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By S. E. Khalafalla

The extremely sluggish oxidation of steel scrap was appreciably accelerated when the charge was pretreated in aqueous solutions of sodium metavanadate or sodium molybdate. The degree of oxidation acceleration was inversely correlated with the melting point of the promoter oxide possessing the highest valency. The magnitude of oxidation enhancement exhibited a systematic inverse dependence on the duration of pickling processes; mere dipping of the oxidizable charge in the vanadate bath was most effective. In general, the rate of steel scrap oxidation increased with increasing concentration of the pickling reagent. The results are explained on the basis of the hydrolytic decomposition of the pickling agent with subsequent slow interaction with the metal surface, coupled with the tendency of vanadium to form polyanions in alkaline media. The data not only served to elucidate the mechanism by which catastrophic oxidation takes place, but also showed that the accelerating species need not be alloyed with the oxidizable metal; surface impregnation by minute amounts of the accelerating species can still produce catastrophic effects.

Jan 1, 1970

By A. Z. Dimitroff

An improvised rock-dust disseminator, consisting of a 10-gallon galvanized metal milk can that dispenses rock dust in return air currents by the injection of compressed air has reduced the float dust explosion hazards at the Koehler coal mine, Koehler, N. Mex.

Jan 1, 1965

By Robert P. Vinson

A sequential sampler, based on the Archimedes screw, has been developed by the Bureau of Mines. Its initial purpose was to collect air samples during tracer gas studies in underground mines. However, the basic concept can be applied to other sampling needs, including sampling of liquids. A prototype was built and successfully tested in the Bureau's Experimental Mine at Bruceton, Pa. The simple design makes the sampler inherently durable and low in cost.

Jan 1, 1976

Cement kiln dust (CKD) is a waste product generated at the rate of 4 to 12 million tons per year in the United States. The dust has considerable resource potential as a neutralizer for coal mine waste effluents and as a lime substitute in the agriculture and construction industries. However, little information has been published on the composition and characteristics of CKD, and a concern arose over the potential environmental effects of the waste when an analysis of a single sample from West Germany revealed lead and zinc concentrations of 5,620 µg/g and 16,200 µg/g, respectively. To assess the hazardous waste potential of CKD,

Jan 1, 1983

By Larry G. Stolarczyk

1.0 FRAMEWORK FOR COMPARISON This document describes the decision factors that bear on the selection of the modulation process for the wireless underground medium frequency (MF) communication system. The selected modulation process must satisfy the Bureau of Mines stated objective of improving general communications within an underground mine. The improvement being sought includes the development of a wireless communication technology of measurable benefit to both mine safety and mine productivity. The improvement will allow wireless communications paths to exist between roving miners. The wireless communication paths will also be made compatible with the existing underground telephone system to extend paging and voice communication throughout the underground mine. The new wireless equipment will include man-pack, vehicular, repeater, and base station transceivers. Repeaters and base stations will feature coupling networks for interfacing with the existing telephone circuits. Frequency modulation (FM) and single sideband (SSB) modulation processes are analyzed in view of the special conditions associated with underground mining. Of primary importance is the tremendous electrical noise generated in an operating mine that could adversely affect communications quality. High noise coupled with high attenuation rate of near field signals forces the communication system to be inherently short range. Fortunately, near field signals can propagate over great distances on underground wires and cables. The framework for comparison is generated by presenting all factors that

"At the request of the Anthracite Institute, the United States Bureau of Mines during February, March, and April 1935, made a field survey of commercial anthracite shipped from collieries scattered throughout the Anthracite regions. In all, 268 samples were taken at 41 breakers from Carbondale at the northern end of the field to Pottsville at the south. These collieries ship approximately 50 percent of the industry’s total production. The geographical distribution of the breakers sampled was as nearly as practicable in proportion to the tonnage of the companies from each region cooperating in the plan.The following are the weighted average analyses, by sizes, of the samples taken in this survey;"

Jul 1, 1935

By J. W. Eckerd

Metal production rates of 42 to 45 tons per day were obtained with hollow-core anthracite briquets in an experimental blast furnace. Tuyere pressures were about the same for both coke and briquet operations, but from 150 to 175 pounds more of briquets were required per ton of metal than were needed with coke. Furnace operations were comparatively smooth, furnace hanging occurring less often than in previous tests with anthracite briquets. Dust production was substantially higher than with coke, however, and metal quality could not be controlled by corrective burdening and moisture control.

Jan 1, 1968

By P. W. Jeran

The Beckley mine is one of five new mines in a heretofore unmined portion of the Beckley coalbed. The remoteness of these new mines from prior mining and their greater overburden preclude applying methane emission experience obtained in the old mines. Four sections of the Beckley mine were monitored. The data gathered show that variations in methane emission cannot be explained by variations in coal production. Although overburdens varied by as much as 30 pct, no correlation with methane emissions could be determined. The rib emissions increase with increased length of rib from a section advancing into virgin coal and do not decline over a prolonged idle period (32 days) whereas some decline has been measured for a section not mining into virgin coal. The indication is that degasification prior to mining will reduce the hazard of methane emissions in this area of the Beckley coalbed.

