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By R. D. Hancock

The complex responsible for the poisoning of anion-exchange resins is identified as the anionic cobaltic penta¬cyanide mono aquo species. It is shown that, at high concentration, this species polymerizes in solutions of pH less than 9. A mechanism for poisoning is presented that involves adsorption of anionic cobalt cyanide by a normal ion-exchange process, followed by polymerization within the resin matrix to form complexes that are too large to diffuse readily through the resin pores. The effects of resin structure and functionality on the extent of cobalt poisoning are examined, and the effect of cobalt poisoning on the kinetics and equilibrium loading of uranium is discussed.

Jan 1, 1979

By N. A. Barcza

Pointing out that South Africa needs to utilize its wealth-creating activities, together with local and international investment, to further develop its industries, the address asserts that the mining and minerals industries, especially in the manufacture of beneficiated products, offer the greatest potential for South Africa to achieve its goal. As many mineral-beneficiation processes are based on pyrometallurgical routes, the address goes on to describe some historical - pyrometallurgical operations and to indicate probable developments in the future. These include growth in the fields of both precious and base metals. After discussing environmental and recycling matters, together with manpower requirements, the address concludes that the major growth in the mining and minerals industries will occur in the manufacture of steel, stainless steel, ferro-alloys (particularly ferrochromium), aluminium, and titania slag.

Jan 1, 1996

It is a great honour to officiate at the celebration of the centenary of the South African Institute of Mining and Metalurgy. Tonight's festivities bring back happy memories of my association with South Africa's mining industry during my tenure of office as Minister of Mineral and Energy Affairs. They also remind me of the illustrious personalities who have preceded me on this podium. The Pioneers They include Sir Percy Fitzpatrick, who spoke in 1909 on the eve of the Union, General Smuts, and, on many occasions during the 1920s and 1930, Jan H. Hofmeyr. The basic issues addressed by them continue to enjoy the Institute's attention today, namely the optimal and safe exploitation of our country's mineral resources and cost-effective extraction of minerals from their ores. Translated into the Institute's key objective it reads: To initiate and give effect to the means whereby the requirements for technology and scientific knowledge if the minerals and metals section if the South African economy is satisfied.

Jan 1, 1994

By D. S. Loubser

The technique of backfilling in the gold mining industry is dependent on the dewatering of slurry to form a solid support system. In many cases flocculants are added to the slurry to increase the rate of dewatering. To ensure that a stable support is obtained it is important that the chemistry, application and limitations of these flocculant additives are understood. Flocculant additives have to be added at a point where minimum shear will occur. (Shear occurs when a flocculant is exposed to excess energy resulting in breakdown, of the floc.) To ensure that optimum results are obtained it is important that personnel involved are trained to use the flocculant additives and dosing equipment correctly.

Jan 1, 1988

By M. B. Cortie

The historical development of materials engineering in the mining industry Is briefly reviewed, and some of the factors currently influencing the industry in South Africa are discussed. Material usages in various parts of the mining operation are surveyed. The predominant mechanisms in the degradation of materials in mines are wear, corrosion, and fatigue. The issue of corrosion-abrasion Is considered, but it Is concluded that abrasive wear predominates in most rock-handling and comminution applications and that, in general, little economic benefit Is to be gained in those applications by the use of existing corrosion-resistant alloys. However, alloys with a measure of corrosion resistance find profitable application elsewhere in the mining environment. The use of other engineering materials such as polymers, ceramics, al1l1inium, and various ferrous alloys may be economically viable in a variety of niche situations. Identification of the most cost-effective material in each case calls for a systematic approach and some patience.

Jan 1, 1996

By W. D. Grimsley, R. P. King, J. B. See

Samples (15 to 20 g) of pre-calcined Mamatwan manganese ore or pure Mn 304 smaller than 48 mesh were reacted at temperatures in the range 1000 to 1300°C with samples of spectrographically pure graphite smaller than 325 mesh. Samples (1 g) of ore or pure Mn02 smaller than 48 mesh were reacted at temperatures of 1000 and 1200°C with pure graphite fines in argon, with graphite in carbon, .'1onoxide, and with carbon monoxide alone. In each case, the loss of mass as a function of time was recorded with a hermobalance. The rate and degree of reduction were found to increase with additions of carbon and with increasing temperature up to 1300oC, when they reached their maximum. The shape of the reduction curves, together with the results obtained from examination of the products of reaction by microscopy and X-ray diffraction, were used as the basis for a postulated reduction mechanism. Some details are given of an initial kinetic model that was used to verify the proposed mechanism. It was found that the reduction of Mamatwan ore by graphite at temperatures in the range 1000 to 1300°C occurs in two stages: (i) an initial stage during which the higher oxides of manganese are rapidly reduced to MnO with concurrent formation of CaMn2O4 and (ii) a longer stage during which CaMn2O4 and MnO are reduced to carbides by carbon dissolved in the ferromanganese phase.

