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By Heng Yi

The salt lake brines that lithium is extracted from have high chloride levels making the brine very corrosive to stainless steel extraction column internals. This is a significant problem in column scale-up to industrial production. Two types of corrosion-resistant ceramic internals, the hybrid ceramic internal and ceramic plate, were designed and tested under pilot conditions for future industrial application in this field. The hydrodynamic results (Yi et al. Ind Eng Chem Res 56 (4):999–1007 (2016), [1]) show that holdup of hybrid ceramic internal is higher than that of ceramic plate by around 50%, while Sauter mean diameter when using the hybrid ceramic internal is smaller than when using the ceramic plate by around 30%. This results in a larger mass transfer area, hence better mass transfer efficiency for the hybrid ceramic internal. Axial dispersion and mass transfer parameters are also examined (Yi et al. Ind Eng Chem Res 56(11):2049–3058 (2017), [2]). The results show that the column with hybrid ceramic internals has 50% lower axial dispersion coefficient and 50% higher mass transfer coefficient, leading to higher mass transfer efficiency. The transfer unit height of the column using hybrid ceramic internals can be as low as 0.2 m, showing very good efficiency. This is promising for near-future applications. Two-phase computational fluid dynamics (CFD) models have been developed for the two columns with ANSYS FLUENT commercial software. CFD successfully predicts the higher holdup and lower axial dispersion coefficients for the hybrid sieve plate pulsed column as measured in the experiments, and the cause for the difference in performance has been explained with information from CFD.

By Aiyuan Ma, Kun Yang, Weiheng Chen, Jinhui Peng, Shiwei Li, Feng Xie, Libo Zhang

In this thesis, a new process of recovering zinc sulfide ores was developed. The novel synthetic coordination leaching process mainly included two steps: microwave assisted phase reconstruction and compound coordination leaching. By applying various techniques, such as chemical composition analysis, X-ray diffractometry (XRD) and Raman spectroscopy, it could be concluded that sulfide phases would directly oxidized to zinc oxides under the 500 ºC microwave roasting and adding 30% Na2O2. What’s more, zinc leaching rate reached to 61.16% within 2 hours. Compared to the current technologies, this procedure had the advantage of avoiding SO2 emission, high leaching efficiency, simple process, manipulate easily, and low cost, which could be expected tremendous application potentials.

Jan 1, 2016

By Lv Guozhi, Niu Liping, Shi Guanyong, Liu Yan, He Jicheng, Du Yanjun, Dou Zhihe

"We proposed thermit reduction-electroslag remelting method of preparing the large scale CuCr alloy. But there are pores and oxide inclusions in CuCr alloy prepared by thermit reduction process. This paper studied mainly the effects of ratio of reactant and additive on the inclusion type and their occurrences in CuCr alloy. The alloy prepared in different process conditions was characterized via XRD, SEM, OM and TEM and metallographic microscope, in which the existing state and micro-structural defects of inclusions are analyzed. The results show that there are three distinct regions: copper-rich regions, chromium-rich regions and the inclusion regions. Inclusions are mainly in the form of stomata and Alz03 phase, mainly locating in the copper-rich phase and the interface area of chromium-rich phase and the copper-rich phase. Adding Na3AlF6 and heating agent can effectively reduce the inclusion content in the alloy.1 IntroductionIn recent years, with the development ofhigh power vacuum and high-pressure technology ,the CuCr alloy contact material which has many advantages gradually replaced the traditional W-Cu and Cu-Bi series alloy contact material, and become the first choice of material in high-voltage and high-power vacuum switch contacts['-3l. The traditional powder metallurgy method, infiltration method and vacuum arc melting method[4-SJ are using metal Cu powder and Cr powder as raw material by casting molding, and have disadvantages such as high production costs, complicated process, poor product density and low yield, especially in the large size alloy ingots[9-12l. At present, the world regards CuCr alloy new preparation technologies as the first place, and how to achieve a large size the CuCr alloy ingot preparation has become a hot research of CuCr alloy[3l. Zhang Ting-an and Dou Zhihe[l-3l who are supported by national natural science fundation of china successfully successful developed new technologies and core equipment to prepare large-size copper-chromium alloy through aluminum thermal reduction-secondary refining method, and obtained two national invention patents. The method includes two key steps: one is get CuCr alloy consumable ingot by Thermit-SHS with electromagnetic stirring, the other is to refme the CuCr alloy ingot to remove the pores, inclusions and other defects by electroslag remelting technology to get dense and uniform CuCr contact material. The preliminary study results show that means of electromagnetic stirring evidently inhibit effect of alloy ingot macrosegregation during the electromagnetic casting stage, but there are still microstructure defects such as alumina inclusions and pores in the alloy ingots. Therefore, Zhang Ting-an et al refer new ideas of using the electroslag remelting to refine Cu Cr alloy ingots and effectively remove the defects of the ingots such as pores and inclusions [3l _ At present, there is no report of study on the electroslag remelting refining processes of CuCr alloy (the refining slag, remelting current). This article will research mode of occurrence and distribution law of inclusions in the large-size CuCr alloy ingots by Al Thermit-SHS under magnetic field stirring action and provide a theoretical basis for chosing refining slag to remove inclusions by electroslag refining. Meanwhile the article analyses the effect of reduction conditions of Thermit-SHS on the types of inclusions, mode of occurrence and distribution of regular inclusions in alloy ingot, and refer theory for inclusions regulation in the large-size alloy ingots."

