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By D. Xie

An in situ gravimetric technique based on wetting and capillary action principles has been used to investigate the wetting and penetration of synthesized alumina samples and commercial magnesia spinel refractories by CaO-SiO2-Al2O3-Fe2O3slags. Synthetic slags of 40CaO-40SiO2-20Al2O3 (in weight per cent) with 0 to 9 weight per cent Fe2O3were used and the experiments were conducted at temperatures 1370 to 1470ºC under argon. The contact time between the sample and the slag was 30 minutes. The results show that the wetting and penetration are enhanced by the iron oxide addition in the slags. Addition of Fe2O3from 0 to 9 weight per cent resulted in a significant increase in the slag penetration into the magnesia spinel refractory by a factor of about 7 and a moderate increase in the synthesized alumina by about 60 per cent. The addition of Fe2O3enhanced the wetting (??cos?, where ? is the surface tension of the slag and the contact angle between the slag and the refractory) by 5 to 18 per cent. An increase in temperature from 1370ºC to 1470ºC resulted in a significant increase in the penetration of a 6 weight per cent Fe2O3slag in the alumina and magnesia samples by a factor of4 to 5 and a decrease in wetting by approximately 30 per cent. Keywords: refractories, slag penetration, wetting.

Jan 1, 2004

By R. A. L. Drew, G. Mendoza-Suarez, J. Filipi, R. Vintila, J. A. Kozinski

Economics and environmental considerations along with the increasing demand of hydrogen encourage development of novel technologies such as plasma processing of hydrocarbons and thermal cracking of natural gas. Plasma discharges, either in thermal or non-thermal regimes are expected to allow low temperature and fuel flexible on-site hydrogen generation. The main drawback of thermal plasma reformers is the high-energy consumption resulting from high-temperature operation. On the other hand, non-thermal plasma, generated by dielectric barrier discharge (DBD), is able to simulate the chemical reactions employing much lower energies than those required by thermal treatment processes. The non-thermal plasma process allows for instance, a direct conversion of methane into hydrogen and carbon black with no CO2 release. The focus of this research was on the GHG-free method of H2 generation in compact non-thermal plasma reactors using low, medium and high permittivity dielectric ceramics. A stable, non-thermal plasma was generated by placing a dielectric ceramic between two electrodes with a 25 thou gap and applying an alternating current of 1-5kHz and voltages of 4-8kV. In order to ensure energetic efficient plasmas, experiments were conducted to analyze the behaviour of different permittivity ceramics. It was found that the dielectric properties of a ceramic, when used in a DBD reactor, have a strong influence on the discharge characteristics, which in turn influence the power consumption. Higher dielectric constant resulted in higher conversion rates of methane (higher yield of hydrogen and carbon). At the same time, the mechanical properties of the dielectric material, which are closely associated with its processability, influenced its resistance to electron bombardment, as well as thermal and mechanical damage. Therefore a reliable ceramic should have good dielectric properties, in addition to good thermo-mechanical stability.

Jan 1, 2004

By Cathy Aimone-Martin, Frank Achuff

The New Mexico Department of Transportation (NMDOT) and the Federal Highway Administration (FHWA) have let a contract to Sierra Blanca Constructors for a design / build contract along 38 miles US 70 in Lincoln County, New Mexico. The project will improve safety of travel along the corridor and facilitate the adopted economic development goals of the state. Proposed improvements include widening the existing highway from two lanes to four lanes, providing left turn lane options at selected locations, improving access for businesses and residences, aesthetically enhancing retaining walls, improving storm drainage and replacing the existing pavement with a 30 year mechanistic imperialistic perpetual pavement design. The US 70 Hondo Valley highway project is situated in a narrow valley with steep limestone walls, passes along a Scenic Byway and numerous historic ranching communities with structures that date back three centuries. The scope of work included requirements to monitor and mitigate blasting, noise, and vibrations. The contract was very presumptive with regard to blasting design and procedures. These included visual impact mitigation to treat and stabilize slope cuts, the Migratory Bird Treaty Act protecting roosting and nesting birds from airblast, and the protection of historic and cultural features such as acequias, wells, and structures. Public involvement affecting the rock blasting design has come from citizen task forces and committees concerned with highwall aesthetics and preserving the scenic byway and cultural resources. Constraints placed on the blasting program from agencies and the communities are often at odds. For instance, blasting must produce stable yet natural-looking walls to preserve aesthetics. Restrictions have been placed on pre-splitting and smooth-wall blasting yet safe slope are of the highest priority. This paper presents details of the design/build process undertaken by the contractors to conduct blast rock in an environmentally sensitive region. Blast designs consistent with good construction practices and used to comply with the many federal and state highway stipulations are described.

