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By C. A. Pickles

Mixtures of silver chloride and copper chloride are produced during gold refining by the Miller process. A study was carried out into the reduction with iron of a synthetic Miller chloride containing 13.64 mass% Ag and 2.42 mass% Cu. The effects of smelting temperature and time and of additions of iron and borax were investigated. The results were interpreted in terms of metal recovery and quality. Temperature did not have a significant effect on metal recovery above the melting point of the metal product. Borax additions reduced vapour losses and improved metal recovery. With excess iron it was possible to achieve silver recoveries of about 100% and copper recoveries of about 70%. The metal product contained on average 76.1 mass% Ag, 7.5 mass% Cu and 12.8 mass% Fe.

Jan 4, 1993

By A. Hemami

In order to automate the operation of mechanical loaders it is essential to have a knowledge of the forces that act on the bucket and of the trajectory that the bucket should follow. A trajectory for the cutting edge of a bucket is derived from studies of the forces acting during the scooping phase. The proposed trajectory has a minimum energy consumption and is simple to automate. It is determined initially by setting to zero certain components of the resistive forces to the bucket motion which would otherwise result in unnecessary work and consequent energy wastage. The method for finding the appropriate trajectory is discussed on the basis of the properties of the material to be loaded and the loader size.

Jan 4, 1993

By M. D. Gibbs, T. N. Smith, B. Verbaan

When heated in the absence of oxygen, pyrite from refractory gold concentrates decomposes endothermically to pyrrhotite, releasing sulphur. The decomposition starts at the particle surface and progresses inwards, leaving an adhering layer of porous pyrrhotite. Use of the conventional shrinking-core model implicitly assumes a negligible partial pressure of sulphur in the bed, but this pressure is in fact at least equal to the equilibrium vapour pressure of sulphur over pyrite, constituting the principal control of the rate of decomposition. Further experiments showed a decrease in reaction rate as the conversion increased. Both phenomena are attributed to the persistence of non-isothermal conditions in the fluidised bed during pyrolysis, caused by the endothermic nature of the reaction and the relatively slow rates of heat transfer to particles and vapour removal from the bed. Equipment must be developed to maximise these two parameters

Jun 19, 1905

By M. Dobias, N. Mayor, J. Lillo, A. Gonzalez, R. Lunar, R. Oyarzun

The central domain of the Spanish Central System contains a series of Ba-(F)-(base metal sulphide) hydrothermal vein deposits that are hosted by adamellitic granitoids. Fluid inclusion and sulphur isotope data suggest that the mineralisation was formed by low-salinity hydrothermal solutions that incorporated fluids, metals and sulphur from a magmatic source. Mineralisation occurred in two main stages; a first stage of open-space filling with quartz-Ba-(F)-(base metals) ; and a second stage of brecciation and deposition of quartz-barite. The two mineralising events can be clearly related to two tectonic episodes of late Variscan age that involved extension along east-west trends followed by ductile transcurrent movements along northeast-southwest trends.

Jan 4, 1992

By T. T. Chen, J. E. Dutrizac, C. Canoo

The calcine consists principally of ZnO and ZnFe2O4, which occur as banded and porous grains, together with lesser amounts of Zn2SiO4, Zn-Fe-Pb silicate, sphalerite, quartz, PbSO4 and Fe2O3. Al is present in solid solution in most of the Fe-bearing phases and also as residual aluminosilicate minerals from the original concentrate. Si occurs mostly as Zn2SiO4, Zn-Fe-Pb silicate and as residual silicate minerals. As is commonly found in the ZnFe2O4, Fe2O3 and Zn-Fe-Pb silicate phases. The major As carrier may be calcium arsenate particles less than 1 micrometre in size which are dispersed throughout the calcine. The neutral leach residue consists mainly of ZnFe2O4 and precipitated masses of iron gel-silica gel. Lesser amounts of ZnO, Zn2SiO4, Zn-Fe-Pb silicate, PbSO4, sphalerite, Pb-K-jarosite and basic zinc sulphate are also present. Al occurs in minor concentrations in most of the Fe-bearing phases and in the Zn-Fe-Pb silicate. The residual aluminosilicates are also an important Al carrier. The major As carrier is the precipitated iron gel-silica gel phase, but some As is also present in the Zn-Fe-Pb silicate, ZnFe2O4 and Fe2O3 phases. Silicon is divided about equally between the iron gel-silica gel, Zn2SiO4, Zn-Fe-Pb silicate and residual silicate minerals. The weak acid leach residue is generally similar to the neutral leach residue except for its reduced content of ZnO and basic zinc sulphate.