Jan 1, 2013

By Mariana Barcelos, Frederico Muylaert Margem, Giulio Rodrigues Altoé, Pedro Amoy Netto, André Gomes, Sergio Neves Monteiro

Environmentally correct composites, made from natural fibers, are among the most investigated and applied today. In this paper, we investigate the mechanical behavior of polyester matrix composites reinforced with continuous fique fibers, through bending tensile tests. Specimens containing 0, 10, 20 and 30% in volume of fique fiber were aligned along the entire length of a mold to create plates of these composites, those plates were cut following the ASTM standard to obtained bending tests specimens. The test was conducted in a Instron Machine and the fractured specimens were analyzed by SEM, the results showed the increase in the materials tensile properties with the increase of fiber amount.

Jan 1, 2015

By Subagyo

The condition of slag in a pyrometallurgical reactor is vital to ensuring control of the process. A new technique based on multivariate image analysis (MIA) of digital images has been developed to provide an online measurement of important slag characteristics, such as the presence of exposed metal, the presence of solid phases, and temperature. This paper shall describe the technique and provide some results from analysis using industrial plant data.

Jan 1, 2003

By Sergio N. Monteiro

Fibers extracted from the ramie plant have been traditionally used in textile and are now being considered as polymeric composite reinforcement owing to their superior strength. Recently the mechanical behavior of ramie fiber reinforced polyester composites was investigated but no significant improvement was found. Therefore, the objective of this work was to carry out a similar investigation by changing the type of polymeric matrix. Specimens with up to 30% in volume of ramie fibers incorporated into epoxy were bend-tested until fracture. The results showed a moderate improvement with a tendency of decreasing stress for higher amounts of ramie fibers due to the weak interface developed with the epoxy matrix.

Jan 1, 2009

By Julie M. Melluish

The metallurgical response of the Point Leamington deposit has been studied. Two series of bench tests were conducted and various ore samples and flotation products were examined using image analysis techniques. The majority of sphalerite and chalcopyrite grains in this texturally complex ore were found to be smaller than 10 micrometres. Copper recoveries were low with losses mainly as fine inclusions in pyrite. Sphalerite recoveries were somewhat better due to a generally coarser habit. Gold and silver recoveries were also low and only solid solution silver was identified in the ore. The deposit shows poor economic prospects unless additional tonnage of high grade zinc ore can be delineated.

Jan 1, 1989

By H. Bernier

The Noranda Inc., CCR Division, copper refinery located in Montreal-East, Québec, Canada, has expanded over the years to reach a capacity of 410,000 metric tons of cathode production per year. The expansion process resulted in nine, parallel, 200 m. long bays each equipped with its overhead cranes and manually operated washing machines. Anode scrap washing and piling was done manually. The mechanization of the tank house involved the elimination of 18 cells at one end of each of the bays in order to install transfer conveyors where anode scrap and cathode loads are deposited by the bay cranes. The cathode loads are brought by new transverse cranes to new machines where cathodes are washed, piled in predetermined bundle weights, check weighed, strapped then shipped in trucks or railroad cars. Suspension bars are automatically removed, stacked in magazines and sent back to the starting sheet machines. Anode scrap loads are brought to machines located near the anode furnaces where they are washed and piled in bundles for easy charging. The mechanization has eliminated numerous hazardous jobs and has realized a reduction of 0.2 man-hours/ton. After these modifications, the refinery production capacity now stands at 370,000 metric tons per year.