Jan 1, 2004

By S. C. Thorley, J. R. Menasce

Trackless mining in low profile (LP) and extra low profile (XLP) platinum stopes has forced equipment designers to re-evaluate their equipment profiles to match the undulating reef. Low profile equipment designed to work in conditions with smooth and flat floors will simply not function with undulating floors and roofs and will become wedged between the floor and roof, beached on undulations due to lack of ground clearance, or suffer excessive mechanical damage. Tyres, too, need special evaluation, as conventional tyres for trackless mining do not work in an extra low profile environment.

Jan 1, 2004

By E. Kordzadeh, M. Reza Bateni, M. Karaminezhaad, A. Moeini

A series of austenitic heat resistant Fe-Ni-Cr-Al alloys with different nickel contents have been investigated at 1100 ° C and 25, 50, 50,100 hours in S/0 bearing atmospheres. Before sulphidation test, the specimens were annealed in argon at 1250 °C for 8 hrs. Weight changes were measured using an automatic thermo gravimetric analyzer and corrosion products were analyzed by scanning electro microscope (SEM), energy dispersive X-ray spectrometry (EDAX), X-ray diffraction and optical microscope. The results showed that sulphidation resistance decreased with increasing nickel content. Internal sulphidation controlled by gaseous transport through cracks and pores and the formation of internal sulphide increased when liquid sulphides formed on the surface.

Jan 1, 2004

By D. S. Limpenny

Marine benthic habitats are vulnerable to the influence of a wide range of anthropogenic activities (e.g. sand and gravel extraction, dredged material disposal and trawling). Traditionally, benthic ecologists have relied on point sampling techniques such as grabs, corers and dredges to provide information on the physical nature of the substrates and their associated benthic fauna. However, information of this nature only relates to the specific point on the seabed from which the sample was collected and the interpolation of such data to predict the wider distribution of substrata and associated fauna may be unreliable. Our approach uses a range of acoustic, photographic and physical sampling methodologies to produce continuous acoustic coverage maps which can be used to assist with the interpretation of faunal distributions. This approach has been used to assess the impacts of marine sand and gravel extraction at the seabed at two sites off the east coast of England in the southern North Sea. The first study site (designated ?Area 222?) is located 20km off the southeast coast of England and was surveyed in 2001 using sidescan sonar, single beam bathymetry, seabed photography and also a 0.1m2 Hamon grab for the collection of benthos and sediment samples. The main objectives of this investigation were to provide an indication of the spatial distribution of the sediments and macrofauna in the wider area encompassing the dredged site, to evaluate the scope for the effects of marine sand and gravel extraction to extend beyond the boundaries of the site and to provide a wider geographical context for time series investigations. At this site, an acoustic basemap was utilised in conjunction with faunal sampling and photographic groundtruthing, to determine the nature and distribution of the seabed sediments and their associated features. Disturbances at the seabed arising from historic sand and gravel extraction activities were mapped, and this information was helpful in establishing biological cause and effect relationships. The acoustic basemap was also used to target biological reference sites against which the effects of adjacent man-made disturbances could be evaluated.

Jan 1, 2004

By Jim Gunderson

Jan 1, 2004

By E. Bane Kroeger

Rib failure is a hazard that has resulted in many injuries and fatalities in underground coal mines, especially in soft coal seams. Conventional rib control methods including rib boarding, shotcreting. steel meshing and geogridding, are fairly expensive and time consuming to install. Some methods, such as rib boarding, have met with marginal success at controlling rib failure. Under this research, the Rib Strap System (RSS) introduced by Dr. Chugh in 1999, was modified and new components were added. Both bench scale and full size prototypes were tested in the labs at SIUC to determine the best materials for fabrication and easier methods for assembly and installation. This laboratory research has developed new methods of securing the strap ends to smaller rib hoards, a new device to post-tension two straps together, and a technique for replacing straps without having to drill new rib bolts or for retrofitting straps to rib hoards that are already in place. The method used to secure the strap end to rib boards developed during bench-scale testing was dubbed the wrapped staple technique. It is very simple, requiring only 10-15 staples, with the end of a strap secured to a rib board in about 45 seconds. Several different prototype designs for a new device to join the strap ends together and tension the strap were fabricated and tested in the labs at SIUC. The device, dubbed the rib strap buckle, was very easy to install and held the straps firmly. One specific buckle design worked extremely well during testing and exceeded all expectations. The laboratory research also developed a method of replacing a damaged rib strap that can also be used to add rib straps to existing rib boards. The technique uses nails, spacer blocks, and band clamps to secure the new board and strap. This technique was developed to allow one person to replace a strap using only a hammer and screwdriver, negating the need to drill and install a new rib bolt using mine equipment such as a roof bolter or scoop. In addition to the technical feasibility, the cost of materials for the rib strap system was compared to the rib boarding method currently being used at a mine in the Illinois Basin. The mine is using 20 rib boards on each pillar at cost of about $223.60. The costs for the rib strap system depend on the materials chosen for fabrication but for the base case, were about $97 per pillar.

