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By F. Dinter, S. A. C. Hockaday, Q. G. Reynolds

The thermal decomposition of carbonate minerals as pre-treatment before smelting reduces the energy requirement for smelting. It can also make the combustion of fossil fuels for heating unnecassary. Thermal decomposition may become important in reducing greenhouse gas emissions when producing ferromanganese alloys while simultaneously reducing electrical energy demand during smelting. A kinetic reaction rate model for the thermal decomposition of manganese ores is presented, based on published reaction rate kinetics for the decomposition of manganese oxides and calcium carbonate. The model was validated against thermogravimetric data for two carbonaceous manganese ore samples and one ferruginous manganese ore sample. The reaction rate model shows that carbonate minerals in the manganese ores are decomposed at temperatures above 900 °C while pyrolusite is decomposed at temperatures from 450 °C to 500 °C. Mn2O3 decomposes rapidly at 550 °C. Braunite decomposition at temperatures below 1000 °C was negligible. The presence of organic carbon in the samples led to further reduction of the samples during thermal treatment.

Aug 3, 2023

By A.M. Edwards

1. Book reviews Platinum in South Africa, compiled by A.M. Edwards and M.H. Silk. Randburg, Council for Mineral Technology (Private Bag X3015, Randburg, 2125 South Africa), 1987. 55 pp. U$30. Reviewer: R.D. Wintle Scientific and technological developments in extractive metalurgy-G.K. Wiliams Memorial Volume. Parkvile (Australia), The Australasian Institute of Mining and Metalurgy, 1986. $A12 (incl. surface postage). Reviewer: T.Y. OweD Ion exchange and sorption processes in hydrometa/urgy, edited by M. Streat and D. Naden. Chichester, John Wiley & Sons, 1987. 229 pp. Reviewer: B.R. Green Role of Government in mineral resources development, edited by Michael J. J ones. London, The Institution of Mining and Metalurgy, 1985. 180 pp. £40. Reviewer: K.E. Ducat 2. Recent publications Annual report 1987. International Tin Research Institute, Kingston Lane, Oxbridge, Middlesex UB8 3PJ, England, 1988.Tin and its uses no. 156. Address as above. 3. Mintek reports Application Report no. 5 The production of and alusite and other refractory minerals. 1988. 16 pp. . Application Report no. 6 The development up to commercial application of a process for the recovery of lead, copper, zinc, and silver from the Black Mountain deposit. 1988. 14 pp.

Jan 1, 1988

Book reviews Natural gas substitutes from coal and oil, by S.A. Qadar. Amsterdam, Elsevier Science Publishers, 1985. U.S.$83.25. Reviewer: U. Grimsehl High heat production (HHP) granites, hydrothermal circulation and ore genesis. London, The Institution of Mining and Metalurgy, 1985. 593 pp. £30. Reviewer: S.A. de Waal 2. Recent publications Uranium recovery from phosphates and phosphoric acid, by S. Huwyler. 3rd edition. Wirenlingen (Switzerland), Swiss Federal Institute of Reactor Research, EIR-Bericht (C) no. 1. Apr. 1985. 56 pp. Geological aspects of mining productivity. Canada's base metal resources, by B.W. MacKenzie. Kingston (Canada), Centre for Resource Studies, Queen's University, Technical Paper no. 6, Aug. 1985. 115 pp. $10.Taxation policies in the Canadian minerals industry, edited by M. Wojciechowski. Kingston (Canada), Centre for Resource Studies, Queen's University, 1985. Mineral policy update 1984: Policy and program changes afecting the Canadian mineral industry, by M.l. Wojciechowski and M.L. McAlister. Kingston (Canada), Centre for Resource Studies, Queen's University, 1985. $12. 3. Mintek reports Report MU7 The selective solvent extraction of pal/adium by the useof di-normal hexyl sulphide. Report M218 Modification of the design of screen boxes for carbonin-pulp and resin-in-pulp plants. Report M225 The commissioning, operation, and maintenance of an on-line corosion-monitoring station for the mining industry. Report M231The determination of selected lanthanoid elements by atomic-absorption spectroscopy using electrothermal atomization. Report M233 A computer programme for the prediction of hydrocyclone performance, parameters, and product size distributions. Report M234 The solvent extraction of base metals by mixtures of carboxylic acids and non-chelating oximes. 6 The efect of particle size and coloid stability on the wet high-intensity magnetic separation of uranium from cyanidation residues. Report M238 The beneficiation of fine coal. Report M240 The spectrophotometric determination of tin in silicates and tungsten-bearing materials. Report M242 Wear and performance of materials in pipelines for the hydraulic conveyance of fused ash. IPMI award for distinguished achievementThe International Precious Metals Institute has announced that Professor Henry C. Taube, Nobel Laureate, wil be the recipient of their 1986 Distinguished Achievement Award. Dr Taube is Professor of Chemistry at Stanford University, Palo Alto, California.