Jan 4, 1993

By P. R. Ineson, D. W. James

For a criterion to be useful it must either demonstrate directly the role of exhalative processes in the formation of a deposit or describe a unique attribute of exhalative deposits. Few of those employed in previous investigations entirely satisfy either condition. The limitations of three of the most frequently employed criteria are illustrated by studies of the geology of the King Island Scheelite deposit in Tasmania.

Jan 12, 1993

By R. Phillips

The low concentration of diamond in workable deposits requires very large samples for grade estimation, and results, even then, may be erratic and difficult to interpret. Although the Poisson probability distribution cannot accurately describe the occurrence of diamond, it is suggested that it gives a better estimate of grade than conventional methods, even from single samples. Examples illustrate the simple calculation required.

Dec 1, 1971

By NA NA

In the third of its features on the new owners of the British coal mining industry, Mining Technology reports on the newest company in the field, Midlands Mining.

Jan 2, 1997

By Zhengya Lu, F. Lawson

The surface tensions of lead and lead alloys with very low concentrations of silver, tin and copper were measured by the sessile-drop method. The enrichment of silver and tin in the surface of liquid lead alloys at temperatures close to the freezing-point of lead was confirmed, which may explain the unusual behaviour of small amounts of silver and tin in lead bulllion during the sulphur-drossing step of the refining process. From the limited data available copper also appears to concentrate at the surface of the liquid alloy

Dec 1, 1991

By ed. comp., S. H. White, A. J. Naldrett, P. R. Simpson

Peter Simpson's introduction, Tony Naldrett's concluding remarks and discussion by Prof. White of D.M.A. Flight's report of the proceedings are presented from the conference held in Keyworth, UK, in April 1992

Apr 1, 1995

By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By P A. Collier

The general view of the author is that all the good intentions of manufacturers can fail completely if the variations in circumstances in underground mining are not considered at all times. With a belief that it is the customer that has the experience and know ledge of problems which occur on long installations. Reilloc talk with customers in coal mines around the world, and have done so from their inception. With considerable experience in their home market, their technical approach was received with enthusiasm by coal companies in both Australia and South Africa, and whilst experience was obtained in other countries, it is the particularly close working relationship in these two areas that is covered in this paper. The refinement of manufacturing techniques and the fine tuning of the specification to which the chain is made was developed in conjunction with factual underground experience obtained by customers as they sought to improve their productivity and a reduction in working costs. With a reliable product the mines are able to concentrate on improved operational techniques to extend the useful working life and plan for multi-panel usage of the chain.

Jan 5, 1996

By O. Dojcar

Equations for calculating the parameters of controlled blasting (burden and spacing of boreholes and weight of the bottom charge) are derived and analysed on the basis of empirical values and made more precise through incorporation of the properties of the rock being blasted and explosive applied. For the success of controlled blasting the correct choice of the blasthole diameter/charge diameter ratio is critical. This relation is defined as the coefficient of radial decoupling of the charge; it is recommended that it is chosen to be between 3 and 3.5. Analysis of smooth blasting, cushion blasting and presplitting indicates that cushion blasting is a less destructive alternative to smooth blasting, but it has a slightly higher blasthole consumption and limited possibilities of use. There are definite economic advantages to controlled blasting, especially in rock masses of low and medium strength

Dec 1, 1996

By J. Drzymala, K. L. Wolters, T. Chmielewski, T. D. Wheelock, D. H. Birlingmair

Microflotation tests were conducted with a modified Hallimond tube equipped with a fritted glass disk and magnetic stirrer to determine whether the results would support an equation that predicts a linear relationship between particle size and the reciprocal of particle density in water for a specified flotation recovery in a given time. Data obtained with the tube for either hydrophilic or hydrophobic solids fit the equation satisfactorily. It was also shown that the natural flotability of molybdenite is somewhat less than that of elemental sulphur and that sodium dithionite is a good depressant for sulphurised pyrite. In addition, it was found that the untreated pyrite and galena used in the study were hydrophilic and did not float by particle-bubble attachment.

