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By H. L. Ehrlich

Marine manganese nodules harbor a mixed population of manganese-oxidizing and -reducing bacteria, as well as bacteria that do not act on manganese. They also host phagotrophic protozoa. Out of several laboratory studies, one line of investigation indicates that some kinds of bacteria found on nodules can catalyze the oxidation of Mn2+ bound to Mn(IV) oxide at the surface of nodules at in situ temperature and pressure. In the absence of appropriate bacteria, the rate of oxidation of the surface-bound Mn2+ is significantly slower. How Fe(III) is incorporated is still unclear. Base metals such as Cu, Ni and Co, which are usually found in marine nodules in various quantities, may be incorporated through scavenging by Mn(IV) oxide. Laboratory evidence shows that some other bacteria on nodules can reduce the Mn(IV) oxide to Mn2+ in the presence of an appropriate source of reducing power in the form of organic carbon. The reduction of Mn(IV) oxide mobilizes manganese and trace metals such as Cu, Ni, and Co in the nodules. These bacteria reduce Mn(IV) whether oxygen is present or not. They could be harnessed in the bioleaching of nodules. The manganese(IV)-reducing bacteria and the bacteria that neither oxidize nor reduce manganese are thought to keep the organic matter in the nodule environment sufficiently low to favor bacterial manganese-oxidation, which in laboratory tests is inhibited by excess organic carbon. The preying by the protozoa on the different kinds of bacteria is thought to control the bacterial population on nodules and ensure continued growth of the manganese-oxidizing bacteria and the nodules. To eliminate interference from seawater salts in the bioleaching of Mn, Cu, Ni and Co, it may be more advantageous to use terrestrial Mn(IV)-reducing bacteria than the Mn(IV)-reducing bacteria resident on nodules. The terrestrial bacteria would allow bioleaching in fresh water. Unlike the marine bacteria, most terrestrial bacteria studied to date reduce Mn(IV) oxide only anaerobically. A general outline for an anaerobic bioleach process of marine nodules with freshwater bacteria is discussed.

Jan 1, 2000

By Warren E. Morrison

The expansion of the United States economy in the postwar period has had a tremendous impact on the demand for energy. Not only has total energy consumption increased at an unprecedented rate, but there have been major shifts in the composition or mix of energy resources within the end-use sectors. Because of the numerous interrelationships between substitutable energy resources and their markets, the energy economy can only be analyzed in terms of the trends of its component parts. This problem takes on additional complexity when attempting to chart the nation's future energy requirements. Total energy consumption can be forecast with reasonable accuracy for periods up to 15 years by relating this to projections of economic indicators. However, forecasting the component parts of the energy economy constitutes a dilemma in that the sum of the projected parts frequently exceeds predictions for total energy. Areas of uncertainty in energy forecasting tend to mount rapidly when proceeding from total energy to the consideration of specific energy resources consumed as fuel, power, or raw materials.

Jan 1, 1965

By Madan M. Singh

This section is unique to the Handbook in that it is the only section that deals with underground excavations for nonmining purposes. The editors were of the opinion that the section should be incorporated because the subject matter covered by the chapters is closely related to mining, and many mining engineers are currently involved in these activities. As we enter the decade of the 1990s activities in this category will increase, enhancing the relevance and utility of the material discussed. As the population increases, especially in metropolitan areas, the necessity to go underground will be greater. At the present time, not only are subsurface shopping malls and pedways connecting buildings becoming commonplace, but structures as diverse as the Civil and Mining Engineering Building on the University of Minnesota campus, a road-and-fleet maintenance facility in Multnomah County, OR, and even an ice cream parlor (Dairy Queen) in northern Wisconsin have been constructed underground. Placing utilities below the surface has numerous advantages and is now customary. Rapid transit and highways through tunnels in urban areas have been the norm for many years, but subterranean stormwater reservoirs, power plants, industrial warehouses, and food storage silos are relatively new innovations. The philosophy of underground defense installations is ancient, but their requirements and designs have trans-formed radically as technology advances. The use of under-ground space for disposition of wastes is modern, since it is recently that environmental concerns and waste disposal costs have assumed increased significance.