Jan 1, 1977

By Ralph B. Adair

The Bureau of Mines conducted laboratory and small-scale, continuous tests of weathered mica-pegmatite ores from Randolph County, Ala., to determine the feasibility of recovering commercial-grade mica concentrates by flotation. Two flotation methods were used in continuous tests for recovery of mica. One method utilized acid-cationic flotation for the recovery of coarse mica and alkaline-anionic-cationic flotation for recovering fine mica. This method yielded mica concentrates containing 98.6 percent mica with a recovery of 85.9 percent. The other method was based on the Bureau-developed alkaline-anionic-cationic method, and yielded concentrates containing 97.5 percent mica with a recovery of over 90 percent. In both methods, preconcentration of the ground ore on a Humphreys spiral was employed to reject over half of the feed in a product virtually free of mica.

Jan 1, 1968

By E. K. Stanek, P. Kantabutra, R. A. Wolf

This paper summarizes the cause and effect of induced voltages in multiple conductor cables supplying alternating current power to equipment in under- ground coal mines. The investigation of this phenomenon revealed that the electrical energy produced by the resultant electric arcing between the frames of mobile electric face equipment was of a sufficient magnitude to ignite explosive methane-air mixtures. The results of laboratory tests and field tests made between equipment frames during actual operation in numerous coal mines are discussed. Several methods of eliminating or suppressing the induced voltages to nonincendive levels are also described. It is the purpose of this paper to convey to the mining industry a knowledge of this problem and to recommend methods of eliminating or reducing these induced voltages or arcing currents to safe levels.

Jan 1, 1975

By R. W. Van Dolah

The feasibility of formulating cap-sensitive slurry explosives for use in underground mines with potentially flammable gas atmospheres was examined. Formulations containing aluminum metal as sensitizer and sodium chloride to reduce incendivity were prepared; some were cap-sensitive and had adequate air-gap. Flaked aluminum metal rather than the atomized type proved to be the more effective sensitizing agent of the formulations tested for incendivity in the large gallery of the Bureau of Mines, some were found to be suitably nonincendive.

Jan 1, 1968

Lower the respirable dust exposure of longwall shearer operators by keeping the dust cloud confined to the face. Approach Change the location of face-side machine cooling, water sprays. How It Works The dust breathed by the longwall shearer operator is usually produced by the shearer itself. The dust cloud originates at the face, and the exposure of the operator depends largely on how quickly this cloud spreads into the walkway. Water sprays on the shearer body can have a large effect on dust cloud spreading. Results to date indicate that sprays can help confine the dust cloud to the face if they are carefully placed. Otherwise they can make dust levels far worse. The worst offenders are often face-side sprays used to discharge cooling water from the cooling jackets of the shearer motors. These face-side sprays set up an air circulation pattern as illustrated in the drawing. Air induced by the sprays to flow towards the face, raises the air pressure in front of the face, which causes the air flow to turn and then move back over the shearer, bringing dust with it into the walkway.

Jan 1, 1981

To inexpensively monitor the ventilating airflow anywhere in underground working places. The Approach: The Bureau has developed a small self-contained monitor which sounds an audible alarm and energizes a flashing lamp if air velocity decreases below normal. How It Works: The sensing element of this inexpensive monitor is a thermistor, which is self-heated by a constant-current electrical source. Airflow over the thermistor increases heat removal and lowers the thermistor temperature. Since the electrical resistance of a thermistor is a function of temperature change, the voltage across it varies with temperature, and, therefore, the air velocity. Changes in the voltage across the thermistor are amplified, and can be used to trigger the alarms.

Jan 1, 1975

By L. B. Pankratz

The Bureau of Mines conducted heat-content measurements above 298.15° K for dehydrated analcite (NaAISi2O6) to 1,000°K, kaliophilite (KA1Si04) to 1,800° K, and leucite (KAlSi206) to 1,800° K. Heat content and entropy increments were tabulated, and the heat content data, were given in equation form. A first order transition was noted for kaliophilite near 810° K with a heat absorption of 160 cal/mole. Leucite had a second order transition which became complete near 955° K. In this transition a crystal change occurred from tetragonal (low-temperature form) to cubic (high-temperature form).