Jan 1, 2004

By M. Tangstad, B. Monsen, H. Midtgaard

The increased attention towards reducing emissions of fossil CO2 due to its potential global warming effect has resulted in a focus on renewable resources, as charcoal. Since charcoal is produced from growing wood it does not contribute to global warming. This paper gives a brief review of consequences of and reasons for using charcoal in the silicomanganese (SiMn) production. Results are presented from practical SiMn smelting experiments, on a pilot scale, using charcoal as reduction material and comparing with coke. As slag- and CO2-reactivity are important for furnace performance these features have also been measured.

Jan 1, 2004

By Zhitong Sui, Feng Zhang, Li Zhang, Tie Ou, Guangqiang Li

Researches on the recovery of iron, manganese and the removal of phosphorus from converter slag were reviewed. The carbon thermal reduction experiments were carried out by induction heating the mixture of converter slag and graphite powders at 1650°C and 1800°C in a graphite crucible. It was found that 62.7% of the phosphorus in converter slag was reduced into carbon saturated iron alloy, 32.8% of that was vaporized and only 4.5% of that remained in the final product. Totally 95.5% of the phosphorus in converter slag was removed. Almost all iron and manganese was reduced to form carbon saturated alloy. It was found that the free lime in converter slag can react with carbon to form calcium carbide at 1800°C. The main phases in the reduced converter slag are dicalcium silicate and tricalcium silicate with small amount of calcium carbide.

Jan 1, 2004

By Axel Preusse

In the Ruhr district, pipelines of public and private infrastructure are made of cast iron, steel, plastics or asbestos cement. Legal framework, technical regulations and normative standards define which pipeline materials may be used for the transmission of which kind of product Thus ground water endangering substances as well as inflammable or explosive products are only permitted to be transported in steel-made pipelines. Ground movements, due to underground mining, are transmitted via the soil to the pipeline and cause extra strain within the steel pipeline (Figure I). In extreme cases durable deformations may occur, characterized by an oval profile or a fold in the pipeline. To avoid or minimize damages, balancing elements are installed into the concerning pipeline, reducing the ground movements which might otherwise cause damages. [ ] The distance between the balancing elements is not arranged by random, but by a calculation method developed in a doctoral thesis [Spielberg, 1999] which represents the actual available standards in science and technology. The calculation method considers all relevant influencing variables with impacts on the movement behaviour of steel pipelines in mining areas, such as technical data of pipeline design (e.g. steel grade, wall thickness, weld seam quality), soil conditions (e.g. friction), laying depths of the pipelines, the operational impacts (working pressure, corrosion) and the mining impacts. As of today, mining has caused no damages to steel pipelines protected by this calculation method.

Jan 1, 2004

By J. Björkvall, L. Bååth, D. Malmberg, J. Malm

Microwave technology has for decades been a tool for astronomers to map and understand the complexities of the universe its composition and extent. It is also used on a laboratory scale by spectroscopists to examine properties of atomic and molecular compounds. In this novel work we will introduce microwave technology to be used for the investigation of liquid slag structures. The preliminary results indicate that the alteration of the slag composition could be correlated to the measured microwave refractive index. Investigations have been performed in the Al2O3-CaO-SiO2slag system. Keywords: Microwave technology, slag, structure, liquid, Al2O3-CaO-SiO2