Jan 1, 2008

By A. D. Randolph

Comminution represents one of the major costs of mineral recovery from low-grade ores. Efficient mineral recovery in a typical low-grade ore grinding-flo¬tation process depends on grinding the ore small enough to liberate mineralization without producing excessive slimes, which would result in higher power and flotation reagent costs. Size criteria for efficient grinding should be stated in terms of the distribution of mineralization sizes, but as the mineralization-size distribution is difficult to determine, less desirable criteria of absolute particle-size distribution (PSD) are used in practice. Thus, there is considerable incentive to be able to analyze and predict the PSD performance of grinding circuits for control and optimization of the process. Any realistic model of a grinding circuit must account for recycle of oversize material; such oversize recycle adds to the total mill load and limits total production rate. Simulation of such closed-circuit operation to study grind factors affecting total throughput can be done in a straightforward fashion provided recycle calculations can be added to an accurate input-output model of PSD in the grinding mill itself. Such a total simulation of mill performance is of obvious practical value in assessing the practicality and benefits of various over-all mill control schemes and/or modes of operation. For example, considerable interest has been shown in the development of continuous on-line particle-size sensors and such instruments should be an operating reality in a few years. A total closed-circuit PSD model of this type would be invaluable in the utilization of, and in predicting the pay-out from, such an on-line particle-size sensor. The purpose of this paper is to present a new approach to the development of an input-output PSD model of a grinding mill. The model is continuous in the par¬ticle size coordinate, L, and is based on the principle of a particle population balance along the particle size coordinate. Most previous studies of the grinding unit operation attempt to relate power

Jan 1, 1971

By Donald R. Williamson

The Cyprus Pima Mining Company's open pit operation was started in 1957 with the normal assumption that the ore reserve estimate was accurate within an acceptable range of values. At that tine reserves were law - volume (+10 million tons) and high grade (+1.5% Cu). Several periods of growth have brought the operation to its present production level of 55,000 tons per day of ore and +125,000 tons of waste. Over the years, a number of attempts to refine and polish the ore reserve figures have been made using a variety of established standard procedures. None of these attempts have produced results which are totally satisfactory, particularly when comparisons are made between ore reserve estimates and short to medium range production figures. Other refinements were tried using adaptations of established methods combined with computer modeling techniques. The resulting mine-model ore blocks were an improvement but they still tended to show too match tonnage of mill feed, often at too low a grade. One attempt at Kriging had only limited success. Statistical studies of operations data revealed relationships which could be used to subdivide ore blocks in much the same way as they are actually mined. Comparisons thus far between these newly developed ore blocks and production data show that the new method of evaluation yields excellent results. A new, better procedure for estimation of ore reserves apparently has been developed for the Cyprus Pima deposits. The specific procedures seem likely to have direct application to other, similar operations. The methods used to develop the procedures could be of value to still other operations.

Jan 1, 1976

By L. R. Berry

The successful selection of a slurry pump depends on the accuracy and completeness of the information provided for the application. Inaccurate or incomplete information can result in incorrect pump selection and / or operational problems. Some information is more critical to the selection process than other information. A full description of the slurry (liquid -solid mixture) including the particle size distribution and maximum concentration, the flow, head and NPSH requirements are most important for successful slurry pump selection and operation. Common problems resulting from improper slurry pump selection will be discussed to illustrate the need for correct selection requirements.

Jan 1, 1996

By John P. Capp

In recent years limited markets have been developed for fly ash, the dust removed from coal-burning powerplant stacks, but most of it is still dumped in spoils areas at a cost ranging from 20 cents to $1.75 per ton. Aside from this cost, the creation of huge spoils areas can present a considerable aesthetic problem. Since the present annual fly ash output of about 20 million tons will probably reach 30 million by 1970, and because satisfactory disposal areas are becoming more limited, markets for much larger quantities of the waste are needed to keep disposal costs from becoming a significant economic factor in coal-burning powerplant operation. Current stress on air-pollution control and beautification, plus the vital need for good powerplant economy, makes it imperative, therefore, that coal producers and consumers expand markets and develop new applications for fly ash. Markets for established uses can be increased by making a greater effort to sell fly ash. New large tonnage markets for fly ash should be sought via more intensive, coordinated research. The economics of fly ash utilization underscores the vital role that must be played by research. To be competitive with other products, processes for the conversion of fly ash into marketable materials face difficulty in regard to two important economic factors--transportation cost and product utility--the other economic factors are favorable. Raw material costs of fly ash, for example, are quite attractive, and supply is no problem because there are many coal-burning powerplants in operation and many more are planned. Demand for products made from fly ash will grow if their utility is established and a good sales program is initiated. The major problems then are transporta¬tion costs and development of useful products.

