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By W. C. Smith

Even with conservative mine planning, rib instability can progress from a nuisance to a major safety hazard. This Bureau of Mines paper examines the mechanisms of progressive rib failure in high mine openings and discusses techniques to control rib slabbing. A field test site in a longwall mine was instrumented to investigate rib behavior during mining. While data analysis showed minor pillar dilation. sporadic zones of progressive rib instability were detected that culminated in eventual rib failure. The failure occurred despite conservative pillar dimensions and shallow depth. Models were used to demonstrate the mechanisms of rib failure and then evaluate the influence of support and other mine-related parameters on rib behavior.

Jan 1, 1991

By LUIS ALBERTO TORRES-CRUZ

The Plewes method is relatively well known among geotechnical engineers interested in assessing the liquefaction potential of soil deposits. Furthermore, it was one of the four methods considered in the post-failure investigation report of the Feijao Dam I, also known as the Brumadinho Dam, in Brazil. The inclusion of the method in that report is likely to increase its visibility among geotechnical practitioners tasked with assessing the liquefaction potential of tailings. While the authors of the method duly presented it as a screening method, more recent technical literature contains conflicting views on its reliability. Considering the popularity of the method and that the safety record of tailings dams is a cause of great concern, this study assessed the uncertainty of results from the Plewes method. The study concludes that, even under optimistic assumptions, the results of the method are too uncertain for detailed characterization of tailings deposits.

By Bobby J. Timmons

Luck; blind, beginner's, fisherman's, or whatever type, plays an important role in romance, racing, football, gambling, and mineral exploration. However, for each of these; education, training, technique, and experience are necessary for a long, continuous, successful relationship. Success, no matter how obtained, is easier to defend than almost success, regardless of the education or the degree of refinement of the seeker. Similarly, investment dollars are more readily available to a successful, uneducated and unscientific practitioner than to his beginning or unlucky professional counterpart.

Jan 1, 1983

By A. Cecala, J. Noll, J. Organiscak

Many underground metal/nonmetal mines are using enclosed cabs on mining equipment to reduce the exposure of miners to diesel particulate matter (DPM). However, some enclosed cab systems may not be meeting their expected efficiency in capturing DPM, which could be a result of inappropriate filter use, cab leaks or insufficient pressurization. NIOSH investigated several types of filters for reducing DPM to determine which type had the best capture efficiency. The laboratory results indicated that a MERV 8 (minimum efficiency reporting value, as defined by the American Society of Heating, Refrigerating and Air- Conditioning Engineers) filter captured about 50% of the DPM, a MERV 16 filter collected 96-98% of the DPM and two HEPA (high efficiency particulate air) grade filters captured over 99% of the DPM. NIOSH also performed a field study to measure the efficiency of two cabs at a limestone mine. The cab filtration systems of a loader and haul truck were found to be over 90% effective in removing DPM, except under certain operating conditions when the efficiency was as low as 41%. A possible reason for the low efficiencies is an open window in the cab, but more studies need performed to obtain a better understanding of the cause and solution of the problem.

Jan 1, 2011

By Fredy A. Elorrieta Agramonte, Gabriel von Rickenbach, Roberto Luis Fonseca, David Córdova Rojas, Rolando Romero, Rico Brändle