Jan 1, 1968

By B. W. Gandrud

[The meaning of the term "bauxite' has always been somewhat vague and indefinite, and the term has been used in various applications to denote sometimes a rock, sometimes a mineral, but more frequently an ore. It seems logical to think of bauxite as an ore, however, because a very large part (probably at least 85 per cent) of the entire world's production of bauxite is at present being used as a source of aluminum and aluminum chemicals. In the United States there are two districts that, produce bauxite - the Arkansas district and the Alabama-Georgia-Tennessee-Mississippi district. The deposits in Mississippi have been discovered recently and are riot as yet productive but it seems reasonable to consider them as apart of the-district hat includes the deposits of Alabama, Georgia, and Tennessee. The, two districts are often referred to as the Arkansas field and the Appalachian field. Of these two the Arkansas field has been by far the largest producer, and at present over 90 per cent of the bauxite production of they United States comes from the Arkansas field. The bauxite industry in the Appalachian field had its beginning in 1889, and since that time the total production of the states of Alabama, Georgia, and Tennessee has been, nearly a million tons. The production of bauxite in this field has languished in the last five, or six, years, and In 1927 its production was only about 14,000 tons, according to Harder4. The recent decrease in production is due mainly to the fact that many .of the known deposits of commercial-grade ore have become exhausted. There are, however, considerable quantities of low-grade bauxite in the Appalachian field, but these have not been available because there has been no satisfactory way of concentrating low-grade bauxite. The quantity, of low-grade material in the Appalachian field is probably, fully as large as the tonnage of commercial ore which the field has already produced.]

Jan 1, 1928

By James W. Vogh

The report covers initial findings in an experimental program to identify diesel exhaust odorants and determine their contributions to diesel odor. The approach was to isolate selected component groups from exhaust and to evaluate the contribution of each group to exhaust odor. Results were obtained for those carbonyls and phenols that could be isolated from exhaust through inter-mediate conversion to oxime derivatives. Unsaturated aliphatic aldehydes and sterically hindered carbonyls were not included. Hydrocarbons intermediate in the diesel range were "also evaluated and an odor contribution was found from those of the aromatic group. The evaluated carbonyls, phenols, and hydrocarbons were found to account for about 20 pct of the total odor in exhaust from an indirect-injection engine during idle. For exhaust from the indirect-injection engine operating under load and from a direct-injection engine at no load, these compounds were found to have no significant levels of odor.

Jan 1, 1972

By Jon C. Volkwein

The industrial sand industry has been exploring new techniques to reduce dust. One company was experimenting with adding water during bagging operations to the surface of the hag, and into the product as it flowed into the bag. The Bureau of Mines, using instantaneous dust sampling instruments, measured the effectiveness of three methods of adding water. Results indicated that various types of water sprays applied in carefully controlled amounts could reduce dust up to 50% at worker locations at the bagging machine and inside a railroad boxcar. This report also discusses constraints such as product handling, customer acceptance, cold weather problems, dust collector performance, and other areas.

Jan 1, 1981

By J. M. Singer

Approximate equations were used to compute the radiant heating of float coal dust by approaching flames for various combinations of particle size, dust path length (flame travel distance), flame temperature, dust concentration, flame speed, and flame length. The computed values of degree of radiant heating and flame travel distance for preheating the coal dust should be useful for estimating the increased fire hazard of different coal dust-flame parameters. Some findings relating to coal mine disaster control are-- 1. Coal dust clouds cannot be preheated to ignition temperatures by flame radiation alone when deflagration speeds are greater than about 10 m/sec. Thus it appears unlikely that radiation alone will cause flames propagating in dust clouds to accelerate to detonation velocities. 2. Small particles in the radiation flame zone caused by burnout and soot formation increase the degree of preheat significantly. 3. The concentration of float coal dust (radii = 3 to 40 microns) for maximum radiant heating usually peaks in the range 50 to 200 mg/liter of air.

Jan 1, 1970

By Suzann C. Ambrosio

Crude petroleum, the only commercially exploited mineral resource in Cameroon, continued to dominate developments in the mineral industry sector. International mining concerns have expressed interest in developing Cameroon's bauxite and iron and steel potentials. Domestically, the mineral industry focused on production of fertilisers for agricultural development, infrastructure construction, and hydrocarbon development, through the nearly self-sufficient production of fertilizer materials, cement, and crude oil. The mineral sector contributed 5.6% to the estimated 1981 gross domestic product (GDP) of $6.5 billion.2 Petroleum exports accounted for approximately 4.5% of the 1981 GDP and exceeded coffee and cocoa exports for the second consecutive year. The trade gap widened during the fiscal year ending on July 80, 1981, owing to a 21% increase in exports and a 25% increase in imports. Offsetting these balance-of-payments difficulties, typical of developing countries' early economic stages, were increases in foreign exchange reserves to $71 trillion by May 1983.

Jan 1, 1983

By Richard J. Bielicki

Poor mixing of methane and air at coal mine working faces causes fluctuating methane concentrations. If these fluctuations are large enough, methane levels can periodically exceed safe limits, even though the time average methane concentration may be satisfactory. Concentration fluctuations measured underground can result both from variations in methane emission rate and poor mixing. The present paper reports on a statistical analysis of fluctuations at a constant methane emission rate, that is, on fluctuations due only to poor mixing. A full-scale model of a working face was used. Both peak heights and elapsed times between peaks were evaluated. Good mixing was indicated by normal, Poisson, and exponential distributions while poor or incomplete mixing was indicated by log-normal or gamma distributions.

Jan 1, 1974