Jan 1, 1966

By K. Katen

In another situation, Dave Zegeer, the Assistant Secretary of Labor for Mine Safety and Health, whom all of you know very well, would have taken the opportunity to talk with you. In his absence, however, I would like to reference some of his recent comments which may help us to see the issue of mine safety in historical perspective. Dave pointed out that this year is the eightieth anniversary of the Great Earthquake and Fire of San Francisco. The whole world heard about that disaster--it and the 452 people who died in it. In that same year, nearly five times as many people died in coal mines, but no one particularly noticed.

Jan 1, 1986

By Nelson Alonso Portal Ravichaua, Melissa Esther Mendoza Tirado, Raúl Arévalo Saavedra

This study analyzes the implementation of an integrated strategy for environmental education and community awareness in Cajamarca, Peru—an Andean region affected by climate variability and the public perception of miningrelated water shortages. In collaboration with the Interactive Water and Earth Museum and the Newmont ALAC Foundation, three-month campaigns were conducted in schools and local communities. Key topics included the water cycle, climate change, and water availability, linked to urban infrastructure projects that improved flow rates through strategically located tubular wells tapping underground aquifers. The initiative addressed the challenge of communication in a context where mining is often blamed for scarcity, fostering scientific understanding of contributing factors. The study highlights how science-based outreach and institutional collaboration can strengthen resilience and promote sustainable water stewardship in mining-influenced regions.

Feb 22, 2026

By A. H. Srnallbone

Over the past few years the rising production costs, shortage of skilled labor, and increased use of lower grade ore bodies have all added justification for the use of on-stream analysis. A rise in the number of on-stream units indicates that this type of assay is now being accepted as a necessity. On-stream analysis is a much more rapid means of obtaining true assays of a flowing product when compared to wet chemistry or "grab" samples dried, briquetted and assayed by x-ray. In contrast, on-stream analysis uses real time samples assayed every 30 seconds while each stream is assayed every 5 to 15 minutes. It is very important not only to know that a change has occurred in the process, but to know what caused the change and how to correct for the change. For example, in a tailing sample the elements of interest comprise between 1% and 10% of the sample. The remainder is water and gangue. Previously the gangue was not assayed nor were the low atomic number elements used for corrections. In addition to the demand for higher accuracies some concentrators were being penalized for excessive Ca or in some cases 5i in their concentrates. This penalty was being imposed by the smelter in order that they could better cope with pollution problems and prolong the life of their furnaces. But until Ca, 5i, and S are measured on-line, nothing can be done about their control. By accurately measuring these light elements on-line, a complete assay is obtained of the total sample providing improved accuracy for the important products. The justification for complete accuracy assays is now even more obvious because they are possible at very 1ittle increased cost and at no increase in analytical time.

Jan 1, 1977

By J de Cuyper, E. J. Parkins, H. L. Shergold, W. Freyberger

The paper is divided into two parts. The first part describes an investigation of the effect of temperature on the conditioning and flotation of an ilmenite ore with a 1:l oleic acid-fuel oil mixture as collector. During conditioning the pulp underwent characteristic changes of flocculation, deflocculation and dispersion which were monitored by measuring the power consumption of the conditioner motor. Optimum flotation results were obtained at the end of the deflocculation period. High ilmenite recoveries were obtained at high temperatures and high concentrate grades at low temperatures. The second part of the paper describes a study of the effect of temperature on the adsorption of oleic acid at the ilmenite/water interface. At high adsorption densities it was chemical and exothermic. Contact angles showed that the hydrophobicity of the collector-coated minerals increased with an increase in temperature.

Jan 1, 1976

By R. G. Reddy

Solid state reduction of roast movat chromite ore with carbon was carried out as a function of C/FeO ratio and temperature in the range 800°C to 900°C by thermogravimetry analysis (TGA). A two stage mechanism, (1) the reduction of FeO present in Roast Movat with carbon monoxide; and (2) the regeneration of CO by the oxidation of carbon with CO2 was proposed. The rate controlling step is the carbon oxidation reaction. A kinetic equation, that of random nucleation, was proposed. The activation energy for the reduction was determined to be 55800 J/mole and is compared to those activation energies determined for other chromite ores.

