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By Yoshisada Michiura, Junko Umeda, Katsuyoshi Kondoh

Rice husks or straws, one of the main agricultural wastes in South-east Asia, have a large possibility to be employed as usefully renewable resources to produce energy and high-purity silica (SiO2), because they consist of about 70% organics such as cellulose or hemi-cellulose, and 20% amorphous SiO2. The former is utilized as bio-mass energy; for example, thermal or electric energy, and bio-mass ethanol. High-purity silica can be used as raw materials in the industrial uses. It would be possible to extract silica elements from rice husks and straws by burning them in air because their main contents are organics. In the previous studies, a strong acid leaching treatment on rice husks before burning was carried out by using H2SO4, HCl and HNO3 to prepare high-purity silica materials. This was available to accelerate the hydrolysis of celluloses and hemicelluloses contained in rice husks, and remove the above metallic impurities. A strong acid leaching treatment, however, is significantly hazardous to environment and human life, and causes an increase of the process cost. In this study, the environmentally benign, harmless to human and economically effective process to produce high-purity amorphous SiO2 materials from rice husks has been established without using strong acids. From a viewpoint of the harmless influence on human body, the carboxylic acids were used in the leaching treatment on rice husks. TG-DTA measurement and GCMS analysis indicated that the leaching was effective for the hydrolysis of celluloses and hemicelluloses contained in rice husks at 473K~873K, which produced the same results in using the conventional sulfuric acid. The metallic impurities could be also removed from the husks via a chelate reaction between carboxyl groups (-COOH) and the metal elements. In particular, it was clarified that cadmium (Cd) were completely removed from rice straws by this reaction. Concerning the burning conditions of rice husks after the acid leaching, it was necessary to supply a suitable amount of air to completely combust organics; for example it required air supplement of 50 ml/min. or more. The burning temperature should be less than 1273K to obtain amorphous structured silica. High-purity amorphous silica materials with 99% or more were prepared from rich husks by applying the citric acid leaching treatment and burning process at 1073K in air.

Jan 1, 2008

By James M. Lockwood

"Eureka Technology has developed and patented a technology for the recycling of EAFD. Through this process all constituents of the material become salable commodities or are returned to the steel making process. In transforming the EAFD ""waste"" stream into a ""process"" stream the Steelmaker eliminates potential liabilities and the uncertain future of current processes while further reinforcing its role as a recycler. This is a cost-effective and energy efficient technology that combines hydrometallurgic and electrolytic processes resulting in the recovery of salable metals. For instance, unlike pyrometallurgic processes, zinc is recovered in metallic form and no elements are volatilized. This on-site operation also eliminates expensive transportation costs. In summary this technology reduces the cost of dealing with EAFD by recycling material currently being landfilled.IntroductionWorld crude steel production reached a new record level in 2007 - 1.34 billion tons of which 31% was produced by EAF steel makers [1]. This resulted in the generation of over 6 million tons of EAFD. This steel byproduct contains significant amounts of lead, cadmium and other hazardous metals. In the United States the Environmental Protection Agency (EPA) has designated EAFD a hazardous waste (EPA waste code K061). With over 50% of steel production in the US coming from EAF steel making this byproduct represents the single largest source of solid hazardous waste generated."

Jan 1, 2008

By J. Borlée, J. P. Birat

"ULCOS is a large European program launched by a consortium of 48 partners led by arcelor and a core group of steel producers, which was started in 2004 with the support of the European Commission (RFCS and 6FP programs) to search for breakthrough process routes that could, in the future, when fully developed, demonstrate the potential of large cuts in CO2 emissions for the production of steel from iron ore.The timescale for commercial implementation is the post-Kyoto period, i.e. 15 to 20 years from today.The present paper presents the progress made in the first 2 years of this 5 year program.Several concepts are being investigated in parallel: re-engineering of the blast furnace to incorporate CCS in the core of the process, smelting reduction with CCS capabilities, massive use of natural with more CO2-lean technologies than today, hydrogen steelmaking and electrolysis of iron ore. Biomass also offers very attractive perspectives, while raising major challenges.None of these new steelmaking routes are ""no regret"", which means that the European Steel Industry has already incorporated extensive energy saving steps in its present process technology and is working as close to thermodynamics limits as is cinematically and economically feasible, and that decreasing GHG emissions further means introducing breakthrough technologies that add significant costs to the operation of the Steel Mills.They will also require much research and development before they can be proven and implemented commercially.IntroductionThe ULCOS program (Ultra Low CO2 Steelmaking) is a large research program of the European Steel Industry and its industrial and research partners launched in September 2004 to investigate steelmaking technologies that have the potential of reducing the CO2 emission of the Industry by a large amount, typically in the order of 50%. It is supported in the European Community by the 6th Framework and the RFCS programs through 3 complementary European projects [1,2].The present paper summarizes the work carried out in the phase 1 of ULCOS and in framing the program of phase 2."

