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By P. Dinham, G. C. Summerton, N. McCulloch, S. Dowling, D. C. Craig

"Development of a process for the treatment of a nickel copper matte rich in the minerals heazlewoodite, chalcocite and bornite has demonstrated significant base metal recoveries and metal separation efficiencies. The determination of chemical and mineralogical changes occurring in the individual leaching stages in laboratory experiments has enabled a better understanding of the complex leaching chemistry. The chemistry and mineralogy of the piloting and laboratory processes are discussed.INTRODUCTIONThe nickel-copper sulfide ores of the South African Bushveld Complex are among the most important Platinum Group Metal (PGM) bearing ores, and contain the world’s largest reserves of platinum. The treatment used in the recovery of PGMs from these ores includes three types of processes, namely ore concentration using physical techniques such as flotation and gravity separation, concentration by pyrometallurgical means, hydrometallurgical extraction of the base metals followed by the PGMs. Following milling of the ore, flotation involves the separation of high value minerals from gangue by taking advantage of the differences in their hydrophobicity. These differences are generally maximized through the use of a surfactant or wetting agent. Concentrates are then thermally treated and melted which brings about physical and chemical changes that enable the recovery of base metals and PGMs. The main aim of the smelting and converting process is to separate and eliminate the valuable metals from the bulk of the unwanted gangue and essentially all of the iron and to concentrate the metal VALUES (into a high grade converter matte. The matte can be further enriched by magnetic separation, producing a PGM-rich magnetic fraction and a base metal-rich non-magnetic fraction. The magnetic fraction is treated by hydrometallurgical processes to produce a PGM concentrate which is further refined to separate and purify the individual metals. The non-magnetic fraction is treated to produce marketable metal VALUES (such as nickel, copper, cobalt and to a lesser extent PGMs. The principal objective of any hydrometallurgical extractive process is to leach the desired elements selectively into an aqueous phase so as to separate them from the bulk of the material. (Crundwell, Moats, Ramachandran, Robinson and Davenport, 2011; Hundermark, Mncwango, de Villiers and Nelson, 2011)."

Jan 1, 2012

By G. Van Weert, O. Wang

"As part of a general review of processing double refractory ores through Barrick Gold’s autoclaves / CIL facility at Goldstrike, blanking the preg robbing native carbon in the process solids with hard (m.p. 55 - 60 º C) paraffin wax was studied, specifically in relation to pressure oxidation. The improvement in CIL gold extraction was found to depend on the wax addition point, with hot, dry contacting of the ore in the presence of wax - prior to POX - yielding the largest, most consistent improvement in gold extraction.INTRODUCTIONDouble refractory gold ores present two barriers to gold extraction. The first is generally a physical barrier: the gold is encapsulated or dispersed in a matrix which is impervious to the gold lixiviant. In most cases, including Carlin Trend, NV, deposits, this involves a pyrite or arsenopyrite matrix, although minor gold may also be dispersed in competent silica (quartz) or iron oxides. Gold can be rendered accessible by oxidative destruction of such sulphide matrices. At Goldstrike this is practised by roasting and autoclave oxidation (Thomas, 1994). It is the latter route to which this paper refers.The second barrier refers to the actual gold recovery. Gold may be extracted from the pressure oxidized solids with cyanide, forming a gold cyanide complex. One characteristic of this complex is that it adsorbs on graphitic surfaces. This is taken advantage of on a large scale by gold millers, who use manmade activated, i.e., graphitized carbon particles to remove the gold from solution during leaching: the Carbon-In-Leach, or CIL process. The gold cyanide bearing carbon particles are larger than the ore solids and can be separately recovered by screening. Goldstrike uses the CIL technology to recover gold. The second barrier becomes problematic when the ore naturally contains graphitic orcarbonaceous material, hereafter referred to as native carbon (versus the man-made activated carbon). This material may also adsorb gold cyanide in competition with the activated carbon. Since the native carbon is ground with the ore it is much smaller than the activated carbon. Any competition between the two carbons may produce a loss of gold from the pregnant leach liquor to the process tailings. This phenomenon is called “preg robbing”. Goldstrike ores come from the Carlin trend, which is known for the occurrence of native carbon (Adams & Burger, 1998; Schmitz, Duyvesteyn, Johnson, Enloe & McMullen, 2001; Tretbar, 2004)."

