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By G. M. Wilemon

The Bureau of Mines conducted preliminary investigations on the use of an acid-alcohol leaching technique for recovering phosphate values from phosphate matrices. H2S04 and methanol were used as the leaching agents. Starting-matrix particle size and acid-apatite ratio were found to significantly affect the efficiency of phosphate leaching. Phosphate extractions of more than 80 pct were obtained when minus 200-mesh ore was used and the acid-apatite ratio was 8:1 or more. The iron and aluminum oxide impurities (R203) present in the crude acid products were monitored, and R203-P205 ratios are reported. Phosphate extractions in excess of 80 pct also were obtained when phosphatic clay wastes were leached. Typically, leach slurries filtered using test leaf filters ex-hibited filtration rates of 100 lb/(h·ft2) or more.

Jan 1, 1987

By A. T. Iannacchione

Designing coal pillars to provide resistance against overburden and gob loads has long been an aim of rock mechanics engineers. This requirement has become more imperative as greater overburdens are encountered and when mining in stiff coal-bearing strata. Current design procedures rely on theories of coal pillar behavior that take into consideration a common hypothesis. This hypothesis states that the elastic core is surrounded by an inelastic yield zone. The distribution of stress at low-to-moderate pillar loads has been effectively defined by this hypothesis. However, it suffers greatly when applied to large width-to-height (w/h >lo) coal pillars under considerable overburden (>500 m) . In these situations, the hypothesis says the elastic core can achieve unrealistic stress states giving the pillars extremely high calculated strength. A growing body of field studies has shown this is not the case. It has become clear that same other mechanism must be involved. It is the purpose of this paper to discuss the importance of an interface slip mechanism between the coal- bed and the surrounding strata in controlling the extent and pattern of stresses and deformations in a coal pillar.

By M. L. Fenger, S. F. Mauser

This 1s a report on an Investigation performed during Contract No. H0166069 "High and Medium Voltage Trailing Cable Splices and Connections," which presents a summary of the requirements formulated. The requirements are presented in the form of considerations for medium-voltage splices, and medium- and high-voltage couplers used in underground coal mines.

Jan 1, 1979

Improve the efficiency of stainless steel pickling (chemically cleaning) operations by providing the industry a quick and convenient method to estimate pickling solution behavior and to estimate recommended ranges of nitric and hydrofluoric acid concentrations for effective pickling of stainless steels. Background Iron, chromium, and nickel in stainless steels react with nitric and hydrofluoric acids during pickling. Ions of these dissolved metals complex or combine with the acid anions. When the total metal concentration reaches about, 50 grams per liter of pickling solution, the solution no longer serves its purpose and is considered spent. Knowledge of cation and anion species in these pickling solutions contributes an insight into pickling chemistry and allows estimates to be made of the most effective ranges of acid concentrations. The Bureau developed a computational model of the complex equilibrium chemistry occurring among iron, chromium, and nickel and the pickling solution. Total concentrations, in grams per liter, of nitrate, fluoride, iron, chromium, and nickel were used as input; output was 17 cation and anion molar concentrations. The model, in the form (if an equilibrium program on a mainframe computer, was used extensively to facilitate Bureau research by determining chemical complexes in numerous stainless steel pickling solutions. However, the program's availability to members of the stainless steel industry, its intended users, was limited because of lack of mainframe compatibility and the difficulty of program maintenance.

Jan 1, 1989

By Gregory J. Chekan

As part of the initial investigation and validation of a new boundary-element formulation for stress modeling in coal mines, the underground stresses and displacements at two multiple-seam coal mines with unique stress problems were modeled and predicted. The new program, LAMODEL, calculates stresses and displacements at the seam level and at requested locations in the overburden or at the surface. Both linear elastic and nonlinear seam materials can be used, and surface effects, multiple seams, and multiple mining steps can be simulated. In order to most efficiently use LAMODEL for accurate stress prediction, the program is first calibrated to the site-specific geomechanics based on previously observed stress conditions at the mine. For this calibration process, a previously mined area is "stress mapped" by quantifying the observed pillar and strata behavior using a numerical rating system. Then, the site-specific mechanical properties in the model are adjusted to provide the best correlation between the predicted stresses and the observed underground stress rating. Once calibrated, the model is then used to predict future stress problems ahead of mining. At the two case study mines, the calibrated models showed good correlation with the observed stresses and also accurately predicted upcoming high stress areas for preventive action by the mines.