Jan 1, 1998

By Alphonse C. Van Besien

It is doubtful if anyone knows precisely how many U.S. coal miners have been killed by roof falls. In 1931, 51 miners were killed by falls or rock in every 10-day period (Paul, 1). Roley (2) indicated that from 1882 to 1945, over 3,700 men were killed by roof falls in Illinois alone. During this 63-year period, roof falls accounted for 47.6 percent of the coal mine accident fatalities. Similarly, Price and Nolting (3) reported that during the 10-year period beginning in 1937, roof falls claimed over 50 percent of the lives lost in West Virginia coal mines. Over 150 miners died under fallen rock in West Virginia alone, in each of those years. Certainly, the statistics have improved over the years. The Theodore Barry Report of 1971 (4) indicated that during, the previous 4 years, fewer than 100 miners per year lost their lives to roof falls--in the entire United States. The improvement is less remarkable when it is realized that the accident rate has declined only as the number of miners employed underground has declined. The TRW Report (4) pointed out that although the number of fatalities in underground coal mining (from all causes) had been cut in half from 1956 to 1965, the fatality rate per thousand miners had remained virtually constant. The decreased accident rate was due not to a reduction in hazards but to a reduction in work force. Roof falls still claim approximately 50 percent of the lives lost in underground coal mines. Considering the increased underground production of coal which must result from our energy crisis, the environmentalists' pressure against strip mining, and our inevitably diminishing supply of strippable coal, it is apparent that some means must be found to reduce the number of lives claimed by coal mine roof falls.

Jan 1, 1973

By Douglas M. Smith

The town of Tayoltita, Durango is located at the bottom of the 2000 m. deep Rio Piaxtla canyon on the axis of the rugged Sierra Madre Occidental mountain range. Throughout most of the year access to the town is restricted to travel by mule or STOL aircraft. Silver and gold have been produced from epithermal veins in the north side of the canyon since 1757. During the last seventy-three years more than 4,588,000 kg. of silver and 76,322 kg. of gold have been produced from approximately 6,000,000 metric tons of ore. The Tayoltita mine is developed within a fault block bounded by normal faults which strike north-northwest and have opposing dips. A thickness of at least 1300 meters of late Cretaceous or early Tertiary volcanic rocks is exposed in the mine. These range in composition from andesite to rhyolite. Andesite predominates in the upper 750 meters of the section. The volcanic rocks were passively intruded by quartz-monzonite and andesite stocks during middle (?) Tertiary time. Mineralization spatially and temporally (?) related to the stocks occurs along the east boundary fault and in intersecting footwall fissures which strike east-west and northeast. Ore was deposited over a vertical range of up to 600 m. prior to tilting of the volcanic rocks 35 to 45° to the east. With few exceptions, the ore bodies are found within the lower 400 to 500 m. of the andesite. Argentite (acanthite), stromeyerite, jalpaite, electrum and native silver are the principal ore minerals. They occur in gangue composed of one or more of the following: quartz, calcite, bustamite, adularia, chlorite, and albite. Base-metal sulfides make up less than 1.5 percent by weight of the ore.

Jan 1, 1974

By Y. C. Kim

Using an exhaustive data set of Walker Lake, four different kriging techniques plus the inverse distance squared weighting were compared with regards to each one's performance in accurately estimating the block grades. The North-West quadrant of the Walker Lake data area was used because of its extreme variability of values and its distinct contour of the values. There were 1900 exhaustive data points in the selected area from which a total of 121 samples were drawn following the sampling strategy given in Isaaks and Srivastava (1989). The average of 5 x 5 exhaustive data points was treated as the true, known block grade. A total of 780 blocks, each block corresponding to the average of 5x5 exhaustive data points, were then estimated using the 121 sample points. The resulting estimates were then compared with the true known values to determine each technique's prediction performance. For this particular portion of the Walker Lake and for the given sampling strategies used, the obtained results for the global estimation are mixed. For the variable U which is much more variable, the rankings are; 1) Jackknife Kriging (JK), 2) Indicator Kriging (IK), 3) Inverse Distance Square weighting (IDS), 4) Ordinary Kriging (OK), and 5) Log-Jackknife Kriging (LJK). For the variable V, the results are; 1) OK, 2) IK, 3) JK, 4) LJK, and 5) IDS. When we apply several cutoff grades to the estimates to determine the conditional mean grades and tonnage, the above rankings generally get shifted around. Two exceptions to these cases are; a) UK for U and b) IDS for V. These two consistently ranked at the bottom.