The mine’s economic life is dynamic by nature. Some factors that create this scenario are the need to recognize new exploitation areas, the evolution of the mineral prices and the development of new technologies to access them. The dynamics of mining development, especially in the underground environment, changes significantly as the stages unfold. In many cases the final solution differs greatly with the initial. The frequent presence of new conditions and factors often cause the mine to develop in a quasi-permanent transition stage, which could be characterized by the generation of dynamic micro-seismic events that could cause rockburst damage in some specific areas. Although they may be infrequent, these dynamic events can have an important adverse impact on mine safety and causes serious losses. Also, changes in the production schedule during exploitation could be a big issue if the problem is not effectively addressed. When the transition of the mine to an active micro-seismic environment begins as an unforeseen scenario, it is frequent to use static ground support systems as they are readily available. Traditionally, the support systems used are reinforced shotcrete with a middle layer of Welded Standard Wire Mesh (WSWM) and Chain Link Standard Wire Mesh (CSWM) of reduced gauges, i.e. wires less or equal than 4 mm in diameter. Although, this support system is used to control static instability problems, there is no good reference of its energy absorption capacity under dynamic load conditions, creating uncertainty in the effectiveness of controlling rockburst events. These support systems are analyzed at the present paper, testing the reinforced shotcrete layer with 4 mm diameter of WSWM and CSWN under dynamic load. Additionally, the influence of the use of high tensile strength steel wire in the meshes (HSWM) compared to the previous ones, is analyzed to assess the scope in controlling rockburst events and keeping the safety of underground environment.

Apr 26, 2022

By M. Gunter, M. Buzon

"Talc formed by hydrothermal alteration of preexisting carbonate rocks is known to be nearly monomineralic, and lacking in amphiboles. In southwest Montana, talc formed from hydrothermally altered dolomitic marbles, and is still actively mined. These talc deposits are typically in contact with quartzofeldspathic gneiss and marble. Accessory minerals vary between these rocks and the ore producing body; the identification and characterization of such minerals requires carefully selected analytical methods. Recent litigation and ensuing confusion over the petrology and asbestos content of these deposits challenges the talc mining industry in Montana, and elsewhere in the world. INTRODUCTION Commercial talc has been mined from the deposits in southwest Montana since the 1940s, and by 1956 the region had output 200,000 tons of talc ore (Chidester et al., 1964). Commercial talc refers to rocks containing more than 20% of the mineral talc (McCarthy et al., 2006); the ores from Montana typically contain upwards of 90% talc. This region remains the leading domestic source of talc in the U.S. partly due to the reserves in the area, and partly due to the diagnostic purity of the ore compared to that of other regions, some of which are no longer actively mined. The mineral talc, a sheet silicate, is expressed by the formula Mg3Si4O10(OH)2, and therefore can form in geologic environments that are rich in Mg, Si, O and water. The protolith for the talc deposits in southwest Montana is a dolomitic marble, but other common protoliths include ultramafic igneous, mafic igneous, and siliceous dolomites (McCarthy et al., 2006). Physical properties such as hardness of 1 on Mohs hardness scale, white streak and slippery feel are among some of the reasons why talc is so widely used as fillers in a number of industries. In decreasing order, ceramics, paper, paint, roofing, plastics, rubber, and cosmetics are the leading domestic industries that use talc despite the decreasing trend in U.S. talc use and production since 1994 (Virta, 2015). The purpose of this paper is to describe the mechanism of talc formation in southwest Montana by focusing on talc deposits and surrounding rocks in the Ruby, Greenhorn, and the Gravelly Ranges, and to relate the mechanism of formation to the composition of talc ores. The compositional data show mineral content of selected ores, and the major and trace element content of those minerals, specifically talc. Our electron microprobe (EPMA), powder x-ray diffraction (XRD) and x-ray fluorescence data for samples from five mines in these three ranges provide continued evidence of the purity of these ores despite claims made during recent litigation that these ores contain asbestos. The five mines that we discuss include the Beaverhead, Treasure, Regal, Willow Creek, and Yellowstone Mines (Figure 1.)"