Jan 5, 1999

By Doris M. Hyde

Belize remained relatively insulated from the social and political turmoil that affected some of its Central American neighbors. This stability encouraged new foreign investments that assisted the economy, especially in tourism and agriculture. The mineral sector remained limited to construction-oriented materials. Oil exploration efforts continued by the various concessionaires.

Jan 1, 1987

By Edward A. Mihok

Laboratory batch-flow tests conducted on a highly ferruginous acid mine water with an activated carbon showed that ferrous iron is rapidly oxidized. This indicates that air oxidation of ferruginous acid in mine waters is catalyzed by activated carbon. The ferrous iron content of an acid mine water flowing through an aspirated activated carbon column was reduced from about 700 to about 10 parts per million in less than 1 minute. Highly efficient ferrous iron oxidation was achieved by conditioning the activated carbon by repeated treatment with acid mine water and air. The reaction proceeds rapidly in the acid environment (pH about 2.5) engendered by ferrous iron oxidation. The activated carbon was used repeatedly with little loss in efficiency, no discoloration, or solids deposition. In these batch tests, about one-third of the iron was adsorbed by the carbon, but with continuous flow, little iron adsorption is expected. Incorporating a catalytic oxidation step in the treatment of acid mine waters containing ferrous iron would greatly facilitate neutralization--precise control of pH, lower reagent costs, elimination of aeration equipment, and smaller holding ponds.

Jan 1, 1969

A construction material based on plasticized sulfur and mineral aggregate, that is superior in corrosion resistance and strength to portland cement concrete. The material can be used in the chemical, metallurgical, and fertilizer industries, and will also provide an attractive market for by-product sulfur resulting from compliance with pollution regulations. How It Is Made Sulfur concrete is thermoplastic material. Plasticized sulfur is mixed with sand and gravel aggregate heated to 375-400° F. The sulfur melts and acts as the binder or cement. The sulfur concrete is poured hot and sets at a temperature of 200° F. Full strength is attained in a few hours, compared to several days for portland cement concretes. Sulfur concrete even pours and sets in freezing weather. Although unmodified sulfur with aggregate will produce a sulfur concrete with good initial properties, it undergoes crystallographic modifications, and deteriorates with time, particularly when exposed to moisture or freeze-thaw conditions. The Bureau of Mines has developed plasticizers which, when reacted with the sulfur, give sulfur concretes with excellent moisture and freeze-thaw resistance. The plasticizers are based on mixtures of dicyclopentadlene (DCPD) and ollgomers of cyclopentadiene. About 5 percent by weight of the plasticizers is reacted with molten sui fur for several hours. The sulfur cement can be used directly or allowed to solidify for easier handling and storage.

Jan 1, 1981

By E. J. White

Data from oil well logs and core analyses were used to quantitatively evaluate formation porosity and water saturation of heterogeneous carbonates and to study the pore geometry and performance characteristics of cores from these formations. Logs and cores from the Madison limestone from 233 wells in three fields in the Williston basin were used in the investigation. A comparison of log and core analyses shows that log porosities are consistently larger than core porosities, and the differences are correlatable with core porosity ranges. Water saturations from logs are usually smaller than the corresponding core saturations by summation of fluids, but the difference is attributable to mud filtrate invasion into the cores during drilling. Petrophysical studies show that the low permeabilities and high residual water saturations in these reservoir rocks are due to their fine crystalline texture and complex pore geometry (heterogeneity). It is concluded that both log and core analyses must be used for reliable evaluation of these carbonate formations.

Jan 1, 1971

Develop a method for control of groundwater inflow to chronically "wet" sections of underground coal mines, in order to reduce groundwater interference with mining activity and to minimize acid mine drainage. Approach In eastern coal regions, groundwater stored in fracture zones in the rock mass can create a significant water problem for underground mining operations. Fracture stored inflow to mine workings impedes mine productivity since storage water sources usually release at the active face, creating the poor mining conditions typical of a "wet" section. Fracture water can also contribute to AMD problems when the water subsequently contacts sulfide minerals in the coal, The Bureau of Mines has developed a mine-dewatering method that eliminates many of the problems associated with mine water inflow by draining these fracture zones before the water can reach the developing face and interfere with mining activity. How it Works The dewatering method removes large volumes of the stored groundwater through high-capacity pumping from a minimal number of wells placed strategically on fracture traces (the surface expressions of fractured rock zones). These fracture traces are located through low-level aerial photographic and geologic investigation. As shown on the map, dewatering wells are sited precisely on fracture trace intersections in order to take advantage of the increased pumping capacity gained from these zones of high permeability. Once well drawdown indicates that the stored water is depleted,