Jan 1, 1987

By D. M. Fermino, C. G. Bastos Andrade, V. F. Justo, F. R. Valenzuela-Diaz, M. G. S. Valenzuela, C. Volzone

The present paper presents the study of light green smectite clay, from Paraiba, Brazil, submitted to mild acid attack under moderated conditions. Usually, clays are subjected to treatment with strong inorganic acids at temperatures near the boiling point and at high acid concentrations and then, widely used as bleaching agents. The treatment occurred under bellow boiling temperature and at short times of reaction (90°C, reaction times of 1, 6, 12, 18 and 24 hours in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5 M, clay/acid solution ratio of 1g/10mL). The purpose of these attacks is to reduce the concentration of impurities providing color, with minimal change in the clay minerals structure, aiming at use in products of high value such as cosmetics and polymer/clay nanocomposites. The raw clay and the attacked samples were characterized by X-ray diffraction (XRD), cation exchange capacity (CEC), stereomicroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray detector (EDS).

Jan 1, 2015

By M. R. Jolly, J. -C. Gebelin

"A number of different types of so-called ""filters"" are used in the metal casting industries to impart some cleaning effect and flow control on the liquid metal as it passes through them. The filters range from simple planar meshes through extruded channels to reticulated foam structures and they are manufactured from a range of material going from metals to glass or ceramics. It is most common that software packages used in the industry model the filters by a simple pressure drop associated with some area fraction and permeability parameters.Recent experimental work at the IRC in Birmingham [1] has shown that filters of the same type can behave very differently depending upon the casting process in which they are employed. Modelling filter geometries for a range of different casting processes has indicated that the flow of metal and heat losses through the filters are rather complex and should be considered when using filters in the casting processes. This paper will present a number of cases of different types of filters modelled and different processes and indicate some of the sensitivities of the processes to boundary conditions imposed by the process.IntroductionFilters are commonly used in the foundry industry. The real action of the filters on the liquid metal is not really understood. Some filters are claimed to have a chemical action on the liquid metal or to be able to clean the metal by stopping the impurities or oxides that will result in inclusions in the cast part. However, some recent experiment carried out at the University of Birmingham in investment casting and results available on sand casting [2] have shown that the action of filters may be different in these two processes. As the main difference between these two processes is the mould temperature, the hypothesis of a partial solidification of the metal in the filter occurring in the sand casting process during the primary stage of the filling has been advanced, whereas there is little or no solidification in investment casting. In order to verify this hypothesis, and to reach a better understanding of how filters work, a numerical investigation of the flow and heat transfer in filters in both sand and investment casting has started at the University of Birmingham, in the framework of the FOCAST project. The FOCAST project is an EPSRC project aimed to increase the understanding of the investment casting process. Another issue is the way the simulation packages predict the influence of the filters on the metal flow. The filters are most of the time modelled as porous obstacles characterised by a pressure drop calculated from porosity and some surface ratios or proprietary coefficients. This paper will present the preliminary results of this numerical investigation. First, the different models that have been used are presented, followed by the obtained results. A discussion of these results and their perspectives conclude the paper."

