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By James W. Evans

It appears that all extractive processes involve, at one or more points, fluids (gases or liquids) and that the flow of the fluid is an essential part of the functioning of the process. Usually that flow is turbulent and the turbulent flow frequently determines the rates of mass and heat transfer as well as other important phenomena such as bubble/droplet breakup and coalescence, particle suspension, etc. Over the past decade many attempts have been made to model turbulent flows in metallurgical unit operations. The present paper summarizes some of that work. Amongst the operations considered are agitated leaching, ladle metallurgy, electrowinning/refin- ing, induction furnaces, Hall cells and electro- magnetic casting. Where possible, comparisons are made between model predictions and experimental results.

Jan 1, 1990

By Sushil Bhandari

A computer model is developed for the problem of dispersal of dust (suspended particulate matter) resulting from blasting operations in surface mines. Undulated surface (lower boundary) simulation was carried through sixth order polynomial by least square approximation. Segmentwise terrain simulation was linearly added to build ground feature extending either side of the blast location. Assuming the initial dust concentration in the vertical column to. be uniform and treating the finite vertical line sources as a series of point sources to height, H varying from zero to top of the dust mushroom, integration was done of the concentration effects from H = 0 toL tan[0] (L = horizontal distance of the blast location and [0] is the angle of the top of dust cloud from the point of observation). Using frame of reference moving with the mean wind, the ground level 'concentration (GLC) has been computed over the undulated terrain. Standard deviation (s) of concentration has been parameterized based on mixed layer similarity theory in convective boundary layer.

Jan 1, 2002

By Malcolm J. McPherson, Satya Harpalani

A thorough knowledge of coal permeability and its variation with factors like stress conditions, and time, is useful in simulation studies of mine ventilation and coalbed methane recovery, as well as characterizing coalbed methane reservoirs. An experimental investigation was carried out to study the gas flow characteristics of coal to enhance the under- standing of the mechanism of methane flow through it. The work consisted of measurement of permeability of coal samples under triaxial stress and an examination of the physical structure of coal using electron microscopy. Effort was made to fit the experimental data to several phenomenological models that have been used to describe fluid flow through porous media. It was realized that gas flow through coal cannot be described by models that assume this flow to be through a bundle of capillary tubes. However, results suggest that this gas flow could be predominantly through fractures and cracks in coal, and this could be represented by flow between parallel plates.

Jan 1, 1986

By Toyohisa Fujita, Mitsuo Mamiya, W. Tai Yen, Hiroki Kogita

Green algae taken from an acidic mine drainage and blue-green algae taken from an alkaline hot spring stream were collected and tested for their ability to recover or remove dilute metal ions. Experimental results demonstrated that unwashed blue-green algae and washed green algae effectively adsorbed base metals ions and eluted them at pH 1. It was also found that washed and dried algae adsorbed precious metal ions more effectively than unwashed algae. For example, the washed and dried blue-green algae was capable of adsorbing 0.31 kg of gold per kg of algae. The gold from tetrachloroaurate solution which was adsorbed on washed blue- green algae was found to change to a metallic state following initial metal binding. In the case of a dilute gold complex solution leached with thiourea, only a small amount of gold could be captured by algae. Further experiments were conducted on components of the algae, such as alginic acid, agar, cellulose and chitin and mixtures of these components, in order to determine their contribution to metal adsorption characteristics. However, a mixture of these two components demonstrated both good adsorption and desorption characteristics indicating an interaction between the individual components.

Jan 1, 1995

By V. Perdikatsis

The aim of this paper is the study of the pollution of soils in greenhouses because of the use of pesticides. The degree of pollution was studied in relation with the mineralogical and pedologic properties of the soil. The study was con-ducted in the region of Kountoura, Palaiochora, situated in the south of the prefecture of Hania/Greece. Several samples of soil, originated from 4 greenhouses were analyzed. 5 pesticides with organic drastic compounds were chosen for analytical determination using GC-MS from 18 which were applied in total during the period of sampling. It was concluded that the adsorption of pesticides in the soil of greenhouses is connected with the percentage of the clay fraction and the content of organic carbon.

