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By T. G. P. Vasquez

The elimination of metal ions from aqueous solutions by biosorption plays an important role in water pollution control. Heavy metals are hazardous to the aquatic ecosystem and pose possible human health risk. Beside the toxic and harmful effects to organisms living in water heavy metals also accumulate throughout the food chain and may affect human beings. Conventional methods for removing metals from aqueous solutions before they are disposed of include chemical precipitation and sludge separation, chemical oxidation or reduction, ion exchange, reverse osmosis, electrochemical treatment, and evaporation. Alternative processing methods are being considered more seriously. Sorption and/or complexation of dissolved metals species based on the chemical activity of biomass, known as biosorption, is the base of the new technology for metal removal and recovery. Different types of biomass (dead and alive) have been investigated for biosorption of heavy metals ions. In the present work, the cadmium biosorption capacity and bioflotation of Rhodococcus opacus were studied. The adsorption capacity of biomass was investigated by batch experiments, the influences of some variables like pH and ion concentration were evaluated and the experimental data obtained for each metal were evaluated and fitted using adsorption and kinetic models. The bioflotation process showed that R. opacus has excellent features as collector and foaming agent after metal biosorption. Around 90% of cadmium uptake by the biomass was achieved by bioflotation.

Jan 1, 2006

By R. M. Damodaran

The flotation performance of Florida phosphate rock was evaluated in terms of the mixing behavior of reagents and particulates during anionic conditioning of phosphate slurries. The various conditioning variables that influence mixing, namely, solids loading, agitation speed and conditioning time, were investigated to determine their effect on reagent coating of the particles. The phosphate recovery was used to monitor the conditioning efficiency. The mixing characteristics of the phosphate feed were evaluated in terms of the ratio of the mixing power (P) to the minimum power (Pm) required to keep the slurry in suspension. It was found that mixing conditions govern the conditioning time required to obtain a high recovery. Reagentization was slower at lower P/Pm ratios. At higher P/Pm ratios, the flotation recovery was optimized, and the agitation speed was found to have no significant effect. Optimum mixing conditions were obtained for a74 wt% slurry at an agitation speed of 450 rpm (47 radians/sec). Under these optimum mixing conditions, the collector dosage required for an improved recovery was lower and the conditioning time was shorter.

Jan 1, 1997

By G. Schriever, H. Thiel, E. J. Foell

A long-term, large-scale, disturbance-recolonization experiment with relevance to the environmental effects of deep seabed mining is described. The study is funded by the German government and was launched in the abyssal eastern tropical South Pacific Ocean in February-March, 1989. After obtaining pre-impact baseline environmental data, a 10.8 km2 (4.2 sq miles) circular area of seafloor was disturbed using a specially designed "plow-harrow" device. An initial post-impact sampling series was carried out immediately after disturbance followed by a second post-impact sampling series six months after the disturbance. Plans call for repeated visits to the site at two year intervals to monitor the anticipated slow recolonization process until the area is inhabited by a new, stabilized community.

Jan 1, 1993

By Jorgen Elbrond

Before and in the early stages of industrialization, mining was the undisputed leader in technology. It represented the high-tech of the time. Early mechanization bears witness to that. Hoisting and rock breaking driven by waterpower are such examples. The mines' use of the steam engine was a major incentive to its development. By these means new mines could be opened and more metal supplied. Understanding of systems was essential for miners when shaping the infrastructure of the mines for the transportation of ore, material and men and for the evacuation of water and for ventilation. The irrigation systems of ancient mines are such examples. However, with the industrial revolution other more specialized branches of industry advanced further, and the mines became users of other industrial branches technologies. The mining industry had, however, always been quick to recognize a good thing and use it, when time was right. But, compared with other branches of industry, the mining industry has the disadvantage of working in a rugged environment with (and actually inside) a raw material which is abrasive and highly variable with respect to mechanical properties. This determines the rather high unpredictability of mining machines' performances and their low availabilities and explains a part of the delays in introducing technological advances.