Jan 1, 2016

By Steven J. Schatzel, Kayode M. Ajayi, Zoheir Khademian

The integrity of unconventional shale gas well casings positioned in the abutment pillar of a longwall mine could be jeopardized by longwall-induced deformations. Under such scenarios, the surrounding fracture networks could provide pathways for gas flow into the mine creating safety concerns. To provide recommendations for developing guidelines that ensure a safe co-existence of longwall mining and unconventional shale gas production, this study evaluates the impact of parameters that could affect potential shale gas flow into the mine in the event of a casing breach using a discrete fracture network (DFN) model. These parameters are evaluated using a conceptualized DFN realization that is representative of the fractured zone in the overburden, and the range of parameter variations is within values validated with field measurements. The results show that a decrease in fracture aperture (potentially due to longwall-induced stress in the likely vicinity of the breach location) reduces the potential gas flow to the mine by a significantly higher proportion. A 50% decrease in the aperture of the fracture that directly transports the gas from the casing breach location reduces the gas flow to the mine by over 70%. Similarly, changes in the fracture water saturation level significantly affect the gas flow. In all cases, the potential gas flow to the mine is higher if the casing breach occurs at an increased gas well pressure. These findings provide critical information regarding the impact of each of the parameters associated with gas flow in the event of a shale gas casing breach near a longwall mine and could help towards the development of guidelines to ensure a safe coexistence of both industries.

Sep 28, 2022

By J. R. Heberger

"The Safety Pays in Mining web application, developed by the National Institute for Occupational Safety and Health (NIOSH) Mining Program, helps mines determine the potential costs associated with mining injuries. This web app groups injuries by type, either by the cause of the injury or by the nature of the injury. When the user selects one of over 30 common types of mining injuries, the app provides information on the distribution of costs of workers’ compensation claims for that type of injury. Based on other user inputs, Safety Pays in Mining will estimate the total costs of the selected injuries, including an estimate of additional indirect costs, the estimated impact of total injury costs on mining company profits, and provide some examples of other items (services, equipment) on which companies could spend the savings that result from the prevention of injuries. This paper reviews the Safety Pays in Mining web application by discussing the development of the app, how it is used to show the true costs of mining injuries, and how mines can benefit from using this app. INTRODUCTION Injuries on the job cause pain and suffering. They can also profoundly affect profits and daily operations. In addition to paying direct costs or increased premiums for workers’ compensation insurance, a company might need to pay overtime for other workers to fill an injured worker’s job role, cover training costs for a replacement worker, or divert administrative resources in the wake of an injury. Safety Pays in Mining is a web app that estimates the distribution of these injury costs and assesses the impact that occupational injuries have on a company’s profits. The costs of specific types of occupational injuries in mining are not readily available as mining and insurance companies don’t usually share this information. As a consequence, companies only have cost information based on previous experience with their own employees. Therefore, if a mine never experienced a finger amputation for one of its miners, it would not be aware of the possible costs associated with this type of injury. In addition, injury costs are unique in that the cost distribution is so wide — with half of the injuries in our dataset having mean costs higher than 90th percentile costs — just using the average cost of a specific injury type does not provide adequate information. Some injuries involve immensely high costs, and even though the risk of these high-cost injuries occurring is low, mines need to be aware of their potential impact on their company’s financial health."

Jan 1, 2018

By Y. FUJII, E. CHANDA, J. KODAMA, D. FUKUDA, M. NISHIHARA, Y. NAKAYAMA, P. SINKALA

This paper describes a creep damage model that was proposed to clarify the rockburst mechanism for the Mufulira underground copper mine in Zambia. Cumulative rock damage was evaluated for the edge elements of each sidewall of the mining drives based on normal stresses by the 3-D displacement discontinuity method (DDM) (Crouch and Fairhurst, 1973). The rockburst occurrences were well hindcasted.

Jan 1, 2023

By J. Y. Hwang

Alunite has been utilized as raw materials for producing alumina and potassium sulfate fertilizer in Russia for many years. In the United States, this mineral has not been commercially processed though reserves of 5 to 10 billion tons of alunite ore have been estimated. Major constituents of these ores include quartz and alunite. The minerals are finely intergrown and liberation occurs below 10 microns. Adequate separation techniques for such fine particles have not been developed. A new method for the beneficiation of alunite ore is proposed in this study. 'Ibis method utilizes a small amount of fine magnetite upon which the liberated quartz is selectively flocculated. The co-flocculated magnetite and quartz are then separated from the alunite in a high gradient magnetic separator. Clean products, e.g. an alunite concentrate of 90% grade with 80% recovery, has been obtained from an Utah ore. Techniques for the selective co-flocculation of magnetite and quartz, the separation of the carried quartz, and the recovery of magnetite after separation are discussed.