Jan 1, 2006

By Z. C. Liu, F. F. Roxborough, Lin. B. B.

The size distribution of coal cut by a mining machine is an important performance factor. It is well established that the main machine system variable that affects product size is the depth of cut. In essence, the greater the amount of coal won by a machine cutting at shallow depths, the greater the proportion of dust and fines produced. Conversely, deep cuts produce less dust and a generally larger product size. When cutting with a rotating drum, as well as with a longwall shearer, the depth of cut always varies from zero in the vicinity of the roof and floor, where most of the dust and fines are produced, to a maximum at mid-drum level. In this paper, minimizing the amount of shallow cutting with a cutting drum is discussed, and the effects of the drum cutting and design parameters on cross-sectional cutting area per revolution are analyzed. This study shows the following: •more shallow cutting occurs during the entry quadrant of a cutting cycle than during pick exit; •the ratio of the projected area of shallow cutting to the total projected area of cutting by a single pick per drum revolution is virtually the same for drums of different radii (however, it decreases as the maximum depth of cut increases); and •for double drums, the use of unequal drum diameters can reduce the production of dust and fines, compared to using drums of the same diameter.

Jan 1, 1998

By Catherine M. Dentan, Yosry A. Attia

The presence of finely divided carbonaceous matter, particularly graphite, in gold ores, adversely affects the adsorption - recovery of gold by activated carbon from cyanide solutions of such ores. Competitive adsorption of gold by graphite and other carbonaceous matter, is thought to be responsible for this deleterious effect In this study, adsorption of gold cyanide complex AU(CN)2- by the activated carbon used in carbon-in- pulp or carbon-in-leach processes, was compared with that by graphite which was chosen to represent the carbonaceous matter. Similar adsorption studies were made with gold chloride complex AuC14-. Correlation of adsorption with surface characteristics and thermodynamics were presented in detail, and a flowsheet for graphite-in-leach was proposed.

Jan 1, 1990

By R. J. Sweigard, G. T. Lineberry, B. K. Slone, F. A. James III, D. S. Maggard

The depth at which it becomes more economical to use slope access instead of box-cut access for nearsurface coal reserves is termed the "transition depth." The transition depth can be established for a given coal property by considering cost estimates for those parameters that determine respective access methods. Fourteen parameters that influence access cost were identified, and ranges for these parameters were determined. A transitiondepth formula was developed to permit the determination of which is the better method of accessing a reserve, given information such as high wall slope, road width, total bench width, pit dimensions, road grade, belt component costs, pumping costs and the cost of overburden removal and reclamation. In most cases in Appalachia, especially in eastern Kentucky, the observed transition depth ranges from 20 to 30 m (66 to l00 ft). This indicates that actual practice is consistent with the analytical approach used.

Jan 1, 2002

By Y. Wang, E. Forssberg

Wet magnetic separation methods for the recovery of hematite and chromite fines and ultrafines were investigated. These methods included wet high-intensity and high-gradient magnetic separation, carrier or "piggy-hack" magnetic separation, magnetic field-induced aggregation and magnetic seeding. This investigation indicated that wet magnetic separation is more efficient for fines and ultrafines. This investigation also indicated that other methods can be used to enhance the particle aggregation and/or the magnetic response. The magnetic behavior of these minerals with respect to the magnetizing field, temperature and particle size is also presented.

Jan 1, 1995

By Arthur W. Darby

Heathrow Airport is owned and operated by BAA who are engaged in a major programme of expansion. In order to link the expansion of the airport in the west with the existing central terminal area, a twin bore, 8.8m outside diameter, road tunnel,1280m long, is being constructed. The tunnel drives pass over, with limited clearances, an operating railway tunnel, and pass under, with about one diameter cover, the airport taxiways and aircraft stands. Selection of the machine was heavily influenced by the need to minimise settlement.

