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By W. W. Adams

Two important facts stand out as features of the metal- and nonmetal-mining4 industry of the United States in 1941 as compared with 1940: First, the number of employees and man-days of employment increased; second, accident-frequency rates, both fatal and nonfatal, decreased. Reports from mining companies to the Bureau of Mines covering underground, open-pit, and surface operations for 1941 re¬vealed the largest number of men employed since 1926 and the largest number of man-days worked since 1929. The combined fatal and non¬fatal accident-frequency rate for 1941, calculated on a basis of one mil¬lion man-hours of exposure to hazard, was (except for 1931 and 1932) the lowest since 1911, the earliest year for which figures are available. During this 31-year period, only 1938 and 1939 showed lower fatality rates, and only 1931 and 1932 had lower nonfatal-injury rates. Operating companies reported that 9,620 mines were active during all or some part of the year. These employed 125,290 men, an increase of more than 4 percent over 1940. The total volume of work performed at all mines, measured in terms of man-shifts, increased to nearly 32 million, a gain of 10 percent; man-hours of employment rose to almost 254 million, an increase of 10 percent over the 231 million man-hours worked in the previous year. The year's operations resulted in an average work-year of 255 days per man, an increase of 13 days per employee over the average working time in 1940. Although the 8-hour day prevails generally at most mines, the industry as a whole averaged 7.94 hours per shift, as in 1940.

Jan 1, 1944

By H. J. Kelly

[This investigation of the refractory properties of seven Pacific Northwest chrome ores and concentrates has shown that five of the ores and one of the concentrates are suitable for making refractories and that all may be used in combination with high-grade chromite. The specific objectives of the investigation were to determine the inherent physic al and chemical characteristics, to shapes using each of the chrome ores and concentrates, to compare the refractory qualities of the laboratory-prepared with commercial chrome refractories. As far as possible, standard tests were used as criteria.]

Jan 1, 1952

By E. C. Lane

For a number of years the Bureau of Mines has been studying crude petroleum from the producing fields of the United States. During the past year 10 crude-oil samples have been collected and analyzed from the producing fields of Pennsylvania and New York. This report gives the results of these analyses and for the purpose of comparison also analyses of samples of crude oils taken previously from some of these fields. This survey includes samples from normal producing properties as well as from properties using stimulative production methods such as water flooding and repressuring. The outstanding feature of the survey is that the crude oils from tine various fields throughout this general area are similar in character and uniform in quality although they were produced from different sands and by various methods. Samples from fields in Venango County, Pa., however, appear to have a lower gasoline content than the others. This report includes two analyses reprinted from Bureau of Mines Bulletin 291.4/

Jan 1, 1938

By Benjamin W. Haynes

This research was conducted as part of the U.S. Department of the Interior, Bureau of Mines program to recover metals, glass, and a combustible fraction from municipal solid waste (MSW). The objective of this analytical study was to determine the concentration of antimony, arsenic, and mercury in samples taken from various sampling areas in the Bureau of Mines raw refuse recycling plant and to compare these values with those for coals used in the generation of electricity. To provide the necessary analytical data, sensitive reproducible ashing-chemical digestion-atomic absorption procedures were adapted from published procedures. It was determined that antimony and mercury concentrations in the combustible fraction of MSW are approximately an order of magnitude higher than those found in coals presently used for power generation;' the arsenic concentration is similar in both fuels.

Jan 1, 1978

By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, -(G° - H°298)/T, ?Hf°, ?Gf°, and log Kf as a function of temperature are given in tabular form. Thermodynamic data were compiled for VOSO4, Cr2(SO4)3, MnSO4, FeSO4, Fe2(SO4)3, CoSO4, NiSO4, Cu2SO4, CuSO4, CuO-CuSO4, ZnSO4, and ZnO-2ZnSO4, together with their stable hydrates.