Jan 1, 1985

By Ulrich Maidl, Gustavo Aguiar, Argemiro Ferreira, Marco A. Peixoto Silva, Marc Comulada

"Metro Line 5 in Sao Paulo is being constructed. This lot extends for 4,940 m with twin EPB shield tunnels under a dense and busy urban area, with an excavation diameter of 6.9 m. The tunnels run predominantly in the tertiary soils of Sao Paulo where extensive experience exists from previous EPB shield tunnel projects. However, new experience is being gained in Sao Paulo in shield tunnelling through Saprolite, the weathered product of the underlying Gneiss crystalline basement, through the resulting residual soils and in rock-soil mixed face conditions. Furthermore, experiences in difficult mixed face soil conditions with overconsolidated clay at the face in combination with loose sands at the crown under the groundwater table will be presented. Additionally, the design, operational and controlling approach followed for the shield drive at particular critical cross-sections where the shields were driven close or under buildings. INTRODUCTION Within the framework of Sao Paulo´s metro network expansion, the excavation of the shield tunnels for Metro Sao Paulo Line 5 is currently taking place. The present paper deals with the description of the most relevant features from the construction of the Line 5 – Lot 3 tunnels. The paper presents how particular challenges were dealt maximising potential of EPB shield tunnelling technology. Challenges were posed not only by the difficult boundary conditions of urban shield tunnelling, such as shield drive under buildings, but also by complex geotechnical situations. PROJECT DESCRIPTION The great urban area of São Paulo is one of the biggest cities in the world, with around 20 Million people living in the city and in the suburb area. The city faces great mobility problems and in the last years the government has been investing great amounts on the megacity´s metro expansion. The Line 5 Extension plays an important role to connect the south area to the central area of the city, with a whole extension of 11 kilometres, including 11 new stations. It is estimated that this line will transport almost 900.000 passengers/day. The first stretch of the expansion, Lot 3, consists of two single tunnels, almost 5 kilometres long each, crossing 4 stations. Figure 1 shows details of the Line 5 Expansion."

Jan 1, 2016

By Fumio Wada

Kuroko deposit is a stratabound massive sulphide and sulphate deposit associated with Miocene submarine volcanics and has been considered to be a prototype of meta- morphosed Palaeozoic and Precambrian equivalents. Since the discovery of Uchinotai deposit of the Kosaka mine in 1959, Dowa and other mining companies have conducted intensive exploration work in the Hokuroku district of northeastern Japan. Dowa has been placing its first priority on the exploration of Kuroko deposits and made a series of remarkable successes in finding the Kuroko deposits, i.e. Uchinotai, 1959; Matsumine, 1963; Uwamiki, 1966; Fukazawa, 1969 and Ezuri, 1975. It is emphasized that our successes have resulted from the proper application of exploration technologies accumulated through our experiences. Firstly we defined the Kuroko horizon and favourable felsic volcanism based on the detailed structural and volczno-stratigraphic study of the Hokuroku district, and then delineated the promising areas by means of the quantitative evaluation of geophysical, geochemical and mineralogical parameters such as the magnetic susceptibility and contents of alkaline and alkaline earth metals in the foot wall dacites and clay mineral assemblages of both hanging and foot wall pyroclastics and dacites. Practical application of these techniques is essential to our routine Kuroko exploration.