Jan 4, 1992

By S. G. Tsimas, A. K. Moutsatsou, S. G. Tsivilis, G. K. Parissakis

(NH4)2SO4 can be used with success as a leachant to remove gypsum contained in celestite ores. The process, which is applied before flotation, provides an upgraded feed and problems related to the simultaneous flotation of CaCO3 and SrSO4 are reduced. The process is independent of the gypsum content of the feed so that each leaching stage decreases the gypsum content by almost 50%. The use of (NH4)2SO4 has an insignificant effect on the co-leaching of SrSO4 (0.45 wt.%) at each stage

Jun 13, 1905

By C. P. Summerhayes, J. W. G. Gilbey, S. Henley, G. P. Glasby, J. J. T. Harvey, J. Larsson, O. Akiman, A. G. Brown

Abstracts are presented from six University of London, one University of Nottingham and one University of Durham PhD theses

Dec 1, 1971

By C R. Ferrari

Residual subsidence is generally accepted as being about 5% of the total subsidence occurring within 12 months of all mining finishing. This paper looks at five case studies from different parts of the country, in various mining settings within a depth range of 430m to 760m. From a single seam single panel working to working the eleventh seam, all are within the concealed coalfield, similar to today's mining. The monitoring of subsidence continued for many years once the mining had finished and the results obtained are at considerable variance from the accepted norm. Subsidence has been found to carry on for up to eleven years after mining has ended, within a range of 8% to 45% of total subsidence. A highly significant factor was that subsidence, as a whole, was generally much more than predicted. The residual subsidence aspect has to he viewed in this context and in order to debate the subject at length, the causes of residual subsidence have to be balanced against the apparent inability to accurately predict subsidence. The results from the case studies were similar, even though the mining settings differed considerably. Subsidence of around 10% to 20% continued for several years after mining had ceased.

Jan 7, 1997

By L Casari

A study of samples from three sectors of the mine, which was worked from Roman times to 1991, revealed different textures, mineral associations and distributions of trace elements in the sulphides. In the last decade before closure, grades of sphalerite concentrate were in the range 51.67-53.30% Zn and 2.21-2.86% Pb and of galena concentrate 69.43-71.62% Pb and 4.70-8.36% Zn, while the estimated by-product germanium content of sphalerite concentrates sold was 300-400 g/t. Passing the different run-of-mine materials through the same concentrator flowsheet produced middlings and tailings during the preconcentration processing. Separate and alternative treatment of run-of-mine products would have yielded improved recoveries of sphalerite and galena and better values of by-product germanium and cadmium

Jun 18, 1905

By L. T. Matthews, C. E. Loo

During sintering, porous ore particles are easily assimilated by liquid melt. Two simple models of the process are considered: the dissolution of a solid by a liquid and the penetration of a liquid into a porous solid. Laboratory sintering studies covering a range of experimental conditions were undertaken to characterise the assimilation of large particles of ore and flux by melts formed from different mixes of fines. For ores, the process appeared to be complicated by the detachment of fines from the ore surface prior to melt formation, according to the mass of adhering fines and surface roughness of the particle. This delayed the onset of assimilation and sometimes reduced it, although melt penetration was fast and effective. Studies using different temperature profiles suggested that the assimilation of haematite was controlled by the transport of Fe2O3 away from the surface of ore particles. The assimilation of limestone depended more on thermal conditions than on the three magnesia-bearing minerals considered. Changing the composition of the initial melt significantly altered the extent of assimilation of ores and limestone, but again had a less marked effect on the magnesia-bearing fluxes.

Jan 8, 1992

The following procedure was used to determine cut-off grades: define the orebody profile; plan the stope layout and quantify the work involved; formulate equipment-performance norms; calculate unit costs; input process recoveries and metal prices; and calculate the cut-off grade. Use of the method is illustrated using data from a copper mining complex in India. Results from the study led to the following conclusions for underground mines in general. Cut-off dependent costs vary significantly with the stoping method employed, orebody thickness, the degree of mechanisation and the working efficiencies of the workforce and equipment. This applies even within the same deposit. Sub-level stoping and its variants can be operated at a lower cut-off grade than cut-and-fill and its variants. Thinner orebodies affect cut-off grades adversely, but with thinner orebodies very little further reduction in cut-off grade can be achieved once a certain minimum width has been exceeded. For the same stoping method and in the same mine the cut-off grade varies with the degree of mechanisation. Labour-intensive methods require higher cut-off grades. An allowance for working efficiency should be made when calculating cut-off grades. Higher process recoveries allow a significant lowering of cut-off grades

Jul 1, 1996