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By Irving Wender

The oxo reaction consists of catalytic conversion of olefins by reacting the olefins with CO and H2 (water gas) to aldehydes that contain one more carbon atom than the starting olefin. The aldehydes are then generally reduced with hydrogen to primary alcohols in a second stage. The two-stage process is called the oxo process. The word "oxo" is derived from the German "oxierung" (ketonization); thus the exact English equivalent of "oxo" is "keto". The oxo process may be applied to nearly all olefins. A wide range of pressures and temperatures may be used in both stages. The pressure range usually employed is 150 to 200 atmosheres. The temperature in the first stage is usually about 140° C. and in the second or hydrogenation stage about 180° C. Although a standard Fischer-Tropsch catalyst may be used for both steps, cheaper catalysts have been utilized to effect hydrogenation of the aldehydes. Most of the information for this, report on the oxo process was gathered from Technical Oil Mission microfilms. T.O.M. Reels 14, 55, and 134 were especially valuable. T.O.M. Report 6 by H. M. Weir was very helpful. Information on the oxo process is scattered throughout documents captured in enemy territory, and the present report does not include all the available data. Some of the information was procured by personal interview. Where, in the body of this report, certain investigators are quoted, the source of the statement is either personal interview or the T.O.M. reports.

Jan 1, 1948

By W. W. Agey

Under terms of cooperative agreements, the Federal Bureau of Mines Inter-mountain Experiment Station assisted the General Services Administration (GSA) in operating the manganese-ore purchasing depots at Deming. N. Mex., and Wenden, Ariz. A resident metallurgist stationed at the depots directed sampling of the ore lots for assaying, took samples for amenability testing, calculated acceptances for payments to shippers, and served as technical adviser to the depot manager. The Intermountain Experiment Station at Salt Lake City, Utah, tested the amenability of the ores to determine how much of the manganese could be recovered in concentrates assaying a minimum of 40 percent manganese (Mn) and containing a maximum of 16 percent iron (Fe), 15 percent silica (Si02) plus alumina (AI203), 0.3 percent phosphorus (P), and I percent copper (Cu) plus lead (Pb) plus zinc (Zn). All chemical analyses of the ores and test products were done at Salt Lake City. In all, 567 ore lots submitted to the Deming depot were tested by flotation to determine their amenability to concentration into specification-grade material; 421 lots were amenable, and 146 were unamenable, primarily because of high copper content or excessive silica or iron in the flotation concentrate. Chemical analyses totaling 42,700 were made on the ores submitted to the Deming depot and on the products of the amenability-test program.

Jan 1, 1959

By R. M. Jimeson

Pressure-drop measurements through beds of granular iron, lathe turnings, steel wool, and parallel-plate assemblies were made at linear velocity and gas-density ranges expected in the Fischer-Tropsch hot gas recycle process.4/ Equations relating pressure drop, linear velocity, gas density, and bed porosity were derived. The results indicate that the exothermic heat of reaction can be removed at a lower cost by using catalyst beds with high porosity. INTRODUCTION The Fischer-Tropsch hot-gas-recycle process requires a catalyst offering low resistance to gas flow as one condition to economic feasibility. Conventional granular or spherical catalysts used during early development of the process in Germany did not meet this requirement. Large pressure drops across these beds made the cost of recirculating the gas excessive. The Federal Bureau of Mines is investigating the process by using novel and unusual catalysts that offer little resistance to gas flow. Pressure-drop measurements across these types of catalyst beds are discussed in this report.

Jan 1, 1959

By Jack O. Jones

The Furnish mine, Caharrus County, W. C., was operated intermittently until 1905 as a gold mine. Scheelite was discovered by A. L. Mash in the mine dumps of the Furniss and Phoenix mines, and he later informed the Bureau of Mines of his discovery. The Bureau of Mines, in two projects at the deposit in 1948 and in drilled 12 holes totaling 1,706.6 feet, examined and sampled the underground workings, excavated by bulldozer and hand, 3,155 linear feet of trenches and collected numerous samples for assay. The best scheelite shown; was found in the underground exposure of the Furniss mine.