Jan 1, 1982

By Christina Dahnér, Kristina Jonsson, Savka Dineva

The iron-ore underground Kiirunavaara mine (Sweden) has been seismically active since 2008. In 2021 the production is on levels 1079 and 1108 m, at the deepest. The seismic activity has changed in character over time with one step change in 2015 when the number of large (ML>2) seismic events increased, and another one when the mine experienced a seismic event with Mw 4.2 in 2020. In 2017, the mine evaluated Hydraulic Fracturing (HF) as a possible mitigation technique for larger seismic events and a one-hole trial was performed. The trial proved promising, and it was decided to go forward with a large-scale trial covering an entire production area in the mine. The large-scale trial consists of 25 fracturing holes, 50 – 100 m long, running along 500 m out of the ~4500 m long orebody and spanning between production levels 1108 m and 1252 m. The fracturing process continued for a year, resulting in ~38,000 seismic events with −3.3<ML<1.4. The breakdown pressure varied between fractures in the same hole as well as between holes in the same area. Average breakdown pressure per hole was between 12 MPa and 50 MPa. The seismic response to HF in 2021 varied greatly from hole to hole and between fractures in the same hole. The variation in response could be related to the geological conditions and the infrastructure, such as large caving ore passes. In this paper some details about the experiments and broad preliminary analysis of the effect of the HF by using seismic source parameters of the induced seismic events are presented: 1) Distribution of seismic activity, 2) the ‘equivalent’ magnitudes for each hole calculated from the cumulative seismic energy and seismic potency released during the fracturing, compared with the local geological conditions; 3) the predominant failure mechanism of the seismic events caused by HF was defined. A difference in the behaviour between larger and smaller events was noticed, as ML>0 events seem to be compression type failures and ML<0 events seem to be related to slip on pre-existing structures. No seismic events related to creation of a new fracture have been identified yet.

Apr 26, 2022

By G. V. Henderson

The San Gabriel Valley contains some of the richest and most extensive sand and gravel deposits in California. Operating quarries within the San Gabriel area mine more than 15 million tons of high quality aggregate per year. This represents about 45 percent of the total mined in the greater Los Angeles area, one of the nation&apos;s largest aggregate markets and producing regions. Popular opposition to continued aggregate production in the San Gabriel Valley is high, especially in the city of Irwindale where 40 per-cent of the city&apos;s property is made up of "excavated holes," some 150-200 feet deep. Reclamation of 70 years of mining is now an almost impossible task. Zoning regulations have the effect of depleting these vast reserves rapidly by changing the definition of total reserves to include only "legally minable reserves." All but two or three of the aggregate mines now operating will be depleted or zoned out of business by the year 2000. Some studies indicate that there will be no aggregate mining operations by 1995. Recent studies show a drastic change in land use patterns within this valuable mineral resource area over the past 20 years. The San Gabriel Valley is a classic example of the lack of adequate regional planning with regard to urban development in MRA&apos;s and represents a "too little, too late" effort by local government and industry.

Jan 1, 1978

By Thomas E. Newman

This paper is a case study using new laser-terrain-mapping technology by EagleScan, Inc., for creating topographic maps. Holnam, Inc., has used this technology to create maps and volumetric calculations of several mines in the United States. The information is superior to conventional methods through accuracy, manpower, time, and cost. Holnam, Inc., was the first cement manufacturer to use the Digital Airborne Topographic Imaging System (DATIS?). The technology uses the DATIS? to produce high-resolution terrain maps and volumetric assessments of any area. DATIS? is a mapping instrument that integrates (1) a Light Detection and Ranging (LIDAR) instrument to measure terrain elevation using laser light, (2) a large-format digital camera, (3) a relative position Global Positioning System (GPS) to measure aircraft position, and (4) an Inertial Measurement Unit (IMU) to measure aircraft attitude. The DATIS? can measure up to 220,000 elevation samples per mil. The system continually collects data on the aircraft&apos;s position and measures the time for each laser pulse transmission to return from the ground, giving each sample a GPS reference. The system can operate at night, in overcast sky, and during high-wind conditions and can measure terrain below vegetation cover, unlike standard aerial photography used for traditional surveying and mapping. Surveyed ground-control panels are no longer necessary with this new technology, and only one ground GPS base station located within 60 mi from the aircraft position is required. A computer elevation-point data file is created with the x, y, z coordinates of each laser elevation sample. With this file, CAD engineering programs can create topographic maps that rival products using conventional aerial mapping techniques. Volumetric measurements of stockpiles and pits are also available due to the high density of points collected from an area. This new technology radically changes the turnaround time for map users, giving a product in the format used by today&apos;s cartographers. The time line from flight to maps is measured in days instead of weeks.