Jan 1, 2004

By T. Markus, K. Hilpert

Discharge vessels of advanced light sources are made of translucent polycrystalline Al2O3(PCA).These tubes contain salt mixtures, which essentially consist of metal halides. The salt mixture is present as a melt at the coldest spot of the vessel under operating conditions and vaporizes partly. The temperatures of the coldest spot range between 1200 K and 1300 K, depending on the lamp performance. The maximum wall temperatures range up to 1500 K and for special purposes up to1700 K. Important constituents of the melt are alkali halides AX (A = Na, Cs, X= Br, I) and rare earth metal halides LnX3(Ln = Dy, Ho, Tm). Severe corrosion attack on the wall material is observed in the PCA discharge vessels. The aim of this work is to elucidate the corrosion mechanism. Annealing experiments under well defined temperatures were carried out in order to understand the complex chemical corrosion processes. Two different annealing vessels were used, one for experiments under isothermal conditions with a temperature of 1473 K and one for experiments with a linear temperature gradient from 1450 K to 1600 K. The vessels were filled with salt mixtures of different compositions and annealed for 1000 h. The corrosion attack was characterised by XRD, analytical electron microscopy, high temperature mass spectrometry, and chemical analysis of the salt melts. The results of our investigations show that the corrosion attack is caused by vapour species and by the salt melt. The most severe corrosion is observed in vessels filled with mixtures of alkali halides and rare earth metal halides. No corrosion of the alumina is practically observed if pure alkali halides or pure rare earth metal halides are present in the annealing vessel. Keywords: thermodynamic, corrosion, lamps, metal halide salt

Jan 1, 2004

By John O. Marsden

Technology development has played a crucial role in the minerals industry throughout history. The development of new technology allows mankind to produce metals and minerals at progressively lower cost of production in real terms, and therefore at progressively lower prices, improving their availability, accessibility and utilization worldwide. However, the developers of such technology are not guaranteed to reap the benefits from this effort: There is an expectation that technology developers will gain an advantage over their competitors. Is this a short-term benefit that results from a temporary cost or efficiency improvement, or is it a sustainable longer term "edge" that prevails even after metal or mineral price has been eroded by the implementation of a major step change technology? This issue is examined by reference to several case study examples in the copper industry. BACKGROUND The development and adoption of new technology has played a crucial role in the commodity minerals industry throughout history. As new, cost-efficient technologies are commercialized, the cost of production decreases, and this enables lower grade ore to be processed profitably. This in turn increases the availability and supply of the metal or mineral of interest, and ultimately (in a free market environment where the supply- demand balance determines price) inevitably decreases the metal or mineral price. This leads to the question: Why should mining companies invest in (new) technology development if the result is a decrease in the product price? The answer is to achieve competitive advantage, where the application of new technology enables one or more

Jan 1, 2004

By B Hooper

Deep cuts in CO2 emissions will be required to stabilise and, in the long term, decrease CO2 concentrations in the atmosphere. Technologies for capturing CO2 from major stationary sources (power stations, industrial plants, etc) and storing that CO2 for long periods of time is one of few near term options for decreasing CO2 emissions. This transition to low carbon intensity energy and possibly the hydrogen economy through renewables and in the long-term technological developments such as artificial photosynthesis.Capture of CO2 from post combustion emissions can be done using a range of technologies though costs are currently high and dependent on the concentration of CO2 in the emissions. Techniques include solvents, pressure swing adsorption and the use of membranes. Options for decreasing capture costs by increasing the concentration of CO2 in the emission stream include the use of oxyfuels (in pulverized fuel types boilers) and by moving to integrated gasification combined cycle (IGCC) operations either simply for power generation or for poly-generation opportunities. Once the CO2 has been captured it can be stored using a variety of methods. Storage in the ocean has been suggested but is considered an unlikely option because of environmental uncertainties and political opposition. Mineral storage is a niche opportunity. The greatest potential lies in geological storage of CO2 and this option is commanding increased attention from the Australian and international community.In Australia, the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) is an important new initiative that will support energy companies and energy intensive industries in meeting challenges posed by greenhouse gas issues and assist them in their efforts to reduce their emissions profile.The progress of geo-sequestration and the challenges in the capture and separation of CO2 in the process industries are discussed.

Jan 1, 2004

The Sams Creek gold deposit near Takaka in northwest Nelson was discovered in 1974 by CRA Exploration (CRAE) geologists. CRAE recognised the potential of the area and subsequently undertook a comprehensive exploration programme of geological mapping, soil and rock-chip sampling, geophysical surveys and diamond drilling. Exploration defined sporadic gold mineralisation contained entirely within a deformed and hydrothermally altered, peralkaline granite porphyry dyke with a seven kilometre strike length, and up to 60 m thickness. Rock chip samples indicated extensive and economically significant gold grades over approximately one kilometre strike of the dyke at Main Zone prospect. CRAE completed 30 diamond drill holes at this prospect and defined a limited resource. Oceana Gold Limited recommenced active exploration at the Sams Creek Project in late 2002, focusing on improving the geological understanding and known resource at Main Zone. Completion of 1041 m diamond drilling successfully increased the estimated resource to 10.7 Mt @ 2.12 g/t Au containing 729 000 oz at a 0.7 g/t cut off. A further campaign of 1560 m diamond drilling was undertaken in 2003 - 2004 to extend the resource and test the continuity of high grade mineralised zones. Deeper intersections of the porphyry dyke indicated geometrical complexity and grade variability similar to that observed at shallow levels. Recent research suggests that Sams Creek can be geologically classified as a variant of intrusion-related gold systems, and therefore comparable to some other, very large gold deposits. However, due to the rugged terrain and dyke geometry, surface drilling is reaching the limits of viability at Main Zone. If infill drilling continues to be successful then an underground decline may be developed to facilitate further exploration. Potential also exists along strike, where other significant gold anomalies are known but largely untested by drilling.