Jan 1, 1950

By CLARENCE G. SMITH

Prior to the actual development of an oil property it is difficult to determine the quantity of oil under the property and the rate at which this oil can be brought to the surface-factors that determine the ultimate value of the property. Consequently, there has been much confusion in devising accounting systems that, during the entire life of a property, will show costs and profits from which the producer can determine whether his property is being worked at a profit or otherwise. The Bureau of Mines publishes this report in recognition of a distinct need for a simple treatise on accounting methods adapted to the peculiarities of the petroleum industry. Probably many companies operating oil wells are not fully acquainted with details important to the welfare of their business, because their account books fail to furnish them with exact and adequate data. With the accountant rests the responsibility of providing the management with reports setting forth the details of the business expressed in fitting terms as well as in dollars and cents. These reports are a means whereby efficiency may be maintained, waste prevented, oil obtained and sold, and money suitably reinvested. They also enable a concern to study the progress of its business in order to conserve to the utmost the possible benefits from an exhaustible deposit of mineral wealth. When managements realize the extent of the waste at their properties more attention will be given to the character of the accountancy records. Herein are presented descriptions and discussions of balance sheets, profit-and-loss statements, and bookkeeping methods peculiarly adapted to the oil business. As far as possible, technical phrases have been omitted in order that those not familiar with accounting terms may be able to follow the subject matter. The systems of keeping books outlined in Chapter X have all been found practical. For brevity as well as clearness the major part of the work refers to the company operating only one property.

Jan 1, 1917

By D. R. Mathews

Electrorefined vanadium was evaluated with respect to tensile properties and the effects of interstitial contaminants in the temperature range of 77° to 273° K. The yield strength of 18,500 psi and hardness of 63 diamond pyra-mid hardness (DPH) of electrorefined vanadium are approximately equal to that of iodide crystal bar vanadium. The ductile-brittle transition temperature was found to be below 77° K, but with 0.175 weight-percent oxygen or 0.10 weight-percent nitrogen, it increased to between 123° and 190° K. With carbon content up to 0.11 weight-percent, the transition temperature remained below 77° K. The yield strength of the interstitial-containing alloys can be expressed by: au = 7.5 + 480 (pct N) + 290 (pct 0) + 280 (pct C), where au is the upper yield stress in 1,000 psi at 273° K. Profuse deformation twinning occurred in the alloys tested at 77° K. However, twinning could be suppressed by dissolved oxygen or nitrogen in excess of 0.15 and 0.086 weight-percent, respectively. Carbon, even though present in excess of the solubility limit, did not affect twinning.

Jan 1, 1965

By Earl C. Redman

The Juneau Gold Belt, centered on Juneau and approximately 120 miles long by 10 miles wide, stretches from Berners Bay on the north to Windham Bay on the south (fig. D-l). Access within the Juneau Gold Belt is provided by the Glacier, Thane, and North Douglas Highways. The Glacier Highway extends northwest from Juneau for approximately 40 miles to Echo Cove, and the other two roads end 5.5 miles southeast and 12.6 miles west from Juneau, respectively. None of these roads connect with other highway systems and access to other areas is restricted to airplanes, the State ferry system, and commercial barge lines. BUREAU ACTIVITIES The majority of lode gold produced in Alaska came from the Juneau Gold Belt portion of the Juneau Mining District. To evaluate the economic potential of the Gold Belt, the Bureau located 173 mines and prospects within the area. A total of 263 ad its and shafts were found and 56,650 feet of underground workings were mapped. The Bureau collected and analyzed 1,557 samples during the study. In addition, considerable detailed geologic map-ping was done in the vicinity of the mines and prospects from which ore control models were developed.

Jan 1, 2012

By John A. Richards

This paper is one of a series being published by the Bureau of Mines on mining methods and costs. It describes briefly the manner in which slusher hoists and scrapers are used in connection with clock-caving methods at the Emma Nevada mine of the Consolidated Coppermines Corporation, Kimberly, Nev. Kimberly is in the Robinson mining district, White Pine County, 7 miles west of Ely. The district is served by the Nevada Northern -Railroad, which branches from the main line of the Southern Pacific at Wells, Nev., 140 miles north, Paved U. S. Highway 50 from Salt Lake City, Utah, to Reno, Nev., passes through Ely. The altitude at the collar of the Emma Nevada shaft is 7117 feet. The surrounding hills are covered with a sparse growth of juniper, pinon, and mountain mahogany.

Jan 1, 1940

By D. A. Reynolds

THIS REPORT gives results of an investigation of the carbonizing properties of two Tennessee coals, one from the Jellico bed in Campbell County and the other from the Sewanee bed in Marion County. Jellico coal and blends with 20 and 30 percent Pocahontas No. 3 coal were carbonized at 800° and 900° C. by the BM-AGA method. Sewanee coal was carbonized by the same method at 800°, 900°, and 1,000° C.; blends with coals of similar and different ranks were carbonized at 800° and 900° C. The coals were subjected to various physical and chemical tests, including complete chemical analyses, low-temperature assays, and agglutinating, free-swelling, friability, plasticity, and expansion tests. The Tennessee coal field is a part of the Appalachian field, which extends from northern Pennsylvania to central Alabama. The Jelico bed, one of the most important in the State, is part of the Jellico formation, which is above the Lee formation of the Lower Pottsville. Sewanee coal bed belongs to the Sewanee conglomerate and is stratigraphically lower than the Jellico bed.