Jan 1, 2001

By S. J. Ojolo, B. E. Ebiobi, J. A. Kehinde

"Anaerobic digestion is being taken seriously because of increasing concerns about the environmental hazards of wastes. The production of biogas, as an alternative source of energy was investigated in a designed and fabricated 200litre biogas reactor. The digester was operated on a batch-fed basis, and the feed stock was cassava waste which is readily available in Nigerian farms. The main aim was to explore other renewable sources as a means of less dependence on fossil fuels. A total of 1.94dm3/60kg waste of biogas was produced in 40 days of hydraulic retention time (HRT) with the average yield of 0.048dm3/day. The gas burned with a bluish colour indicating presence of methane (CH4). Temperature during the period of experiment varied between 27 and 330C. The pH of the slurry after the experiments averaged 3.21.1. INTRODUCTIONAnaerobic digestion and biogas production are promising means of achieving multiple environmental benefits and producing an energy carrier from renewable resources (Borjesson and Berglund, 2005).Biogas is one of the by-products of anaerobic decomposition of organic matter by microorganisms, mainly bacterial, a process referred to as anaerobic digestion.Biogas is produced by the process of anaerobic digestion of organic material by anaerobes. Biogas can be produced either from biodegradable waste materials or by the use of energy crops fed into anaerobic digester.Biogas, also called digester gas typically refers to methane produced by the fermentation of organic matter including manure, wastewater, sludge, municipal solid waste or any other biodegradable feedstock under anaerobic conditions. The content of biogas varies with the material being decomposed, and the environmental conditions involved. The gas generally composes of methane, carbon dioxide, nitrogen, hydrogen, and hydrogen sulphide (Anunputtikul and Rodtong, 2004). Potentially, all organic waste materials contain adequate quantities of the materials essential for the growth and metabolism of the anaerobic bacterial in biogas production."

Jan 1, 2008

By Hiroyuki Matsuura, Fumitaka Tsukihashi

"Emission of CO2 gas from steelmaking industry covers more than 12 % of total CO2 emission in Japan. Though many efforts have been made to curtail energy consumption and high energy efficiency of Japanese steel production process has been achieved so far, further reduction of CO2 emission is strongly requested to develop sustainable steel production process and produce “green material”. Recently, authors have proposed the innovative hydrogen production process, in which water vapor is reacted with discharged steelmaking slag to produce hydrogen gas. This reaction can be achieved without any external energy source and operated by huge thermal energy associated with steelmaking slag and FeO or unrecovered Fe droplets that are relatively rich in the slag. In this paper, thermodynamic calculation results with various initial conditions in terms of hydrogen productivity were presented. Laboratory-scale experiments were also conducted to clarify the validity of thermodynamic calculation and the reaction rate in realistic conditions.IntroductionIronmaking and steelmaking process from iron ore through blast furnace and BOF is an essential steel production route for Japanese steel industries to supply high quality steel products in large quantity to society stably. Blast furnace – BOF process requires huge amount of fossil fuels such as mainly coal, resulting the emission of considerable amount of CO2 gas. Since the emission of CO2 gas from steel industries, about 147 Mt (FY2011), accounts for approximately 12 % of domestic CO2 gas emission in Japan (FY2011),[1] it is an urgent issue for steel industries to develop environmental-friendly ironmaking and steelmaking process and reduce CO2 emission. Various kinds of gases and by-products generated from ironmaking and steelmaking processes have been recycled as much as possible at present. Enormous thermal energy is also generated from processes and released to surrounding atmosphere as various forms such as sensible heats of gases, molten steels or by-products, and as heat losses. However, these energies are not utilized before final dissipation to atmosphere. Although various technologies to utilize thermal energy from ironmaking and steelmaking processes have been attempted to develop, practical application of these technologies has not been achieved because the thermal energy is not always useful as an energy source. In steelmaking process by BOF, fluxing agent such as CaO is added during reefing and thus about 100 kg/t-steel of steelmaking slag are generated. Since the steelmaking slag is discharged at temperature range between 1873 and 1923 K after discharge of refined molten steel, it also has large thermal energy. Amount of generated BOF slag is 11.0 Mt/y (FY2012) in Japan.[2] Assuming the amount of steelmaking slag is 10 Mt/y and its average heat capacity from room temperature to 1923 K is 1 kJ/kg·K,[3] unutilized heat is estimated to be 16 PJ/y, which is equal to annual energy consumption of 420 thousand families in Japan.[4]"

Jan 1, 2014

By Sharon L. Eyer

"FTIR spectroscopy is employed to define mineable ore deposits based on exploration samples. The RAMBO (Robotic Assessment of Mineable Bauxite Ore) technology is operating successfully at an alumina refinery in K winana, Australia, for assessment of a number of critical ore attributes including available alumina, extractable organic carbon and total iron. Classical methods of analyses for these properties require laboratory-scale digestion of alumina ore (bauxite) or XRF analyses.Multivariate calibration is used in the RAMBO system to generate robust mathematical models that are able to estimate classical data from FTIR spectral data. Furthermore the models can highlight regions of ore that are relatively unusual. Unusual ore may be investigated for potential impacts on refinery processes well in advance of mining.The components of the technology are described and some results for an example application (bauxite) are presented. Challenges and difficulties are discussed. The potential to apply the technique to process control is introduced."

