procedure of fire refining consists of sulphur removal via air injected through tuyeres, arsenic slagging via soda-lime flux and oxygen reduction by air or oxygen deficient air or a steam fuel mixtures. The use of porous plugs to stir with an inert gas has been mainly considered as a surface renewing agent that increases the product quality and shorten the refining cycle. In the present study the effect of the bottom stirring by nitrogen gas injection through porous plugs for the treatment of the crude copper in the range of 400-150 ppm sulphur, 3,000-2,000 ppm arsenic and 14,000-7,000 ppm oxygen content was investigated. The combined effect stirring-reducing, by the use of air or a steam fuel mixtures through tuyeres for oxygen removal, follows a kinetics of first order where the constant, K, can be represented by the following polynomial expression: K = A * R2 + B * R + C Where A, Band C are constants that depend on the nitrogen flow rate and R is the air-fuel ratio or the steam-fuel used in the reducing step. Depending on the optimization of the flow of nitrogen and the air-fuel or steam-fuel mixture and only if just the oxidation, complexing and reducing steps are considered, the process cycle might be shortened by 45%.

Jan 1, 2003

The present contribution examines the main components of a sustainable land reclamation program applicable to surface coal mines and the environmental threats that hinder the transition to sustainable land management. It compares the main ?waste streams? that cause adverse impacts to the environment with the so-called ?best available technologies and managing practices? that are proposed by organisations with high expertise in land management. Also, it addresses the environmental and socio-economic indicators that should be monitored in order to assess the results of the land management program and to allow remedial actions and continuous improvement. Based on the Greek lignite mines experience in land reclamation, this paper presents the common weaknesses of the land management programmes and proposes an improved communication scheme that moves things towards sustainability. This scheme is based on a more rational exploitation of the available economic resources and a constructive dialog between the mining companies, the local authorities, the state institutions and other stakeholders.

Jan 1, 2003

By M J. Nugus, S C. Dominy

Mesothermal lode-gold deposits often pose problems during sampling because of their complex and erratic gold grade distribution, and the presence of coarse gold. Effective sampling and sample preparation protocols must form the basis of any resource estimate at whatever stage a project is at. Design of a sampling regime must be based upon a thorough understanding of orebody mineralogy and geology. This should include consideration of gold particle size and distribution. The sample type, size and density employed must also be based on the underlying geology of the deposit. Choice of sample preparation procedure and assay type is of critical importance if fundamental sampling error and analytical errors are to be minimised. Traditional fire assays, using small charge sizes, consistently understate assays gained from large charge sizes and techniques such as screen fire assay and bulk leach extractable gold assay. The proportion of coarse gold within samples will have a profound effect on the requirements for sample preparation and assay method. The application of Gy sampling theory can help to reduce errors within the processing of samples of broken rock. Quality control/assurance of sampling regimes must also be critically assessed. The problems associated with sampling mesothermal lode-gold type deposits are presented as case studies from Western Australia and North America.

Jan 1, 2003

Blast vibration analysis under relatively near-field conditions has been carried out in a narrow-vein underground operation. The objective was to characterize the vibration signal (particle acceleration and velocity) from carefully controlled stope blasts. The limitations of such analysis in deriving design guidelines for reducing dilution has been elucidated. It has been shown that identification of each individual hole with specific explosive types can yield explosive-specific predictive equations for particle velocity. This has been coupled with measurement of actual overbreak to arrive at a limiting vibration level to generate a realistic design tool for controlling dilution in narrow-vein mines.

Jan 1, 2003

By L. Burdukova

In flotation, depressants are used to reduce the amount of gangue that reports to the concentrate and hence increase the selectivity of the flotation process. At the University of Cape Town extensive batch flotation tests are carried out to evaluate industrial depressants and standard procedures have been developed over the years. This study was conducted in order to develop an improved method for comparing depressants using machine vision as an aid. The modified method of batch flotation involved a test with prolonged intervals between scraping to allow more time for the froth to build up and mature.

Jan 1, 2003

By Victor Avdokhin, Valery Morozov, Valery Stolyarov

"The adaptation-determination method provides for keeping given relationship between concentrations of ionic and molecular components of a pulp liquid and correction of parameter of the model on the basis of analysis of ore composition, technological parameters of flotation, and cost of valuable components.• optimisation program “ADDEFLOT” and combined analyzer of pulp “RA-931”An adaptation-determination method provides for two-level control of bulk and selective flotation of polymetallic ores. The lower level provides for control of reagent dosing on the base of control of ionic composition parameters in the pulp liquid phase. The control goal is to keep the basis relationship among parameters of ionic composition (ions A, B, C) in pulp liquid phase given by equations of type:• alg[A] + blg[B] + clg[C] = K (1)Values of a,b,c coefficients are uniquely determined by a physico-chemical model used. Kind of the model depends on mineral composition of an ore and reagent regime applied. As parameter of ionic composition, also values of one or two parameters (or their combinations) can be used, for instance, pH, concentration of sulfide ions, ions of collector.The upper level of control is based on calculation and use of technological results of selective flotation. At the level, an adaptation of the model (1) is conducted. A principle of the adaptation is in determining (and including in pre-setting function of the lower level) such value of K parameter, at which maximal economic effectiveness of the process is reached. As a criterion of economic effectiveness of the process, a function of losses of several valuable components, taking into account cost of the metals lost, is used. For 2-component ore, in simplified form, the function is as follows:"

Jan 1, 2003

By Rob Morrison, Andrew Scott

"Long before a modern mine commences operations it has already become a wealth of information. After start up, it can generate enormous quantities of data – especially with semi-automated data acquisition by instrumented mine equipment. Much of this data is of limited use for evaluation of (potential) performance unless it links in some way to the site business model.An underlying reason for this waste of data is that the different cultures, financial, technical, community, environmental, etc, not only have many areas of interest but also have very different conceptual models by which they evaluate performance.It is too ambitious to attempt to bring all of these cultures together – in a single step. However, the success of the Mine to Mill ™ project has demonstrated that substantial operational value can be added by using a more integrated approach to comminution. The next logical step is to integrate measured data and then to track performance from ore body model to saleable product and waste disposal.The path from resource to product also represents a path from very sparse, highly variable data to much more detailed measurement and more representative sampling. However, in both cases the data collected is usually strongly focused on the technical requirements – not on the business model.This paper emphasises the difference between data and information. There is considerable potential for confusion between the two as both data and information are often expressed as numbers. For the purpose of this paper, data and information are distinguished by their uses.A data point (or datum) is a measurement. By way of contrast, information provides a basis for decision making."

Jan 1, 2003