Jan 1, 1986

By P. L. Ngwenyama, I. Maubane

Soundless chemical demolition agents (SCDAs) are proving to be the future of sustainable and environmental-friendly mining. These expansive chemicals become critical when there is a need to break rock close to communities, environmentally sensitive areas, and critical structures and infrastructure. Unlike explosives, the SCDAs do not generate air-blast, ground vibrations, flyrock, noise, dust, and noxious fumes, which can negatively affect the environment, surrounding communities, sensitive areas, and critical structures and infrastructure. Over the years, several types of SCDA products have been used successfully in the civil and construction industries for the demolition of old and dilapidated buildings near vibrations and environmentally sensitive areas. They have also been used to fragment boulders in the mining and construction industries. However, to date, no study has investigated the applications of soundless chemical demolition on a large-scale in opencast mines. Therefore, this study evaluated whether soundless chemical demolition can break large volumes of in situ rock. This was done by conducting five trials using Nex-Pand soundless chemical demolition agents in four different surface mining sites. Trial 1 was unsuccessful as it was unable to break the rock due to the large confinement between the drilled holes and the use of a hole diameter that was 182% larger than recommended. Trial 2 was a success as it was able to fracture the rock with a crack width that reached 110 mm after 72 hours. Trial 3 generated cracks at the biggest hole diameter of 102 mm. The cracks developed and ceased to increase after 96 hours at a crack width of 100 mm. Trial 4 achieved the smallest crack width due to a very competent rock compared to the other sites. Trial 5 generated cracks at a slower rate than other trials because of the use of Nex-Pand powder at lower ambient temperatures than recommended. These trials proved that soundless chemical demolition agents can replace explosives in areas closer to sensitive infrastructure and communities. This will ultimately enable mines to unlock value and access deposits in these areas.

Jul 23, 2025

By K. C. Corin, M. Tadie, R. M. Manenzhe

The near depletion of high-grade ores, among other factors, has necessitated the consideration of alternative PGM sources. Various factors in the metallurgical processing of ores result in valuable minerals being lost to the tailings, and hence, PGM tailings are a possible alternative PGM source. However, as the value residing in PGM tailings remains unquantified and uncharacterised, there is a challenge in knowing the recoverable fraction of value contained in PGM wastes. This paper outlines the in-situ techniques of oxygen uptake and EDTA extraction for their possible use for determining the recoverable value in PGM tailings. Both methods have shown efficiency in determining the weathering of sulphide minerals and sulphide-bearing ores. Keywords: PGM tailings, tailing retreatment, oxidation, oxygen decay, EDTA

Jan 1, 2020

By R. C. Nkhoma, K. A. Annan, S. Ngomane

The effects of welding current, electrode force, and welding time in a resistance spot weld were studied to investigate the effectiveness of welded joints between a thin EN10130: DC04 material and a thicker 817M40 part, through analysis of the microstructural and mechanical properties. All welded specimens were subjected to tensile testing at room temperature (25°C) and sub-zero temperature (–46°C) to test the strength of the welded joints. No full button failure was observed at either room temperature or sub-zero temperature after optimization of the weldng parameters. The fusion zone was observed to consist mainly of martensitic phase, due to rapid quenching, while the HAZ was composed of clusters of martensite in a ferrite and bainite matrix. The base 817M40 metal remained fully ferritic after welding. The hardness was found to increase with increasing welding current. An increase in nugget size, indicating good fusion of the weld, was observed with an increase in the welding current.

