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By Richard D. Miller

The helium resources base of the United States was estimated by the Bureau of Mines to be 961 Bcf as of January 1, 1983. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas re- serves, 271 Bcf, (2) helium in probable natural gas resources, estimated at 202 Bcf, (3) helium in possible natural gas resources, estimated to be 351 Bcf, and (4) helium in speculative natural gas resources, which makes up the remaining 137 Bcf. These helium resources are further divided into depleting, nondepleting, and stored classifications. The depleting resources are those associated with natural gas fields that are, or will be, produced for the natural gas they contain. All of the helium in potential (probable, possible, and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 789 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, those in shut-in, abandoned, or otherwise nonproducing natural gas fields, are estimated to total 134 Bcf. There is 38 Bcf of helium in storage in the Federal Government- owned Cliffside Gas Field near Amarillo, TX.

Jan 1, 1985

By E. E. Donath, L. L. Hirst, L. C. Skinner

Two processes are available for the production of synthetic fuels from coal high-pressure hydrogenation and the carbon monoxide-hydrogen synthe- sis. This paper presents some ideas and new developments in coal hydrogen- ation that have been incorporated in an estimate for the production of 30,000 barrels per day of liquid fuels, mainly gasoline. A few comparisons of the processes will be helpful before discussion of the details of pro- posed improvements in the hydrogenation process. The principle of the high-pressure hydrogenation process ie the addi- tion of hydrogen at pressurea in the range of 3,000 to 10,000 p.s.i. to coal at elevated temperature and with the help of catalysts. On the other hand, the principle in the Fischer-Tropsch synthesis is the complete break-down of coal into a mixture of carbon monoxide and hydrogen, followed by the catalytic combination of these two gasse into hydrocarbons or suitable catalysts. For the synthesis, moderately elevated pressures of about 350 p.8.1. will bo used in the immediate future, although it can be carried on at atmosphoric pressure with certain catalysts. The products of these two processes using coal as raw material are almost as differont as hydrocarbons can be. The products of the high-pres- sure hydrogenation of coal reflect the original constitution of the coal. They are, therefore, rich in ring compounds, both aromatic and naphthenic, but, due to the action of highly comprcesed hydrogen and catalyst, are satu- rated and very stable. These constituents give the gasoline a high octane number and excellent rich-mixture performance, combined with good gum and storage stability. Therefore, this gasoline is suitable for aviation gaso- line or base stock. The Diesel fuel can be hydrogenated to a centane number of 45 or higher, which is entirely satisfactory for operating normal Diesel

Dec 1, 1948

By Noel N. Moebs

This report summarizes 10 selected Bureau of Mines research contract reports produced from 1970 to 1980 which consist largely of geologic studies of coal mine roof support problems. Significant highlights from the contract final reports are discussed and presented in practical terms. The selected reports focus on the Appalachian and Illinois coal mining regions. In the Appalachian coal region, two geologic structures, roof rolls and slickensides, predominate over all structures as features that directly contribute to roof falls. Studies of these and other structures are reviewed, and improved methods of utilizing drill core and core logs to prepare hazard maps are presented. Among the reports described are several on the weakening effects of moisture on shale roof, as determined from both laboratory and underground measurements, and an assessment of air tempering as a humidity-control method. Also summarized are findings concerning the time lapse between roof exposure and permanent support installation as a factor in the effectiveness of roof bolting.

Jan 1, 1984

By A. B. Hooker

Investigations at the Pittsburgh Experiment Station of the Bureau of Mines have shown that satisfactory operation of a flame safety lamp depends not only upon proper design and assembly of the lamp but also upon the kind

Jan 1, 1945

By Ivan F. Avery

OUTPUT of carbon black in 1959 increased in all producing States except New Mexico. The national increase was 20 percent. Domestic sales and exports increased 22 percent and 16 percent, respectively, resulting in a 21 percent gain in sales. Sales to the rubber industry, which purchased 95 percent of the domestic output of carbon black, increased 23 percent. Sales to all other major consumers also increased. Stocks decreased 82 million pounds during the year. [ ]

Jan 1, 1960

By W. N. Cathey

Many materials including carbides, silicides, phosphides, borides, nitrides, oxides, and metals were studied by the Bureau of Mines as potential fuel cell catalysts for electroreduction of oxygen in a 1[N]H2S04 electrolyte. The objective of this study was to assess the potential of abundant, low-cost materials as substitutes for platinum or to increase the catalytic efficiency of platinum. Several compounds were rejected because of their reaction in the corrosive environment of the oxygen electrode. However, some of the remaining were the most active catalysts. Activity of carbides such as tungsten carbide could be improved by doping with platinum-group metals, by varying stoichiometry, or by sputtering on a layer of platinum. While no catalysts were found with activity as high as platinum, some compounds were shown to be deserving of further investigation.