Jan 1, 1983

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

SUMMARY The objective of this program was to develop a system to extinguish coal mine fires by remote sealing of the underground passageways. The system developed had to be versatile enough to function under a wide range of operating conditions, including large variations in passageway geometry, depth of mine, water conditions, both in the mine and at the surface, and rubble in the mine passage. The system developed had to include instrumentation for the remote probing of the passageway prior to sealing, a system for sealing the mine passages, and instrumentation for remote monitoring of the quality of the seal during and after construction. These objectives were successfully achieved during this program. The remote mine sealing capability of the system was satisfactc rely demonstrated in a field test conducted at the Eastern Associated Coal Corporation Federal No. 1 Mine in Grant Town, West Virginia. The remote sealing consists of: (1) A sonar initial probing system which can operate satisfactorily even in the presence of dense smoke. The system is capable of determining both the local passageway geometry, identifying the presence of cribs and other obstructions, and the position of the borehole in the mine passage. (2) A mine sealing material system which utilizes fly ash for making the complete seal or as a bulk filler in conjunction with a urethane, froth foam, seal topping system. The choice of using fly ash alone or fly ash with foam topping depends on a number of factors, such as quality of seal desired, time available per seal, depth of borehole, passageway geometry, and water holding require¬ment. The fly ash-foam seal is a better seal, capable of sealing against a higher water head than fly ash alone. The fly ash sealing

Jan 1, 1973

By H. W. Wainwright

One phase of the research and development work on synthetic liquid fuels conducted by the Bureau of Mines at Morgantown, W. Va. in cooperation with West Virginia University deals with the purification of synthesis gas.2/ Most of the experimental studies on gas purification have been directed toward the removal of organic sulfur from gas, either catalytically or by adsorption with activated carbon. An important part of the purification program has been the development of suitable analytical methods for determining organic sulfur compounds. As the total sulfur content, organic and inorganic, of purified synthesis gas should not exceed 0.1 grain per 100 cubic feet, the need for accurate analytical methods is apparent. It is also apparent that such methods must be rapid if one wishes to evaluate various processes for removing sulfur from gas. The organic sulfur found in most gas produced from coal is usually present as carbon disulfide, carbon oxysulfide, methyl and ethyl mercaptans, and thiophene, with the exception of thiophene, the remaining organic sulfur compounds respond similarly to catalytic treatment and can be removed effectively. Not only does thiophene resist most catalytic treatment, but it poisons some catalysts, rendering them ineffective in removing the other forms of organic sulfur.

Jan 1, 1950

By A. B. Cecala

A new prototype bag nozzle system has been designed under a Bureau of Mines contract to reduce dust generated during the bagging operation on fluidized air baggers. A field analysis of the new system has shown that the bag operator's dust exposure was reduced 83 pet. The amount of blowback was reduced 89 pet, which corresponds to a significant product savings. The new prototype system has been operating for a substantial period of time with no major problems.

Jan 1, 1984

Protect rescue workers fighting fires or mine personnel temporarily working in hot environments from heat stress. Approach A specially designed ice-cooled vest is worn while working in hot environments where cooling the mine air is not possible. How It Works The vest holds a total of 44 individual ice cells in packets that are firmly held near the wearer's skin. These ice cells remove heat from the wearer, reducing heat stress and increasing comfort. The locations of the ice cells and packets are shown in the diagram. The vest is constructed in three layers with the outer layer being aluminzed fiberglass cloth. Its aluminized surface reflects radiated heat, and its fiberglass cloth provides fire resistance and strength.

Jan 1, 1979

By Donald W. Fausett

This Bureau of Mines publication presents a system of thermal decompositions providing an adequate description of the mechanism of oil shale pyrolysis. Specific rate constants for systems of thermal decompositions studied are estimated via a least-squares procedure. The estimates thus obtained provide a mathematical model of the corresponding thermal decomposition system. A model that generates a good fit to published Bureau of Mines experimental data, in comparison with other models studied, is based on a thermal decomposition system consisting of two first-order reactions and three second-order reactions. Values computed for the specific rate constants corresponding to this system are shown to exhibit a temperature dependence that is in good agreement with the Arrhenius equation.