Oct 1, 2021

By T. Chikande

"Falls of ground pose costly hazards to personnel and equipment and thus measures should be taken to prevent them. This study endeavours to improve the support systems used in geotechnically poor ground at a Zimbabwean platinum mine by analysing the status quo and recommending an effective support system. Various techniques were used to determine the quality of ground conditions, predict the rock mass behaviour, and to identify the appropriate rockbolt type. An analysis of the current ground control methods and their limitations was also undertaken.The results showed that the current support system and mining practices in poor ground need to be modified to improve safety and productivity. Stoping overbreak is influenced by poor ground conditions and the explosives currently used. The use of emulsion is recommended to replace ANFO. Redesigning of pillars is also recommended in poor ground conditions. An evaluation of the current roofbolt system indicated an opportunity for improvement. With new insight on the performance of the shorter length roofbolts currently in use, a new support system was recommended taking into consideration cost-benefit analysis. Barring down using pinch bars in poor ground was seen as a risky and time-consuming exercise, hence the use of mechanical scalers is recommended to achieve zero harm and to meet production targets. Smoothwall blasting is recommended in poor ground to minimize excavation damage. Other recommendations include the use of hydrological surveys to determine groundwater levels and implement corrective measures. Both empirical and numerical modelling approaches need to be utilized in determining the optimum support. IntroductionThe presence of geological discontinuities such as faults and joints weakens the rock mass. Adequate support is critical in achieving zero harm in underground mines. This paper reviews the current support systems used in poor ground conditions at a Zimbabwean platinum mine. The area of research is located on the Great Dyke of Zimbabwe. The mine exploits platinum group elements (PGEs) and base metals. It is shallow, having a maximum depth of less than 300 m. The Great Dyke is the second largest reserve of PGEs, following the South African Bushveld Complex (Oberthur et al., 2012). It is a linear layered intrusion that extends for about 550 km with a maximum width of 11 km (Prendergast, 1989). The generalized section of the Great Dyke is almost like a trumpet, comprising layers that dip towards the centre. The reef exploited at the mine, the Mineralised Sulphide Zone (MSZ), is located in the pyroxenite layer, which is hosted in the ultramafic sequence. The MSZ is a uniform layer about 2– 3.5 m thick, dipping at around 10–14° from surface outcrop towards the axis of the basin, and located between bronzite and websterite horizons. The visible disseminated sulphide mineralization shows a typical and consistent vertical distribution of platinum group metal (PGM) and base metal values. The research was undertaken to review the current support systems used in geotechnically poor ground conditions in a bid to improve both safety and productivity."

Jan 1, 2016

By D. Kok

A challenge in mine planning is the optimal allocation of resources to the appropriate workplaces within the shift cycle (labour, equipment type, and other resources) in order to carry out the shift cycle activities, achieve planned production targets, and ultimately maximize production within all infrastructure constraints. Generally, detailed mine planning is done on a monthly basis at a workplace level in order to determine the production targets. The production supervisor, mine overseer, or equivalent production manager must then make the appropriate resource allocation trade-off decisions on a daily basis per shift to try and deliver to the plan and required production target. Due to the complexity and number of permutations of possible resource allocation decisions, it is impossible for a human brain to make the appropriate and optimal allocation decisions that will result in achieving the maximum or target production. These allocation decision permutations must deal with the current status of workplaces (availability, position in the cycle etc.), the status of equipment availability (available, planned maintenance, or breakdown etc.), distance between the workplaces (traveling time of equipment between workplaces, etc.) and equipment type required for that shift cycle activity. All these factors need to be taken into account in resource allocation to plan for the shift, and even during the shift if a major piece of equipment becomes unavailable or a workplace activity is not progressing as planned. This paper is a case study on how an optimization algorithm can be used to create a production planning system for optimization of resource allocation in a mechanized underground platinum operation. A business case for optimal allocation of resources is demonstrated and compared to the current manual planned allocation.