Jan 1, 1982

By G. Richards Gwinn

"Mica" is a group name for a number of orthosilicates of aluminum with magnesium, ferrous iron, and the alkalies. They are characterized by their high reflection and a basal cleavage so well developed that they can be split into exceedingly thin laminae, which are more or less tough, elastic, and transparent, according to variety. Barium, manganese, lithium, chromium, titanium, boron, and ferric iron occur in same varieties. Eight distinct species of true mica, which appear in the following table, are recognized by mineralogists, but only the first five are of commercial importance. [Species General Formula Muscovite H2KA13 (SiO4)3 Phlogopite [H,K, (MgF)]) Mg3A1 (Si04)3 Biotite (H,K)2(Mg,Fe)2(Al)Fe)2 (S104)3 Lepidolite K,Li Al(OH,F)2 Al (5103)3 Ros coalite H8K(Mg,Fe) (A1,V)4 (S103)12 Paragonite H2NaAl3(S104)3 Zinnwaldite (K)Li)3 FeAl3 Si5016(OH,F)2 Lepidomelene HK2F3IIIFe6III A13 (S104)9]

Jan 1, 1951

By James H. Scott

Well-logging techniques that have been used to evaluate various types of mineral deposits are discussed briefly, and many pertinent references are cited. Information is categorized by mineral commodity to make it easy to determine what logging techniques have been used for evaluating specific metals and nonmetals. Part 1 discusses logging techniques applied to deposits of the following metals: aluminum, antimony, beryllium, boron, copper, iron, lead and zinc, maganese, mercury, nickel, silver and gold, tin, tungsten, and uranium. Part 2 covers the following nonmetals: coal, evaporites, fluorspar, oil shale, rock salt, and sulfur. Separate bibliographies are given for English and foreign language references.

Jan 1, 1974

By Jennifer A. Slatnick

Chlorofluorocarbons (CFC's), once universally accepted as ideal compounds for use in cooling and refrigeration, in foam production, and in cleaning electronic components, are being phased out and eventually banned under extensive international agreements because the chlorine in CFC's is thought to deplete the Earth's ozone layer. The industry has responded with the introduction of alternatives in the form of hydrofluorocarbons (HFC's), which contain no chlorine, and with hydrochlorofluorocarbons (HCFC's), which fill an intermediate gap in the replacement of CFC's. As a result of the elimination of chlorine in the HFC's and the reduction of it in the HCFC's, these alternatives contain more fluorine than the CFC's do. Other nonfluorocarbon substitutes, known as not-in-kind alternatives, contain no fluorine at all. As a result, the fluorspar mining industry, which is the source of fluorine in fluorocarbons through intermediate hydrofluoric acid, is being affected. Concern for this impact has led the U.S. Bureau of Mines to employ its capabilities to analyze various scenarios in the evolution of CFC replacements and substitutes to determine their effect on fluorspar mining. This report utilizes a network flow model to examine the effects of proposed replacements for CFC's, in terms of fluorine content, on fluorspar operations worldwide and on hydrofluoric acid plants in North America and Europe.

Jan 1, 1994

By D. A. Reynolds

Yields of ammonium sulfate obtained in the carbonization of coal frequently vary from plant to plant, because ammonia is an unstable compound at high temperatures and therefore sensitive, to changes in carbonizing conditions. Differences in byproduct yields of ammonium sulfate obtained at different plants generally are accounted for by variations in plant procedure, either in preparing the coal or in its carbonization. However, technicians of one large corporation,- which frequently obtained higher yields of ammonium sulfate in its Alabama plants than ever were attained in its Ohio plants, "could not reconcile the differences in yields with their plant operations. These investigators suspected that the Alabama, coal used in their southern plant yielded more ammonia because its composition differed inherently from that of the Pennsylvania and West Virginia coals fused in their Ohio plants, although this concept could not be proved readily in their large-scale operations. Their view is supported by experimental data obtained A Beau of Mines-American Gas Association (BM-AGA) carbonization tests) -21 of a large number of coals including those carbonized commercially in Alabama and Ohio.

Jan 1, 1949

By Laurel A. Powers

The Bureau of Mines process for recovering Ni and Co from low-grade domestic laterites uses a reduction roast followed by an ammonia, ammo-nium sulfate leach. This investigation examined the waste streams of the process for their potential environmental impact and focused on the laterite residue produced. The U.S. Environmental Protection Agency's extraction procedure (EP) toxicity tests and column leaching showed that leachable metal concentrations would be low enough so that the residue would not be considered a hazardous waste under present definitions. Under nonacid leaching conditions, about the same amount of metal was extracted from laterites as from their residues, and the leachates were similar to water samples from an undisturbed laterite deposit. Washing tests on the laterite residue showed that ammonia and ammonium sulfate concentrations were reduced according to equilibrium stage calculations, resulting in residues that would be acceptable for revegetation. With water washing only, the residue would not be considered a hazardous waste even though significant amounts of Ni and Co were absorbed from entrained leach solution onto the residue. Washing first with fresh leach solution and then with water prevented this absorption and thus improved the overall metal recovery.