Jan 1, 1979

By A. B. Hooker, J. W. Paul

"There was a time when any suggestion that the Davy flame (safety) lamp be discarded, would have evoked unlimited, criticism. However, that time is past.Investigations both here and abroad have shown conclusively that the Davy lamp does not have the necessary factor of safety against ignitions of mine gas, and England, the lost stronghold of the Davy lamp in Europe, has eliminated this lamp and substituted safer types.In the United States there are companies who still use the Davy lamp in spite of all that has been said and published as to the dangers connected with its use.Recently the purchasing agent of an anthracite coal company requested the Department of the Interior, Bureau of Mines, to pass upon the safety of some braise gauzes for use in a shielded Davy lamp. A shielded Davy lamp is an ordinary Davy safety lamp equipped with a circular brass shield that is attached to the lamp posts. This shield extends about one-half way around the gauze and one-half of the gauze height. The main purpose of the shield is to prevent the lamps being extinguished by a sudden increase in the velocity of the air current past the lamp.The brass gauzes submitted for this test represented two grades of brass - a yellow brass and a red brass. The analysis of these brasses was not determined. Two shielded Davy lamps that were submitted for the tests each had a steel gauze. These steel gauzes were also tested. Tests were made in horizontally moving mixtures of Pittsburgh natural gas and air at velocities of 400 to 1,000 feet per minute. The gas percentages used were 7%, 8.6%, and 11%. Tests were made with the lamp shield in two positions relative to the lamp and direction of flow of the gas-and-air mixture. In one position the shield was between the gauze and flow, as normally used. In the other position the shield was on the downstream side of the lamp. The tests were continued until one or more failures or gas explosions been obtained with each of the six gauzes. The results of these tests summarized as follows:"

Jun 1, 1923

By David C. Byrne

PURPOSE: Evaluate practical technological advances in level-dependent hearing protectors and inexpensive personal acoustic monitors. RESEARCH SUMMARY: The results of previous NIOSH research show that miners develop hearing loss much more quickly than nonoccupationally noise-exposed individuals and that miners experience a greater severity of hearing loss than would be expected for nonoccupational noise-exposed persons of the same age and gender. Using hearing thresholds at 4,000 Hz as an indicator, coal miners experience hearing loss 2.5 to 3 times greater than would be expected for persons not exposed to occupational noise. At age 50, 90% of coal miners and 49% of metal/nonmetal miners were found to have a hearing impairment. In comparison, only 9% of a nonoccupationally exposed control group had a hearing impairment at age 50. There are numerous barriers to the prevention of hearing loss among miners. In an effort to overcome some of these obstacles, this work was initiated to evaluate practical technological advances in level-dependent hearing protectors and inexpensive personal acoustic monitors. Experiments will involve analysis of this new technology under both laboratory and field conditions. Laboratory components will consist of controlled studies using an anthropometrically correct test fixture as well as human subjects to evaluate the adequacy/effectiveness of various hearing protective devices. Electroacoustical performance testing of new noise monitors will also be conducted in a laboratory setting. Subsequent field studies will determine the actual usefulness and practicality of the personal protective/monitoring equipment as used in different mining situations. It is anticipated that increased on-the-spot awareness of hazardous noise levels and the availability of better-suited hearing protectors will provide a degree of protection beyond what is currently attained in different mining environments. Therefore, the intent of this project is to identify and adapt new acoustical technologies and products that have a direct application to individual mine workers. With increased knowledge of these technological advances, a greater demand for similar devices will likely occur, which, in turn, will lead to a better understanding and awareness of hearing loss prevention methods throughout the mining community. The ultimate goal is for widespread integration of useful hearing loss prevention products and devices into the daily routines of miners