Jan 1, 2012

By Wei Sun, Ruolin Wang, Wenjuan Sun, Junhao Fu, Haisheng Han, Zhao Wei

Pb–benzohydroxamic acid (BHA) (lead complexes of benzohydroxamic acid) exhibits high selectivity but low collecting efficiency in scheelite flotation. This paper reports the manner in which BHA and sodium dodecyl sulfate (SDS) were employed as ligands to coordinate with the lead ions to obtain a colloidal lead-group multiple ligand complex, i.e., the Pb–BHA–SDS, for improving the collecting efficiency of Pb–BHA. The flotation mechanism of Pb–BHA–SDS with respect to scheelite was investigated from the viewpoint of interface science based on the pure mineral flotation, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. The results showed that the BHA and SDS coordinated with Pb2+ to form novel leadgroup multiple ligand complexes, which are different from the traditional understanding associated with the mixed collectors. Pb–BHA–SDS was a better collector with stronger collecting ability and excellent selectivity in regard to a scheelite flotation than Pb–BHA. The addition of SDS to Pb–BHA enhanced the latter’s adsorption ability on the scheelite surface and improved the hydrophobicity of the collector’s nonpolar groups, rendering Pb–BHA–SDS as a more efficient collector at a low dosage. Keywords: Scheelite; Pb-BHA complexes; sodium dodecyl sulfate; multiple ligands; Pb–BHA–SDS

Jan 1, 2020

By R. G. B. Pickering

Successful management of mining operations depend on the accurate and reliable measurement of performance as a monitoring instrument in a feedback and control loop. However, when changes are being considered, the probable effect of the change on bottom line results requires different measuring techniques incorporating an in depth understanding which can identify hot spots in the operation which exhibit strong sensitivity to change. The CSIR's Division of Mining Technology has therefore been devoting a considerable effort to the establishment of techniques which enable changes to be analysed in terms of their impact on the two key parameters describing mine performance, i.e. profitability and safety. This paper describes these techniques, outlines their application to some example situations and discusses planned enhancements. The first section of the paper addresses the profitability model, and this is followed by a section considering the mine safety model.

Jan 1, 1996

By I. Çinar

Cappadocia is not only a region of Turkey with historical and touristic importance. During the cutting and processing of volcanic tuff, quarries in this region release large amounts of tuff into the environment that is viewed as waste. The release of this waste constitutes an economic loss and contributes to environmental pollution. However, through experimentation with deformation, weight per unit of volume, water absorption, uniaxial compression strength, modulus of elasticity, and point load strength index, volcanic tuff and marble dust composite materials can be produced for use in the building sector. In this study it was observed that, as the percentage of volcanic tuff dust in the mixture increased, the water absorption rate of the material increased, and uniaxial compression strength and point load strength decreased. The produced composite samples used in this study were kept for a predetermined number of times per day, and no deformation in the surface characteristics of the materials was observed. In a statistical parameter analysis, averages, variances, standard deviations, coefficients of variation, and skewness coefficients were calculated. Covariance changes between experimental parameters were also determined. In this study, two types of volcanic tuff dust, that is, yellow and red, were produced during the production of tuff-marble dust composite material. When the percentage of either type of volcanic tuff dust was increased, an increase in water absorption was observed. It was also observed that when the percentage of volcanic tuff dust was increased, uniaxial compressive strength and point load strength decreased. Furthermore, the physical and mechanical properties of the materials obtained by mixing different colored tuff powders and marble powders in different proportions were evaluated using statistical parameter analysis.