Jan 1, 1983

By R. Lindsay Mundell

In the first half of 1990, lessening of cold war tensions was welcome. But Iraq's invasion of Kuwait in August led to the Persian Gulf War in January and February 1991. The subsequent oil shock contributed to a dampening of the U.S. economy, and the U.S. gross national product rose only 0.9 % to $5,463 billion (U.S. billion = 109). The buildup of military forces in the Persian Gulf area focused greater attention not only on petroleum but also on other strategic materials. The U.S. Department of Defense continued to review stockpile goals and upgrade several mineral materials. In addition, the U.S. Bureau of Mines continued to maintain the standby Emergency Minerals Administration. After the Defense Production Act, which authorizes priorities, allocations, and supply expansion, lapsed on October 20, 1990, the Selective Service Act of 1967 became the authority to ensure that orders of the Armed Forces and defense atomic energy programs were given priority treatment.

Jan 1, 1993

By Paul M. Tyler

A great variety of substance that differ widely in chemical, mineralogical, and physical properties are loosely linked under the generic term "clay", but for the average man all that matters is whether a given material can be sold or used profitably. So-called "clays" range in texture from true clays and allied minerals that are typically "fat" or sticky to fine sand. Sand and other strictly silicious materials, such as tripoli and diatomite, are not clays in any sense; but many commercial clays are strictly loams, for they are intermediate in texture and always contain a mixture of minerals, though the term "loam" has little commercial usage except in foundry work. Even pure kaolinite, ordinarily considered the typical "clay substance", recently was found to exist as three distinct minerals; and each of these, in turn, exhibits variations in particle size and other physical attributes. Probing with the X-ray and employing other modern tools and techniques, scientists are tracing the patterns of molecules and finding chemical and physical phenomena that seem to disclose the causes for the markedly different behavior of the various aluminum silicates with varying proportions of combined and adsorbed water that are the essential ingredients of commercial clays; but rule-of-thumb definitions and enforced reliance upon empirical tests of actual samples still hold sway. In addition to the hydrated simple silicates of aluminum, almost all clays contain quartz, feldspar, and mica with varying amounts of organic matter and, in addition, other impurities - such as iron, manganese, and titanium oxides - that may discolor them sufficiently to render them unfit for certain important uses. The white clays are generally the purest, but no two clays are really alike, and great care must be exercised to maintain a reasonable uniformity in successive shipments even from the same deposit.

Jan 1, 1938

By William T. Reid

Low-temperature carbonization of coal in Japan served as an important source of liquid fuels during the war. Six plants operating in Japan Proper produced 203,069 KL (53.7 million gallons) of liquid fuel from 1940 until the end of the war in August 1945, while four additional plants in Karafuto and Korea produced 211,943 KL (56.0 million gallons) for a total of 415,012 KL (109.7 million gallons) of liquid products. Semicoke produced in these plants was used for domestic fuel, for gasi- fication in portable gas producers on automotive vehicles, and to replace imported low-volatile bituminous coal in the manufacture of metallurgical coke. Since 1936 one plant had produced more than 300,000 metric tons of semicoke for blending with bituminous coal to form coke, while the total production of semicoke since the beginning of the industry in 1923 is approxi- mately 2,000,000 metric tons. Despite an apparent annual carbonizing capacity of about 2,000,000 metric tons of coal for the entire country, the maximum amount of scmicoke produced during the peak year, 1943, was 468,446 metric tons. The equipment used is primarily of Gorman design. Just before the end of the war, 6 plants using 20 Lurgi carbonizers were operating with a total rated capacity of more than 1,500,000 metric tons of coal per year, while 2 Koppors units had a combined annual rated capacity of 400,000 metric tons of coal. One plant using the Japanese-designed Mimura system was in service but with so much mechanical trouble that its output was small, while in another plant 4 Wanisht carbonizers of Japanese design but based on an early German development were running satisfactorily, and carbonizing about 100,000 metric tons of coal per year. A single installation of 15 American-designed Knowles ovens was operating near Tokyo but was carbonizing pitch for electrode carbon. ..! No true low-temperature process used in Japan could carbonize strongly. caking coals satisfactorily. The Mimura process designed for this purpose was unsuccessful, as was the Shimomura process before it, while the Lurgi, Koppers, and Wanishi systems operated only with noncaking or very weakly caking coals. The Knowles ovens, really a medium-temperature process, could carbonize-caking coal without difficulty...