Jan 2, 2000

By W. P. Haynes

The Bureau of Mines has been studying a modified steam-iron process using coal-derived producer gas for making either hydrogen plus carbon monoxide or methane. To provide a guide for this experimental study, compositions of equilibrium product gases for the reaction of steam plus carbon dioxide with iron were calculated and are discussed in this report. The calculations, which are described in this report, are based on thermodynamic data in the literature and cover temperatures from 800° to 1,300° K., pressures from 1 to 30 atmospheres, and hydrogen-to-carbon atomic ratios in the gas of 4 to 12. The equilibrium gas compositions are discussed in regard to making hydro-gen, carbon monoxide, and methane in the oxidation step of the modified steam-iron process. From the viewpoint of thermodynamics alone, assuming the reactions reach equilibrium, the discussion considers the effects of temperature, pressure, and composition of feed gas upon the composition of the product gas, the degree of oxidation of the iron, and the possible deposition of carbon. The results indicated the following: (1) Nearly all the carbon can be converted to methane at low temperatures (800° to 900° K.) and high pressures (over 20 atmospheres); (2) to obtain high yields of synthesis gas, high temperatures are required. For example, at 30 atmospheres, a temperature over 1,200° K. is required to convert 60 percent of the steam plus carbon dioxide to hydrogen plus carbon monoxide. Lower temperatures may be used at lower pressures) (3) oxidation of the iron increases with increasing pressure and decreases with increasing temperature; and (4) process conditions favoring carbon deposition were found within the range of variables studied, but it is thermodynamically possible to operate the oxidation process with steam and carbon dioxide outside this range of carbon deposition.

Jan 1, 1961

By Kenneth E. Hay

The Bureau of Mines collected coal and coal waste aggregate material from two different mine sites to determine their strength characteristics for use in concrete. The concrete would be placed underground as support walls for ground control in adverse conditions or unique mining applications. A standard mix design was established for a "wet" mix using a water-to-cement (w/c) ratio of 1.0 to facilitate pumping into place. Later, material was collected from four more mine sites and used to make 2-by 2-by 2-ft test blocks with the same w/c ratio. A pull-out cone device and borehole shear tester were used to determine the in situ material strength of the test blocks. These techniques will provide a simple and quick way of determining support wall strength in an underground environment. Test results from the pullout cone de-vice showed a good correlation of 0.98 to test cylinder compressive strengths of the same mix. Results of the borehole shear tester were inconclusive.

Jan 1, 1986

By J. K. Whyatt

Researchers at the U.S. Bureau of Mines have been exploring recent advances in the use of strain-softening constitutive laws that approximate shear fracturing. The purpose of these tests is to investigate shear-fracture-related rock bursts in hard-rock mines. The capabilities and remaining problems in the use of strain-softening laws in finite-element, distinct-element, and finite-difference methods are reviewed. Performance of the finite-difference implementation of strain softening is compared to classic experimental results and observations of rock mass behavior in the Coeur d'Alene Mining District of northern Idaho. The results show promise for developing methods to identify the general location and orientation of shear fractures and their sequence of occurrence, but such methods cannot be relied upon to quantify post-fracture loads or displacements accurately. Uncertainty over the amount of energy consumed by failing rock and the dependency of energy consumption on model mesh definition prevent direct application of the results to analyses of rock bursts.

Jan 1, 2010

By William K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating the electrochemistry of mineral flotation. A significant need in this area is greater reliability of sensors. The USBM is testing electrolytic methods to clean and condition redox-sensing electrodes to improve the reliability and extend the service life of these instruments in the harsh physical and chemical environment of mineral processing slurries. A novel method for removing scale from fouled electrodes has been developed that includes anodic polarization to 1.2 V versus the Ag/ AgC1 reference potential, followed by brief potentiodynamic conditioning. Laboratory results show that this technique removes calcarious deposits from gold sensing electrodes and returns the electrodes to useful service within approximately 10 min. Mechanical abrasion to remove the scale is thereby avoided.

Jan 1, 2010

By Mark I. Copeland

The formation of A1203 dispersoids 0,14 and less in size in dilute iron-aluminum alloys by internal oxidation in wet hydrogen and dispersion strengthening of iron by application of the technique to iron powder were found to be feasible by the Bureau of Mines. In flowing H2-1.5 H20 gas, A1203 dispersoids 0.1w and less in size formed (at 650° to 750° C) in Fe-l and 2 Al sheet material but not in Fe-3 or 4 Al alloys. With higher temperatures and/or higher H2O/H2 volume-ratio gases, A1203 and FeA1204 dispersoids >0.14 in size formed in all the sheet materials- Minus 100-mesh Fe 2 Al powders were internally oxidized under conditions that promoted formation of fine A1203 particles in sheet material, and then the oxidized powders were hydrogen reduced, sintered, extruded, and evaluated. During internal oxidation, fine A1203 dispersoids formed within the powder grains, and coarse FeA1204 particles formed on the powder surfaces and grain boundaries. The FeA1204 content was essentially eliminated during sintering by reacting with the unoxidized aluminum that remained in the center of the larger internally oxidized powders. The tensile strength at 800° C depended upon the aluminum-oxygen weight ratio of these elements in the extrusions and reached a maximum of 17,000 psi. The stress-rupture strengths at 800° C of the better alloys were comparable with those of type 310 stainless steel.