Jan 1, 1978

By N. R. Shoko, J. Chirasha

Refractory design remains the most fundamental factor in furnace construction. Refractory design details and proven technology consideration is of paramount importance to come up with an optimum furnace life and to maintain productivity in the life span of the furnace lining. The failure to produce a technically or operationally durable refractory design lining could give rise to pre-mature deterioration of the refractory lining and furnace shell. The premature failure of the furnace lining will lead to extensive heat losses, furnace bath shift, change in taphole orientation and alteration of the Pitch Circle Diameter. A combination of these were experienced at Zimbabwe Alloys? new high carbon ferrochrome furnace. The Zimbabwe Alloys experience has shown an excellent furnace performance in the first two years of operation although signs of an anomaly showed within the first six months of the new furnace. Production slowed down due to induced problems from refractory failure causing furnace distortions impacting on the availability of the furnace and smelting capacity. This paper presents the lessons learnt, measures taken to deal with the premature failure and constraints within which the situation was managed.

Jan 1, 2007

Cutting strong rock with a drag bit assisted by high-pressure water jets By M. HOOD. B.Sc. Hons. (Min. Eng.). B.Sc. (Mech. Eng.). A.M.I.M.M. (Visitor) Experiments are described that led to the discovery that coherent high-pressure water jets directed immediately ahead of drag bits while they are cutting strong rock reduce the magnitudes of the forces on the bits significantly. Tests were carried out to assess the effects of the pressure of the water jets on bit-cutting performance. The pressure was varied between 10 MPa and 50 MPa, the water flow rate being a constant 30 I/min. Over this pressure range, the force on the bit was reduced to the extent that the depth of cut of the bit was at least doubled with the point of impingement of the jets optimized. Forces on the bit were found to be particularly sensitive to the point of impingement of the water jets relative to the bit. The optimum configuration was found to be with two jets, one directed towards each corner of the bit and impinging on the rock approximately 2 mm ahead of the leading edge of the bit. Experiments in which a drag bit and high-pressure water jets were used to cut strong abrasive quartzite in the underground mining situation have demonstrated a potential increase of up to five times in the average depth of cut due to reduction of the forces on the bit. The results from the underground tests indicate that the life of the bit is improved significantly - by a factor of approximately two - when highpressure water jets are used.

Jan 11, 1976

By R. Morris, W. D. Clough

SYNOPSIS The design of an opencast coal mine over areas previously mined by underground mining methods presents several potential methods of mining the coal. The paper describes some basic methods of mining for the No. 2 seam of the Witbank Coalfield, which had previously been mined by the bord-and-pillar method.

Jan 1, 1985

By P. C. Seligmann

The theory of firing of electric detonators is developed insofar as it affects the design of blasting circuits. Practical values for the firing conditions suited to detonators of local manufacture are tabulated. The design principles of blasting circuits are outlined. This information can be used by mine management to ensure that electric blasting will be done efficiently and economically.

Jan 1, 1979

By R. Hummel

In the quest to reduce overall costs and improve operating efficiency, the application of GPS based technology in open pit mining has evolved significantly in recent times. Venetia Mine has been leading the way in the De Beers group in the implementation of these systems and the realization of significant benefits from them. Following on from the successful results and the notable benefits obtained from the Wenco Truck Dispatching system and the Caterpillar CAES system on the loading and dozing equipment, Venetia has implemented the first fully functional and integrated GPS based drill monitoring system in southern Africa to its drilling operations. This paper elaborates on the concept of drill monitoring and how the vision for the application of the system at Venetia has developed and been implemented. The paper further describes the workflow involved, beginning with the initial test work done with SSI Kaltex and the Australian Drill Advisor system through to the final details of the integration of the Aquila system with the CATERPILLAR Computer Aided Earthmoving System (CAES) and the alliance with SandvikRock Tools. Most importantly, the paper details the benefits that are derived from drill monitoring and the use of the information generated by such a system. Venetia has pioneered the move towards smart partnerships and alliances with strategic suppliers within the De Beers group. The area of drilling, as the important start of the entire mining process, has been no exception and the final part of the paper covers how drill monitoring provides vitally important information that enables a supply partnership, to function cost-effectively and profitably for both parties involved. By having the type of accuracy, detail, validity and timeousness in the information being received as a result of the implementation of such a system, better management decisions can betaken, creating a more focused and efficient mining environment. In these times of increasing costs and reduced commodity prices, the mining industry will be required to continue pushing the boundaries on these technology applications in order to remain competitive.