Jan 1, 1989

By G. S. Dobby, N. J. Contini, S. W. Wilson

Scale-up and simulation of flotation columns requires construction of mathematical models which employ, as a minimum, rate constants for quantifying particle recovery in the collection zone as well as split factors for quantifying froth zone performance. To date, measurement of these rate parameters has proven to be difficult, due to the interdependent nature of the collection and froth zones. This paper describes a technique for making these measurements. The method requires recovery data from two modes of operation: countercurrent and cocurrent. In cocurrent flow slurry is fed at the bottom of the column and tailings are withdrawn a short distance below the froth interface. Countercurrent mode is conventional operation. The critical difference is that particles which are dropped out of the froth in cocurrent mode are immediately lost to tailings, while in countercurrent mode the particles are subjected to recollection. Fitting of the measured recoveries to the equations that describe flotation in the two modes yields rate constant or recovery values for both the collection and the froth zones.

Jan 1, 1988

By K. H. Al-Rawahy

Appreciation and awareness of the unique nature of mineral investment and ultimate development of a mine are crucial in promoting sustainable development. Special characteristics of mineral development include high capital intensive, long pre-production period, high risk, and the unavoidable ?economic? depletion. This paper examines ways to integrate these unique attributes of the mineral industry into the educational process, so that a properly advised and knowledgeable culture in terms of a sustainable mineral industry can be developed. Specific approaches are investigated in order to achieve this objective. These include a stochastic evaluation of a mineral investment proposal, adding a premium to the cost of capital that is used for valuation process, and internalizing incidental costs to the private cost function, thereby realizing the true (vs. apparent) marginal social cost of the proposed development. Undoubtedly, a total evaluation of any mineral project that accounts for both tangible and intangible parameters will contribute to sustainable development objectives. By incorporating the practical application of apparent theoretical topics such as risk, probability, and externality, and their relevance and impact on mineral lifecycle (prospecting, exploration, development, exploitation, use, and ultimate disposal) into the educational process, it is hoped that a generation of technocrats and decision makers that are familiar with and concerned about sustainable development will emerge.

Jan 1, 2007

By M. Makarenko

The sandstone type Devladivske uranium deposit is located within the limits of Eocene pale-ovalley filled with alluvial sediments. Mineralization with uranium content up to 0.1% forms several ore beds divided by redox barriers. In the period 1962-1983 the deposit has been exploited over an area of 918000m2 by in situ leaching (ISL) using drillholes with a depth between 35 and 100m. During mining operation about 200,000 t of H2SO4, 6,300 t of HNO3, and 15,000 t of NH4NO3, have been pumped in the ore body. In 1983, the groundwater pollution aureole had a length of 4.5 km and a width of 400-600 m. There is a hydraulic connection between the uranium-bearing aquifer and both the upper and lower ones. The technological solutions used for ISL caused partial contamination of these horizons. After mining completion, dilution of the residual technological solutions with "pure" natural waters took place through gaps in impermeable sediments between aquifer horizons. Calculation of self-purification process kinetics shows that the sulfate ion pollution aureole will disappear approximately after 120-150 years at a distance up to 2.0-2.5 km from the western margin of the deposit. This means that there is no risk for contamination of the river Saksagan? that flows at a distance of 17km from the deposit.

Jan 1, 2005

By K. N. Han, Q. Xu

The adsorption behavior of gold in ammoniacal solutions on activated carbon was studied. The gold adsorption capacity of the activated carbon and the recovery efficiency were examined. The parameters affecting the adsorption of gold on the activated carbon included temperature, agitation speed, the concentration of cation and anion and the concentration of ammonia. It was found that the maximum gold adsorption was about 10 kg/t of carbon. The recovery of gold by the adsorption, from ammoniacal solutions was found to be dependent upon the initial gold concentration. Under experimental conditions, a gold recovery of 98% was obtained after 120 hrs of adsorption. It was also found that the initial adsorption rate was relatively fast, when compared to the entire adsorption period. The apparent activation energy for the adsorption was determined to be 15.8 kJ/mol. It was believed that the kinetics of gold adsorption on the activated carbon was controlled by pore diffusion.