Mar 5, 2025

By J. Engelbrecht

Understanding the deportment of minerals in size fractions has already led to improvements in the flow sheets for platinum minerals beneficiation. There are, however, more potential changes in the flow sheets that may improve the recovery of platinum group metals or reduce the costs of beneficiation before refining. Based on known technology of pre-concentration, milling, gravity concentration, flotation, and magnetic separation a number of potential alterations or additions can be considered and motivated based on the mineral deportment in size fractions.

Jan 1, 2012

By F. Dutoy, M. B. Stella, C. F. Carrozza

Rare earth elements (REEs) are indispensable components in the manufacturing of high-tech devices, renewable energy technologies, and defence applications. As global demand for these elements continues to rise, there is a pressing need to optimize extraction processes for both efficiency and environmental sustainability. This study explores approaches to rare earth extraction using Ionquest® 801 and integrates a predictive modelling to enhance process understanding and optimization. We conducted a screening test varying pH process to evaluate the best extraction efficiency. Starting pregnant leach solution (PLS), solution was prepared in the lab with the following rare earth elements: La, Ce, Gd, Dy, and Υ, at 0.02 M for each element. The data obtained were used to develop empirical and mechanistic models to predict rare earth extraction yields and flowsheet. Further tests were performed by mixing specific concentrations of different extractant and/or phase modifier. Our experimental results demonstrated the effectiveness of the proposedextraction methods, highlighting improvements in both yield and selectivity. The developedmodels successfully captured the complex relationships between process parameters and extraction efficiency, providing valuable insights for process optimization.

Nov 6, 2024

By M. Bryson, J. Taguta

The Prieska deposit, mined between 1971 and 1991, is one of the world’s top thirty volcanogenic massive sulphide (VMS) base metal deposits. The Prieska Copper Mine in the Northern Cape Province was closed by Anglovaal when underground mining had extended to depths which did not allow for safe and economic extraction of the deposit at the time. The mine has a recorded historical production of over 1 Mt of zinc and 430 k tonnes of copper from 46.8 Mt of milled sulphide ore, achieving life-ofmine metal recoveries of 85% for copper and 84% for zinc into high quality concentrates (refer ORN ASX release 15 Nov 2019). Orion Minerals Ltd is currently investigating the feasibility of developing a new mine in the footprint of the historical Prieska Copper Mine, using the extensive remaining infrastructure, with the intent of extracting the unmined zinc-copper mineralisation from the Prieska deposit. This paper reports results on the flowsheet development philosophy on the hypogene ore, and challenges encountered in the process. This study initially failed to replicate historic copper and zinc recoveries employing the historic production flowsheet and reagent conditions unmodified on bench scale, as the copper and zinc were co-floating. Flowsheet modifications were therefore made to improve differential flotation and recovery, resulting in achieving comparable saleable products and recoveries from processing the hypogene ore on bench scale. Flotation variability test work on the hypogene ore focused on the use of the original flotation procedure and reagent suite using a sodium cyanide-zinc sulphate depressant system on the copper circuit, and it generated a saleable copper product of 20-26% Cu grade at 80-86% recovery. The zinc circuit generated a saleable zinc product grading at 48-55% Zn at 80-94% recoveries. Some zinc losses were due to the deportment of some zinc in sauconite. It is recommended that further test work may further improve the copper grades and recoveries. Keywords: Prieska, flotation, hypogene ore, flowsheet development, sulphide flotation, reagents