Sep 1, 2001

By D. A. J. Ross-Watt

Right now the South African mining industry is a high-profile, vital contributor to the nation just as it has been for the past one hundred and twenty-six years since the discovery of diamonds-perhaps even further back if the mining of copper, iron ore, tin, and other minerals in earlier centuries is included. The media in 1995, as has been the case over the years, bear testimony to the complex interactions between the industry and its stakeholders: shareholders, government, employees and their unions, training and educational institutions, researchers, markets, the public, and suppliers of goods, services, and infrastructure. The pressures and challenges that the industry continues to face can be summarized as safety and health, competitiveness, and social and environmental responsibility. There are no surprises here. The motivation for the industry to perform well in these areas is clear; the focus I intend to bring is on the most important tool required for success-that of good mining engineering. This Address sets out - to review the mining aspects that have been discussed in South Africa during the first five years of the decade, a discussion that shows the return of the country as an important mining forum, confirms the role of professional institutes and associations in the development of mining engineering, and brings current relevant issues into focus - to highlight the vital role of mining engineering in the industry, and to identify priorities for the remainder of the decade - to provide the prospective mining engineer, the mining-engineering student and trainee, and the practising mining engineer and mine manager with a better appreciation of the mining-engineering discipline. institutes and ssociations

Jan 1, 1995

By C. Chongo, F. X. Paquot, C. Ngulube

"Over the last six years, the Kansanshi copper-gold mine has continued to process significant quantities of complex transitional mixed ores. Initially, the ore treated came predominantly from accumulated stockpiles. Subsequently, the feed source shifted primarily to freshly mined ore that generally showed less tarnish with better flotation kinetics, but with the downside of lower concentrate grades. A number of changes were made to improve the efficiency of the rougher circuit and quality of concentrate produced. These changes were as a result of initial mineralogical studies and laboratory flotation test work that were discussed at length in a previous paper1. Salient among the recommendations adopted as a result of previous work were increased circuit capacity and a modified configuration to increase the residence time and the number of sulphidization stages. These modifications were completed and commissioned in 2011. This, however, resulted in significantly low rougher concentrate grades and a below-specification final concentrate product. This was due primarily to higher mass pulls from the extended rougher bank with multiple concentrate discharge streams, and which necessitated an enlarged cleaning capability. The extra cleaning capacity came on stream in 2014. Of note was the development of a recovery model, based on the strong correlation between the total copper and acid-soluble copper ratio, as a tool for monitoring plant performance. IntroductionThe Kansanshi mine, the largest copper mine in Africa, is 80% owned by Kansanshi Mining plc, a subsidiary of First Quantum Minerals. The remaining 20% is owned by the state through the parastatal Zambia Consolidated Copper Mines Ltd (ZCCM). The mine is located approximately 10 km north of the town of Solwezi and 180 km to the northwest of the Copperbelt town of Chingola. The mine has been in commercial operation since 2005."

Jan 1, 2016

By A. V. L. Narasimham

The practice of refractory lining in Fe Cr furnaces is purely based on the behavior of various refractories used in different parts of the Furnace at elevated temperatures. The choice of the pattern of lining is mostly done on traditionally based concepts. Refractory Lining of a furnace is the most crucial enabler for operational excellence for Ferro Alloys production. During the last few years, no major technological change has taken place in ?Refractory Lining Management?, only freeze lining concept is becoming popular. Many ferro chrome furnaces today, have the refractory lining problems especially at tap holes, resulting in shutdowns and production losses. The author with his experiences for the last 37 years in furnaces of all sizes tried to attempt to investigate into the reasons for premature failure of lining.

Jan 1, 2007

By J. H. Bulloch

The paper gives an assessment of the available data on the linear elastic fracture mechanics involved in stress corrosion cracking and in the behaviour of reactor pressure-vessel materials exposed to a simulated pressurized water-reactor environment. As a result of the different experimental techniques used in the various studies mentioned, only a few detailed conclusions can be drawn. The data from constant-displacement wedge-opening loading (WOL) tests, with the exception of one study, exhibited very limited or no crack extension during exposure periods of up to 14000 hours. The data from constant-load tests indicated evidence of crack extension, but the nature and extent of the crack extension are still unclear. When crack extension did occur, it was exclusively transgranular in nature. Certain differences in the available test data are tentatively explained in terms of the experimental procedures used, and the need for a consistent code of experimental techniques is highlighted.