Jan 1, 1972

By J. D. McLenegan

The purpose of this investigation was to prepare a market survey of the refractories industry in California and Nevada (referred to in subsequent paragraphs as the region), and to determine the degree of self-sufficiency and the potential capacity for anticipated growth. The report includes estimates of the total annual refractories consumption, the quantity of refractories imported into the region, the tonnage of raw materials required for their manufacture, and the resources of fire clay and high-alumina minerals in the region.

Jan 1, 1956

By Maria I. De Rosa

Table 28 and figure 10 show the number of fires and fire injuries for coal preparation plants by state during 1990-1999. Table 28 also shows the risk rates, employees' working hours, and lost workdays by state. For coal preparation plants, 91 fires occurred in 1 1 states during 1990- 1999. Twenty-three of those fires caused 25 injuries (the yearly average was 9.1 fires and 2.5 injuries). Ten fires and eight injuries involved contractors. The Ewhr value was 24 1 x 10' hr (Irr = 0.02 l), and the LWD value was 198. Pennsylvania had the most fires (24 fires and 4 injuries), whereas West Virginia (22 fires and 7 injuries) and Kentucky (22 fires and 7 injuries) had the most fire injuries. Among these states, Kentucky had the highest injury risk rate value (Irr = 0.025). Table 29, partly illustrated in figure 11, shows the number of fires, fire injuries, risk rates, employees' working hours, and lost workdays by time period. The number of fires decreased during most of the periods (an increase is seen only during the last period). The number of fire injuries show a decrease followed by an increase during the periods, accompanied by a decline in employees' working hours throughout the periods. The Irr values follow patterns similar to those shown by the injury values (see table 29 and figure 11). Tables 30-35 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 12 shows the major variables during 1990-1999. Table 36 shows the fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By W. G. Pariseau

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. The present study uses rock deformation measurements to validate and calibrate a geomechanical model of the experimental Lucky Friday underhand longwall (LFUL) stope on the 5,100-ft level of the Lucky Friday Mine, Mullan, ID. The calibrated three-dimensional, finite-element model and measurements of rock mass displacement show a correlation of 0.795. The calibration reduces rock mass modulus to 14 to 17 pet of laboratory values and rock mass strength (with an energy rule) to 37 to 41 pet of laboratory values. This model suggested that stress-related ground control problems would be encountered west of the stope where the vein makes a right-angle turn and then splits. Rock burst activity was concentrated in this area during mining of the LFUL stope.

Jan 1, 2010

By M. Viswanathan, M. J. Jorgensen, N. K. Kittusamy

Operating heavy construction equipment is often associated with elevated rates of low back discomfort (LBD). However, there have been few formal studies that dealt with evaluating controls that can reduce the LBD among these workers. The objective of this study was to determine the effectiveness of using a continuous passive lumbar motion system (CPLMS) in reducing low back discomfort among operators of heavy earthmoving equipment. The CPLMS is an additional seat support that has a lumbar support bladder and a pump to provide cyclic inflation and deflation. Two groups of operators were identified as potential subjects for this intervention study, the intervention group with a mean age of 41.2 years and experience of 9.7 years used the CPLMS, and the control group with a mean age of 37.5 years and experience of 7.6 years did not use the CPLMS. Body part discomfort surveys were collected from both groups. In addition, the intervention group completed a CPLMS preference survey. The body part discomfort survey was collected up to eight days at three different times of the day. Results from the body part discomfort survey showed a decreasing trend the longer the CPLMS was used, for both the upper and low back region. A decreasing trend for the low back was also found comparing morning to evening discomfort scores across the days when using the CPLMS. When compared to their regular seat, 54% of the operators felt very comfortable in using the CPLMS, 36% of them wanted one for their equipment, and 54% showed interest in experimenting with the CPLMS for a longer time period. Results from this study indicate that the use of a CPLMS can effectively reduce the low back discomfort experienced by operators of heavy construction equipment.