Jan 1, 1999

By N. Edmonson

Introduction An examination of statistics for the world phosphate fertilizer industry since 1980 reveals that there is an increasing tendency for fertilizer-manufacturing activity to concentrate in the areas of phosphate-rock mining. The economic justification for this resource-oriented strategy is clear. The choice between shipping phosphate rock, a comparatively low-value product, and shipping a more valuable finished fertilizer product will always, as long as cost considerations control the decision, be resolved in favor of the latter. The historical existence of substantial phosphate fertilizer-manufacturing capacity, which is oriented toward fertilizer-consuming activities and dependent on imported phosphate rock, shows that narrow cost considerations have not always determined the industry&apos;s location. One is entitled to ask what conditions have changed to precipitate the observed relocations, and how permanent are these changes. These questions are the subject of this investigation. Recent trends in world phosphate trade Since 1980, the changing pattern of world trade in phosphate materials reflects an increased interest in manufacturing phosphate fertilizer in rock-producing areas. This is shown by the decline in the total tonnage of phosphate rock being traded worldwide compared to world consumption of phosphate fertilizers (Fig. 1). This relative decline has continued since 1984, which is a longer period of time than could be explained by temporary cyclical market factors. Other evidence corroborates this conclusion. The world&apos;s phosphate-rock production is relatively concentrated geographically. In 1992, the top ten producing countries accounted for 92% of world production. Figure 2 shows that the share of world fertilizer production in the top ten rock producers has increased. Yet, further evidence of the direction of trade changes can be had by looking at the pattern of the world&apos;s sulfur trade. The first step in the manufacture of any of the widely used phosphate fertilizer products is the acidulation of phosphate rock with sulfuric acid. In most instances, phosphate fertilizer producers have found it economical to produce their own sulfuric acid by burning elemental sulfur, and such operations account for over 60% of all sulfur consumption in the world. 1 Therefore, a concentration of phosphate fertilizer production in rock-producing countries should produce a similar concentration of sulfur imports in the same countries. Figure 3 suggests that there has been a tendency since 1989 for sulfur exports to go increasingly to the rockproducing countries. World phosphate-location strategy is not limited to the alternatives of shipping rock and shipping finished fertilizers. A third alternative consists of producing phosphoric acid, the principal phosphate fertilizer intermediate, at the rock deposit, and then exporting it to market-oriented ammonium phosphate plants. This arrangement offers the importing country the advantages of shipping a more concentrated product while retaining the economic multiplier benefits of a domestic high-analysis fertilizer industry. India, and several other countries, imports merchant-grade phosphoric acid to use as input for the domestic value-added fertilizer industries. For various reasons, the trade in phosphoric acid has never quite lived up to the promise suggested by the foregoing discussion. Figure 4 shows no growth in this trade in the last ten years, either in absolute terms or in relation to the world&apos;s consumption of phosphoric acid. Most of the decline in the trade in phosphorous in rock form has been replaced with trade in finished fertilizers. The trade in superphosphoric acid was a growth activity in the late 1970s with the growth in US exports to the USSR, and this trade survived the Carter-era embargoes of US-Soviet trade. However, no additional sizable markets for superphosphoric acid developed, and other suppliers sought out the Soviet market. The problem with superphosphoric acid is that the cost of its incremental concentration is as great as the savings from shipping the more concentrated product. The Soviet market was a special case. The political breakup of the Soviet Union disrupted the superphosphoric acid trade after 1991 and led to a shutdown of the US export capacity.