Jan 1, 1987

By C. Chapman, M. G. Reading, M. P. Amsden

Computer control of flotation at the Ecstall concentrator By M. P. AMSDEN, C. CHAPMAN, and M. G. READING Ecstall Mining Limited, a subsidiary of Texas Gulf Sulphur Company, operates the Kidd Creek Mine, a 10000 tons per day base metal producer, near Timmins, Ontario. Two different types of ore are mined and milled: copper-zinc and silver-lead-zinc. At the highly automated Ecstall concentrator the ores are processed by selective flotation in three individual circuits. One of the most important metallurgical tools for process control is a sample system incorporating continuous on-stream X-ray analysis. Recently this system was automated further by the addition of computer control of reagents for two copper-zinc flotation circuits. The computer programs, utilizing optimum seeking methods and smelter contract terms, have increased copper recovery by 1,1 per cent, zinc recovery by 1,4 per cent, and have reduced reagent costs by 16 per cent. Although not expected, copper and zinc concentrate grades were improved slightly as well.

By E. J. Margi

Deep gold exploration such as is used for Witwatersrand gold deposits is both expensive and time-consuming. This paper provides quantitative guidelines as to the economic optimum number of boreholes and deflections within each borehole for a certain reef characterized by its variability pattern and depth below surface in order to maximize the level of confidence for a fixed drilling budget or to minimize the total drilling cost for a given level of confidence. Portions of the Basal, Vaal, and Elsburg Reefs that show a wide range of variability (sample logarithmic variances of 0,63, 1,05, and 2,06 respectively) are examined at depths below surface ranging from 1000 m to 4000 m over a simulated mining property covering 7000 ha (7000 m by 10000 m). It is concluded that four intersections per borehole are optimum in al the cases considered, which cover the majority of current Witwatersrand exploration, with the exception of the highly variable Elsburg Reef at depths of 1000 m and 2000 m, where boreholes with one and two intersections respectively should be preferred.

Jan 1, 1987

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar

An electrochemical technique based on the solid oxide galvanic cel Mo / Mo + MoO2/ ZrO2-MgO / Fe + (FexO)slag + Ag / Fe was used in a determination of FexO activities in liquid slag systems. The emf measurements, scanning electron microscopy, and microprobe analysis of the cross-sections of the electrolyte tubes used in direct contact with the slag melts indicated that slag attack did not affect the open-circuit emf values during normal cell operation, The reliability of the cell was confirmed by the good agreement between the standard free energy of formation of liquid Fep obtained in the present study and those reported in the literature, The FexO activities were determined in FexO -CaO and FexO-SiO2 slags at 1673 K, and are in good agreement with those measured by the conventional gas-equilibrium technique. The experimental technique was successfully extended to the measurement of Fe2O activities in the complex slags that are used for the external desilliconization of the hot metal product of the blast furnace.

Jan 1, 1986

By D. D. Howat, J. van der Colf

This paper is the first in a series of three dealing with this subject and also with the rate of oxygen removal from the slags in the presence of solid carbon and with the physicochemical properties of the reduced slags. For selected members of the system, the melting temperatures and primary crystallization products were determined. as were the viscosity and the electrical resistivity of the corresponding melts. All the experiments were conducted in a neutral atmosphere. Where determined, the primary phase was found to be either perovskite or magnesium aluminium titanate. The composition variable exerting the most pronounced influence on viscosity or resistivity was found to be the basicity expressed as the mass ratio (CaO + MgO)jSiO,. The ratio CaOjMgO became important only at Iow basi<:ity values. Although generally there is a direct proportionality between log (viscosity) and log (resistivity), slags h&apos;lving either a very high silica content or a very high titania content have anomalously Iow electrical resistance.

Jan 1, 1979

By M. I. Brittan

SYNOPSIS The key reactions of the copper segregation process have been studied with a view to establishing the kinetics of the system. The investigation was carried out using two refractory copper ores from the Zambian Copperbelt in a small-scale, fluidized bed, chloridization reactor. The rate of chloridization of the copper in the ores is compared with the rate of volatilization of the cuprous chloride produced and with the rate of reduction of the cuprous chloride to form segregated metallic copper. In conjunction with available data on the rate of production of hydrogen chloride in a segregation system and with due regard to the conditions applicable in a TORCO reactor, it is concluded that the chloridization reaction is the major rate limiting step of the process. Factors influencing the rate of this extraction step and aspects of its mechanism are examined. The findings have confirmed the validity of the existing theory of segregation and provide insight as to the viability of the system of reactions involved in the copper segregation phenomenon. Experimental results which relate to observations made in the course of TORCO plant operation and segregation studies are discussed.