Jan 1, 1995

By J. Lovering, H. Wilhelm, P. Siewert

Introduction The Afton property is located 290 km (180 miles) by air east-northeast from Vancouver and 14 km (8.7 miles) west of Kamloops, a city of 60,000 people, in south central British Columbia, Canada. The mine is adjacent to the Trans-Canada Highway at an elevation of 670 m (2198 ft) above sea level. The ore body is a porphyry copper deposit that has undergone supergene alteration. The major economic minerals in the supergene zone are native copper and chalcocite with chalcopyrite and bornite in the hypergene areas. The grade is 1% with an overall copper distribution - 70% native, 25% chalcocite, and 5% chalcopyrite with bornite and covellite. The ore also contains important but variable amounts of gold and silver. The mill was designed to treat 6350 t/d (7000 stpd). Semiautogenous grinding was selected to minimize capital cost and because of the expected high clay content of the ore, which would have caused problems in a conventional crushing and screening plant. Test work indicated that a recovery of 87% was possible in a circuit incorporating both flotation and gravity separation. Flowsheet Run-of-mine ore is crushed in a 1.06 x 1.65-m (3.5 x 5.4-ft) Allis Chalmers gyratory crusher set at 228.6 mm (9 in.), closed side setting. The surge pocket, below the crusher, is emptied by a Hydrastroke feeder onto number one conveyor, which discharges onto a 180,000-t (198,416-st) coarse ore stockpile. Six Hydrastroke feeders on two conveyors withdraw the crushed material from the bottom of the pile. These two conveyors, in turn, discharge onto the belt feeding the semiautogenous mill. The live storage in the stockpile is approximately 22,000 t (24,250 st), sufficient for three days' mill feed. Primary grinding is accomplished in an 8.5-m (28-ft) diam by 3.7-m (12-ft) long Koppers (Hardinge Cascade) mill (Fig. 1) containing a 10% ball charge and driven by a 4000-kW dc variable speed motor. The mill dis¬charge is pumped by a 10 x 12 G.I.W. pump to a 1.22 x 4.88-m (4 x 16-ft) stationary screen sloped at 20°. Screen oversize returns to the semiautogenous mill (SAM), and the undersize flows by gravity to the ball mill discharge pump box. Secondary grinding is performed in a 5-m (16.4-ft) diam by 8.84-m (29-ft) Koppers overflow ball mill driven by a 3430-kW synchronous motor through an air clutch. The mill is in closed circuit with a Krebs Cyclopac containing 10 635-mm (25-in.) cyclones and the cyclone overflow, at 35% solids and 65% to 70% -200 mesh, is flotation feed. In order to limit the buildup of native copper, circulating in the secondary grinding circuit, a portion of the underflow from the cyclones is processed in a circuit containing screens, cyclones, and shaking tables to produce a finished metallic copper concentrate. Primary mill variable speed drive The overall waste to ore ratio at Afton was 4.5:1. The mining was to be done with only three shovels, which meant that it was highly unlikely that more than one of them would be in ore at any one time. The resulting inability to blend the mill feed made it impossible to prevent wide swings in the grade and grindability. The variable speed do drive motor installed on the semiautogenous mill was selected because of the extreme variability of the Afton ore body. This variability has persisted throughout the lifetime of the mine. There are times, however, when due to ore conditions, the mill is operated at full speed (78% of critical) for extended periods of several shifts duration. There are other times when the mill speed may be changed several times in a 12-hour shift due to changing ore conditions. When ore is processed that contains a fairly large proportion of fine native copper, the primary mill speed and, consequently, the tonnage may be reduced to improve the secondary grind and to maintain an acceptable grind and recovery. High clay ores require less mill speed and more dilute grinding densities. In the latter case, the slower primary mill speed also helps to minimize damage to the mill liners. Approximately 57% of the time the mill operates between 90% and 100% of full speed or between 71% and 78% of critical. The variable speed is also used for inching during mill relines.