Jan 1, 2012

By Viviane Tavares de Moraes, Denise Crocce Romano Espinosa, Jorge Alberto Soares Tenorio, Adriana Johanny Murcia Santanilla

"Increasing volumes of solid waste are generated worldwide, due to the continuous technological advances, the electronic scrap is part of these waste, requiring the study of recycling processes to stimulate this activity or the reuse of its components. The separation of nickel from sulphate leach solution, which also containing iron, zinc and aluminium was carried out using bis-(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272) as extractant, in order to determinate the effects of pH and temperature. The number of stages required for extraction was also assessed. The results showed that the metal extraction increased with increasing pH. On the other hand, increasing temperature was not favorable for all metals. However, under conditions used in this paper the purification of solution containing nickel was possible.IntroductionIncrease in the demand of metals in the world for use in industry causes a great exploration of natural resources. One outcome of this is increased investigations for the recovery of metals from industrial wastes. Nickel is found in wastes, such as batteries and electric and electronic devices, this kind of waste becomes a significant source for metals recovery. Since nickel is also present in printed circuit boards, which are associated with electric and electronic equipment, it can be recovered from this kind of waste through different techniques. It is important to highlight that iron is generally associated with this scrap [1] and for its removal chemical precipitation is often used. On the other hand, the solvent extraction process is widely used for treatment of leach liquors, because it can be produce high purity solutions [2, 3]. This technique is based on the purification of solution using contact between a liquor leaching and the immiscible organic solution, which contains an extractant that promotes the desired metal transfer [4]."

Jan 1, 2012

By Haile Manteqi

In longwall coal mines, estimation of roof strata condition, sequence of loading, and supporting requirements are of a high degree of importance, and they are directly related to production and safety. Also, a prediction of the initial caving distance is rather complicated to calculate, because there are many parameters that effect caving process?roof and floor strata conditions, thickness of immediate roof, depth of cover, excavation geometry, and magnitude, and direction of principal stresses. This paper presents the results of 3D numerical modeling of the initial caving mechanism using the finite difference code FLAC3D at the E1 longwall panel of the Parvade 1 underground mine located in the Tabas area in the central part of Iran. The initial caving distance obtained was 10.4 m. Also, the results of numerical modeling have been compared to the analytical methods, such as Peng?s method. The results show good agreement with each other.

Jan 1, 2012

By A. Villanueva

The effect of High Pressure Grinding Rolls (HPGR), as a preceding stage to a conventional ball mill circuit at PT Freeport Indonesia?s C1/C2 concentrators, has been studied in terms of downstream grinding efficiency and circuit performance. When milling the product from the HPGR, mill capacity increased by 21% for the same product grind size, when compared to processing similar ore from a conventional crushing circuit. This achievement is a result of several reasons, among them: reduction in feed size (F80), fines generation beyond the proportional reduction in F80, reduction in ore hardness induced by HPGR comminution mechanism, optimization of the recycle system of the HPGR and ball string optimization in the ball mill circuit given the new feed to the mill.

Jan 1, 2012

By Carla L. Zenti

In recent years, considerable advances have taken place worldwide in the design and construction of first tunnel linings. With these advances, there is a tendency to move away from traditional support that includes heavy open profiles of rolled steel arches, to a lighter solution with the use of an optimized tubular steel cross section rib, and shotcrete reinforced with steel mesh and/or steel fibers, providing a continuous support (Lunardi, 1982). The development of tubular ribs has provided greater design options, increasing flexibility to engineers and contractors while providing a efficient and cost effective construction method. In this article, the authors describe numerical and experimental investigation on this problem, suggesting as a new first lining steel arch design approach by using tubular ribs cross section as new technical solution for first lining underground support.