Jan 1, 2008

By I. Yu. Melekestseva

Two types of hydrothermal massive sulfide fields were discovered in the Mid-Atlantic ridge (MAR) in the last twenty years. The first type associates with basalts and includes the TAG, Snakepit, Broken Spur, Lucky Strike and Krasnov hydrothermal fields. The second type is related to ultramafic rocks and represented by the Logatchev, Rainbow and Ashadze hydrothermal fields. In 2007 a new, probably, the largest cluster of hydrothermal massive sulfide field on the MAR (Fig. 1), related both to basaltic and ultramafic rocks, was discovered at 13°31'N of the MAR (Beltenev et al., 2007). [ ]

Jan 1, 2008

By Rick Deschamps

A reoccurring problem with support of excavations in urban areas involves the placement of external support components like anchors or nails in right-a-ways, subway and utility setbacks, in areas occupied by adjacent structures, and within the property of non cooperative neighbors. Such a situation occurred for a project in Arlington, Virginia, which ultimately resulted in the preliminary design of a large footing supported cantilever retaining wall that was extremely costly and impractical to build. An innovative design alternate consisting of a series of vertical concrete elements (VCEs) supported by post tensioned tiedowns was proposed to the General Contractor and accepted by the owner. The VCEs were designed to serve as the main structural elements for both the temporary support of excavation system and the permanent wall. The VCE?s were constructed using single bite diaphragm wall panels oriented perpendicular to the excavation face including a rebar cage and tremie concrete. Threaded inserts were placed within the rebar cage to attach the cast in place exterior wall. Overall stability and lateral movement of the VCEs were controlled by high capacity vertical anchors embedded within the VCE. A detailed instrumentation program was installed to monitor the movements of the VCEs with relation to the excavation depth. The paper present the project case history by discussing the design concepts of the VCE, the construction approaches used to install them, the construction challenges encountered, and the performance of the unique system.

Jan 1, 2008

Research cruises dedicated to seafloor hydrothermal activity along the Kermadec arc first began with the Sonne-135 expedition in 1998. This was followed by the worldÆs first systematic survey for venting along an arc during the 1999 NZAPLUME I expedition. Since then, cruises dedicated to mapping plumes along the Kermadec arc include NZAPLUME II (2002), NZAPLUME III (2004) and ROVARK (2007). In addition, the manned submersible cruises SWEEP Vents (2004) and NZASRoF (2005) utilised the Shinaki 6500 and Pisces V, respectively, to sample in detail select hydrothermalsystems for mineralised samples, rocks and vent fluids. The ROVARK (2007) cruise was the first to deploy an autonomous underwater vehicle (ABE) along the arc which surveyed Brothers volcano at a far greater resolution than had been done previously by ships on the sea surface. While these expeditions have largely been led by GNS Science, together with its collaborators from National Oceanic and Atmospheric Administration, Pacific Marine Environmental Laboratory (NOAA/PMEL), significant contributions have been made by other groups from various nations, exemplifying the global interest in seafloor hydrothermal activity associated with intraoceanic arcs. This is an ASTRACT only. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Hiren J. Shah