Jan 1, 2020

By O. A. Bascur

Ores are becoming extremely variable with mineralogy and hardness disturbing the grinding and flotation circuits. The current grinding and flotation sensors provide large amounts of data for process optimisation. Adding the right context and operational events augments operational knowledge for proactive actions to improve the performance of the grinding and flotation circuits. A data-driven strategy is needed to enable operations, maintenance, and business personnel to quickly and easily take corrective action when abnormal conditions occur. A digital plant template transforms data into operational insights in real-time. It uncovers the hidden, idle and downtime losses. By measuring and managing these unproductive times, people find new ways of avoiding them, improving the profitability of the plant. The information created by the real time analytics enables the calculation of recovery in real time and develops predictive analytics models to find the best operating condition based on the type of ore currently mined. The creation of new workflows and collaboration between mining and concentrator plant and the enterprise, including services providers, are enabled. A grade recovery model is used to identify the best operating conditions in real-time. An optimal Gaudin size distribution shape is used to find the grinding operating conditions that optimise the metal recovery in the rougher sections of the mineral processing plant. Sensors in the flotation circuits enable estimation of metal recovery and determine the optimal froth depth and aeration profiles, using an industrial air holdup flotation model. The implementation of a recovery/grind strategy with industrial examples in non-ferrous metal concentrator is presented in the paper. Keywords: Digital transformation, soft sensors, predictive analytics, grinding flotation optimisation, flotation bubbles, particle size, particle size distribution shape, froth aeration profiles, flotation air hold up model, recovery predictive analytics

Jan 1, 2020

By J. J. Cilliers, J-A. Lamamy, J. N. Rasera, K. Hadler

Production of oxygen on the moon can be achieved by reduction of lunar soil. One such reduction technology, hydrogen reduction, favours a high proportion of ilmenite in the feedstock. Ilmenite is present in lunar soil as a minor mineral phase, but it can be upgraded using electrostatic separation. This study presents the results of a preliminary investigation into the operating parameters and sensitivities of a free-fall electrostatic mineral separator for lunar applications. Samples of ballotini and ilmenite as well as simple binary mixtures of the two were tribocharged on copper and passed through a uniform electrostatic field. The field is varied to change the electrostatic force acting on the particles. The proportion of material reporting to the positive electrode collectors, negative electrode collectors or the central collector was measured to determine the separation performance. The data confirmed that the charge transferred from the tribocharger to each species is in agreement with the triboelectric series; ballotini was found to charge positively on copper and ilmenite negatively. Particle-particle contacts were dominant, however, resulting in a somewhat symmetrical particle distribution in the collectors. These findings indicate that the copper tribocharger design requires optimisation in order to substantially increase particle-wall contacts. Four binary mixtures with feed grades of ilmenite ranging from 5% to 20% were prepared and tested. This study found that a higher ilmenite head grade resulted in a higher concentrate grade (26.3% from a head grade of 20%) with low recovery (3.4%). In contrast, the lower feed grade resulted in a low concentrate grade but higher recovery. The mass yield of ilmenite was 1.4 times greater for the highest-grade feed than for the lowest. A subsequent study into the reprocessing of middling fraction found a nearly constant relationship between cumulative grade and recovery. This is the first investigation into the effect of feed grade on the concentrate grade and recovery for lunar mineral processing. Keywords: Lunar resources, beneficiation, electrostatic, SRU, ISRU

Jan 1, 2020

By S. Zhao, S. P. He, M. Y. Zhu, Y. Tao

"The effect of two refining slags (A: 1.0–1.8 CaO/Al2O3 ratio, 11–20 wt% SiO2; and B: 1.0–1.2 CaO/SiO2 ratio, 25–35 wt% Al2O3) on the inclusion morphology of a carbon structural steel (Q235B) was studied by controlling the balance between the steel and the refining slag at 1600ºC in a Si–Mo resistance laboratory furnace. The results showed that most of the inclusions in the molten steel balanced with slag A were formed by a lowmelting CaO–MgO–Al2O3–SiO2 system with a total oxygen content (T[O]) being fixed at 6–13 ppm. The inclusions in liquid steel balanced with the slag B were mostly formed by the CaO–MnO–Al2O3–SiO2 system, with T[O] controlled to 19–26 ppm. The overall size of the inclusions under balance conditions was higher in the steel reacted with the slag B than that reacted with slag A, with the latter showing more inclusions smaller than 3 um. In order to generate a large number of spherical CaO–MgO–Al2O3–SiO2 inclusions smaller than 3 ??m while decreasing the T[O] in the resulting steel, the composition of slag A should be used. This composition allowed improving the cleanliness of the slab, and is also advantageous for the castability of the molten steel. IntroductionThe sample used in this study was a typical carbon steel manufactured by CQ Steel. The galvanized, tinned, and plastic composite steel plates made of the original plates are used extensively for decorative panels, general dust pipes, drums, instrument cases, switchboxes, and train cars, among other uses. The target control composition is shown in Table I. The S and P contents are usually fixed during production below 0.020 and 0.025 wt%, respectively, with the aim of reducing longitudinal cracks on the slab surface."