Jan 1, 2012

By John Sakala, Jeyapandian Sasikumar, Sydney Kwalela

The Isasmelt Furnace was commissioned in September 2006 with a concentrates treatment capacity of 850,000 tonnes per annum. However, the converter section became a bottleneck to the high throughput. Over 25% of the Isasmelt Furnace down time was attributed to lack of converter space. Factors that affected converter operations were low tuyere line campaign life (an average of 150 blows), high reverts generation, low conversion rates, and high converter cycle time. As a result of efforts carried out to improve converter operation, the average campaign life has increased to over 250 blows and reverts generation has been reduced from 22% of concentrate treated to 15%. Blister copper conversion rate has increased from 15 tonnes per hour to 19 tonnes per hour and blowing time per cycle has been reduced from 5.7 hours to 4.7 hours.

Jan 1, 2012

By C. Liley

Open cut blasting at the Ernest Henry mine has the potential to cause damage to nearby underground workings. This paper is a case study of the blast vibration management project which was conducted to ensure pit blasting did not adversely affect the stability of upper production levels or cause damage to the underground primary fan units.

Jan 1, 2012

By S. Perkins, E. Young, L. Dufour, K. McVey, L. Rolandi

This paper presents a review of plant layout considerations incorporated into recent designs of SAG/Ball mill circuits for two medium sized concentrators. The plant layouts presented and the design concepts discussed, relate to smaller SAG circuits, but can equally apply to larger milling circuits. Included are design concepts and ideas introduced by the various project teams, and the focus is on the primary factors of any layout design which are safety, constructability, operability, and capital cost.

Jan 1, 2012

By Katragadda Sarveswara Rao

"In view of the increasing importance of processing lean ores as potential future resources, efforts are being made worldwide to develop suitable technologies for the recovery of both nonferrous, base and precious metals. There are various types of low grade ores present in many countries. Gradually, the mineral reserves for production of metals have undergone complex changes with regards to their grades and particularly the physical and chemical properties of the minerals to be separated from each other. So, there is a need for new processing routes or the upgrading of existing technologies to recover metal values that are otherwise unutilized. Accordingly, an overview of the different types of mineral resources and economical processes, based on ore horizons, consumption of energy and reagents and environmental concerns, is made in this paper. In addition, the paper provides a summary of metallurgical and engineering challenges to be overcome when implementing new technologies and concepts with regard to base metal extraction and sulphur removal efficiency.IntroductionLow grade multimetal complex sulfide ores are likely to become an importance source for nonferrous as well as precious metals in the near future. The principle metallic minerals are chalcopyrite, sphalerite, galena, pyrite, pyrrhotite, arsenopyrite, tetrahedrite, boulangerite and cassiterite. Such ores are located throughout the world as multi-pocketed reserves which have present complex challenges with regard to their grades and particularly the physical and chemical properties of the minerals to be separated from each other. Their compositions can vary widely from one deposit to another and even from one location to another in the same deposit, and this poses a problem for the recovering metals present therein. Successful aqueous processing of complex sulphide ores depends on the composition and mineralogy of the raw materials and on their leaching behaviour."