By John A. Davis, John Gross

Six tests were made by the Alaska Station of the Bureau of Mines on a sample of black sand delivered to the station by Messrs. James, Eagan & Griffen from Fairbanks Creek, Fairbanks mining district, Territory of Alaska, to devise a method of recovering the gold content. More than 90 per cent of this black sand consisted of magnetite and garnet which can be separated magnetically. The Station has no equipment for magnetic separation other than an electromagnet similar to the one used by Day and Richards, (Day, D.T., and Richards, R.H., Investigations of Black Sands from Placer Mines, U. S. Geol. Survey, Bull. 285, 1906, pp. 150-163), which can only be used satisfactorily on small samples. To treat the entire lot of black sand with this machine would have been impracticable. Therefore only a small part of the sand was so treated, the rest being divided into five lots in order to obtain comparative results from other methods of treatment.

Aug 1, 1920

In laboratory tests using reconstructed soil columns, rubber latex showed good sealing efficiency when applied at a rate equivalent to 4000-5000 pounds per acre. Results of field testing, however, were inconclusive. The ideal situation in which latex would coagulate in a narrow zone two to three feet below the surface by reacting with acidic or metallic constituents of the soil was not attained. Rather, the latex was deposited progressively as it passed through the soil (most of it remained in the top foot), the rate of deposition being dependent on soil structure and composition as well as on properties of the latex such as particle size and emulsion stability. Latex stability appears to be a more critical property than latex particle size in controlling penetration. Addition of excess anionic or nonionic surfactants to latex improved its penetration into the soil. A styrene-butadiene (SBR) rubber latex of 2400 Å average particle size with high mechanical stability gave the best balance of penetrating ability and sealing capacity in laboratory tests and this was confirmed in tests on a 5 x 5 foot test plot at Lanse, Pennsylvania. This latex was subsequently applied to three one-quarter-acre plots at Lanse by sprinkler irrigation, and compared to adjacent areas that were sprinkled with water only. Soil moisture measurements did not enable us to judge the effectiveness of the seal because differences between sampling positions were greater than differences between treated and untreated sections, but permeability tests showed that water flow was much slower (90-99% reduction) within the top ten inches of soil in the latex- treated sections. This sealing effectiveness was reduced after wintering. There was no deleterious effect on the vegetation as a result of sprinkling the areas with latex. A laboratory study conducted in a 5 x 5 x 5 foot box containing uniform reconstructed soil from a New Jersey source suggests that latex penetration into the soil in the field occurs mainly through natural macro openings and not through the capillaries of the soil structure. Dilute solutions of ammonium hydroxide or sodium carbonate (with no latex present) were found to seal effectively in laboratory soil columns as well as in field applications. However, since these chemicals are water soluble, the seal is temporary. Raw material costs of latex at the application rates used in the field testing are in the order of $1000 per acre. Equipment and operating

Jan 1, 1972

By R. E. Head, Virgil Miller

"Under existing conditions in the treatment of oxidized lead ores containing small quantities of molybdenum no provision is made for the recovery of the molybdenum. Considerable quantities of this important element are lost in the slags of the lead smelters and constitute an economic waste. There is little or no probability that slag dumps containing molybdenum in small quantities could be economically treated for the recovery of the element, and steps for the prevention of waste in this respect must be taken prior to smelter treatment.Wulfenite, lead molybdate (PbMo04), and molybdite, molybdic ocher (Mo03), are the molybdenum minerals most abundantly found in deposits of oxidized lead ores. Wulfenite contains 39.3 per cent molybdenum trioxide and 60.7 per cent lead oxide; molybdite contains 66.7 per cent molybdenum and 33.3 per cent oxygen. Plumbojarosite, argentojarosite, cerussite, and occasionally anglesite are commonly associated with wulfenite ores, and the oxidized iron content is usually fairly high.The recent discovery and development of a body of wulfenite ore in the Star district near Milford led to a cursory microscopic examination of samples of the ore, followed by a few preliminary tests which had for their object the separation and recovery of the lead and molybdenum in separate products.The microscopic examination showed that the samples used in the work were composed of wulfenite, plumbojarosite, and a small quantity of cerussite, and indicated that the iron content was quite high. The ore was porous and yellowish-brown; crystals of wulfenite appeared to be quite uniformly distributed through it, and this mineral and plumbojarosite (Pb0.3Fe203.4S03.6H20) apparently accounted for the major part of the lead content, although lead"

Sep 1, 1928