Feb 1, 1948

By Tilman M. M.

The effects of substituting cobalt for nickel on the acid corrosion resistance of two types of austenitic stainless steel were determined. Cobalt substitutions to a maximum 2.2 weight-percent were made in types 302 and 309 stainless steels. Total immersion corrosion tests were made in 10 volume-percent hydrochloric acid, and boiling-acid tests were conducted in 65 weight-percent nitric acid and in undiluted glacial acetic acid. For modified type 309 in acetic acid, corrosion rates decreased for additions greater than 0.57 weight-percent cobalt. Corrosion rates increased as cobalt was increased up to about 1 weight percent for modified type 302 in nitric and hydrochloric acids and for modified type 309 in nitric acid, but these rates decreased with a further increase in cobalt content. A gradual increase in corrosion rates with increasing cobalt content was shown for type 302 in acetic acid and for type 309 in hydrochloric acid. Cobalt substitutions in larger amounts (above a ratio of 8 Ni to 1 Co) may increase the corrosion resistance of the austenitic stainless steels.

Jan 1, 1965

By J. M. WADSWORTH

The purpose of this bulletin is to describe the methods of constructing and operating representative types of plants in the United States used for removing the light hydrocarbons from petroleum by continuous distillation, such plants being commonly known in the trade as topping or skimming plants. In the discussion of each plant an endeavor has been made to arrange the text similarly in order to facilitate comparison and to emphasize the important features. The various experimental values for the specific and the latent heats of the oils apply approximately to the oil treated. Careful experiments with each oil and its commercial fractions were not justifiable in view of the purpose of this report. It is regretted that limitations for recording data at the different plants made impossible the determination of a heat balance for each, which would have provided an equitable method of comparing efficiencies. The writer has confined himself to a comparison of the relative efficiencies of the distilling apparatus alone by the following method: Effi . f till d tt" _ Heat theoretically required. ciency 0 SIS an se mgs - Heat content of fuel consumed. The plants described are all in California where the topping industry has had its growth accentuated by the character and the use of the oil handled. The scarcity of suitable coal made the adoption of other fuel necessary, and the heavy oil of California supplied the need. To raise the flash point and to dehydrate this oil, various plants have been developed. However, the topping industry is represented in other fields; the Roxana Petroleum Co. of Cushing, Okla., and the Warner-Quinlan Asphalt Co. of New Jersey, are operating Trumble plants, and Texas and Oklahoma operators have been experimenting with different pipe retorts for continuous running. In addition to the reasons for topping cited above, in California topping has other purposes which give the plants practically a universal field in the oil industry. These additional purposes are (1) to remove the lighter constituents of the oil prior to storage for a long period, thus reducing the losses from evaporation, (2) to dehydrate and clean the oil, and (3) in conjunction with a complete refinery, to remove the lighter fractions cheaply and quickly, leaving a residue to be rerun for lubricants, coke, and other products. The reader in studying a plant for possible adaption to his own use should note that local considerations enter into the design and size of a plant. Several questions present themselves, as follows: 1. What type is suitable for the oil? 2. How much money is available for construction? 3. Will the volume of residuum be large enough for heat exchange with the crude? 4. Can the heat content of the vapors be used to reduce the cooling-water requirements? 5. What method will best recover the heat from stack gases? 6. Are the various pieces of apparatus adequate in size and best adapted to their purpose? 7. Is every possible provision made for the recovery of waste heat? 8. What products will be made, and what volume of each? 9. Is there provision for the recovery of light vapors? 10. Will the saving of fuel justify the capital and maintenance charges on the regenerative apparatus contemplated? It is regretted that information concerning the operation of topping plants with eastern and Middle West oils is not available. The writer carefully canvassed the Middle West, but did not find a plant where operation had progressed beyond the early experimental stages and reliable figures could be furnished. The reader will find fuel economy and heat recovery emphasized throughout the descriptions. The conservation of the available petroleum supply is of the utmost importance, and the Bureau of Mines presents this paper to encourage the hearty cooperation of operators to that end. The Baume gravity scale used throughout the report is that of Tagliabue with a modulus of 141.5 for conversion to specific gravity.