Jan 1, 1997

By M. R. Wormald

A real time data acquisition system has been developed for implementing standard radiometric analytical techniques, applied to the monitoring and control of mineral processing plants. The system uses standard ECB-bus microprocessors and peripherals, in conjunction with a specially designed nucleonic pulse ADC. It is being applied to the accurate on-line analysis of naturally-,occurring radioelements in processing plants, for example by simultaneously measuring the intensity of 1.46 MeV gamma-rays from the naturally-occurring radioisotope K-40, and the stream density by gamma-ray transmission of 662 keV gamma-rays. Gain stabilisation of the NaI(T1) scintillation detectors is maintained by the microprocessor in slave units, each of which may control up to four sample presentation systems. Data analysis - including corrections for bulk density, radioactive decay of the Cs-137 gamma-ray source, pulse pile-up, dead time and external background - is carried out in a master computer which is connected to the slave unit, and can be interfaced to the plant control computer via data links.

Jan 1, 1986

By N. B. Aughenbaugh

Compacted, fine-grained soils, often referred to collectively as clays, are used as permeability barriers in many mineral engineering projects such as heap leaching, containment ponds, tailings disposal and earth dams. Source materials for these liners include a variety of sand, silt and clay admixtures. These exhibit dramatically different engineering properties when densified. Therefore, it is imperative to adequately assess and characterize any soils being considered for compacted liners. The permeability and plastic properties of fine-grained soils are reviewed with respect to the state of compaction as the water content varies. Because they are weak in tension, compacted clays are susceptible to cracking when subjected to differential flexural movements. Designs of compacted clay liners also must include an evaluation of their flexibility. That is the ability of a fine-grain soil to bend plastically without cracking. This paper will also discuss the importance of flexibility with respect to soil types, compaction effort, failure mechanism and testing evaluation to the performance of clay liners in preventing seepage of pollutants from a containment site.

Jan 1, 1991

By John E. Urbanic, William D. Faulkner, Robert W. Ruckel

Guidelines are presented for the selection, handling and regeneration of activated carbon used in gold recovery operations. The guidelines are based on Calgon Carbon Corporation's own investigations and experience gained in working with gold mine operators all over the world. Gold adsorption rate and adsorption capacity are shown to be independent variables thereby requiring testing of both properties when selecting activated carbon. Means of measuring these properties are provided. Historical activity tests on activated carbon are shown to be minimally useful in selecting carbon for gold recovery. Proper thermal regeneration techniques to maximize recovery of adsorption rate without weakening the carbon structure are suggested. Simple positive means of measuring efficiency of regeneration are presented. The subject of hardness measurement as a predictor of "in process" abrasion is discussed. The cost/benefit issue of carbon activity level is addressed.

Jan 1, 1986

By Simona Markic

With the aim of environment protection the program package HOMOGEN is used for realizing the planning and noxious components control in the coal produced. Using the program package PRIPREMA the division in levels and transformation (Hermite polynoms) in the N (0,1) distribution are made. By separated kriging 50 m x 50 m blocks are estimated on the levels and detailed distributions of the estimated component content are obtained. The face - longwall face is built in the blocks estimated in this way, and the direction of mining is determined. Using the stochastic simulation the distribution of the estimated production component (e.g. sulfur) on the face is obtained. Simulating the production of all faces in operation the distribution of the estimated daily mine production component is obtained. The estimated depot component is obtained in the same way. This procedure is used in the short-term planning of the estimated component movement for a given period in advance, and also in the daily production control in the case of changing conditions, e.g. the increased atmospheric pressure. The technology is successfully applied to the Velenje Lignite Mine Slovenia.

Jan 1, 1992

By I. Stavrakas

This work studies the variations of the electric current caused by the application of an electric field on marble samples when they are subjected to continuously increasing mechanical stress at a constant rate up to fracture. The external electric field is applied in a direction perpendicular to the applied mechanical stress. An increase of the level of the electric current was observed when micro-damages started to occur in the samples. The increase of the electric current was approximately 14%. Consequently, the current started to decay abruptly and the sample failed. This electric current recording is compared with the corresponding electric recording without applying the external electric field (Pressure Stimulated Current technique). Both recordings show similar qualitative characteristics. The most obvious of these characteristics are that the electric current starts to develop when microcrack structures start to form due to the externally applied stress. Both recordings show a maximum in the vicinity of fracture.