Jan 1, 1953

By F. A. Rutledge

The Bureau of Mines Investigated the Copper Bullion claims at Rua Cove on the east coast of knight Island in Prince William Sound, Alaska, during November-December 1948 and March-April 1949. This project was part of the Bureau of Mines program for developing critical and strategic minerals in Alaska, Mineralization at the copper deposit on the Copper Bullion group of claims is mainly pyrrhotate and chalcopyrite, confined to a northeast-trending shear zone in the greenstone 2,000 feet northwest of Rua Cove. The property has been partly developed by two adits, by a number of crosscuts from the upper adit, and by several diamond-drill holes.

Jan 1, 1953

By T. W. Quayle

This paper describing mining practices at the United Verde copper mine, Jerome, Ariz., is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts f the United States. At present mining operations are being conducted both underground and by electric shovels in an open pit. The open-pit work has been described by E. M. J. Alenius in a previous publication of the Bureau of Minos;3 the present paper will be confined to a description of the underground mine. The underground methods comprise horizontal cut-and-fill, shrinkage with delayed filling, horizontal square-set, inclined square-set, and top slice. The normal daily production of the underground mine is 3,000 tons of copper ore per day, requiring the employment of 900 men underground.

Jan 1, 1931

By L. B. Pankratz

Thermodynamic data on the halides were reviewed, evaluated, and compiled at the Bureau of Mines Albany Research Center. Values for Cp°, S°, H-H°298, -(G°-H°298)/T, ?Hf°, ?Gf°, and log Kf are given in tabular form. CP°, H-H°298, ?Hf°, and AGf° are also expressed algebraically.

Jan 1, 1984

By Curtis A. Jones

Continuing interest has been shown in developing processes for extracting nickel and cobalt from low-grade domestic deposits of these metals and in improving existing methods. Of special concern is the nickel-recovery installation at Nicaro, Oriente Province, Cuba, operated for the General Services Administration. The Bureau? of Mines felt that a bibliography would help familiarize personnel at various Bureau of Mines stations and General Services Administration contractors with extraction methods both in the United States and in foreign countries. When this task was under way it became apparent that to compile a complete bibliography would require considerable time, so it was decided to limit the first part to the later literature and issue it independently, thus making it available sooner. The present work supplements the first part and extends the coverage to the earliest years of nickel and cobalt metallurgy.

Jan 1, 1959

By Ferdinand Roehlich

An evaluation of the use of manually activated, installed,. dry chemical fire protection systems on underground metal and nonmetal mine vehicles is described. In addition, an assessment of the possible health risks posed by the dry chemical extinguishing agents used in such systems is provided. Work involved installation of fire protection hardware on an operating piece of underground metal/nonmetal mine equipment and, via actual fire tests, a determination of the effectiveness of the hardware in extinguishing on-vehicle fires. Two fire protection systems were installed on a Caterpillar 988 front-end loader in St. Joe Mineral's Fletcher mine, near Viburnum, Mo. Both a fully pressurized Safety First CM-20 and a nonpressurized cartridge actuated Ansul A-101 were installed for comparative purposes. Both systems operated satisfactorily during an 8-month endurance trial period which preceded the actual fire tests. Each system was able to extinguish an 18" x 4" class B test fire placed in the engine area of the machine. The health hazards analysis of dry chemical powder consisted of a detailed search of published literature relating to these multipurpose agents. This data was verified via a controlled laboratory analysis of two monoammonium phosphate based powders (Safety First Unikem and Ansul Forey) and an analysis of air samples collected at various locations on the test vehicle during the fire tests. Although the powder was found to be nontoxic, two potentially dangerous thermal decomposition products were identified--ammonia and phosphoric acid. However, later analysis indicated that an operator would not be exposed to dangerous concentrations of either compound if he were to remain outside of the powder cloud. A "Selection and Use Manual for Manually Activated, Fixed Fire Suppression Systems on Underground Metal and Nonmetal Mining Equipment" was prepared both as an, appendix to the report and for distribution under separate cover.