Jan 1, 1919

By R. T. DeWoody, J. W. Chester, W. C. Miller

The work was done to develop a relatively efficient muffler for quieting the exhaust of a rock drill . The exhaust of a pneumatic rock drill is the source of the major part of the noise generated by the drill . The exhaust noise can be reduced in a number of different ways , but this study involved only reactive mufflers . The reactive muffler can be simulated by an electrical circuit . Information obtained from analogous electrical circuits was used to design an efficient exhaust muffler for pneumatic rock drills . Electrical analogies proved to be a valuable tool in the design of mufflers .

Jan 1, 1964

By B. W. Naugle

The Bureau of Mines investigated the changes that occur in decomposition products when coal is carbonized in a fluidized bed with steam as the fluidizing medium and the vapors are subsequently cracked without condensation in a fluidized bed of high-temperature coke. The coal used was from the High Splint bed, High Splint mine, Harlan County, Ky. Since this coal is agglomerating, it was blended with char. The integrated unit used in this investigation consisted of a 3-inch-diameter fluidized coal carbonizer, a 3.5-inch-diameter cracker containing a bed of high-temperature coke fluidized by the tar vapors and steam from the carbonizer, and gas-cleaning and product-recovery systems. The carbonizer was operated at 485° C and the cracker at 600°, 700°, and 800° C. The process variables investigated were temperature, residence time, and concentration (pound of tar vapors per pound of steam to the cracker) of tar vapors in the cracker. The total tar yields decreased as the temperature of the cracker increased, and at a constant cracker temperature of 600° C the yield of paraffins, acids, aromatics, and olefins in the distillate increased directly with the tar vapor concentration in the cracker. At 700° and 800° C only the acids and aromatics increased with increased concentration. Bases remained essentially constant regardless of the temperature and concentration. Similar results were obtained when the tar from the carbonizer was condensed prior to feeding to the cracker.

Jan 1, 1965

By P. T. Brooks

This Bureau of Mines study describes a process for recovering nickel, cobalt, molybdenum, and chromium contained in complex waste superalloy grindings that, for lack of an economical domestic recovery process, are being largely marketed abroad. The process, devised by laboratory scale operations, includes scrap preparation, dissolution of metallics in hot chlorinated acidic liquor, carbon adsorption, three successive solvent extraction separations, and selective chemical precipitations. Nearly 90 percent of the nickel, cobalt, molybdenum, and chromium were separated and recovered as oxides, carbonates, and basic sulfate products.

Jan 1, 1969

By Donald E. Redmon

This Bureau of Mines report reviews injury experience in the nonmetallic mineral industries (except stone and coal) for 1968-69. For each of the years, 23 tables summarize disabling work injuries by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By J. S. Dunning

The objective of this research by the U.S. Bureau of Mines was to determine the effects of AI additions on the sulfidation resistance of Fe-Cr-Ni alloys. A series of Fe-Cr-Ni alloys with and without -additions of 4 pet AI were tested in a wet S vapor atmosphere at 677 C. A study of the morphology and composition of corrosion scales indicated a different corrosion mechanism for AI-free alloys compared with AI-containing alloys. Aluminum-containing alloys formed a compact, tightly adherent layer at the metal-scale interface that reduced corrosion rates by a factor of 3 to 10 compared with that of AI-free alloys. The thin, adherent AI-containing scale limited inward diffusion of 0 and S to the base metal and outward diffusion of Ni from the base metal. Aluminum-containing alloys formed a three-layer scale in oxidizing-S environments, while AI-free alloys formed a less protective two-layer scale.

Jan 1, 1989