Jan 1, 2003

By A. A. Kornyshev, M. Burstein, S. T. Hall

The surface "roughness" of mineral particles has long been known to influence the fundamental process of particle-bubble attachment and other subprocesses in froth flotation. The physical nature of the surface of fine mineral particles can be analysed by determining their fractal geometry. A number of techniques are available to measure the fractal properties of mineral particles, these include gas adsorption, mercury porosimetry, neutron or X- ray scattering and image analysis. From the resultant Richardson plots or their Fourier-space analogs, the fractal dimension of flotation feed and product samples can be determined. Textural characteristics of particles have an influence on the stability of 3-phase flotation froths and the selectivity of recovery in the froth. Decrease of the equilibrium froth height for particles of higher fractal dimensions was experimentally established. The induction time of quartz particles of different fractal geometry has also been studied.

Jan 1, 1995

By Tanya Arsh, Thomas P. Kwiatkowski, Heather Marsh, Barry Doyle

The Big Walnut Sanitary Trunk Sewer Extension Project consists of two segments, the first a 10' excavated diameter tunnel in rock through the gas producing Ohio Shale formation and the second will be microtunneled through unconsolidated water-bearing deposits. Relatively large quantities of methane gas have been encountered in the Ohio Shale. In the softground segment, the sands and gravels contain large water storage capacity and contain shallow residential wells. This paper will present an evaluation of potential gas inflows in the rock tunnel, design considerations for contract documents preparation to inform bidders as to the volumes of gases which may been countered and design options for construction of an impermeable shaft excavation support system to insure residential wells remain in service.

Jan 1, 2001

By P. Somasundaran, Bruno Lartiges

Two different groups of mechanisms have been considered in the past to explain the effects of chemical additives on grinding. While one group of explanations is based upon alterations of surface and mechanical properties of the individual particles, the other group depends mainly on the arrangement of particles and their flow in suspensions. In this paper some of the past work on grinding aids is reviewed and attrition grinding of a commercially important ceramic material, zirconia (stabilized with yttria) with polyaaylic acid as grinding aid, is studied in order to determine the effect of the aid on the ground product itself. It was observed that even though polyaaylic acid did cause a drastic decrease in the viscosity of the pulp, it did not have any major effect on the grinding of zirconia at least up to 2000 ppm and only minor detrimental effect above it. Importantly, complexation by the polymer was found to cause extraction of yttrium into solution with possibly significant changes in the surface chemical composition of the product.

Jan 1, 1992

By Judith M. Ballantyne

Carlin-type. disseminated, sediment-hosted gold deposits can be better described as hydrocarbon-associated gold deposits. A new genetic model for these deposits involves the intrusion of one or more small bodies of magma into a shallow hydrocarbon reservoir or ma of hydrocarbonenriched rocks, imposing a convecting geothermal system on the local groundwater. Pyrite, commonly associated with the organic material, provides a substrate for deposition of gold and other trace elements in an environment rich in dissolved sulfide. Both diagenetic and hydrothermal pyrite may act as gold depositional sites. Thermal cracking of hydrocarbons, catalyzed by illite, subsequently generates an oxidizing environment by depleting hydrogen. As oxidation increases, arsenic sulfide minerals and barite m stabiied at first. Increasing hydrogen depletion converts sulfide to sulfate, generating acid oxidizing conditions which: alter pyrite to hematite; continue the deposition of sulfates; and ultimately develop late stage acid-sulfate assemblages containing minerals such as kaolinite. alunite. and jarosite. Gold released from the oxidizing pyrite is redeposited as free gold, and pehaps remobilized.

Jan 1, 1988

By S. Chander

A comparison of gold, platinum and sulfide ion selective electrodes was made for determination of Eh in solutions containing hydrosulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. The sensitivity of each electrode towards changes in hydrosulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of hydrosulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1992