Jan 1, 1999

By M. Demuth, B. Holleis, M. Potesser, D. Spoljaric

"In 2005, Messer Group established a technology competence centre for metallurgy in Gumpoldskirchen (Austria), with the aim to develop oxygen burners which satisfy today's and upcoming standards of legislation as well as customer requirements. With the assistance of the Development Sponsorship Fund (FFF) of Austria, cooperation with the University of Leoben was agreed on. With the long term experience of the Gas-Warme-Institut ""GWI"" in Essen (Germany) and the University of Leoben, different new burners have been developed.The efficiency of industrial combustion processes can be increased in two ways (which can be seen in Figure 1 ), either by preheating the fuel and combustion air or by adding oxygen. Due to the high 79 % Nz ballast in air combustion, only low flame temperatures can be reached. This results in high heat loss in the exhaust gas, caused by the low combustion efficiency. Oxygen can be introduced into the combustion chamber using different techniques:• Oxygen fuel burners• Direct oxygen injection into the fuel air flame• Underlaying of the fuel air flame• Enrichment of the combustion airIn Figure 2, the theoretical flame temperature for the stoichiometrical combustion of natural gas is plotted as a function of oxygen enrichment. Therefore, it can be concluded that even low enrichment values produce higher flame temperatures and result in higher combustion efficiency."

Jan 1, 2012

By V. V. Khristenko, V. I. Dubodelov, V. A. Seredenko, B. A. Kyryyevsky, H. V. Seredenko

"During the last decades investigators of many countries shows an increased interest to alloys which are characterized by miscibility gap in a liquid state. It is connected with essential possibilities of control of structurization in such alloys because of the melt at certain temperature parameters is · emulsion with disperse phase inclusions. These ensure essential influence ·on structurizations.The certain inclusions can play a role of lubrication ensuring ""wearless"" process. The sizes of inclusions of this phase can be rather large proportional to sizes of strengthening phase (up to 1000 nm). Other inclusions ensure process of strengthening of a main material. In this case requests to a dispersibility character of distribution and structure of such inclusions are much higher.The multicomponent alloys of system of copper - (Fe - Cr - C)- alloy concern to the number of advanced compositions. The copper alloys with structure of a type of a ""frozen emulsion"" in which strengthening phase· is a chromium pig-iron are characterized by high thermal stability in the extreme operating conditions. The mechanism of inclusions forming is emulsifying of a melt in miscibility gap at temperatures close to temperature of binodal under superimposition of external effects.The main complexity of producing of ware from such alloys is .a providing in their structure of necessary dispersible inclusions uniformly distributed all over the volume. Thanks to a selective action of electromagnetic fields on liquid phases with various electroconductivity relative velocity of phases is created and is regulated the ratio of their ""apparent"" specific gravity is changed. Excitation of pulsing force effects with the certain frequency on interphase surface allow actively to influence on process of a dispersion of a liquid metal medium."

Jan 1, 2000

By Elli Miettinen, Markku Lahtinen, Ilkka Kojo

"The recent trends of decreasing energy consumption and environmental emissions and utilization of economies of scale are strong drivers favoring continuous copper converting processes. Flash Converting benefits from low off-gas volumes and low investment and operational costs for off-gas treatment. Separate matte and blister furnaces allow the adaptation to concentrate quality changes and flexibility in layout and maintenance.The stationary blister copper bath in Flash Converting furnace is less aggressive to the furnace linings than agitated processes, resulting in low refractory consumption, long campaign life and high on-line availability.Copper Flash Converting has been successfully applied in Kennecott with a campaign life now exceeding five years. A second FCF was started at Xiangguang Copper in China in 2007. The process itself is proven, as its features are similar to those in FSF, Direct-to-Blister and Direct Outotec Nickel Flash Smelting (DON), with one significant difference: it is the easiest of all to operate.The paper presents differences between continuous Flash Converting and conventional converting based on recent experiences and studies."