Jan 1, 2008

By E. C. H. Becker

When data points, plotted on X-Y coordinates, lie along a simple line, their regression can be matched to a high degree of accuracy by one or other simple algebraic expression (Boot and Cox, 1970). Under these conditions, interpolation is axiomic. Further, if the expression defines no more than a straight line, a parabola or other such line which can be related to some specific mechanism which generates the points, then extrapolation might be valid. However, any extrapolation would depend on the continued, unchanged functioning of the mechanism. Studies of more intricate assemblages of data points have long been based on representation by means of series (Fourier, 1811). If sufficiently complicated, several different algebraic expressions can represent the same intricate regression accurately (Hoerl, 1954). However, without reference to a mechanism, no extrapolation is contemplated. Typically, variations in the prices of minerals with time are. sufficiently complicated to render invalid any simple attempts at extrapolation. The computer, however, can be used to derive algebraic expressions which match complicated regressions and also can be represented by the functioning of a mechanism (Becker, 1984). The techniques involved have been applied with advantage in the study of time series representations of mineral prices.

Jan 1, 1986

By Charles Fisher

When considering the biodiversity of fauna endemic to hydrothermal vents or hydrocarbon seeps one must consider not only the numbers of unique species, but also the physiological diversity (and potential biochemical/physiological uniqueness) of the fauna. The deep ocean ridge system is home to some of most extreme animal habitats found on Earth. In addition to the high pressure, low temperature, and lack of light characterizing the deep-sea in general, hydrothermal-vent environments are characterized by toxic chemicals and temperatures that would be hostile to most other animal life. Perhaps even more challenging than the absolute levels of chemicals, dissolved gases, and temperature with which vent animals contend are the extreme gradients in time and space of all of these parameters. For example, temperatures around some vent animals can fluctuate from ice-water to hot-tub levels over seconds and can exceed 350°C only inches away. Specially adapted animals not only tolerate these conditions, they often thrive under them. As a result, the biomass of many deep ocean ridge ecosystems rivals that of coral reefs and tropical rain forests. In the Gulf of Mexico, hydrocarbon seepage through the sea floor driven by salt tectonics results in environments that are geologically very different from hydrothermal vents, but are geochemically similar enough that closely related animals are found in the two habitats. This includes seep mussels, clams, shrimp, worms, and other animals whose close relatives are found in hydrothermal vent environments. Although many aspects of the biology of the animals from the two environments are very similar, there are also significant differences in their life histories and physiologies that reflect the fundamental differences in the geology of their habitats.

Jan 1, 2008

By Lawrence Neal Post

Introduction Synthetic soda ash production began to decline in the late 1930s. This was due to high operating costs and waste disposal problems. Since soda ash was used as a major component in manufacturing glass, an alternate method of producing that chemical was necessary. A process to produce soda ash from trona was developed by FMC Wyoming Corp.'s predecessor, as well as an economical way to obtain trona. Existing trona operations are located about 40 km (25 miles) west of Green River, WY. Five operators presently mine trona in this area. FMC's property has 153 km2 (59 sq miles) leased. Its eight shafts reach 488 m (1600 ft) deep to the uniform trona deposit. The seam ranges in thickness from 2.4 to 3.6 m (8 to 12 ft). History Egyptian tombs, dating from 4000 to 3000 BC, contained mummies preserved by an embalming process using soda ash. For many years, soda ash was produced by burning marine plants, then dissolving the soluble material (sodium carbonate) from the ashes. The name soda ash is derived from this method of production. In 1791, Nicola LeBlanc developed black ash, or salt cake, from salt, sulfuric acid, coal, and limestone. This process remained in use until 1863, when Ernest Solvay developed a method for producing soda ash from salt, coke, and limestone with ammonia as a catalyst. This Solvay process was widely used. And, in the 1930s, there were 17 plants in the US alone. High plant operating costs and waste disposal problems, however, necessitated finding an alternative to the Solvay process.