Jan 1, 1987

By J. P. McDonald

Exposure to particulates containing metals and metal fumes (PCMMF) is a potential concern in ore refining and smelting. Some metals of primary interest are arsenic, cadmium, copper and lead, which have been linked to various adverse health effects. The current National Institute for Occupational Safety and Health (NIOSH) sampling method for metals in particulates requires the use of a filter, precision airflow pump and laboratory analysis. A major concern with this method is the one-to-two weeks? wait before laboratory results are available for use in determining if additional controls are needed to assure adequate exposure protection for workers. Particulates containing these metals were sampled during sixteen sampling events at a copper smelter using the traditional NIOSH methods. Monitoring of particulates was simultaneously conducted using a TSI 8520 Dust-Trak real-time aerosol monitor with a 10-µm-cutpoint sampling inlet. NIOSH analytical methods related to particulates and metals (methods 0500, 0600 and 7300) were used to determine particulate mass and individual mass contributions of metals on sample filters. Linear regressions with y-intercepts forced to zero were developed to determine the relationship between the PM10 measurements recorded by the DustTrak and laboratory-reported total particulate mass, PM10 and respirable arsenic, cadmium, copper and lead concentrations. These linear regressions yielded correction factors that can be applied to DustTrak readings to obtain total particulate mass, PM10 and respirable concentration estimates for each of the four metals. The R2 (coefficient of determination) values from the linear regressions ranged from 0.65 for total lead to 0.91 for total copper. These results suggest that the DustTrak may produce real-time data useful in providing estimates for airborne concentrations of arsenic, cadmium, copper and lead in copper smelter particulates.

Jan 1, 2011

By Walter E. Heinrichs

Early history of the district is typical of many, particularly in Southwestern United States. The usual early Spanish influence was felt; Marcos de Niza, Coronado and Father Kino are most notable, but authentic records regarding Spanish mining activities are sparse. About 1769 the Indian village of Tucson became a Spanish settlement. During the next century prospecting attempts were largely interrupted by the Indian, Mexican and Civil Wars. By 1870 Tucson had a population of 3200 and by 1880 the Southern Pacific Railroad extended all the way from Los Angeles. Pyrometasomatic copper ore was first produced with some local direct ore smelting done during the late 1800s. By 1907, a rail line was built from the Twin Buttes mines to Tucson by the Twin Buttes Mining and Smelting Company. World War I was a very active period, with mixed copper, lead, zinc, gold and silver production. This came mainly from underground replacement and contact metamorphic deposits and from practically all portions of the district. Some of these operations continued intermittently until the 1929 depression.

Jan 1, 1976

By Bright Oppong Afum, Kojo Boakye, Kwaku Boakye

This research developed and simulated a novel multi-indicator Fatigue Detection and Alert System (FDAS) designed to enhance fatigue detection accuracy in mining environments. The system integrates a comprehensive set of inputs: eye blink rate, eye closure duration, yawning frequency, distraction levels, Pre-shift Check-in Scores (Self-report) and Electroencephalography (EEG) Levels. Using MATLAB’s Fuzzy Logic Rule Viewer (FLRV) and Simulink, simulations demonstrated the FDAS’s robust ability to process these diverse physiological and behavioural indicators accurately. It effectively classified operator fatigue into low, moderate, and high fatigue levels, consistently providing appropriate outputs and corresponding intervention recommendations across various mixed-signal scenarios. The system achieved a calculated accuracy of 85.19% across 27 test entries, with a standard deviation of approximately 1.8459, confirming its reliability for real-time fatigue monitoring. These findings highlight the significant potential of this fuzzy logicbased approach to proactively identify early signs of fatigue, substantially enhancing safety and operational efficiency in demanding mining operations.

Feb 22, 2026

By Lauren M. Roberts, Ralph R. Sacrison

Pipeline or borehole free-fall transfer of material has long been done in support of underground mining. This paper addresses some characteristics and design elements in selecting systems suitable to the transferred media and the mine requirements. Though aspects of overall systems are discussed, principal attention is directed to the slickline/dropline/transfer line and the discharge diverter/rockbox/energy dissipator/boot. These terms are common to these systems, often used interchangeably, and will be used as appropriate to the material, equipment and construction. Following several design sections, fabrication and construction, and system operating and maintenance procedures are discussed.

Feb 1, 2025