Across much of New York City, the geology of glacially deposited soils follows a common sequence. Outwash sands generally overlie varved silts and clays, which lie above a basal till deposit underlain by the bedrock. Pile foundations at projects with such typical stratigraphy generally develop their axial capacities by extending below the fine-grained deposits into the till or the bedrock. Contrastingly, at a project site on the Brooklyn waterfront, high capacity piles were efficiently and economically installed by driving them into the relatively shallow glacial drift and till deposits which lay above thick fine-grained compressible glacial lake deposits. An unusual aspect about the foundation design at the Brooklyn project site is that, relatively short and high capacity piles were driven into the shallow glacial drift and till deposits, overlying the thick fine-grained glacial lake deposits. In order for this unusual foundation scheme to be feasible and economical, the piles needed to achieve their driving criteria in the upper strata. Consolidation settlements in the lower stiff and over-consolidated glacial lake deposits below the pile tips had to be relatively small. The paper discusses the unusual stratigraphy in this area of Brooklyn in greater detail with geologic profiles and engineering characteristics of the glacial strata. It also discusses the design aspects of the pile foundations, settlement estimates, a pile drive test program during design, results of the static load test program during construction, and production pile installation results.

Jan 1, 2008

By E. Benguerel, G. Monteith, L. Centomo, S. Pelletier

In early 2007, it became apparent that with changing concentrate feeds, the magnesium (Mg) load projected for CEZinc starting in 2009 and beyond would quadruple and overwhelm the current Mg process bleed capacity. A project was started, following design for six sigma (DFSS) standards, to select both the optimal process and to evaluate its target capacity for the Mg bleed circuit. The economic and process risks of under or over-designing while Mg reduction efforts were underway at the mines also needed to be evaluated. This paper describes the project methodology, the impact on the plant, and some potential optimizations for CEZinc's basic zinc sulphate (BZS) Mg bleed process.

Jan 1, 2008

By Susan B. Bealko

Mining provides a large part of the energy and raw materials that feed this Nation's economy. Copper pipe, concrete, and window glass serve as well known examples of the reliance on minerals in modern society. Less appreciated, but as important, are the hundreds of mined commodities that are an integral and necessary part of everyday products, ranging from medicines and computers to carpet and paper. Coal is a major portion of the country's energy mix today, as it will likely continue to be in a future hydrogen-based economy. The domestic mining industry also provides strategic minerals that are important for the Nation's security. The processes to recover these mineral commodities are among the most demanding and complex in an industrial society, and this inherently dangerous industry has historically had the highest risks of fatality and injury. The mining industry has been undergoing some trying and challenging times because of the recent mine disasters in the coal fields. These events have been alarming in light of the strong and encouraging safety record that has characterized mining in the United States for most of the past decade. While mining communities deal with their grief, mine operators, government regulators, and other safety personnel, set about trying to determine why these fatalities occurred. Subsequently, the mining industry is currently experiencing changes in legislation at an unusually rapid pace. The most recent regulatory changes are the Mine Improvement and New Emergency Response Act of 2006 (MINER Act) and the temporary emergency standard for mine seals. The new mine safety laws call on the nation's mines to adopt certain procedures and safety technologies immediately, or as soon as they become commercially available. Putting all the provisions in place from these new laws is a major undertaking, and will necessitate strong collaborations and partnerships among mine operators, manufacturers, regulatory and research agencies, labor unions, and community groups. It is against this background that Prevention through Design (PtD) components for the Mining Sector are recommended.

Jan 1, 2008

By S. Shairp

Copper is an impurity as well as a necessary reagent in the processing of zinc sulfide concentrate at Hudson Bay Mining & Smelting Co., Limited's (HBMS) zinc pressure leach plant. Copper is present in the zinc concentrate as chalcopyrite, which consumes reagents necessary for zinc leaching. A small percentage of copper precipitates in the autoclaves, discharge lines, and flash tanks, requiring maintenance of the equipment and disposal of the solids. Copper also precipitates in the neutralization stages and is removed to low levels in a specific copper removal stage of purification. Yet some copper, as copper sulfate, is required, along with potassium antimony tartrate, in the final purification stage to improve cobalt removal from the zinc sulfate solution prior to electrowinning. The behaviour of copper experienced at HBMS's zinc pressure leach plant is discussed.