Jan 1, 1977

By D. N. Tallman

The Bureau of Mines has completed 4 yr of deep-bed filtration research comparing the efficiencies of granular magnesium oxide (MgO) and conventional filter sand in single- and dual-medium filters when filtering mineral-processing and mine waters. Bench and field evaluation tests were conducted using water types ranging from synthetic suspensions of asbestos, kaolin, metal hydroxides, and milled sand to process waters from magnetite beneficiation, iron ore flotation, granite cutting, and a steel mill. Even though the turbidity reductions were similiar, MgO filters were found to be advantageous when filtering water pretreated with alum because the volume throughput before breakthrough (turbidity > 1 NTU unit) was much more for the MgO filter than for the sand filter. Reduced head loss owing to the greater porosity of the MgO filter beds is potentially the most beneficial advantage in employing MgO as the filter medium, especially when filtering water pretreated with polymer flocculants. Granular MgO (periclase) is durable and can be backwashed Like sand. It is compatible with anthracite in a dual-medium filter and apparently is not poisoned by dissolved metals in the process water. No single solid-removal mechanism could be identified for the improved filtration observed with granular MgO.

Jan 1, 1987

The Minerals Data Source Directory is a compilation of descriptive information on the availability, content, and location of minerals data in the Federal Government. It is intended to assist Government personnel and the general public in locating and acquiring minerals information. Included in the Directory are descriptions of data bases, publications, information systems, and information offices containing data pertaining to ail aspects of mineral production, consumption, trade, and related information. These mineral data sources include the Federal agencies such as the Department of the Interior's Bureau of Mines and Geological Survey whose major mission is the collection and dissemination of mineral information. Also included are agencies such as the Departments of Agriculture, Commerce, Labor, State, Transportation, and Treasury, the Central Intelligence Agency, the Environ- mental Protection Agency, the Federal Reserve System, the interstate Commerce Commission, and the Securities and Exchange Commission, whose primary mission is the collection of data in nonmineral subject areas, but in which the mineral industry is a component.

Jan 1, 1983

By George E. Fish

This report describes investigations conducted by the Bureau of Mines from 1957 through 1959 in the Roseland anorthosite-titanium belt of Nelson and Amherst Counties, Va., for the purpose of studying the titanium resources of the area. Three titanium deposits containing much saprolite ore derived from the decomposition of anorthosite and diorite were selected for detailed study Following a reconnaissance of the reported titanium occurrences in the belt. These three deposits occur in or are associated with anorthosite. Most of the occurrences are situated on or near the contact between the anorthosite and the gneissic country rock. The saprolite deposits are as much as 1.5 miles long, 1,000 feet wide, and 100 teat deep and contain significant reserves of titanium-bearing material estimated in excess of 20 million tons. Where it was penetrated by drilling, the unweathered rock beneath the saprolite contains nearly the same titanium values as the saprolite.

Jan 1, 1962

By J. Bruce Clemmer

[Gypsum is one of the most important nonmetallic c minerals, as is indicated by the fact that the United States consumed approximately 3,500,000 tons of natural and calcined gypsum in 1937. The building trades were the largest users required 2,520,000 tons of calcine for production of plaster, wall board, tiles, block, and various other insulating and building materials. The glass and ceramic industries and other manufacturers required an additional 126,000 tons. The balance was used in the uncalcined condition as retarder in Portland cement and or agricultural purposes.]

Jan 1, 1941

By C. H. McNaughton

The Tennessee Copper Co. operated two mines in the Ducktown district during 1928. The Burra Burra mine is much the larger operation and is the chief source of the ore smelted and treated in the, company's smelter and acid plant rat Copperhill, 4.5 miles from Ducktown. This mine operates steadily and furnishes a regular output of about 40,000 tons per month. The Eureka mine is operated irregularly and produces a much smaller tonnage of high-sulphur ore the rate of output depending upon the demand for sulphur. During 1928 about 60 per cent of the combined output of these mines was shipped directly to the smelter, and the balance was concentrated before shipment in the flotation plant located near the mines. ACKNOWLEDGMENTS The author acknowledges the assistance of Lamar Weaver, Assistant mine superintendent of the Tennessee Copper Co, and of C. F. Jackson, mining engineer, U. S. Bureau of Mines, in the, preparation of this paper, U. S. Geological Survey Professional-Paper 139, by W. H. Emmons and F. B. Laney, has been drawn upon for information contained 'in the paragraphs on history and geology.

Jan 1, 1929

By Staff

This U.S. Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles.

Jan 1, 1989