Jan 1, 2004

By D Craw

Interactions between structure and lithology in the Hyde-Macraes Shear Zone controlled the style of gold mineralisation at the Macraes mine. Large volumes of rock in some mine pits have most gold disseminated in hydrothermally altered schist, rather than in quartz veins. Mineralisation was initiated in the latter stages of metamorphism. Pods of massive schist rich in quartz and feldspar are surrounded by more fissile schist consisting of interlayered micaceous and quartzofeldspathic schist. Later shears have been partly controlled by the micaceous schist, and anastomose around pods of more massive schist. Micaceous schist was replaced by pyrite and arsenopyrite, accompanied by recrystallisation of phengitic muscovite under lower greenschist facies conditions. Gold occurs in sulfides and with microcrystalline quartz formed during minor silicification. Massive schist is locally mineralised along sulfidic microshears which have phengitic muscovite largely illitised under sub-greenschist facies conditions. Mineralised massive and micaceous schists were overprinted by cataclastic shears, with addition of graphite and more sulfides. Mineralisation occurred during a transition from ductile to brittle deformation regimes as the schist was uplifted in the late Jurassic.

Jan 1, 2004

By Ann Barron

For millions of people, cold weather is a fact of line – and one that can make a major challenge out of just getting to work. But for those working in the blasting industry, a number of obstacles are created when old man winter blows in. In addition to the obvious concerns regarding personal protection, Mother Nature can throw some very nasty weather at the blasting crew trying to travel with explosives products from the magazine site to the job site. As such, divers need to be familiar with cold, ice, and snow driving conditions both on and off the blast site. It’s critical to know what to expect before you leave. Keep informed of the latest weather and road conditions as they change often; it will help you make the right choice in clothing and driving habits. Remember bridges and overpasses will freeze first even in temperatures above or near the freezing mark due to the effects of wind chill. Plan to take extra time to and from the job site.

Jan 1, 2004

By H. J. McQueen

The modeling of the extrusion of 6061 alloy and its composites with 10 to 20 vol% Al203 or SiC by two techniques. The uniaxial finite element method FEM (DEFORM" ) provided force-stroke curves and temperature rise over the range 450-500 °C, 2.6-5mm/s and extrusion ratios of 31 and 64. The traditional technique considers ideal work and redundant work as well as friction and uses average temperatures and strain rates. The two techniques are used to clarify each other and to extend the analysis to 400 and 350 °C. The calculated efficiencies are compared to measured values in extrusion trials and to values derived for 7075 extrusion analyses. The analyses are based on constitutive equations determined by torsion testing tests.

Jan 1, 2004

By J F. Seale

The design of the settling pond for the Malvern Hills opencast coal project was based on a primary requirement to control runoff and sediment generated from the immediate 6 ha mine catchment, which included two seepages from old underground workings. The pond has been particularly effective in controlling turbidity in the outflow water, with the consent limit of 50 NTU being met on all but one occasion and normal levels of discharge less than 10 NTU. Water quality testing carried out at the time of consenting indicated that there were no acid-generation issues with the proposed mine site in dominant mudstone strata of the Broken River Formation, and that water from the old mine workings was near-neutral in terms of pH and well-buffered. However, it became apparent over the very dry summer of 2003 - 2004 that slaking of the exposed mudrocks in the mine batters was resulting in significant acidity generation, and outflow pH levels were well below the consent limit of 6.5 during and following periods of rainfall. Although these acidity problems have been remediated in the short-term by the use of lime products, it is clear that a programme of lithotype characterisation for AMD should have been undertaken and this has now been implemented. Design of long-term acid drainage control measures is being carried out, and will probably be based around the use of hydrated lime for pH control with enhancement of natural wetlands.

Jan 1, 2004