Jan 1, 2009

By David Rees

Tomago Aluminium, a 400,OO tonnes per annum primary aluminium smelter in Australia, has installed Ozone for biological control of its process water. The system was designed in Australia by Ionics Watertec Engineering, whilst ANCO Australia monitors the water quality and provides technical support for the project. The motivation was initially to reduce operating costs, however investigations indicated that there were substantial environmental benefits to be achieved by the elimination of a part, or all of, the chemicals being used to control the system. Also the existing chemicals appeared to be losing their ability to control biological growth in the system, in particular, the legionella bacteria. Ozone water treatment commenced in January 1998 and after a short transition period has operated without chemical addition since. There appears to be no doubt that the biological control is effective, the clarity and purity of the water has improved and initial testing indicates that the corrosion control rate is acceptable, although some chemical corrosion control may be introduced after further testing around the total circuit to guarantee protection

Jan 1, 1999

By Junwei Han, Wenqing Qin, Dawei Wang, Fen Jiao, Wei Liu

The removal of iron impurity from zinc calcine was studied by magnetization roasting and magnetic separation. The effects of roasting temperature, magnetic intensity, ore grinding, and leaching pretreatment on iron grade and recovery were investigated. The results indicated that iron recovery increased with the increase of roasting temperature or magnetic intensity, while iron grade was always less than 22%, depending on the fact that the magnetite were not liberated completely. The good liberation was difficult to be achieved by ore grinding but was easier by acid leaching, since the magnetite grains were very fine. After the leaching pretreatment, the recovery of 76.31% with iron grade of 53.24% was obtained by one roughing and cleaning. The SEM/EDS analysis showed that a part of sphalerite, zinc ferrite and other gangues were mixed into the iron concentrate, while some of fine magnetite was reported to the tailing.

Jan 1, 2016

By Ajit Kumar Jaiswal

"Electric Arc Furnace (EAF) being a power-intensive equipment, EAF based industries are highly dependent on scarce electric energy. This is the reason Government of India is highly concerned about this and laid emphasis on the conservation of electric energy.This paper highlights factors contributing to reduction in specific electric energy consumption in EAF and suggests measures not only for power saving, but also for productivity improvement. To name a few, these are proper sealing of furnace, introduction of oxy-fuel burners, foamy slag practice, increased usage of hot metal/DRI, post-combustion of CO gas for preheating of scrap, improved selection & design criteria of electrics, power demand management, and process automation. Few cases also have been cited, where the above measures have helped in reaping significant benefits.IntroductionFor a long time, Government of India had focused on increase in energy supply, in particular, through electricity generation. Now the emphasis of Government of India has shifted from electricity generation to its conservation for following two reasons:??Power plants have become very cost-intensive??By saving energy, more of it can be delivered at lower cost to the consumersPower generating units, transmission & distribution agencies as well as consumers all have roles to play in the area of energy conservation. By energy conservation, we mean curtailing energy requirement by reducing energy wastages and taking up measures to improve energy efficiency of electric equipment/appliances. In almost all cases, this would be economically beneficial.India’s cost-effective energy conservation potential has been estimated by the Planning Commission at 23 per cent of total commercial energy generated ?1?. A national movement for energy conservation can significantly reduce the need for fresh investment in energy supply systems in coming years. It is imperative that we make all-out effort to realize this potential. Whether a household or a factory, a small shop or a large commercial building, a farmer or an office worker, every user can and must make this effort for his own benefit and for the nation’s benefit as well."

Jan 1, 2009

By Yan Wen

For the impurities in the copper smelting waste acid, SO3, Cu, As, Pb, Zn, Re and other elements enter the waste acid and generate a lot of arsenic residue, gypsum and neutralized residue, in which Cu, Zn and Re metals have not been recycled. Cu, Re and As are separated by step-wise vulcanization. The valuable metals of Cu, Zn and Re are recovered by separating zinc through pH adjustment. Calcium injection is conducted for boiler for reducing the amount of SO3. The residues generated in the form of arsenate and hydroxide will be returned together with arsenic filter cake for smelting treatment so as to achieve the purpose of valuable metal recycling and solid waste reduction and harmless treatment.