Jan 1, 1996

By Glenn J. Phillips, Debra L. Musick

The operating mine is dynamic, everchanging, and a continuous moving target. The only way to effectively manage such a creature is to be able to evaluate the cost of operation over short enough time periods that rapid effective controls can be implemented before loss can erode the marginal profits in todays market place. Such short term evaluations can provide the basis for the long range planning that can keep an operation healthy in the future. The spreadsheet programs on small computers (PC&apos;s) offer the possibility of such evaluation by accumulating data in a useable format, providing timely cost reporting and providing a tool for use in evaluating the day to day alternative choices of the real mining world.

Jan 1, 1987

By G. R. Luster

In most current practice, the methods that are employed in technical evaluations of cement raw materials are deterministic; i.e., decisions among alternative raw mixes and alternative plant designs are reached with the aid of only "average" compositions and "representative" samples of the available raw materials. Nevertheless, cement plants are sensitive to raw-material variability, and uniformly high-quality raw materials are not so abundant as they once were. Some simple examples will illustrate how geological techniques can be combined with geostatistical and operations-research approaches to customize mining and processing systems to deal with variable raw-material compositions.

Jan 1, 1987

By Saul J. Escalera

Mechanisms involved in the depression of the sulfides: pyrite, chalcopyrite, galena and sphalerite with potassium permanganate have been investigated. Flotation tests were conducted using potassium amyl xanthate, Z-6, and pine oil in the absence and presence of potassium permanganate at around pH = 6. 5 naturally yielded by the sulfides in the pulp. On the basis of crystal chemistry considerations, the amount of xanthate adsorbed by the sulfides depends on the amount of sulfur and metal ions present on the surface; thus, the avidity of the sulfides for xanthate should increase in the order: sphalerite C chalcopyrite 4 galena 4 pyrite, and the ease of depression response to the permanganate action should be in the same order. Depression of the sulfides in the system occurs primarily due to the removal of the collector ions by the permanganate ions to form manganese dioxide and dixanthogen according to the reaction: 3 M(RX)2 + 2 Mn04 + 4 H20 2 ? MnO2 + 3(RX-XR) + 3 M+2 8OH where M represents the metal ion, RX the xanthate ion and (RX-XR) the dixanthogen molecule. Results seem to indicate that the permanganate ions play a triple role in the system: (1) they convert xanthate ions into dixanthogen, (2) they further oxidize the mineral surface and (3) if present in excess, they may oxidize the xanthate beyond the dixanthogen stage with the formation of CO2, H20 and SO4. All sulfides, except for chalcopyrite, showed a depression response in the order predicted regardless of the order of addition of xanthate and permanganate reagents. Chalcopyrite did not depress as easily; this behavior may be due to the avidity of the colloidal MnO2 to adsorb Cu+2 ions on its surface, this would destabilize the colloid making it coalesce with the formation of a layer of precipitated MnO2 on the surface of the mineral. The presence of this layer would prevent further action of the permanganate ions on chalcopyrite.

Jan 1, 1970

By Paul H. Earl

This paper discusses the evolution of a modeling methodology for explaining price behavior in the aluminum industry. Three generations are described, each utilizing as a foundation a microeconomic stages-of-processing approach. The second generation represents an improvement over the initial version, by incorporating more rigorous specifications of energy cost, and market strength (demand-supply balance) as well as endogenous treatment of market strength. International linkages across prices, costs, and markets, are the major extensions in the third generation. The discussion covers theoretical considerations, data problems and limitations, and model specifications. Simulation and forecasting properties of the models are also addressed.

Jan 1, 1979