Jan 10, 1985

By I. Tsolas

Sustainable development is becoming increasingly more important for the mining industry and therefore mining companies should be able to measure their progress towards sustainability. Greek Public Power Corporation (PPC) S.A. is a company which produces lignite in open cast mines in Western Macedonia and in Peloponnesos. The present paper uses operational data kindly offered by PPC S.A. to derive sustainability indicators by means of Data Envelopment Analysis for three large scale lignite open cast mines of PPC (i.e. Main Field, Kardia Field and South Field mines). It also examines three environmental parameters related to the contribution of these mines to sustainable development; namely, the annually produced volume of waste masses, the annually produced quantity of ash from the lignite combustion and the annual volume of pumped water. The calculated sustainability indicators were keeping constantly better during the last years of the different periods for each one of mines studied here, showing that the mines met their goals from both economic and environmental aspects during the last years of their operational periods studied. The contribution of open cast lignite mines studied here to sustainable development can be monitored by the derived indicators analyzing annual mine operational data. The derived indicators can serve as tools to detect where improvements can be made, though another potential use of these indicators can also be during the preparation of feasibility studies or environmental impact studies using necessary benchmarking data.

Jan 1, 2007

By Thomas W. Traylor

Today, in Detroit, Michigan, a 14 ft. 6 in. diameter soft ground tunnel is being mined at penetration rates limited only by the logistics of liner handling and spoil removal. Soil conditions are highly variable and include clays ranging from very plastic to very hard, gravels, sands, silts and boulders. The permeable soils contain high concentrations of methane gas, compressed by groundwater levels some 40 ft. above tunnel invert. Despite these adverse conditions, mining crews frequently complete their 70 ft. production quota in six hours and go home. In one 4000 ft. reach of tunnel, progress averaged 68.9 ft. per mining shift. This paper has been written to explain this extraordinary accomplishment, and to demonstrate that truly continuous rapid excavation in difficult grounds is now limited by factors other than the excavation process itself. BACKGROUND The Detroit metropolitan area has a long and interesting history of soft ground tunneling. From 1949 to 1968 the city of Detroit alone constructed some 75 miles of soft ground tunnel. During this period the development and common usage of rotary or "wheel-type" soft ground tunneling machines was pioneered in the Detroit area. These machines are designed for, and were successful in, the cohesive or clayed soils that predominate the downtown Detroit geology.

Jan 1, 1997

Coal fly ash and flue gas desulfurization (FGD) sludges can be returned to mine pits, fills and revegetation zones in Virginia by regulation if (and only if) a positive beneficial use can be shown. Utilization of alkaline fly ash for control of acid drainage from pyritic coal processing waste piles, and use as a soil amendment for revegetation, are the two dominant beneficial uses proposed over time. Both applications must be controlled by the basic chemical properties of the ash proposed for utilization. Currently, public concerns over long-term As and Se leaching from various applications are increasingly driving regulatory options for mine site utilization. Many fly ash materials are relatively low in inherent alkalinity or neutralizing ability, and certain ashes are actually acidic. Failure to add sufficient total alkalinity will result in strong acidification of the ash utilization zones, stripping heavy metals like Mn, Zn and Cu from the fly ash matrix. Similarly, if alkaline ash is loaded into non-acid forming coal wastes at high rates such that leachate pH is > 9.5, significant leaching of As and Se has been documented in large scale laboratory leaching columns. Utilization of fly ash and FGD as a mine soil amendment for revegetation is based upon combined liming and water holding capacity benefits, however, levels of soluble salts (primarily sulfate and borates) limit one-time application rates to 100 Mg/ha or less.

Jan 1, 2006

By G. B. Misra

Heat transfer in partially wet mine airways has been the subject of study for quite some time. Of the available models some are quite empirical while some involve highly complicated computation. Models developed by Amano, Mizuta and Hiramatsu and Banerjee and Chernyak as well as that modified by Misra were evaluated for prediction of the rise in temperature and humidity (mixing ratio ) of partially wet mine airways at four different levels in the Mosaboni Mine of Hindustan Copper Ltd. Measurements of barometric pressure, virgin-rock temperature and changes in dry- and wet-bulb temperatures along a certain length of airway were made. The rise in dry-bulb temperature and mixing ratio of air over the sections were calculated using the three models. The study reveals that calculated values of temperature and moisture content agree within possible rage of experimental error with all the three models in case of three levels with low wetness factor, but the agreement was poor for the relatively more wet airway on the 30th level. Errors in the estimation of fw to the tune of 0.025 can lead to fair error up to 0.94 K in the estimated temperature while alternative ways of estimating the heat transfer coefficient [] can introduce errors up to 1.45 K.

Jan 1, 1987