Jan 1, 2008

By Brian L. Quick

Problem: The National Institute for Occupational Safety and Health's [NIOSH] National Occupational Research Agenda (DHHS Publication No. 96 115) reports that approximately 50% of miners will experience hearing loss by age 50, compared to only 9% of the general population. The present investigation examines three antecedents believed to be associated with miner's use of hearing protection. Method: A posttest delayed posttest control group field research design was employed to assess antecedents toward wearing hearing protection. Results: Following the initial posttest, miners' attitudes and subjective norms were antecedents to intentions to wear hearing protection devices. Also, intentions toward wearing hearing protection predicted hearing protection behaviors. Approximately six weeks later, miners' attitudes and perceived behavioral control were each significant predictors of intentions to wear hearing protection and again, intentions were positively associated with hearing protection behaviors. Impact on Industry: Our results indicate that appeals to normative influences may be the most effective antecedent to employ when persuading coal miners to wear hearing protection. However, messages designed to impact attitudes and perceived behavioral control were also effective.

Jan 1, 2008

By A. Longval, Q. Jiao, T. Shannon

In 2000, Xstrata Zinc (former Falconbridge Ltd.) Brunswick Smelter commissioned a modified lead blast furnace. Since then, efforts have been made to improve its operation in order to achieve optimal operation in terms of coke consumption, lead loss to slag, and improved environmental and hygiene conditions. This paper will review the important step changes in operational philosophy, undertaken since 2004, for the control of the blast rate, oxygen enrichment in blast, slag chemistry and charge level. Furthermore, a review of the improvements made in secondary materials consumed at the blast furnace will be made. This paper will also discuss the significant reduction of the frequency of accretion removal as a result of improved furnace operation.

Jan 1, 2008

Two years ago I was sitting in a big lecture theatre at the School of Mines in Kalgoorlie at the annual New LeadersÆ Conference listening to a guy tell us all how much he loved his job, travelling the country ælegallyÆ blowing stuff up à and getting paid to do it. I would have paid to see and do the things he spoke of à now IÆm that guy. From finishing a mining engineering degree at the University of Ballarat, through the job hunt, to firing environmental blasts in Tassie and designing and implementing construction blasts in the middle of the Gold Coast. My name is Rohan Stevens and IÆm a blast-o-holic. While the æjob huntÆ we all embark on toward the end of our degrees is a stressful time, itÆs also very exciting in the current climate. There are a number of things I have learnt through both my hunt for the job that best suited me and working for the worldÆs largest explosives manufacturer. If at least you donÆt benefit from my learnings IÆm certain you will enjoy hearing about (and viewing) some of the work I have had the opportunity to be involved with over the last 18 months with Orica Mining Services.

Jan 1, 2008

By G. G. Richards, D. J. Rioux, R. L. Stephens

Teck Cominco Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. The year 2007 marks ten years of operation of KIVCETTM flash smelting technology for the treatment of zinc plant residues and lead concentrates. Since start-up in 1997, the furnace throughput has been increased to exceed its design rate and other metallurgical performance targets while continuing to meet its environmental objectives. This was achieved through resolution of key mechanical issues, improved understanding to stabilize the reaction shaft operation and control furnace accretions, significantly reduced boiler corrosion by molten chloride salts through the extensive application of weld overlay, a suite of projects to improve furnace integrity, and some debottlenecking of the surrounding unit operations in the lead smelter. The combination of increased feed rate and improved on-line time allowed the KIVCETTM furnace to set a new quarterly feed throughput record of 129,300 tonnes in the first quarter of 2008.

Jan 1, 2008

The Ernest Henry Mine is an open pit copper-gold mining operation located in north-west Queensland, Australia. It is owned and operated by Xstrata Copper with a current concentrator throughput of approximately ten million tonnes per annum. The pit will cease mining towards the end of 2010. Extensive surface diamond drilling has confirmed an extension of the orebody to depths of 1000 m below surface. A prefeasibility study was commissioned in late 2006 to investigate underground mining options with the preferred mining method being an inclined sublevel cave. In February 2008 mining of a decline commenced in conjunction with a feasibility study to further investigate the project. Work from the prefeasibility study indicates that an underground crusher, conveyor and hoisting shaft could be utilised to crush and transport broken ore from the sublevel cave workings to the concentrator. The study suggests that a production rate of five million tonnes per annum could be achieved and sustained for up to ten years. Ventilation designs and requirements will form a large section of the feasibility study. This paper will detail investigations of preliminary ventilation network designs of the proposed sublevel cave. Work has been completed using both Ventsim and VumA ventilation simulation packages. Ventsim was used to provide preliminary estimations and suggest alternatives for: surface fan duties;airflow characteristics (direction, velocity, pressure and quantity); andventilation network design in key mine areas. With mining activities reaching depths in excess of 1000 m below surface an analysis of heat conditions should be conducted. The VumA software package was used to model the thermal properties of the ventilation system. This model will provide a basis for the preliminary decisions on refrigeration requirements for the mine.