Jan 1, 1974

By W. H. Eddy

The Bureau of Mines conducted laboratory batch-and small-scale continuous flotation processing tests on waste granite fines from Georgia, to determine the feasibility of recovering usable feldspar and quartz products by flotation. Two flotation methods were utilized for the removal of biotite and other iron-bearing minerals: One was in an acid-cationic circuit, and the other in an alkaline-anionic-cationic circuit. Feldspar was recovered using an acid-cationic method. To produce commercial-grade feldspar and quartz products it was necessary to employ either two sequential froth flotation circuits or one froth flotation circuit supplemented by wet-magnetic separation techniques to remove iron contaminants. Continuous flotation processing yielded a commercial-grade feldspar concentrate containing, in percent, 3.8 Na20, 5.4 K20, and 1.10 CaO, with recoveries of 77.8, 70.3, and 64.4, respectively. The feldspar tailing was high-quality glass sand containing 98.2 percent SiO2 and 0.024 percent Fe2O3. About 42 percent of the quartz was recovered at glass sand specifications. An effective separation of, potash feldspar from the bulk feldspar concentrate was achieved by batch flotation in a mineral separation cell.

Jan 1, 1974

Develop design and support guidelines for coal mine entry intersections based upon results of integrated field and numerical modeling analyses of structural parameters for improving ground stability. Background Underground coal mines contain a large number of entry intersections. Dome-shaped zones over the intersections are unstable and are often associated with roof falls. These roof falls may occur during mine development, trapping equipment and endangering miners. These high-risk areas of the mine account for 10 pct of the total number of ground-failure-caused fatalities. The falls, ranging from heights of 1 to 20 ft, cause high dilution and slow the advance rates. Stability at intersections is influenced by four structurally interrelated parameters: in situ stress, geological discontinuities and physical properties, intersection geometry, and roof span. Because of the complex interaction of these parameters, the actual mechanism of roof failure may vary considerably, depending upon the roof lithology, rock strength, and stress conditions.

Jan 1, 1990

By L. E. Schultze

The Bureau of Mines operated a mineral recovery unit to recover metal values from post-flash geothermal brines from the Salton Sea known geothermal resource area as part of its research into the use of plentiful resources. The brine was available for metals recovery after its heat content had been used to generate electricity. The brine source was treated with lime to precipitate the contained iron, manganese, lead, and zinc before injection of the heat-depleted brine into the underground reservoir. Data are presented on the effects of process variables, such as rate and method of lime addition and air oxidation versus air exclusion. Variations in precipitation of metal values, composition of precipitates, effectiveness of slurry thickeners, and methods of treating the precipitates to recover metal values are discussed.

Jan 1, 1982

By J. J. Cummins

Green River oil shale previously extracted by benzene was heated at 150°, 200°, 250°, 300°, and 350° C for 0.5 to 360 days to determine the rate at which kerogen degrades to thermal products, the types of thermal products formed, and the effect of prolonged low-temperature heating (preheating) upon subsequent assay yields. Thermal decomposition of kerogen at 150° to 350° C is treated as a first-order reaction. The specific reaction rate for kerogen decomposition increases from 2.2 X 10-4 per day at 150° C to 2.0 X 10-1 per day at 350° C. The calculated kerogen activation energy is 19 kcal. Variations in the rate of formation of individual type components of the pyrolytic products were found. Carbon balances show an increase in the amount of kerogen converted to bitumen and oil (from assay of preheated oil shale) as the temperature of preheating increased from 150° to 350° C. Total product from shale preheated at temperatures of 150° and 200° C gave less than 100 percent of Fischer assay yields while the total products from shale preheated at temperatures of 250° to 350° C gave greater than 100 percent of Fischer assay yields.

Jan 1, 1972

By H. C. Ko

As part of the Federal Bureau of Mines effort to provide thermodynamic data for the advancement of minerals technology, energy conservation, and environmental preservation, the standard enthalpies of formation of a-magnesium sulfate, a-magnesium sulfate, and magnesium sulfate monohydrate were determined by hydrochloric acid solution calorimetry. The values of the standard enthalpies of formation in kcal per mole at 298.15 K are -307.95 ± 0.13 for a-MgS04, -307.03 ± 0.13 for ß-MgS04, and -384.72 ± 0.13 for MgS04 .H2O.

Jan 1, 1979