Jan 1, 2012

By Ehsan Vahidi, Fereshteh Rashchi, Ataollah Babakhani, Alireza Zakeri

"The synergistic effect of Cyanex 302 on solvent extraction of nickel and cadmium from sulfate solution with D2EHPA diluted in kerosene was investigated with the aim of increasing separation efficiency. Experiments were carried out within a pH range of 0.1-5.0 using sole D2EHPA and D2EHPA-Cyanex 302 mixtures in different ratios. Increasing Cyanex 302 to D2EHPA ratios in the organic phase caused a left shifting of the extraction isotherm of cadmium and a right shifting of the extraction isotherm of nickel. As a result, optimum separation was found with a Cyanex 302 to D2EHPA ratio of 0.1M:0.5M. In the present system, effect of a modifying reagent such as TBP was studied. The influence of various diluents including kerosene and carbon tetrachloride was also investigated.IntroductionBatteries are popular sources of portable energy. Ni-Cd batteries are manufactured in two main groups of small domestic cells and large industrial batteries with 80% being in domestic use. Ni-Cd cells have various uses, for example in cordless electric utensils, cordless telephones, airplane engine starters, and communicational distribution systems [1].Depleted Ni-Cd batteries are classified as hazardous waste since nickel and cadmium are heavy metals and suspected carcinogens. Given the risk associated with uncontrolled disposal, directions for issuing legislation on disposal and recycling of used batteries have been made in industrialized countries [2]. Recycling of Ni-Cd batteries is important from both economic and environmental points of view. Different methods have been used for recycling these wastes through pyrometallurgy [3], biotechnology [4,5], and hydrometallurgy [1,2].Due to the advantages of hydrometallurgical processes, several studies have been implemented on leaching and solvent extraction (SX) of the used Ni-Cd batteries. Leaching of batteries is usually done in sulfate or chloride media; while solvent extraction has been used in different extractants: two-stage solvent extraction by D2EHPA and Cyanex 272 [6]. Solvent extraction of Cd from leach solutions has been studied using various extractants; Cyanex 301 [1], D2EHPA [7], Cyanex 302 [8], Cyanex 923 [9], Cyanex 272, Tops 99, PC88A [10]. Application of phosphorus based extractants for the solvent extraction studies of Ni such as TOPS 99 [11], D2EHPA [12], Cyanex 272 [2], has been investigated. Separation of Cd(ll), Ni(II), and Co(ll) from chloride leach liquor of spent batteries [13], were explored in the earlier studies. Cd extraction with D2EHPA involves co-extraction of both Ni and Co [14], which causes issues in the separation process efficiency."

Jan 1, 2012

By H. Fayed

Two-phase (water and air) flow in a self aerated WEMCO flotation machine has been investigated using computational fluid dynamics (CFD). A 0.8 m3 model is considered. The flow is modeled by Euler-Euler approach, and transport equations are solved using a commercial software ANSYS-CFX5 [1]. Because of the lack of circumferential periodicity in this machine, the entire machine is modeled and unsteady simulations are conducted in the whole volume of the bulb. Uniform bubble diameter is specified, and the effects of bubble diameter are determined by conducting simulations for three diameters of 0.5, 0.7, and 1.0 mm. The unsteady air flow rate through the machine is predicted as an outcome of the simulations. Air volume fraction contours and velocity field in different parts of the machine are presented and discussed.

Jan 1, 2012

By Alan A. Campoli

The mining industry has long been searching for an effective structural application that prevents weathering and falls of loose rock, debris, and sediment. J-Crete is a fiber-reinforced, engineered, cementitious composite rock application that is designed, tested, and successfully utilized as such a material. Laboratory evaluation of J-Crete material properties has shown the final compressive strength to be in excess of 7,300 psi (50.34 MPa), with 24 hour strength in excess of 1,500 psi (10.34 MPa). The flexural tensile strength is in excess of 600 psi (4.1 MPa) and is provided through a unique combination of polyvinyl alcohol (PVA) fibers activated by a proprietary liquid additive that prevents them from clumping and enables even distribution throughout the grout. Tensile bond strength in excess of 350 psi (2.4 MPa) at 28 day cure tightens the strata and holds loose material in place. Practically impervious to gas and liquids, J-Crete protects strata against long-term weathering, does not require screening to be effective, and has proven to be a successful waterproofing material. J-Crete has demonstrated the potential to alleviate coal mine roof cutters in soft, wet clay formations. J-Crete reinforces coal mine ribs by bonding directly to the rib, conforms to the strata, strengthens the rib, and eliminates sloughing due to long-term weathering; stabilizes coal mine entries by bonding directly to the brow and roof, and creates a monolithic shell with double reinforced corners.