Jan 1, 2008

By Steve Rogers

Nautilus Minerals was listed on the Toronto Stock Exchange in May 2006. The company now has major mining companies Anglo America (5.7%), Teck Cominco (7.2%) and Epion Holdings (22.4%) as significant shareholders, and has raised approximately $US346 million dollars to develop the world's first deep-water mine. The company is currently targeting high-grade copper and gold in seafloor massive sulphide mineralization, located near plate boundaries in back-arch basins of the Western Pacific. The first mine scheduled to be developed by the company is located in 1,600 meters of water at Solwara 1, in the relatively quite waters of the Bismarck Sea approximately 50 km from the port of Rabaul, within the Territorial Waters of Papua New Guinea. During 2006 and 2007 the company completed detailed environmental and geological studies, culminating in a number of world firsts, including the world?s first NI 43-101 compliant resource statement and environmental impact study for a seafloor massive sulphide system. Permitting is well advanced for the project, with initial production scheduled for late 2010, subject to timely grant of the permits. Extensive government and stakeholder liaison and engagement has been undertaken throughout the projects life, and is a core feature of Nautilus' desire to "do it right" in all aspects of this new industry.

Jan 1, 2008

By M. Holmes, R. Molnar, E. Norton, K. Baxter, J. Riordan

The Boleo Copper-Cobalt-Zinc-Manganese Project of Baja Mining Corp. is situated adjacent to Santa Rosalia on the Baja Peninsula of Mexico. The El Boleo ore is a mixed oxide-sulfide deposit with major values in copper, cobalt, zinc and manganese. The metallurgical process designed to treat the El Boleo orebody involves a sulfuric acid leach in seawater using oxidative and then reductive leaching to maximize metal extraction. The leach solution is separated from the barren solids via counter current washing through a series of high rate thickeners. Copper is recovered using conventional SX-EW processing as cathode. Zinc and cobalt are extracted from the copper SX raffinate after iron and aluminum precipitation. The CSIRO DSX solvent system (Versatic® 10 and LIX® 63 mixture) are used in this extraction. Manganese remains in the DSX raffinate and is recovered by soda ash addition as a high quality manganese carbonate precipitate. Zinc and cobalt are acid stripped from the loaded DSX solvent. Zinc is then re-extracted away from cobalt using Cyanex® 272 extractant and stripped into a highly concentrated strip liquor (+100 g/L Zn) and directed to either a spray dryer or a granulator for production of zinc sulfate monohydrate. The zinc solvent extraction raffinate, containing cobalt, advances to another SX circuit using Cyanex® 272, for the recovery of cobalt as cobalt cathode. In this paper, the detailed results from bench and integrated pilot plant testing for zinc recovery from the El Boleo ore will be described. The results of this testing are currently being used to engineer the commercial plant at El Boleo.

Jan 1, 2008

By Dennis R. Dolinar

The National Institute for Occupational Safety and Health?s Pittsburgh Research Laboratory conducted a full-scale test of a composite polyurethane-aggregate seal in a hydrostatic chamber at the Lake Lynn Experimental Mine. This composite seal consisted of a polyurethane and limestone aggregate core that was formed between two concrete block walls. In the hydro-static chamber test, water is used to pressurize the seal. During the test, the maximum average water pressure the seal was able to withstand was 18.9 psi. Further, the seal began to yield at an average water pressure of only 17 psi. At the time of the test, the minimum seal design requirement was 20 psi under 30 CFR4 75.335 (2005). Therefore, based on this test, the seal did not meet the regulatory minimum design requirement. Uniaxial compressive tests conducted on samples from the polyurethane-aggregate core revealed that both the compressive strength and the elastic modulus of the material were much less than that for polyurethane only with a density of 10.0?12.0 lb/ft3. The significant reduction in the strength and stiffness of the polyurethane-aggregate mixture results from the formation of a soft polyurethane foam around each piece of aggregate. The formation of the soft foam seems to be caused by residual moisture from the aggregate. The moisture also caused the density of the polyurethane in the polyurethane-aggregate mixture to be less than the design requirements. The lower density of the polyurethane in the mixture, along with the formation of zones of pure polyurethane only, resulted in the overall seal density being less than the design requirements. During seal construction, steps were taken to control the moisture, but were not successful. An analysis of the seal failure showed that the calculated shear stresses at failure and the estimated shear strength of the polyurethane-aggregate mixture are fairly close. This suggests that the strength properties of the polyurethane-aggregate mixture along with a weak zone of poorly bonded aggregate controlled the maximum pressure the seal could withstand. At the time of the seal testing, the minimum design requirement was 20 psi, as specified at 30 CFR 75.335 (2005). New emergency temporary standards for seal designs were promulgated on May 22, 2007, with a minimum requirement of 50 psi under specified conditions. However, it will be shown that the evaluation of the polyurethane seal performance as designed to meet the older 20-psi criterion can be relevant to the design requirements under the new standards.