Jan 1, 2017

By G. W. Donaldson

Theoretical and engineering aspects of slimes-dam construction by G. W. DONALDSON, M.Sc. (Eng.)(U.C.T.), D.I.C. (Visitor) Tile paper reviews the recommendations made in 1959-60 as a result of research into slimes-dam construction and finds that these recommendations are still valid. The requirements for pollution control, vegetating, in situ leaching, and future development of slimes dams as building areas are considered as they affect the engineering aspects of slimes-dam construction, and it is found that these requirements can be met without any major changes to current recommended slimes-dam construction practice.

Jan 12, 1973

By E. Marè, D. R. Groot, R. Engelbrecht, T. Coetsee

Hydrogen peroxide is often used as an oxidising agent in experimental waste electronic equipment (WEE) leaching work. However, the high cost of peroxide is a negative factor in its consideration in further process development. A few studies have reported on the efficient application of peroxide addition schedules to ensure optimum reagent consumption. Large quantities of unleached substrate material contained in WEE feed material result in a large dead volume of material in the leaching reactor. This factor necessitates fast reaction rates to enable the use of a high feed material throughput reactor to enhance overall project viability via hydrometallurgical processing. In this study the effects of hydrogen peroxide addition schedules on base metal leaching efficiency and solution temperatures were tested at laboratory scale. The results showed that overall peroxide consumption can be optimised to lower levels by matching peroxide additions to the particular feed material’s leaching behaviour. A simplified integrated model for peroxide decomposition is used to explain its effect on solution temperatures and leaching rates. Keywords: Peroxide consumption, waste electronic equipment, copper leaching, integrated model

Jan 1, 2020

By B. M. Munyungano

Rössing Uranium Mine operates a recovery circuit with continuous ion exchange followed by solvent extraction. Serious organic degradation problems were encountered during 1985/6, 2000 and 2005 in the solvent extraction plant. The preferential loss of the tertiary amine extractant was observed during the above-mentioned period. Previous investigations revealed that the tertiary amine was breaking down to nitrosamine, which cannot take part in the exchange reaction with U3O8. A reduction in the redox potential of the solvent extraction plant feed to below 500 mV halted this preferential loss. A lot of effort has been made to try and understand the actual mechanism for nitrosamine formation. Current understanding for the degradation is that formation is due to high nitrates on the strip side of the circuit emanating from nitrates from the precipitation process using ammonia. It is the current belief that pH lower than 3.7 on the strip side results in loading of nitrates onto the solvent. If oxidizing conditions prevail on the extraction side of the solvent extraction circuit, the tertiary alamine will then degrade into nitrosamine. This phenomenon is yet to be established and verified. It has, however, been established that the above process is brought about the following conditions ?High redox potential greater than 550 mV predominately caused by a high Fe3+/Fe2+ratio (4:1) ?Perception that if Fe2+<0.5 g/lit will contribute to high redox ?High concentrations of NO-3 in the conc eluate (feed to SX)/ammonium sulphate (NO-3> 4 g/l based on historic values) ?Presence of Mo as a catalyst ?Tests also have proved that the presence of nitrous acid in a concentration of 1 g/lat 550 mV leads to formation of nitrosamines from alamine.

Jan 1, 2007