Jan 1, 2012

By Daniel Kim, Ari Rantala

Efficient on-line monitoring of electrolytic cell performance in copper electro-refining has been challenging due to the need for complex electrical measurement systems and the management of the enormous volume of data. Based on Kennecott Utah Copper's innovation Outotec has developed a novel and innovative electrolytic cell monitoring system called CellSense™ System. As the system is based on self-powering from bus bars, wireless communication, on-line adaptive modeling and easy to access information and alarming, traditional obstacles of electrolytic cell monitoring are eliminated. With cell voltage and electrolyte temperature measurements, CellSense System enables real-time cell performance discovery and early reaction to critical production or quality disturbances such as short-circuiting, flow blockages, cold cathodes or electrolyte temperature excursions. During the past few years the system has been delivered to over 3500 commercial cells. In this paper the largest CellSense™ System ever delivered and recently adapted by Kennecott Utah Copper with 1412 cells monitored on-line for high tankhouse performance, cathode quality and optimized operator work flow is presented. Early results and benefits are discussed.

Jan 1, 2012

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Jan 1, 2012

By Timothy D. Stark

Jet grouting has increasingly become a ground improvement technology used to address seepage concerns and provide strength improvement to soils underlying dams. The technique of jet grouting uses high pressure/volume jet fluids to erode existing soil, evacuate some or most of the soil, and mix the remaining cuttings with cement slurry to form soilcrete. While considered a useful technology, this paper discusses some of the problems that can develop while jet grouting in or below a dam with an operational reservoir and seepage condition. Jet grouting experience at Tuttle Creek Dam indicates concerns with respect to ground fracture; spoil return, column diameter consistency, and homogeneity of resulting soilcrete. Recommendations are presented to increase monitoring of downhole parameters during jet grouting to better understand the downhole pressures and soil response during jet grouting.

Jan 1, 2012

By O. Chemezov, Yu Zaikov, A. Apisarov, A. Isakov

"Silicon deposits containing 99,9 wt.% of main component were obtained by SiO2 electrolysis from chloride-fluoride melts. The operating temperature was varied from 973 up to 1073 K. The conditions for obtaining crystalline fibrous micro- or nanodeposits were determined. The deposits were investigated by ESM methodIntroductionThere are large reserves of natural quartz of high purity in Russia. Processing of this raw material by electrolysis in molten salts produces silicon containing 99.9 weight percent of basic substance.[1]This method is less energy-consuming in comparison to existing methods for producing high purity silicon from gas phase.Another advantage of the electrolytic method for producing silicon from its oxide in molten salts is the possibility of production of high-purity silicon under air atmosphere. It dramatically reduces costs of the electrolytic cell construction, and the operating costs at electrolysis.On our opinion, the main advantage of the electrolytic production from SiO2 in molten salts is a unique opportunity to obtain micro-and nanostructures of silicon deposits. In particular, it is possible to obtain fibrous structures of silicon. The electrolytic method allows smoothly adjusting the thickness and length of silicon micro- and nano-wires by varying the cathode current density and temperature of the process."

Jan 1, 2012

By Egbert Burchardt

The challenge of "ore bodies getting steadily harder and lower in grade" was brought to light during the first oil crisis in the 70's. Shortly afterwards, HPGRs appeared on the scene with the promise of saving energy. This combined with developments in wear protection for the rolls ushered in a period of trade-off studies that considered the HPGR as an option to improve project economics or to even make projects feasible at all. Since then, applications of HPGRs at Cerro Verde (Freeport), PTFI Grasberg (Freeport), Mogalakwena (Anglo Platinum), Tarkwa (Goldfields), Boddington (Newmont), Penasquito (Goldcorp), and others have contributed to the creation of a formidable basket of operating experience. Collected through years of successful operation, this information has been used to validate design criteria, scale-up factors and establishing a clearer picture of what "to do" and what "not to do". This paper compares results from various mining operations using HPGRs in their processing plants. Some of the lessons learnt in different operating environments are reviewed in order to support proper implementation and operation of HPGR's. Some of the development programs that have been initiated to improve wear life of the tyres and to reduce overall operating costs are reviewed. It is timely to summarize today?s experience and analyse its implications for existing and new operations.