Jan 1, 2008

By Eric S. Weiss

The National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted joint research to evaluate explosion blast effects on typical U.S. mine ventilation stoppings in the NIOSH Pittsburgh Research Laboratory?s (PRL) Lake Lynn Experimental Mine (LLEM). An innovative Australian-designed brattice stop-ping was also evaluated. After mine explosion accidents, MSHA conducts investigations to determine the cause(s) as a means to prevent future occurrences. As part of these postexplosion investigations, the condition of underground stoppings, including the debris from damaged stoppings, is documented as evidence of the approximate strength and the direction of the explosion forces. The LLEM data showed that a typical dry-stacked and coated solid-concrete-block stopping survived a total explosion pressure of ~6.7 psi (~46 kPa) and was destroyed at a total explosion pressure of ~7.6 psi (~52 kPa). In comparison, a typical dry-stacked and coated hollow-core concrete block stopping survived a total explosion pressure of ~3.4?4.3 psi (~23?30 kPa) and was destroyed at a total explosion pressure of ~3.6?5.2 psi (~25?36 kPa), depending on the length of the pressure pulse and the value of the pressure-time integral. A typical steel panel stopping design survived a total explosion pressure of 0.8 psi (5.5 kPa) and failed at a total explosion pressure of 1.3 psi (9 kPa). The LLEM data also showed that an obstacle blocking the path of a pressure wave resulted in a higher reflected pressure at the obstacle. An 8-in (20-cm) thick wet-laid solid-concrete-block stopping coated on one side survived a total explosion pressure of ~26 psi (~180 kPa); this stopping was not tested to failure. A 6-in (15-cm) thick wet-laid solid-concrete-block stopping coated on one side survived a total explosion pressure of ~14 psi (~97 kPa) and was destroyed at a total explosion pressure of ~25 psi (~172 kPa). An innovative Australian woven cloth stopping survived an explosion pressure of 4.0 psi (27 kPa) and was destroyed at an explosion pressure of ~6.1 psi (~42 kPa). These results will help investigators determine the approximate explosion forces that destroy or damage stoppings during actual coal mine explosions.

Jan 1, 2008

By John A. Organiscak

Enclosed cabs are a primary means of reducing equipment operators? silica dust exposure at surface mines. The National Institute for Occupational Safety and Health experimentally investigated various factor effects on cab air filtration system performance. The factors investi­gated were intake filter efficiency, intake air leakage, intake filter loading (filter flow resistance), recirculation filter use, and wind effects on cab particulate penetration. Adding an intake pressurizer fan to the filtration system was also investigated. Results indicate that intake filter efficiency and recirculation filter use were the two most influential factors on cab penetration performance. Use of the recirculation filter reduced cab penetration by usually an order of magnitude over the intake air filter alone because of the multi­plicative filtration of the cab interior air. Intake air leakage and filter loading affected the cab penetration to a lesser extent, while wind had the least impact on cab penetration between the calm and 10-mph wind velocities tested. Adding an intake pressurizer fan notably increased intake airflow and cab pressure with only minor changes to cab penetration. A mathematical model was developed that describes cab penetration in terms of intake filter efficiency, intake air quantity, intake air leakage, recirculation filter efficiency, recirculation filter quantity, and wind penetration.

Jan 1, 2008