By Richard Meriwether Smith

Mining-related earthy bodies in contact with the atmosphere are now counted, generally, as minesoils. Because soils within this broad category are extremely young the influence of parent material is stronger than in older soils, where climate, organisms, and topography have had time to interact with near-surface rocks to form more distinctly differentiated profiles. Understanding of minesoil properties and processes is aided by definitions of rock types in terms of chemical, physical, and mineralogical characteristics that are, with some degree of consistency, translatable into soils. Geological correlations based on age or sedimentary sequences are helpful if they assure details of mineralogy and lithology, but our pedologic objectives demand that any conflicts involving rock types must be resolved in favor of distinctions having strongest implications for soil properties after mining. Chemically this approach emphasizes accounting of potential acid-base status, plant nutrient availability by adapted and calibrated extraction procedures, and absence of biotoxins. Physically it anticipates particle sizes, shapes, and arrangements in readily pervious soil profiles that will favor plant growth with desired levels of moisture and oxygen. Concurrently we are considering soil property suitability for uses other than growth of plants. Above all we need to be able to predict pedogenic processes in the particular environment, including rate as well as direction of chemical and physical change.

Jan 1, 1974

By A. S. Mallicis, Li Xiawoei, P. W. Weiblen, I. Iwasakl

Platinum group metals (PGM) are often found in close association with arsenide and sulfarsenide minerals in copper-nickel bearing gabbroic rocks. Major losses of platinum in flotation have been attributed to the susceptibilities of the arsenic minerals to oxidation and subsequent losses of their recoveries in cleaner flotation stages. The use of a nitrogen atmosphere in grinding and in flotation, the effectiveness of activation for improving their floatabilities, and the role that electrochemical interactions play not only between grinding media and minerals, but also among different minerals, are discussed.

Jan 1, 1989

By E. D. Goddard, D. S. Murphy

Acid resistance, zeta potential and ESCA (electron spectroscopy. for chemical analysis) experiments were performed on emperador marble and four calcium carbonate samples (onyx calcite, travertine calcite, Iceland spar calcite and aragonite). Six fluorine-containing reagents were used to treat the surfaces of these materials: magnesium hexafluorosilicate, zinc hexafluorosilicate, sodium fluoride, zinc fluoride, strontium fluoride and stannous fluoride. The acid resistance of treated samples proved to be much higher than that of their untreated equivalents. The isoelectric point of treated samples approaches the isoelectric point of fluorite. Also, the fluorine content, as measured by ESCA, of a marble surface treated with magnesium hexafluorosilicate is much higher than that of an untreated sample. The binding energy off of fluorine and calcium the treated marble is consistent with the formation of calcium fluoride.

Jan 1, 1994

By John O. Marsden

The project development metallurgist is faced with an interesting dilemma: The use of overly conservative metallurgical projections and cost estimates can kill a project that has the potential to provide needed jobs and growth to a company's bottom line. On the other hand if the metallurgist uses a highly aggressive approach by trimming capital and operating cost estimates to the bone and by applying highly optimistic metallurgical projections, there is a risk of creating a project that can never live up to expectations. The metallurgist must walk a tightrope between "sandbagging" and "overoptimism," and this tightrope is fraught with political intrigue and difficulty. This paper takes a some- what lighthearted look at some of the political aspects associated with this issue, and other issues, and offers a few guidelines for walking the "political metallurgical" tightrope.

Jan 1, 2001

By J. H. Lalor

The Olympic Dam deposit was discovered in July 1975 with the intersection of 38 m (125 ft) of 1.05% copper in diamond drill hole RD 1. A further eight holes were drilled with only marginal encouragement to November 1976 when RD 10 cored 170 m (558 ft) at 2.12% copper and an economic discovery was confirmed. The discovery of Olympic Dam is an excellent example of the application of broad-scale scientifically based conceptual studies to area selection combined with the backing of an exploration management willing to support its exploration scientists in testing their ideas with stratigraphic drilling. It also illustrates the persistence required in mineral exploration. The project began in 1969-1972 with the development of a conceptual model for the formation of sediment-hosted copper deposits. This model suggested that the alteration of continental-type basaltic rocks could release copper into solution from which it could be concentrated in favorable stratigraphic positions. In mid-1972, this concept was applied to a review of the Proterozoic and Lower Paleozoic rocks in South Australia aimed at defining targets for stratigraphic copper deposits.

Jan 1, 1991