Jan 1, 2012

By Renxing Li, Yongyong Gong, Yufeng Cheng, Zhenxing Yin, Xin Cao, Qijie Zhai

"The influence of electric current pulse (ECP) on the solidification structure of SUS430 ferritic stainless steel (FSS) was investigated in the current study. The technology of ECP has been widely used to improve the properties of metals with relatively low cost. The parallel electrodes were inserted into the free melt surface to constitute a current loop. The different influences of three parameters on solidification structure were studied by changing the peak current value, frequency and treating time respectively. The results indicated that the ECP significantly increased the number of equiaxed grains of SUS430 FSS. The as-cast structure without ECP treating was almost wholly columnar, while the number of equiaxed grains of the specimen, which was treated 3min with a peak current of 400kIA, increased to 2698 in the observed surface. To get the best refinement, an optimum range of these three parameters is required and the peak current value plays the most important role.IntroductionFor the lack of nickel resource and the pressure of environment protection, ferritic stainless steel is increasingly adopted to replace the austenite stainless steel because of its low nickel content and good mechanical properties. SUS430 steel is a typical example with excellent performance and relatively low price to replace the application of austenitic stainless steel[1-3]. This type of steel with high thermal conductivity coefficient, low expansion coefficient, good oxidation resistance, excellent stress corrosion resistance and other fantastic characteristics is often used to make components which need to have resistances for atmosphere, water, steam and oxidizing acid corrosion[4]. Since the developing of columnar grains and low toughness at high temperature, its products are easily crinkled and cracked during the subsequent rolling process[5]. The application of ferritic stainless steel is limited by these defects[6-8]."

Jan 1, 2012

By P. Amelunxen

It is well-known that the particle breakage mode that occurs in a semi-autogenous mill is significantly different from that which occurs in a ball mill, enough so to warrant very different lab scale breakage tests and scale-up models. This phenomenon, at the plant scale, leads to changing process constraints depending on the particular properties of the ore. For example, hard or coarse ores might bottleneck the SAG/AG mill throughput, while the ball mills might constrain throughput when milling soft or fine ores. Because the power draw of a ball mill is fairly constant compared to that of a SAG/AG mill, periods of SAG/AG mill bottlenecks lead to increased ball mill circuit specific energy consumption and a finer grinding circuit product size, which together constitute a loss of efficiency of the overall process. Because HPGR circuit throughput is less sensitive to changes in ore hardness, this situation is less common or severe in those circuits. Furthermore, the ball mills are somewhat decoupled from the upstream crushing circuits through the use of surge bins, which also helps to mitigate this effect. As a result, ore hardness variability constitutes a significant cost penalty that should be applied to SAG mill/ball mill/pebble crusher SABC circuits when evaluating the relative economics of different grinding circuit configurations. Nevertheless, the issue is by-and-large ignored, because most current HPGR trade-off studies are based on averaged ore hardness parameters. This paper provides an estimate of the magnitude of this penalty for a typical operation by using Monte Carlo simulation methods and plant data from Freeport-McMoRan?s autogenous, semi-autogenous, and HPGR-based comminution circuits. A case study from an in-house 96K t/d sulphide project is presented to illustrate the concept. It was found that by including variability effects, the trade-off NPV of the HPGR circuit over that of the SAG mill circuit increases to $84 million from negative $33 million, effectively reversing the original decision of selecting a SAG mill circuit for the fixed hardness case.

Jan 1, 2012